• Title/Summary/Keyword: 열화학

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Magnetic Properties of $\alpha$-Fe Based Nd-Fe-B Nanocrystalline with High Remanence (고잔류자화 $\alpha$-Fe기 Nd-Fe-B 초미세결정립 합금의 자기특성)

  • 조용수;김윤배;박우식;김창석;김택기
    • Journal of the Korean Magnetics Society
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    • v.5 no.1
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    • pp.38-41
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    • 1995
  • The effects of Nb and Cu additives as will as substitutional Co into $Nd_{4}Fe_{85.5}B_{10.5}$ melt-spun alloy were studied aiming for finding a $\alpha$-Fe based Nd-Fe-B composite alloys with high energy product. The addition of Nb and Cu to $Nd_{4}Fe_{85.5}B_{10.5}$ decreased the average grain size and increased the coercivity up to 207kA/m(2.6kOe), Further-more, the substitution of Co for Fe in $Nd_{4}Fe_{82}B_{10}Nb_{3}Cu_{1}$ alloy resulted in the decrease of the average grain size (<20nm) and improved the hard magnetic properties. The remanence, coercivity and energy product of optimally annealed $Nd_{4}Fe_{74}Co_{8}B_{10}Nb_{3}Cu_{1}$ alloy were 1.345, 219kA/m(2.75kOe) and $95.5kJ/m^{3}$(12MGOe), respectively.

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A Study on the Preservation Programs in Libraries and Archives (도서관 및 기록관 자료보존프로그램에 관한 고찰)

  • Cho, Young-Ju
    • Journal of Korean Society of Archives and Records Management
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    • v.4 no.1
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    • pp.101-116
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    • 2004
  • Deterioration and brittleness of resources on the shelves of institutions such as libraries and archives have been increased and accelerated as time passes in accordance with the preservation environment and the nature of their own material. It can be a loss of current information with little importance in prolong the life of valuable materials and to preserve them in security, integrated preservation programs should be developed and implemented according to missions, sizes, the nature of collections, users, and budgets of individual institutions. In reality, most institutions, however, are not able to implement perfect preservation programs due to lack of budget, human resources, and expertise. To solve this problem, some institutions in similar circumstances have planned cooperative preservation programs in various levels. Through cooperative systems individual institutions can not only pursue common interests but gain real benefits for themselves. Consequently institutions are recommended to collaborate with in development and implementation of various preservation programs at local, national, and international levels in addition to individual institutional programs.

Effect of Lead Concentration on Surface Oxide Formed on Alloy 600 in High Temperature and High Pressure Alkaline Solutions (고온, 고압 알칼리 수용액에서의 Alloy 600 산화막 특성에 미치는 납 농도 영향)

  • Kim, Dong-Jin;Kim, Hyun Wook;Moon, Byung Hak;Kim, Hong Pyo;Hwang, Seong Sik
    • Corrosion Science and Technology
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    • v.11 no.3
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    • pp.96-102
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    • 2012
  • Outer diameter stress corrosion cracking (ODSCC) has occurred for Alloy 600 (Ni 75 wt%, Cr 15 wt%, Fe 10 wt%) as a heat exchanger tube of the steam generator (SG) in nuclear power plants (NPP) during long term operation. Among many causes for SCC, lead (Pb) is known to be one of the most deleterious species in the secondary system. In the present work, the oxide formed on Alloy 600 was characterized as a function of the PbO content in 0.1 M NaOH at $315^{\circ}C$ by using an electrochemical impedance spectroscopy (EIS), a transmission electron microscopy (TEM), equipped with an energy dispersive x-ray spectroscopy (EDS). The oxide property was analyzed in view of SCC susceptibility.

Thermal Stability and the Effect of Substrate Temperature on the Structural and Magnetic Properties of Pd/Co Multilayer Films (Pd/Co 다층박막의 구조 및 자기적 특성에 미치는 기판온도 및 열적안정성에 관한 연구)

  • 허용철;김상록;이성래;김창수
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.298-304
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    • 1993
  • The effects of the substrate temperature and the Pd underlayer on the structure and the magnetic properties of Pd/Co multilayer films prepared by the thermal evaporation were studied. As the substrate temperature increases up to $150^{\circ}C$, the crystallinity of sublayers, (111) texture and the interface sharpness of Pd/Co multilayers were improved due to the enhanced mobility of adatoms. As results of that, the perpendicular and surface anisotropy energies were increased but the coercivity was decreased because the pinning sites of domain wall decreased due to the grain growth. The grain size of the multilayers increased with Pd underlyer thickness. Thermal degradation was enhanced at above $200^{\circ}C$ due to interdiffusion at the Pd/Co interface. The intensity of the main diffraction peak rapidly decayed in the initial stage of aging and then decreased slowly. The rapid change of the intensity in the initial stage was speculated to be due to the structural relaxation phenomena and the later stage change was due to the interdiffusion. The activation energy for the interdiffusion in Pd4/Co1 multilayers was 14.9 KCal/mole.K.

