• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.11a
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• pp.165-168
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• 2000

로켓엔진에서 노즐은 추력을 발생하고, 단위 면적당 열 전달이 최대가 되는 곳으로 구조적으로 가장 취약한 부분이다. 이런 가혹한 조건에서 사용되어질 수 있는 4D 탄소/탄소 복합재를 제조하였으며. 초밀도화시, 탄화압력은 100bar 와 900bar 에서 각각 시행되었다. 만들어진 시편의 밀도는 1.5~l.9g/$cm^3$ 이었다. 실제 로켓을 모사할 수 있는 지상연소시험을 통해 밀도에 따른 삭마율을 계산한 결과, 밀도가 높을수록 삭마율은 감소하였다. 또한 3-point bending test를 통해 굽힘강도(flexural strength)를 측정하였으며, 굽힘강도를 개선시켜주었다.

• Korean Chemical Engineering Research
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• v.47 no.6
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• pp.734-739
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• 2009

Characteristics of pyrolysis, partial oxidation, combustion of chlorella, which is one species of micro-algae, were determined by using thermobalance reactor(I.D. 5.5 cm, Height 1 m). Effect of reaction temperature($500{\sim}800^{\circ}C$), water content in chlorella(0~60%), and oxygen content(0~21vol%) on thermal decomposition of chlorella were also determined and analyzed to investigate the kinetic characteristics of pyrolysis, partial oxidation and combustion. As the temperature and partial pressure increases, the carbon conversion increases. In case of pyrolysis, carbon conversion and reactivity sharply decreased with increasing moisture content. However, carbon conversion and reactivity decreased at 60% water content in case of partial oxidation and combustion. As reaction temperature and oxygen content increased, carbon conversion increased and the combustion reaction rate equation for chlorella has been presented. $\frac{dX}{dt}=(7.41{\times}10^{-1})$exp$\left(-\frac{19600}{RT}\right)(P_{O_{2}})^{0.209}(1-X)^{2/3}$.

• Resources Recycling
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• v.22 no.2
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• pp.11-17
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• 2013

The recycling technology of carbon residue produced from the process of oil recovery in waste tire pyrolysis is significant in environmental and economical aspects. This study was done to figure out the recycling possibility of carbon residue to activated carbon. For this, the characteristics of the carbon residue obtained from the commercial pyrolysis process of waste tire were studied. Also, the variation of pore structure of carbon residue was studied after 1 hour of carbonization at $600^{\circ}C$ and $800^{\circ}C$ and 3 hours of activation at $950^{\circ}C$. The specific surface area of the carbon residue was $8.0m^2/g$ and it increased to $548.3m^2/g$ after carbonization and activation.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.26 no.1
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• pp.39-47
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• 2002

Performed here is an assessment study for deterministic fracture mechanics analysis of a pressurized thermal shock(PTS). The PTS event means an event or transient in pressurized water reactors(PWRs) causing severe overcooling(thermal shock) concurrent with or followed by significant pressure in the reactor vessel. The problems consisting of two transients and 10 cracks are solved and maximum stress intensity factors and maximum allowable nil-ductility reference temperatures are calculated. Their results are compared each other to address the general characteristics between transients, crack types and analysis methods. The effects of elastic-plastic material behavior and clad coating on the inner surface are explored.

• Journal of Ocean Engineering and Technology
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• v.8 no.2
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• pp.157-165
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• 1994

Effect of an accelerated iso-thermal aging (375 degree C x 66days, 375 degree C x 200days) on elastic-plastic fracture resistance curve were examined in SA533B low alloy steel. Fracture toughness test are conducted by unloading compliance method at room temperature. But the apparent negative crack growth phenomenon, usually arise in partial unloading compliance test. The phenomenon of negative crack growth may be eliminated by the offset technique. There is no effect of aging on J sub(IC) and dJ/da in iso-thermal aged (375 degree C x 66 days) specimen, but there is very little effect in iso-thermal aged (375 degree C x 200 days) specimen.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 1996.05a
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• pp.265-272
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• 1996

