• Title/Summary/Keyword: 열화학

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Analysis of Thermal Oxide Behavior with Isothermal Degradation of TBC Systems Applied to Single Crystal Superalloy (단결정 초내열합금에 적용된 열차폐코팅의 등온열화에 따른 산화물 거동분석)

  • Kim, K.;Wee, S.;Choi, J.;Kim, D.;Song, H.;Lee, J.;Seok, C.S.;Chung, E.S.;Kwon, S.H.
    • Journal of the Korean Society of Safety
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    • v.34 no.4
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    • pp.1-5
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    • 2019
  • In the field of combined cycle power generation, thermal barrier coating(TBC) protects the super-heat-resistant alloy, which forms the core component of the gas turbine, from high temperature exposure. As the turbine inlet temperature(TIT) increases, TBC is more important and durability performance is also important when considering maintenance cost and safety. Therefore, studies have been made on the fabrication method of TBC and super-heat-resistant alloy in order to improve the performance of the TBC. In recent years, due to excellent properties such as high temperature creep resistance and high temperature strength, turbine blade material have been replaced by a single crystal superalloy, however there is a lack of research on TBC applied to single crystal superalloy. In this study, to understand the isothermal degradation performance of the TBC applied to the single crystal superalloy, isothermal exposure test was conducted at various temperature to derive the delamination life. The growth curve of thermally grown oxide(TGO) layer was predicted to evaluate the isothermal degradation performance. Also, microstructural analysis was performed by scanning electron microscope(SEM) and energy dispersive X-ray spectroscopy (EDS) to determine the effect of mixed oxide formation on the delamination life.

Identifying Process Capability Index for Electricity Distribution System through Thermal Image Analysis (열화상 이미지 분석을 통한 배전 설비 공정능력지수 감지 시스템 개발)

  • Lee, Hyung-Geun;Hong, Yong-Min;Kang, Sung-Woo
    • Journal of Korean Society for Quality Management
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    • v.49 no.3
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    • pp.327-340
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    • 2021
  • Purpose: The purpose of this study is to propose a system predicting whether an electricity distribution system is abnormal by analyzing the temperature of the deteriorated system. Traditional electricity distribution system abnormality diagnosis was mainly limited to post-inspection. This research presents a remote monitoring system for detecting thermal images of the deteriorated electricity distribution system efficiently hereby providing safe and efficient abnormal diagnosis to electricians. Methods: In this study, an object detection algorithm (YOLOv5) is performed using 16,866 thermal images of electricity distribution systems provided by KEPCO(Korea Electric Power Corporation). Abnormality/Normality of the extracted system images from the algorithm are classified via the limit temperature. Each classification model, Random Forest, Support Vector Machine, XGBOOST is performed to explore 463,053 temperature datasets. The process capability index is employed to indicate the quality of the electricity distribution system. Results: This research performs case study with transformers representing the electricity distribution systems. The case study shows the following states: accuracy 100%, precision 100%, recall 100%, F1-score 100%. Also the case study shows the process capability index of the transformers with the following states: steady state 99.47%, caution state 0.16%, and risk state 0.37%. Conclusion: The sum of caution and risk state is 0.53%, which is higher than the actual failure rate. Also most transformer abnormalities can be detected through this monitoring system.

A study on weighting algorithm of multi-band transmission method using an estimated BER (추정 BER을 이용한 다중 밴드 전송 기법의 가중치 알고리즘 연구)

  • Shin, Ji-Eun;Jeong, Hyun-Woo;Jung, Ji-Won
    • The Journal of the Acoustical Society of Korea
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    • v.40 no.4
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    • pp.359-369
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    • 2021
  • In underwater communications, to compensate performance degradation induced from rapidly changing channel transfer characteristic, multi-band communication method which allocate the same data to different frequency bands is used. However, the multi-band configuration may have worse performance than the single-band one because performance degradation in a particular band affects the output from the entire bands. This problem can be solved through a receiving end that analyzes error rates of each band, sets threshold values and allocates lower weights to inferior bands. Therefore, this paper proposed a weighting algorithm based on estimated Bit Error Rate (BER) which analyzes reliability of received data based on the performance difference between demodulated and decoded data. Employing turbo codes with coding rate of 1/3, we evaluate the performance of the proposed weighted multi-band transmission model in real underwater environments based on optimal simulation parameters. Through the sea trial experiment, we confirmed error performance was improved by applying the proposed weighting algorithm.

