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Sorption of Ni(II), Cu(II) and Fe(III) ions from Aqueous Solutions Using Activated Carbon (활성탄소를 이용한 수용액으로부터의 Ni(II), Cu(II) 그리고 Fe(III) 이온의 흡착)

  • Hanafi, H.A.;Hassan, H.S.
    • Journal of the Korean Chemical Society
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    • v.54 no.5
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    • pp.533-540
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    • 2010
  • An activated carbon was tested for its ability to remove transition metal ions from aqueous solutions. Physical, chemical and liquid-phase adsorption characterizations of the carbon were done following standard procedures. Studies on the removal of Ni(II), Cu(II) and Fe(III) ions were attempted by varying adsorbate dose, pH of the metal ion solution and time in batch mode. The equilibrium adsorption data were fitted with Freundlich and Langmuir and the isotherm constants were evaluated, equilibrium time of the different three metal ions were determined. pH was found to have a significant role to play in the adsorption. The processes were endothermic and the thermodynamic parameters were evaluated. Desorption studies indicate that ion-exchange mechanism is operating.

바실러스에 의한 중금속 제거 및 EPS 추출물질 비교에 관한 연구

  • Son, Han-Hyeong;Kim, Pan-Su;Lee, Sang-Ho
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2006.05a
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    • pp.423-427
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    • 2006
  • 1) 바실러스는 불리한 환경조건에서 포자를 형성하며 포자는 균체가 죽어도 살아 남고, 외부 환경이 좋아지면 다시 발아하여 영양형 균체를 형성하게 된다. 본 연구에서 바실러스를 우점화와 포자의 활성화를 위해 열처리(80$^{\circ}C$, 10min)를 한다 울산분뇨처리장 슬러지 Cake를 배양하여 포자화 전 후 상태의 미생물의 EPS 추출결과 RCF법을 적용하였을 때 Carbohydrate물질이 다른 추출법에 비해 가장 많이 추출되었고, Steaming extraction법을 적용하였을 때 Protein이 가장 많이 추출되는 것으로 나타났으며, 포자화 전 보다 포자화 후의 EPS 양이 더 많이 추출될 것이라는 가설을 가지고 실험한 결과 포자화 전보다 포자화 후의 EPS 양이 더 많이 추출되었다. 울산분뇨처리장의 슬러지 Cake를 배양하여 포자화 전 후의 Cu의 제거정도를 비교한 결과 포자화 후의 EPS물질이 포자화 전의 EPS물질보다 Cu를 더 많이 제거하는 것으로 나타났으며 EPS 물질이 중금속 제거능력이 탁월하다고 할 수 있겠다. 2) 용인분뇨처리장과 천안하수처리장의 MLSS의 중금속 제거능력을 알아보기 위해 미생물량을 고려했을 경우와 미생물량을 고려하지 않은 경우로 나누어서 실험을 하였는데 울산분뇨처리장의 슬러지 Cake를 가지고 실험한 결과와 마찬가지로 Bacillus의 EPS물질이 중금속 제거에 탁월하다는 것을 알 수 있다. 3) Baillus를 사용하는 김천 식품폐수 처리장과 활성슬러지를 사용하는 천안하수처리장과의 EPS 함량을 비교한 결과 김천 식품폐수 처리장의 EPS 물질중 Protein과 Carbohydrate가 천안하수처리장의 활성슬러지보다 더 많은 것으로 나타났다.TEX>, DIN/DIP비 표층수 $23.91\pm3.42$, 저층수 $23.43\pm3.38$이었으며, 전반적으로 해역별 수질기준 I등급 내지는 II등급을 유지하고 있었고, 공간적으로는 외해측으로 갈수록 외해수와 혼합 확산되어 양호한 수질을 나타내었다. 장기적인 변동특성은 세그룹으로 구분되어진다.기 실험결과 용출용매로 증류수와 해수를 이용했을 때, 제강 슬래그에서 용출되는 납, 구리, 카드뮴, 수은의 용출 경향의 차이를 확인할 수 있었고 이에 따라서, 납, 구리, 카드뮴의 용출 유해성은 낮기 때문에 해양구조물로의 제강슬래그 유효이용은 적합할 것으로 판단되었다.im80%$로 계산되었다. 열형광선량계로 측정된 방사선량은 각각 1.8, 1.2, 0.8, 1.2, 0.8 (70 cm 거리) cGy로 측정되었으며, 환자의 복부 표면에서의 서베이메터를 이용한 측정량은 10.9 mR/h였다. 차폐구조물의 사용 시 전체 치료 동안에 태아선량은 약 1 cGy 정도로 평가되었다. 결론 : AAPM Report No.50의 자료에 따르면, 임산부의 방사선 치료 시 태아의 방사선 피폭선량은 5 cGy 이하일 경우에 방사선 피폭에 따른 태아의 위험이 거의 없는 것으로 제시되고 있다. 본원에서 차폐 구조물을 설치하였을 경우에 측정된 태아선량은 약 1 cGy로 측정되었고, 고안된 차폐구조물은 태아에 도달하는 방사선량을 감소시키기에 적합한 설계임이 입증되었다. 아니라 일반종합병원에서도 CTX-M형 ESBL 생성 E. coli와 K. pneumoniae가 존재하며 확산 중임을 시사한다. 앞으로 CTX-M형 ESBL의 만연과 변종 CTX-M형 ESBL의 출연을 감시하기 위한 정기적인 연구와 조사가 필

