• Title/Summary/Keyword: 염소이온 침투

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Effect of Coating System to Prevent the Deterioration of Concrete Subjected to Compressive Stress (압축응력이 인가된 콘크리트의 열화제어를 위한 표면도막공법의 효과)

  • Yoon, In-Seok
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.16 no.3
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    • pp.23-30
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    • 2012
  • For cracked concrete, it is obvious that cracks should be preferential channel for the penetration of aggressive substances such as chloride ions according to the previous researches. In order to extend the lifetime of cracked concrete, critical issues in the performance of the concrete is the risk of chloride-induced corrosion. Even though crack width can be reduced due to the high reinforcement ratio, the question is to which extend these cracks may jeopardize the durability of cracked concrete. If the size of crack is small, surface treatment system can be considered as one of the best options to extend the service life of concrete structures exposed to marine environment simply in terms of cost effectiveness versus durability performance. Thus, it should be decided to undertake an experimental study on the effect of surface coating system, which can be able to seal the concrete and the cracks to aggressive substances-induced corrosion in particular. In this study, it is excuted to examine the effect of surfaced treated systems on chloride penetration and carbonation through compressive stress induced cracks. Experimental results have showed conclusively that critical stress linked with deterioration, should be existed in compressive stress ratio 50 ~ 70% for chloride penetration and 70 ~ 80% for carbonation, respectively. When the critical stress is exceeded in concrete, a comparatively large deterioration was measured where the critical stress in concrete, the increase in the mass transportation is marginal in spite of the large increase in micro-cracks. As for the effect of surface coating system on crack-sealing, it can be seen conclusively that cracks can be healed.

An Experimental Study on the Effect of Sensor Line Number on the Reactivity Characteristic of Corrosion Sensor Reactive with Chloride Ion to Immigrate into Concrete (콘크리트내로 침투하는 염소이온 반응형 부식센서의 응답특성에 미치는 센서 세선 수의 영향에 관한 실험적 연구)

  • Lee, Hyun-Seok;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.18 no.3
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    • pp.143-152
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    • 2014
  • In this study, the sensor response and sensitivity is experimented and analyzed quantitatively by the line numbers of chlorine ion reaction type corrosion sensor that is developed. The sensor response of the developed corrosion sensor is verified with properties of chlorine ion. The multilineal sensor is shown a large resistance change more than the single line sensor by damage of the sensor. And, the resistance change of sensor is as large as high concentration of NaCl aqueous solution, the sensitivity of multilineal sensor is higher than single line sensor's, and the depth of sensor's location is as large as the increasing of resistance change time (cycle). These results suggest that, the developed corrosion sensor could sense corrosion reaction, sensor sensitivity and change of resistance for chloride ion. Especially, It was judged that 7 line sensor was the most superior for monitoring chloride ion immigration into concrete.

Long-Term Durability Estimation of Cementless Concrete Based on Alkali Activated Slag (알칼리 활성 슬래그 기반 무시멘트 콘크리트의 장기 내구성 평가)

  • Lee, Hyun-Jin;Lee, Seok-Jin;Bae, Su-Ho;Kwon, Soon-Oh;Lee, Kwang-Myong;Jung, Sang-Hwa
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.2
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    • pp.149-156
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    • 2016
  • It has been well known that concrete structures exposed to chloride and sulfate attack environments lead to significant deterioration in their durability due to chloride ion and sulfate ion attack. The purpose of this experimental research is to evaluate the long-term durability against chloride ion and sulfate attack of the alkali activated cementless concrete replacing the cement with ground granulated blast furnace slag. For this purpose, the cementless concrete specimens were made for water-binder ratios of 40%, 45%, and 50%, respectively and then this specimens were cured in the water of $20{\pm}3^{\circ}C$ and immersed in fresh water, 10% sodium sulfate solution for 28, 91, 182, and 365 days, respectively. To evaluate the long-term durability to chloride ion and sulfate attack for the cementless concrete specimens, the diffusion coefficient for chloride ion and compressive strength ratio, mass change ratio, and length change ratio were measured according to the NT BUILD 492 and JSTM C 7401, respectively. It was observed from the test results that the resistance against chloride ion and sulfate attack of the cemetntless concrete were comparatively largely increased than those of OPC concrete irrespective of water-binder ratio.