Design Planning and Evaluation using Mock-up for the Short-term Temporary Housing (단기 임시주거를 위한 설계계획 및 목업을 통한 성능평가)

  • Lee, Won-Hak;Lee, Byung-Yun;Cho, Young-Jun
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.609-616
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    • 2019
  • This paper proposes a design plan of short-term temporary housing for the victims by disaster. Also construction workability and residential environment evaluated by mock-up. In particular, in the event of a disaster, victims have lived the auditorium or gymnasium of the nearby school which is an emergency shelter. However, there was a problem of livability. Therefore, it is the purpose of study to provide temporary housing that resides within 30 days. For this purpose, a composite panel with light weight and insulation select to produce mock-up. The mock-up complete in about an hour. This is because it is made only of the composite panels. The composite panels confirm to be easy to load and construct. And mock-up evaluates insulation and waterproofing performance in the laboratory. As a result, Mock-up has insulation and waterproofing performance. This suggests an alternative to short -term temporary housing.

A Study on the Shrinkage Cracking Properties of Concrete by Using Blast Furnace Slag Cement and Frost-Resistant Accelerator (고로슬래그시멘트 및 내한촉진제를 사용한 콘크리트의 수축균열특성에 관한 연구)

  • Choi, Hyeong-Gil;Choi, Hee-Sup
    • Journal of the Korea Institute of Building Construction
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    • v.19 no.2
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    • pp.123-130
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    • 2019
  • As a cold-weather-concrete construction technique for enhancing the sustainability and improving efficiency of cold-weather construction, the cracking timing, the starting point of deterioration for concrete, due to the shrinkage of the blast furnace slag cement concrete including accelerator was evaluated. As a result, by using blast furnace slag and accelerator, the cracking was developed faster with higher cracking potential under the restrained conditions at constant age and free-shrinkage strain. It can be considered that the results of decreased stress relaxation by creep or increased restraint with increased free-shrinkage strain causes the increased cracking development speed. Hence, it should be considered the necessary of cracking due to the shrinkage when blast furnace slag or accelerator was used for cold-weather construction.

Evaluation of Service Life of Silicate Impregnated Concrete (실리케이트 함침제를 사용한 콘크리트의 내구수명 평가)

  • Kim, Hyeok-Jung;Jang, Seung-Yup;Yoon, Yong-Sik;Kwon, Seung-Jun
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.533-541
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    • 2018
  • Chloride attack, one of the major deterioration phenomena in RC(Reinforced Concrete) structure, causes corrosion of reinforcement, and this leads degradation of serviceability and structural problems. The application of silicate based impregnant to concrete surface are known for excellent constructability and cost-benefit for the maintenance of RC structure. In the work, the compressive strength and resistance of chloride diffusion for concrete were evaluated after improving property of concrete surface through two types of silicate based impregnant. Furthermore, based on the previous research and the result from the work, service life analysis was performed. After impregnating of silicate, strength and resistance of chloride diffusion were remarkably improved, and the service life increase to 159% for silicate A impregnation and 304% for silicate B impregnation, respectively.

