• Resources Recycling
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• v.31 no.2
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• pp.40-48
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• 2022

In this study, the effects of solution components were investigated in the recovery of vanadium as ammonium metavanadate from vanadium-ore-salt roasting-water leaching solution. The vanadium-containing solution is strongly alkaline (pH 13), so the pH must be lowered to 9 or less to increase the ammonium metavanadate precipitation efficiency. However, in the process of adjusting the solution pH using sulfuric acid, aluminum ions are co-precipitated, which must be removed first. In this study, aluminum was precipitated in the form of an aluminum-silicate compound using sodium silicate, and the conditions for minimizing vanadium loss in this process were investigated. After aluminum removal, the silicate was precipitated and removed by adjusting the solution pH to 9 or less using sulfuric acid. In this process, the concentration and addition rate of sulfuric acid have a significant influence on the loss of vanadium, and vanadium loss was minimized as much as possible by slowly adding dilute sulfuric acid. Ammonium metavanadate was precipitated using three equivalents of ammonium chloride at room temperature from the aluminum-free, aqueous solution of vanadium following the pH adjustment process. The recovery yield of vanadium in the form of ammonium metavanadate exceeded 81%. After washing the product, vanadium pentoxide with 98.6% purity was obtained following heat treatment at 550 ℃ for 2 hours.

• Journal of the Korean Electrochemical Society
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• v.17 no.1
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• pp.37-43
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• 2014

In this study, capacitive deionization (CDI) was introduced for desalination of mining water. Ion-exchange polymer coated carbon electrodes (IEE) were used in CDI to desalt mining water. The CDI performance using the IEE for desalination of mining water was carried out and then was compared with that using general carbon electrodes without ion-exchange polymer coating (GE). Moreover, to investigate the effect of the concentration of influent solutions on CDI performance, the CDI performance using the IEE for desalination of brackish water (NaCl 200 ppm) was also performed and analyzed. As a result, the higher salt removal efficiency, rate and the lower energy consumption in the CDI process using the IEE and mining water were obtained compared with those using the GE and mining water. It is mainly due to higher non-Faradaic current, low ohmic resistance of the influent, overlapping effect of electric double layers in micropore of the electrode. In addition, the CDI process using the IEE and brackish water shows much higher salt removal efficiency and lower salt removal rate than that using the IEE and mining water. This results from the lower concentration (i.e., higher ohmic resistance) and salt amount of the influent.

• Membrane Journal
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• v.24 no.1
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• pp.69-77
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• 2014

To prepare the hollow fiber nanofiltration composite membranes, the poly(vinylidene fluoride) (PVDF) membrane was hydrophilized with $K_2Cr_2OH$ and $KMnO_4$ aqueous solutions. And then the composite membrane was synthesized on that membrane surfaces using interfacial polymerization with piperazine (PIP) and trimesoyl chloride (TMC). The resulting membranes were characterized in terms of the rejection and flux for NaCl, $CaSO_4$, $MgCl_2$ 100 ppm solution and 300 ppm of NaCl and $CaSO_4$ mixed solution by varying the coating time, drying time, and the concentration of the coating materials. As a result, the higher rejections were shown for $K_2Cr_2OH$ solutionas a hydrophilization material, and the flux was enhanced while the rejection reduced as the hydrophilization time is longer. Also, the rejection increased and the flux reduced as the concentrations of triethyl amine (TEA) and sodium lauryl sulfate (SLS) were higher. Typically, the rejection 50% and flux 40 LMH for NaCl 100 ppm solution, and the rejection 55% and flux 48 LMH for $CaSO_4$ 100 ppm solution were obtained for the PVDF hollow fiber composite membrane prepared with the conditions of PIP 2 wt% (Triethyl amine (TEA) 7 wt%, SLS 20 wt% mixed solution against PIP concentration) and TMC 0.1 wt%.

• Journal of The Korean Ophthalmological Society
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• v.60 no.5
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• pp.480-485
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• 2019

Purpose: We report a case of postoperative endophthalmitis in the cataract patient, associated with removal of an intralenticular foreign body that had remained in place without symptoms for 20 years. Case summary: A 45-year-old male visited our outpatient clinic complaining of gradual visual loss in his right eye over the past 3 months. In slit-lamp examinations, anterior capsular opacification, nuclear sclerosis, and posterior subcapsular opacity were observed in the right eye. Twenty years before, a tiny metallic projectile had hit his right eye, but slit-lamp examination at the time of injury did not reveal any intraocular foreign body. We decided to undergo cataract surgery. During phacoemulsification, a metallic foreign body was found in the lens and safely removed; then an intraocular lens was implanted. As hypopyon was evident 3 days later, we injected intravitreal antibiotics and applied fortified antibiotic eye drops to the right eye. The anterior chamber inflammation improved and the best-corrected visual acuity recovered to 1.0. Conclusions: Surgeon should be aware of that endophthalmitis could develop after cataract surgery with removal of an intralenticular foreign body that had been in place for 20 years. But did not trigger inflammation or cause any symptoms as the cataract progressed.