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Assessment of cell adhesion, cell surface hydrophobicity, autoaggregation, and lipopolysaccharide-binding properties of live and heat-killed Lactobacillus acidophilus CBT LA1 (락토바실러스 아시도필러스 CBT LA1 생균과 사균체의 세포부착력, 자가응집력, 소수성 상호작용력, LPS 결합력에 대한 평가)

  • Shin, Joo-Hyun;Lee, Joong-Su;Seo, Jae-Gu
    • Korean Journal of Microbiology
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    • v.51 no.3
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    • pp.241-248
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    • 2015
  • Although studies on probiotics have been performed mostly with viable microbes, the beneficial functions of dead or heat-killed form of probiotic strains have also been examined. In this study, live and heat-killed forms of Lactobacillus acidophilus CBT LA1 were investigated in vitro and in vivo to evaluate the properties necessary for gut barrier protection. Cell surface hydrophobicity (CSH), autoaggregation (AA), cell adhesion, and lipopolysaccharide (LPS)-binding properties were evaluated. In addition, the suppressive effect on LPS-induced interleukin (IL)-8 expression was investigated in HT-29 cells. To identify optimal conditions for CBT LA1 to adhere to HT-29 cells, CBT LA1 cells were heat-treated at 80, 85, 90, 95, 100, or $121^{\circ}C$ for 10 min; cells treated at $80^{\circ}C$ for 10 min showed the highest adhesion. Heat-killed bacteria at $80^{\circ}C$ showed higher levels of LPS-binding, CSH, AA, adhesion to HT-29, and suppression of IL-8 expression than did live CBT LA1. In vivo imaging was performed to evaluate the ability of live or heat-killed CBT LA1 to remove LPS from the intestine in a rat model of infection. At 16 h after infection, fluorescence from FITC-conjugated LPS had mostly disappeared from the intestine of the rats administered with live or heat-killed CBT LA1; the effect was greater with heat-killed CBT LA1 at $80^{\circ}C$. These results suggest that heat-killed CBT LA1 as well as its live form can be applied as a pharmabiotic for protection of the gut barrier.

Numerical analysis of the cooling effects for the first wall of fusion reactor (핵 융합로 제1벽의 냉각성능에 관한 수치해석적 연구)

  • Jeong, I.S.;Hwang, Y.K.
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.1
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    • pp.18-30
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    • 1999
  • A heat transfer analysis for the two-dimensional (2-D) steady state using finite difference method (FDM) is performed to predict the thermal behavior of the primary first-wall (FW) system of fusion reactor under various geometric and thermo-hydraulic conditions, such as the beryllium (Be) armor thickness, pitch of cooling tube, and coolant velocity. The FW consists of authentic steel (type 316 stainless steel solution annealed) for cooling tubes, Cu for cooling tubes embedding material, and Be for a protective armor, based on the International Thermonuclear Experiment Reactor (ITER) report. The present 2-D analysis, the control volume discretized with hybrid grid (rectangular grid and polar grid) and Gauss-Seidel iteration method are adapted to solve the governing equations. In the present study, geometric and thermo-hydraulic parameters are optimized with consideration of several limitations. Consequently, it is suggested that the adequate pitch of cooling tube is 22-32mm, the beryllium armor thickness is 10-12mm, and that the coolant velocity is 4.5m/s-6m/s for $100^{\circ}C$ of inlet coolant temperature. The cooling tube should locate near beryllium armor. But, it would be better for locating the center of Cu wall, considering problems of material and manufacturing. Also, 2-D analysis neglecting the axial temperature distribution of cooling tube is appropriate, regarding the discretization error in axial direction.