Analysis of Causes PCB Failure for Collective Protection Equipment and Improvement of Quality (집단보호장비 내의 회로카드조립체 고장 원인 분석 및 품질 향상)

  • Pak, Se-Jin;Ki, Sang-Sik
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.5
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    • pp.87-92
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    • 2019
  • This study is the analysis of causes of printed circuit board (PCB) in collective protection equipment failure and quality improvement. The equipment is a component of the weapon system currently in operation and serves to defend against enemy chemical and biological attack as well as heating and cooling functions. However, during operation in the military, fans of condensate assembly failed to operate. The cause of the failure is the burning of PCB. It was found that the parts were heated according to the continuous cooling operation under the high temperature environmental conditions. Accordingly, the electronic components exposed to high temperature were deteriorated and destroyed. To solve this problem, PCB apply to heatsink. The performance test of improved PCB has been completed. Futhermore system compatibility, positive pressure maintenance and noise test were performed. This improvement confirmed that no faults have occurred in PCB so far. Therefore, the quality of the equipment has improved.

Study on Application of the Preserving Valuation Index for Environmental Management of a Stack Room (서고환경관리를 위한 보존성 평가지수 활용에 관한 연구)

  • Yoon, Dai-Hyun;Shin, Hyun-Chang
    • The Korean Journal of Archival Studies
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    • no.31
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    • pp.139-161
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    • 2012
  • Donald K. Sebera model can quantitatively compare the preserving environment by calculating the preserving valuation index with changing only the temperature and humidity. In this study, Donald K. Sebera model was used in order to compare and evaluate the preserving valuation index on the best condition and the worst condition in the temperature and humidity range of public records management act. As the results, the preserving valuation index in the best conditions was larger 2.47 times than the worst conditions within the preserving environment permitted in public records management act. Also, the influence of the humidity on the preserving valuation index of a paper archives as decreasing the activation energy for the hydrolysis reaction was larger rather than temperature. Thus the preserving valuation index can easily evaluate the suitability of the temperature and humidity conditions for preserving a archives. Therefore it can be used as useful tool for preservation of archives on change of the temperature and humidity.

Establishment of Hygrothermal Aging Mechanism via Thermal Analysis and Extraction of Reaction Kinetics of Ti Metal-based Pyrotechnic Materials (티타늄 금속 기반의 파이로테크닉 물질에 대한 열분석 및 반응특성 추출을 통한 열·수분 노화 메커니즘 구축)

  • Oh, Juyoung;Yoh, Jai-ick
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.49 no.9
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    • pp.759-769
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    • 2021
  • For aerospace propulsion systems, Titanium Hydride Potassium Perchlorate (THPP) is a material commonly used as a pyrotechnic initiator that generates gas when energy is supplied or as a supplement charge for NASA standard initiator (NSI). However, when the energetic materials are stored for a long time, it faces the problem of 'aging'. In this study, changes in thermodynamic properties of THPP aged under various humidity environments were identified through thermal analysis and surface analysis. First, a considerable amount of cracks on the surface of the oxidant was found in the aged THPPs. Particularly, when the humidity level increased, the number and length of the cracks rapidly increased. Also, the deterioration of Viton was found only in the thermally aged sample whereas the oxidation of the fuel was more pronounced in the hygrothermally aged samples. The extracted kinetic parameters of THPP on the reaction progress vary greatly by the humidity level, indicating that moisture significantly changes the performance and combustion reaction of THPP, which may eventually result in a reduced lifespan.

Preparation and application of silica-based coatings for corrosion protection of marine structures (해양구조물용 silica 기반 내해수성 코팅제의 제조 및 응용)

  • Lee, Byeong Woo
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.31 no.3
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    • pp.137-142
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    • 2021
  • In this study, the development of the room temperature curable silica-based coating compositions for anticorrosive and antifouling performance in marine environments was carried out. The marine (plant) structures with many exposed parts are operated in harsh marine environments such as strong ultraviolet rays, extreme temperature differences and salt water corrosion. Organic paints that are easily degraded under these environments and easily eroded by physical stimuli such as waves can not play a role properly. Dense ceramic coatings on marine structures provide careful protections even in saltwater environments due to their high hardness and rust resistance. Therefore, in the case of ceramic coatings, their use and application range in marine structures can be greatly improved due to their functional advantages. In the present study, silica-based coating compositions based on colloidal silica with silane coupling agents, curing salts, and ceramic fillers were developed, and their applications as protective coatings for corrosion protection and fouling prevention in seawater were also studied.