• Pediatric Gastroenterology, Hepatology & Nutrition
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• v.2 no.2
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• pp.194-203
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• 1999

Purpose: Childhood pancreatitis has more various and somewhat different etiology than adult. Until now the analysis of severity in childhood pancreatitis were not well-known, although several studies have been made. Therefore, we studied the etiology and complications in childhood pancreatitis and analyzed whether Ranson and CT criteria could be applicated to evaluate the severity of childhood pancreatitis patients. Methods: The records of 30 patients with pancreatitis under 15 years of ages who were diagnosed in Asan medical center were reviewed. Age, sex, history, etiology, clinical features and treatment was reviewed in all patients but complications, Ranson and CT criteria were available in only 12 patients. Correlation between the number of complications and both Ranson and CT criteria were calculated with Spearman correlation coefficient. Results: 1. Median age at diagnosis was 7.3 years of age. 28 cases were acute pancreatitis and 2 cases were chronic pancreatitis. 2. Etiology: choledochal cyst(8 cases), drug (7 cases), trauma (4 cases), infection (3 cases), biliary stone or bile sludge (3 cases), idiopathic (2 cases) Hemolytic uremic syndrome, pancreatic duct obstruction, iatrogenic (1 case). 3. Local complications were ascites (5 cases), pseudocyts (4 cases) and systemic complications were hyperglycemia (4 cases), hypocalcemia (3 cases), pleural effusion (3 cases), etc. 4. Positive correlation was found between the number of complication and Ranson creteria (r=0.78, P=0.0016) and between the number of complication and CT criteria (r=0.65, P=0.015) in 13 cases. Conclusion: A trial to search the biliary duct anomaly may help to find the causes of childhood idiopathic pancreatitis, and both Ranson and CT criteria can be applicated to pediatric patients to evaluate the severity of childhood pancreatitis.

• Journal of Life Science
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• v.25 no.7
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• pp.826-832
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• 2015

This study describes the effects of activated charcoal on the removal of salts, detergents, and pigments from protein extracts of ginseng leaves and roots. Incubation of protein extracts with 5% (w/v) activated charcoal (100-400 mesh) for 30 min at 4℃ almost removed the salts and detergents including NP-40 as can be observed on SDS-PAGE. In addition, analysis of chlorophyll content showed significant depletion of chlorophyll (~33%) after activated charcoal treatment, suggesting potential effect of activated charcoal on removal of pigments too along with the salts and detergents. 2-DE analysis of activated charcoal treated protein samples showed better resolution of proteins, further indicating the efficacy of activated charcoal in clearing of protein samples. In case of root proteins, although not major differences were observed on SDS-PAGE, 2-DE gels showed better resolution of spots after charcoal treatment. In addition, both Hierarchical clustering (HCL) and Principle component analysis (PCA) clearly separated acetone sample from rest of the samples. Phenol and AC-phenol samples almost overlapped each other suggesting no major differences between these samples. Overall, these results showed that activated charcoal can be used in a simple manner to remove the salts, detergents and pigments from the protein extracts of various plant tissues.

• Analytical Science and Technology
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• v.18 no.5
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• pp.436-443
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• 2005

A study of physical properties and their application using K-powdered activated carbon system followed powdered carbon dispersion was carried out at laboratory. scale. Two types of K-powdered activated carbon for the dispersion have been used in this study to investigate the catalytic removal efficiency of pollutants from the wastewater. From the surface properties obtained for carbon samples treated with aqueous solutions containing potassium salts, main investigations were subjected to isotherm shape, SEM, EDX and surface functional groups. K-powdered activated carbons were dispersed to wastewater with pH variation to investigate the removal efficiency for the color, COD, T-N and T-P. From these removal results of the piggery waste using K-powdered activated carbon, satisfactory removal performance in the region of pH 6~8 was achieved. The excellent effects for the dispersion of the K-powdered activated carbon were proved by the above mentioned properties of the material for adsorption and trapping of organics, and catalytic effects.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.1
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• pp.169-177
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• 2006