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A Study on the Low Concentration Carbon Dioxide Adsorbent and Optimal Conditions (저농도 이산화탄소 포집용 흡착제 개발 및 최적조건에 관한 연구)

  • Lee, Ju-Yeol;Park, Duck-Shin;Cho, Young-Min;Kwon, Soon-Park;Hwang, Yoon-Ho;Song, Hyung-Jin;Lee, Sang-Bong
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.1
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    • pp.1-12
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    • 2012
  • In this study, $CO_2$ adsorbent was developed for removing low concentration of $CO_2$ in multiple-use facilities. The efficiency of the adsorbent which was improved selective $CO_2$ adsorption capabilities was evaluated. The pellet type adsorbent was modified from a commercial zeolite with mixing LiOH, binder, additives, and $H_2O$. Column tests showed over 90 % of $CO_2$ was adsorbed within 400min. Chamber tests including batch and continuous types were performed for evaluating the adsorbent module. By batch tests, it was evaluated that about 92% of $CO_2$ was removed within 30 min. By continuous tests, 70% of $CO_2$ was removed within 30 min. It was analyzed that over 2,500 ppm of $CO_2$ was continuously removed as shown chamber tests. The reproducibility tests repeatedly performed for 15 days shows that over 1,000 ppm of $CO_2$ was continuously removed. Adsorption capacity of the developed adsorbent was 5.0mmol $CO_2/g$ adsorbent which was analyzed by TGA. It was estimated that the modified adsorbent was applicable to low $CO_2$ concentration and low temperature of indoor environment.

Analysis of Cooldown Capability for the HWR Shutdown Cooling System (중수로 정지냉각계통의 냉각능력 분석)

  • Sin, Jeong-Cheol
    • Journal of Energy Engineering
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    • v.20 no.4
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    • pp.259-266
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    • 2011
  • Following the reactor shutdown, the reactor shutdown cooling system must be designed to supply the coolant sufficiently not only to remove the decay heat but to maintain the adequate cooling rate to protect the reactor equipments. In this study, KDESCENT code for the light water reactor and SOPHT, SDCS codes for the heavy water reactor were compared and analyzed to investigate the cooling capability during the shutdown cooling process. The shutdown cooling system design requirements were satisfied during cooling process for both the SDCP and the HTP modes and the design cooling rate of $2.8^{\circ}C/min$ or below was maintained using the SDC heat exchangers. This study shows that the shutdown cooling system in the Wolsong 2, 3, 4 reactors provides sufficient cooling to maintain the nuclear fuel integrity by removing the decay heat of the nuclear fission product.

Design of the Stand-alone Autothermal Reformer for Natural Gas (자체 기동형 천연가스 자열개질기 설계)

  • Koo, Jeongboon;Kim, Youngae;Kwon, Hyunji;Kwak, Inseob;Sin, Jangsik
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.11a
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    • pp.113.1-113.1
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    • 2010
  • 본 연구에서는 중 소형 SOFC에 적용할 수 있는 연료 변환 시스템으로 자체 기동 및 독립운전이 가능한 천연가스 자열개질(ATR) 반응기를 $10Nm^3/hr$급으로 개발하고자한다. 설계된 천연가스 자열개질기는 자열개질 촉매를 코팅한 금속 모노리스형 촉매체를 반응기 내에 장착함으로써 반응열을 신속하게 제거 또는 공급할 수 있는 시스템으로 구성되었다. 이는 금속 모노리스의 뛰어난 열전도 능력에 의해 반응기 내의 촉매층 전체 온도 분포를 균일하게 유지할 수 있는 저에너지형 자열개질 반응기이다. 또한 빠른 기동 특성을 실현하기 위하여 전기 발열식 촉매체(EHC ; Electically Heated Catalyst)를 장착한 start-up 시스템을 적용하여 천연가스 자열개질 반응기의 신속한 기동과 장치 간편화를 실현하였으며, 합성 syngas의 배열 회수를 위한 최적 열교환 시스템을 설계/적용함으로써 에너지 효율 향상을 도모하였다. 이와 같은 촉매 및 구조 시스템을 가지는 천연가스 자열개질 반응용 소형 연료변환 시스템을 원통형의 이중관 구조로 구성하고, 독립운전 모드로 개발함으로써 소형 SOFC의 연료 변환장치의 적용에 용이하게 하고자 한다.