액츄에이터에 사용되는 터어보 펌프의 터어빈을 구동시키기 위한 가스발생기용 고체연료 추진기관의 뒷마개부에 대하여 열/구조 해석을 수행하였다. 가스발생기는 장시간 연소모타로써 뒷마개에는 단열이 되어 있지 않은 배출튜브가 나사로 체결되어 고온, 고압의 연소가스에 의해 뒷마개 구조물에 작용하는 열 하중이 상당히 클 것으로 판단되므로, 최적설계를 위하여 뒷마개부의 열 및 구조해석을 수행하여 열하중의 영향을 예측하고 경량화를 위한 설계자료를 얻고자 하였다. 본 논문에서는 해석결과만을 언급하였으며 차후에 수행될 지상시험시에 해석치와 실험치를 비교한 후 좀 더 정확히 모델링을 하여 열/구조 해석 결과를 뒷마개부의 최적설계에 활용하고자 한다. 해석 결과 열하중이 연소관과의 조립부에는 거의 영향을 주지 않았으나, 열과 압력하중이 동시에 작용할 경우에 뒷마개 배출튜브의 조립부 근접한 곳에서 항복응력을 넘는 응력이 발생하여 정확한 구조 해석을 위해서는 탄소성해석을 수행하여야 할 것으로 판단된다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.11
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• pp.727-734
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• 2017

The electrochemical conversion of $CO_2$ is one of the methods for reducing $CO_2$. Four materials (Ag, Ni, Pt, and Ir) were selected as the electrodes. The electrochemical conversion was performed under a cell voltage of 4.0 V at $600^{\circ}C$. The amounts of $CO_2$ reduction and carbon production were at the highest for Ag, followed by, Pt, Ni, and then Ir. The produced carbon samples were analyzed by thermogravimetric analysis and XRD. The thermogravimetric analysis results indicated that all the carbon produced at each electrode exhibited similar thermal reactivity. The XRD results showed that the crystallization of carbon was different depending on the electrode utilized. Although electrochemical conversion was the highest for the Ag electrode, a loss of material accompanied it. Therefore, for this study, the optimal electrode is Pt, taking into account reactivity and material losses.

• Applied Chemistry for Engineering
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• v.18 no.3
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• pp.227-233
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• 2007

Carbon/carbon (C/C) composites as unique materials possess exceptional thermal resistance with light weight, high stiffness, and strength even at high temperature. However, one serious obstacle for application of the C/C composites is their poor oxidation resistance in high temperature oxidizing environments. SiC coating has been employed to protect the composites from oxidation. This study explored combustion characteristics of 4-directional (4D) carbon/carbon composites using liquid fuel rocket engine to investigate ablative motion of the materials. C/C composites were made of coal tar pitch as a matrix precursor, and heat-treated at $2300^{\circ}C$. Throughout repeated densification process, the density of the material reached $1.903g/cm^3$. After machining 4D C/C composites, the nozzle surface was coated by a SiC layer by pack-cementation method to improve oxidation resistance. Erosion characteristics of SiC-coated C/C composites were measured as function of the ratio of oxygen to fuel. The morphological change of the composites after combustion test was investigated using SEM and erosion mechanism also was discussed.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.42-48
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• 2021

In this study, a sensor for detection of nitric oxide (NO) gas was developed using petroleum pitch-based activated carbon which was synthesized from pyrolysis fuel oil (PFO). Polyethylene terephthalate (PET) was added to increase molecular weight by stimulating a polymerization of components in PFO during the pitch synthesis process. The increase in the molecular weight of pitch contributed to the improvement of textural properties of activated carbon, such as the specific surface area and micropore volume. It also enhanced the sensitivity of NO gas sensor based on the activated carbon. In addition, the effect of PET addition during the pitch synthesis on the surface oxygen content and conductivity of activated carbon was investigated. Finally, the correlation of the sensitivity with physical properties of activated carbon was analyzed.

• Proceedings of the Korean Vacuum Society Conference
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• 2001.02a
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• pp.103-103
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• 2001