In this study, it was studied that the removal rate of VOC by the catalytic combustion. The combustion temperature was changed by the contact type of VOC(space velocity and catalyst depth) and the space velocity(SV) was defined by the rate of gas volume flow rate(Q, $m^3/hr$) over volume(V, $m^3$) of catalyst (SV=Q/V). The space velocity of catalytic combustor is maintained $10,000{\sim}50,000hr^{-1}$. it was studied that the conversion rate of VOC by the catalytic combustion. The combustion temperature was changed by the contact type of VOC and catalyst and the space velocity was defined by the rate of gas volume flow rate over volume of catalyst. The VOC which pass thru the heat exchanger was measured by the hydro ionic detector and measured the VOC removal rate by the activated catalyst in the reaction temperature range of 373K-423K. The removal rate was measured over 100 times. In the automobile painting booth The VOC concentration was 63.37ppm and the removal rate was 70 % at 373K and 78.92% at 423K. The removal rate was increased as increased the temperature.

• KSBB Journal
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• v.22 no.3
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• pp.151-156
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• 2007

Increasing public concerns over odors and air regulations necessitates the remediation of a wide range of odorous compounds for industrial purpose. Currently, wet scrubbing technique by neutralization using essential oils is utilized to treat methyl mercaptan odor. The chemical analysis is performed to analyze the composition of an essential oil by GC-MS. The objective of this study is to clarify the possibility of the neutralization of odors sprayed in the fixed bed and determine the removal efficiencies in the misty aerosol by different input odor concentration. It is found that methyl mercaptan is significantly removed in the wet scrubber, and their removal efficiency of methyl mercaptan is obtained by 98%.

• Proceedings of the Korean Society for Agricultural Machinery Conference
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• 2017.04a
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• pp.97-97
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• 2017

천일염의 생산공정은 바닷물(나트륨 농도: 2~3%)을 저수지로 유입시킨 바닷물을 농축하는 1차 증발지(난치)와 2차 증발지(누태)로 보내 일반적으로 2주 정도 증발시켜 나트륨 농도 12~15% 소금물을 만든다. 온도가 낮은 겨울철에는 결정지를 거치거나 2차 증발지의 농축시켜 창고(해주)에서 보관 하는 동안 나트륨 농도 25~27%정도로 상승되어 소금 결정을 이루고 채염하여 창고로 운송한다. 보관창고에서 천일염에서 쓴맛을 내는 간수를 제거한 뒤 선별, 건조 및 포장하는 유통하는 단계로 이뤄진다. 천일염의 생산과정 중 해주는 함수를 저장하여 고농도의 함수를 저장하여 불용분 및 이물질을 자연 침전시켜 맑은 함수를 다음 공정으로 이송시켜 천일염 품질향상에 중요한 공정 중에 하나이다. 그러나 일반적인 염전의 해주는 지붕의 복사열로 인하여 저장중인 해수의 대류로 인하여 침전물이 상승되고 이물질이 부유함으로 인하여 품질저하의 원인이 되고 있다. 또한 해주 구조 및 해주 품질에 대한 자료는 전무한 실정이다. 따라서, 본 연구의 목적은 해주의 깊이에 따른 해수의 대류 방지 깊이 및 품질 변화를 측정하여 고품질 천일염 생산공정에 적용하는데 목적이 있다. 해주분석을 위한 염전은 결정지 채염공정을 공유하는 2개지역 3개 염전을 대상으로 하였으며, 무안, 운남 및 만품지역의 3개소를 선정하여 생산방식이 비교적 동일한 염전을 선정하여 조사 및 분석하였다. 해주의 깊이는 1.0, 3.0, 3.5m인 해주의 시료를 채취하여 Calcium, Magnesium, Sulphate, Chloride 의 함량 분석은 Arena 20 XT 자동흡광분석기 (Automated photometric analyzer)을 이용하여 분석을 하였다. 각 염전에서 채취한 해수의 평균 탁도 값은 해주의 깊이가 깊을수록 탁도 값이 낮은 것으로 나타났다. 해수의 색상 "b" 값은 해주 깊이가 깊을수록 낮은 결과를 보였다. Mg 함량은 전반적으로 15,000~40,000 mg/L 범위의 값을 나타냈으며, Sulphate 함량은 약 30,000~65,000 mg/L 범위의 값을 나타났으며, 깊이가 깊을수록 Mg, Sulphate 함량이 낮아지는 결과를 보였으나 Chloride 함량은 뚜렷한 경향을 보이지 않았다. 실험 결과 해주 깊이에 따른 함수의 품질 차이가 발생하는 것을 확인 할 수 있었으며, 해주의 바닥 깊이가 깊을수록 함수의 불용분 침전, 분리에 효율적인 것으로 판단되었다.