• Membrane Journal
• /
• v.20 no.4
• /
• pp.335-341
• /
• 2010

This study focuses on the investigation of the anion exchange membrane through blending poly(ethylenimine) (PEI) and poly(vinyl alcohol) (PVA) varying the mixing ratio. To characterize the resulting membranes, the water content, contact angle, FT-IR, thermal gravimetric analysis, ion exchange capacity, ion conductivity and elastic modulus were measured. The PVA / PEI = 90 / 10 membrane showed the ion conductivity, $5.16{\times}10^{-2}S/cm$ and simultaneously the contact angle, $78.3^{\circ}$. According to TGA measurement, the resulting membranes seemed durable at room temperature. Through the modulus test, the mechanical properties increased with increasing PVA content and apparently the membranes looked very robust.

• The Proceedings of the Korean Institute of Illuminating and Electrical Installation Engineers
• /
• v.5 no.2
• /
• pp.58-66
• /
• 1991

This paper measured the characteristic of the thermal expansion, dielectric and conductivity to use $Sb_2O_3$ Filler in epoxy resin.The results are summarized as follow : 1 ) In the [$155^{\circ}C$] 1, The coefficient of thermal expansion increasing temperature obtained 8.19 in the case of pure epoxy resin and $4.5{\times}10^{-5}$ in the case of the mixing 7[%].2) The peak point of $\varepsilon\iota, \varepsilon\rho$ increasing $Sb_2O_3$ mixing ratio moved on the part of the high temperature. 3) The conductivity value increasing temperature shows the corner on the part of the Tg and it's Value became low the sample material with mixing I[%] than in case of pure epoxy resin.

• Journal of the Korea Institute of Building Construction
• /
• v.20 no.1
• /
• pp.11-18
• /
• 2020

Carbon nanotubes are used in various industries with their excellent mechanical properties and electrical conductivity. In the construction industry, research is being conducted to give self-sensing capabilities to structures, but the results of experiments vary among researchers, and the analysis is insufficient. Therefore, in this study, the hydration and electrical properties of MWCNT-added cement pastes were measured. The electrical resistance values of hydration heat, porosity, Rietveld quantitative analysis, compressive strength, and distance were measured.. The heat resistance, porosity, Rietvelt quantitative analysis, compressive strength and distance were measured according to electrical resistance. Experimental results showed that the heat of hydration decreased with increasing MWCNT. XRD Rietveld quantitative analysis showed that there was no significant difference in the amount of hydration products with increasing addition rate of MWCNT. As a result of SEM analysis, the MWCNT is agglomerated by van der Waals forces, and this area is considered to be caused by voids and weak areas. The electrical resistance value decreases as the addition rate is increased, and thus may play a role for magnetic sensing in the future.

• Polymer(Korea)
• /
• v.34 no.3
• /
• pp.202-209
• /
• 2010

Aromatic copolyamides were prepared and their applicability to proton exchange membrane wasstudied. The copolymer contains thermally stable and mechanically strong poly(m-phenylene isophthalamide) segments, and easily processable and good film forming polysulfone segments. For the copolymer, amineterminated sulfonated ether sulfone monomer, m-phenylene diamine, and isophthaloyl chloride were reacted, and the obtained copolymer was transformed into crosslinkable prepolymer by the reaction with acryloyl chloride. The prepolymer was thermally cured and converted into proton exchange membranes for fuel cell application. Each reaction step and the molecular characteristics of precursor copolymers were monitored and confirmed by $^1H$ NMR, FTIR, and titration. The performance of the membranes was measured in terms of water uptake, proton conductivity, and thermal stability. The water uptake, ion exchange capacity (IEC), and proton conductivity of the membranes increased with the increase of sulfonated ether sulfone segment content. Membrane containing 30 mol% sulfonic acid sulfone segment showed 1.57 meq/g IEC value. Water uptake was limited less than 44 wt% and the highest proton conductivity up to $3.93{\times}10^{-2}S/cm$ ($25^{\circ}C$, RH= 100%) was observed.

• Polymer(Korea)
• /
• v.35 no.2
• /
• pp.106-112
• /
• 2011

Aromatic copolyamides were prepared and their applicability to proton exchange membrane was studied. The copolymers contain two segments; thermally stable and mechanically strong poly (p-phenylene terephthalamide) (PPTA), and easily processable and good film-forming polysulfone. For the copolymers, different ratios of amine-terminated sulfonated ether sulfone monomer, terephthaloyl chloride, and p-phenylene diamine were sequentially reacted. The obtained copolymers were mixed with trimethylolpropane triglycidyl ether (TMPTGE), thermally cured, and converted into proton exchange membranes for fuel cell application. The reactions at each step and the molecular characteristics of precursor copolymers were confirmed by $^1H$ NMR, FTIR, and titration. The performance of the membranes was measured in terms of water uptake and proton conductivity. The water uptake, ion exchange capacity (IEC), and proton conductivity of the membranes increased with the increase of sulfonated ether sulfone segment content. Membrane containing 60 mol% sulfonic acid sulfone segment showed 1.88 meq/g IEC value. Water uptake was limited less than 110 wt% and the highest proton conductivity was up to $7.4{\times}10^{-2}$ S/cm ($25^{\circ}C$, RH=100%).