Repair LCC Evaluation of RC Structures through the FEM Analysis of Chloride Ion Penetration (염소이온 침투 FEM 해석을 통한 RC구조물의 보수 LCC 평가)

  • Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.10 no.1
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    • pp.223-230
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    • 2006
  • In this paper the method for repair LCC evaluation of reinforced concrete structures deteriorated by chloride attack was constructed. Also, the FEM analysis for chloride ion penetration into concrete was conducted to evaluate the repair LCC which was decided by the number of repair times including early stages of construction and repair construction during the service life of structures. As a result, the number of repair times is obtained from the comparing the concentration of the chloride ion in a rebar position, and the critical chloride ion concentration of rebar corrosion through the FEM analysis considering the kind of repair materials and methods. Also, the repair LCC could be calculated by the number of repair times during the service life of structures.

Mathematical Modeling of Re-Diffusion Response of De-Sorbed Chloride Ions in Concrete Due to Carbonation (콘크리트의 탄산화로 인해 탈착된 염소이온의 재확산에 대한 해석 연구)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2009.05a
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    • pp.259-260
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    • 2009
  • Many concrete structures have suffered from carbonation or chloride ion diffusion induced reinforcement corrosion, and a number of studies have been done on these topics. Many studies were mostly confined to the single deterioration of carbonation or chloride ion, although the environment actually presents a combined condition. This paper tried to develop the approach to compute re-diffusion of de-sorbed chloride due to carbonation of concrete. This is a key for successful combined deterioration model of carbonation and chloride. It is thought that this paper can contribute to express mathematically chloride enrichment and re-diffusion of chloride at front of carbonation.

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Long-Term Experiment of Chloride Penetration in Concrete through Cracks (콘크리트의 균열부를 통한 염소이온 침투의 장기 실험연구)

  • Yoon, In-Seok;Sung, Jae-Duck
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.11a
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    • pp.809-812
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    • 2008
  • Over the past few decades, considerable numbers of studies on the durability of concrete have been carried out extensively. The majority of these researches have been performed on sound uncracked concrete, although most of in-situ concrete structures have more or less micro-cracks. It is only recent approach that the attention has shifted towards the influence of cracks and crack width on the penetration of chloride into concrete. The penetration of chlorides into concrete through the cracks can make a significant harmful effect on reinforcement corrosion. Author of this study examined the effect of cracks on chloride penetration by short tem experiment. However, it is necessary to accomplish the effect by long term experiment to get reliable goal. In this study, the long term experiment was carried out and the experimental result was compared with short term experiment. Crack tends to decrease with elapsed time because of self-healing. Especially this trend was obvious in concrete sample with wide crack with.

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Time Evolution of Material Parameters in Durability Design of Marin Concrete (해양콘크리트의 내구성 설계를 위한 재료 매개변수의 시간단계별 해석)

  • Yoon, In-Seok;Kim, Young-Geun
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.1077-1080
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    • 2008
  • Material parameters such as surface chloride content, water permeability coefficient, chloride diffusivity and critical chloride content are a substantial key parameter for understanding the durability performance of concrete and its micro-structural densification. Over the past few decades, a considerable number of studies on the durability design for marine concrete structures have been carried out. However, the results are different to each other. In order to establish a consistent durability design system of concrete, it is a precondition to define material parameters, which affect deterioration of concrete due to chloride penetration. Such parameters are surface chloride content, chloride diffusivity, and critical chloride content. Usually these parameters are assumed as temporary constant values or obtained from the experimental results for short term. However, it is necessary to define these parameters reasonably, because these significantly influence the calculation of service life of concrete. In this paper, it is introduced to define material parameters of concrete for chloride diffusion, such as surface chloride content $[Cl]_s$, water permeability coefficient K, chloride diffusivity $D_{Cl}$, critical chloride content $[Cl]_{cr}$. These are expressed as time function considering hydration evolution of hardened cement paste. The definition of the material parameters is a prerequisite to simulate chloride penetration into concrete as time elapsed.