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Effect of pulse plasma for thermally hardened photoresist residue removal (플라즈마 충격 방법을 이용한 열경화된 Photoresist 잔여물(residue) 제거 연구)

  • Ko, Hoon;Kim, Soo-In;Choi, Soo-Jeong;Lee, Chang-Woo
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.11a
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    • pp.132-133
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    • 2007
  • 반도체 소자의 제조 공정 기술이 발전하고 초고집적화가 됨에 따라 소자 선폭도 급속하게 감소하였다. 이로 인하여 기존의 식각 공정에서 식각 후 남은 잔여 Photoresist residue는 소자 생산에 큰 영향이 없었으나 현재 이러한 잔여물은 초고집적 소자에 치명적인 문제를 발생시킬 수 있다. 본 실험에서는 세정액 분자에 플라즈마 충격을 가하여 세정액을 활성화함으로써 기존의 세정액과의 세정능력을 비교 분석하였다.

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Analysis of Loss of Offsite Power Transient Using RELAP5/MOD1/NSC; II: KNU1 Design-Base Simulation (RELAP5/MOD1/NSC를 이용한 원자력 1호기 외부전원상실사고해석;II:설계기준사고)

  • Kim, Hyo-Jung;Chung, Bub-Dong;Lee, Young-Jin;Kim, Jin-Soo
    • Nuclear Engineering and Technology
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    • v.18 no.3
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    • pp.175-182
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    • 1986
  • The KNUI (Korea Nuclear Unit 1) loss of offsite power transient as a design-base accident has been simulated using the RELAP5/MOD1/NSC computer code. The analysis is carried out using the best-estimate methodology, but the sequence and its assumptions are based on the evaluation methodology th at emphasizes conservatism. Important thermal-hydraulic parameters such as average temperature, steam generator level and pressurizer water volume are compared with the results in the KNU1 Final Safety Analysis Report (FSAR). The present analysis gives much lower RCS average temperature and pressurizer water volume, and much higher S/G water volume at the turnaround point, which may be considered to be additional improved safety margins. This is expected since the present analysis deals with the best-estimate thermal-hydraulic models as well as the initial conditions on a best-estimate basis. These additional safety margins may contribute to further validate the safety of the KNU1 in this type of accidents(Decrease in Heat Removal by the Secondary System).

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MARS Code Applicability Assessments for the HTGR RCCS (고온가스로 원자로공동냉각계통(RCCS)에 대한 MARS Code 적용성 평가)

  • Kang Doo-Hyuk;Kim Hyung-Seok;Chung Bum-Jin
    • Journal of Energy Engineering
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    • v.14 no.4 s.44
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    • pp.232-240
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    • 2005
  • In this study, the IAEA Benchmark problems far HTR-10 and HTTR RCCS were assessed in order to assess the applicability of MARS code, a thermal-hydraulic safety analysis code developed for water reactors. The calculated results were compared with those or THERMIX, THANPACST2 code, and available experimental data. The calculated results showed generally good agreements with those obtained by the THERMIX code and THANPACST2 code. Deviations were analyzed to be originated from the simplification of complicated geometry and from the modeling capability of heat transfer characteristics in the HTGR components such as water cooler and air tooler. Especially, it was found that the radiation heat transfer in the reactor cavity played an important role in the after heat removal in the RCCS. Thus, it is concluded that MARS code can be successfully applied to the calculation of the RCCS cooling capability of the HTGR in this study.