• Journal of the Korean Vacuum Society
• /
• v.17 no.4
• /
• pp.302-310
• /
• 2008

Heat transfer between substrate and substrate-heater in low vacuum was investigated. The convection related with gas flow and pressure, the heat conduction considering surface roughness and contact pressure, and the heat loss by radiation depending on the surface emissivity were considered. The coefficient of heat conduction $h_c$ in the Fourier's law were determined experimentally from the temperature difference between the substrate and the substrate-heater in the range of substrate-heater temperature $100\;-\;500^{\circ}C$, in the pressures of 300 mTorr - 1 Torr. The temperature difference was then calculated in the reverse way for the purpose of verification, using the heat flow and the experimentally determined coefficients. The verified temperature differences were thus obtained within 0.33 % error.

• Proceedings of the Korea Water Resources Association Conference
• /
• 2006.05a
• /
• pp.824-828
• /
• 2006

SWAT-MODFLOW 모형은 물리적 기반의 준 분포형 모형인 SWAT모형의 지하수 모듈을 분포형 모형인 MODFLOW로 대체하여 하천과 대수층간의 수위차이에 따른 물교환량으로 지하수 유출량을 결정하는 완전 연동형 지표수-지하수 통합모형이다. 이 모형을 구동하기 위해서는 유역자료, 기상자료, 하천특성자료, 토지 이용자료, 토양자료, 작물자료, 지하수자료 등 다양한 입력 자료를 필요로 한다. 이러한 입력 자료의 변동양상에 따라 모형의 결과가 크게 다르게 나타나므로 모형의 입력 매개변수 변화에 따른 모형의 반응을 분석하여야 한다. 본 연구에서는 지하수유출해석을 담당하는 MODFLOW 모형의 수리지질학적 매개변수 변화에 따른 모형의 반응을 검토하였다. SWAT-MODFLOW 모형을 경안천 유역에 적용하여 투수계수, 저류계수, 하상수리전도도 등의 주요 수리지질학적 매개변수가 지하수 유출현상에 미치는 증감과 변화율 등을 정량적으로 분석하였다. 유역출구점에서의 연평균 지하수유출량의 변화, 하천과 대수층의 상호작용에 따른 지하수 유출량 시계열의 변화 등을 분석하여 그 결과를 제시하였다.

• Journal of computational fluids engineering
• /
• v.8 no.4
• /
• pp.41-49
• /
• 2003

This study presents a numerical model to analyze dynamic thermal behavior of a hot chuck designed for flip-chip bonders. The hot chuck of concern is a heater which has been specifically developed for accomplishing high-speed and ultra-precision soldering. The characteristic features are radiative heat source and the heating tool made of a material of high thermal diffusivity. A physical modeling has been conducted for the network of heat transport. A simplified finite volume model is deviced to simulate time-dependent thermal behavior of the heating tool on which soldering is achieved. The reliability of the proposed numerical model is verified experimentally. A series of numerical tests illustrate the usefulness of the numerical model in design analysis.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.30 no.10 s.253
• /
• pp.996-1002
• /
• 2006

Experiments in methane-air low strain rate counterflow diffusion flames diluted with nitrogen have been conducted to study the behavior of flame extinction and edge flame oscillation in which flame length is less than the burner diameter and thus lateral conduction heat loss in addition to radiative heat loss could be remarkable at low global strain rates. Critical mole fraction at flame extinction is examined with velocity ratio and global strain rate. Onset conditions of edge flame oscillation and flame oscillation modes are also provided with global strain rate and added nitrogen mole fraction to fuel stream (fuel Lewis number). It is seen that flame length is closely relevant to lateral heat loss, and this affects flame extinction and edge flame oscillation considerably. Edge flame oscillations in low strain rate flames are experimentally described well and are categorized into three: a growing oscillation mode, a decaying oscillation mode, and a harmonic oscillation mode. The regime of flame oscillation is also provided at low strain rate flames. Important contribution of lateral heat loss even to edge flame oscillation is clarified

• Polymer(Korea)
• /
• v.34 no.1
• /
• pp.45-51
• /
• 2010

This study focuses on the investigation of the possibility of the crosslinked poly (vinyl alcohol) membranes with both poly (acrylic acid-co-maleic acid) (PAM) and 3-(trihydroxysilyl)-1-propane-sulfonic acid (THS-PSA) for the direct methanol fuel cell application. In order to characterize the prepared membranes, the water content, the thermal gravimetric analysis, the ion exchange capacity, the ion conductivity and the methanol permeability measurements were carried out and then compared with the existing Nafion 115 membrane. The ion exchange capacity of the resulting membranes showed 1.6~1.8 meq./g membrane which was improved than Nafion 115, 0.91 meq./g membrane. In the case of the proton conductivity, the THS-PSA introduced membranes gave more excellent $0.042{\sim}0.056\;S{\cdot}cm^{-1}$ than Nafion 115, $0.024\;S{\cdot}cm^{-1}$. On the other hand, the methanol permeability was increased more than Nafion 115 for all the range of THA-PSA concentration.