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Chloride Binding Properties of Portland Cement Binder Incorporating CaAl2O4-CaAl4O7 (CaAl2O4-CaAl4O7 혼입 포틀랜드 시멘트 결합재의 염소이온 고정 특성)

  • Han, Jae-Doh;Lee, Yun-Su;Lee, Han-Seung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.4
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    • pp.1-9
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    • 2020
  • This study conducted to understand effects of CA (CaAl2O4) and CA2 (CaAl4O7) ratio on chloride binding ability and compressive strength and pore structure of cement mortar incorporating mixture of CA and CA2. The Portland cement based specimens were mixed with the clinkers CA and CA2, and these calcium aluminate clinker mixture were replaced 0, 5, 10% by weight of cement. After all the test specimens were cured for 28 days under water curing, they were immersed in the distilled water and NaCl solution. As a result, 28 days compressive strength of all specimens was similar, and As the replacement ratio of calcium aluminate clinker in the specimen increased, Friedel's salt production tended to increase. However, it was dependent on the amount of Al2O3 in the level of 5% replacement and CA ratio in the level of 10% replacement. Through equilibrium isotherm result, it was also indicated that as replacement ratio of calcium aluminate clinker in cement matrix increased, chloride binding capacity was improved, and chloride penetration was suppressed. In this study, the specimen replaced with 10% of the calcium aluminate clinker mixture (CA 39%, CA2 60%) was remarkable to control chloride attack. We figured out necessity to understand optimal CA/CA2 ratio to effectively apply CA2 as a sustainable building material by improving the chloride binding ability in Portland cement based system.

Compressive Strength and Chloride Ion Penetration Resistance of SHCC Coated by PDMS-based Penetrating Water Repellency (PDMS 흡수방지재를 적용한 SHCC의 압축강도 및 염화물이온 침투저항성)

  • Lee, Jun-Hee;Hyun, Jung-Hwan;Park, Su-Hyun;Kim, Yun-Yong
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.22 no.6
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    • pp.16-23
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    • 2018
  • In this study, Polydimethylsiloxane (PDMS) was applied to Strain Hardening Cement Composites (SHCC) for penetrating water repellency. The penetration depth of PDMS, strength of SHCC, and chloride ion penetration resistance of SHCC were investigated. As a result of measuring penetration depth of PDMS when applying different application method, it was confirmed that all methods satisfied the requirements of KS F 4930. Although the immersion method showed the largest penetration depth, the spray method was considered to be more appropriate considering the ease of field application. Compressive strength tests showed that the penetration depth of PDMS decreased as the compressive strength of SHCC increased. The compressive strength of M4-A and M4-B specimens with large PDMS penetration depths decreased by 9.6% and 8.0%, respectively, compared with those of M4 specimens produced without PDMS. Compressive strengths of the M1-A and M1-B specimens with small PDMS penetration depths were reduced by 4% and 2.2%, respectively, compared with the M1 specimen. As a result, it can be seen that the strength reduction rate of SHCC increases as the penetration depth of PDMS increases. The chlorine ion penetration tests showed that the chlorine ion penetration resistance increases with the penetration depth of PDMS.

Parametric Analysis for the Simultaneous Carbonation and Chloride Ion Penetration in Reinforced Concrete Sections (중성화와 염화물 침투가 동시에 발생하는 철근콘크리트 단면의 매개변수 분석)

  • Zhu, Xingji;Kim, Soye;Kwak, Dong-Woo;Bae, Kyung-Tae;Zi, Goangseup
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.20 no.5
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    • pp.66-74
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    • 2016
  • The objective of this study is the investigation of the influence of carbonation on the penetration of chloride ions in reinforced concrete sections for different mix proportions and environmental conditions. A comprehensive numerical model based on the change of the pore structure and the chemical equilibrium was used for this combined action of carbonation and chloride ingress. The empirical formulae of some parameters in this model are estimated according to numerous experimental data. And, a set of data analysis is carried out to simplify the estimation of model variables to reduce the computational cost. A coupled simulation of the transports of carbon dioxide, chloride ions, heat and moisture is carried out. Then, the parametric analysis is given and the numerical results show that the effect of carbonation of the free chloride ingress is significant and depends on the binder types and concrete mix proportion.