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Electrochromic Properties on $\textrm{MoO}_3$ Thin Films with Heat Treatment ($\textrm{MoO}_3$ 박막의 열처리 효과에 따른 일렉트로크로믹 특성)

  • Jo, Bong-Hui;Kim, Yeong-Ho
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1144-1147
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    • 1999
  • The effect of the heat treatment on electrochromic properties of $\textrm{MoO}_3$ thin films is investigated by studing optical modulation, optical density, response time, and cyclic voltammetry. From the results of XRD analysis, heat-treated at $450^{\circ}C$ in air for 1 hour Moo3 thin films are found to be crystalline while as-deposited and heat- treated at low temperature ($\leq\;300^{\circ}C$) film are amorphous. The electrochromic devices using as-deposited $\textrm{MoO}_3$ films exhibit good electrochromic properties compared to those using the heat treated $\textrm{MoO}_3$ films. It has shown that the heat-treatment affected the reversible color change and the electrochromic properties of $\textrm{MoO}_3$ films.

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$CO_2$ 클러스터 표면 처리를 이용한 그래핀 특성 향상에 관한 연구

  • Choe, Hu-Mi;Kim, Jang-A;Jo, Yu-Jin;Hwang, Tae-Hyeon;Lee, Jong-U;Kim, Tae-Seong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.655-655
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    • 2013
  • 그래핀은 높은 전자 이동도, 열전도도, 기계적 강도, 유연성 등의 고유한 특성으로 다양한 분야에 응용하기 위한 연구가 수행되고 있으며, 특히 전자 소자에의 적용에 관한 연구가 활발히 이루어지고 있다. 전자 소자에 적용하기 위해서는 성장 및 물성에 관한 규명, 응용 소자에 따른 특성 평가가 필요하다. 이러한 소자 특성은 그래핀 물성에 의한 영향이 기본적이지만 에칭, 전사 등의 공정 중 발생하는 오염, 표면 특성, 잔여물 등에 의한 물성 변화 또한 분석 및 제어에 관한 연구가 필요하다. 열화학증착법(thermal chemical vapor deposition)을 이용한 그래핀 합성은 구리 기판을 사용하며, 합성된 그래핀의 에칭, 박리 및 전사 공정이 있다. 이러한 공정 중 발생하는 오염 입자가 그래핀 표면에 흡착되거나, 제거되지 않은 PMMA 잔여물이 그래핀의 특성에 영향을 미치게 된다. 따라서 본 연구에서는 $CO_2$ 클러스터의 표면 충돌을 이용하여 이러한 오염 물질 및 잔여물을 제거하고 그래핀 표면을 평탄화하는 것에 관한 연구를 수행하였다. 가스 클러스터란 작동기체의 분자가 수십에서 수백 개 뭉쳐 있는 형태를 뜻하며 이렇게 형성된 클러스터는 수 nm 크기를 형성하게 된다. 그리고 짧은 시간의 응축에 의해 수십 nm 크기 까지 성장 하게 된다. 클러스터를 이용한 표면 처리는 충돌에 의한 제거에 기반 한다. 따라서 생성 및 가속되는 클러스터로부터 대상으로 전달되는 운동량의 정도가 세정 특성에 영향을 미치며 이는 생성되는 클러스터의 크기에 종속적이다. 생성 클러스터의 크기 분포는 분사거리, 유량, 분사 각도, 노즐 냉각 온도 등의 변수에 관한 함수이다. 본 연구에서는 이러한 변수들을 제어하여 클러스터를 이용한 그래핀 표면 처리 실험을 수행하였다. 평가는 클러스터 표면 처리 전과 후의 특성 비교에 기반 하였으며, 광학 현미경을 이용한 표면 형상 측정, 라만분광 분석, AFM을 이용한 표면 조도 측정, 그래핀 면저항 측정 결과를 비교하였다. 평가 결과를 통하여 표면 처리를 하지 않은 그래핀에 비하여 면저항과 표면 조도가 낮아지는 것을 확인 할 수 있었다. 또한 클러스터 세정은 300 mm 웨이퍼 크기 이상의 대면적을 짧은 시간에 건식으로 세정할 수 있다는 장점이 있어 향후 최적화를 통해 그래핀 양산 시 특성 향상을 위한 후처리 방법으로 사용될 수 있음을 확인하였다.

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Simulation of Unsaturated Fluid Flow on the 2nd Phase Facility at the Wolsong LILW Disposal Center (경주 중저준위방폐장 2단계 처분시설의 불포화 환경하에서 침투수 유동 해석)

  • Ha, Jaechul;Lee, Jeonghwan;Yoon, Jeonghyoun
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.3
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    • pp.219-230
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    • 2017
  • This study was conducted to predict and evaluate the uncertainty of safety after closure of the second phase surface disposal facility of the Gyeongju intermediate and low level repository in Korea. In this study, four scenarios are developed considering both intact and degraded states of multi-layered covers and disposal containers; also, the fluid flow by a rainfall into the disposal facility is simulated. The rainfall conditions are implemented based on the monthly average data of the past 30 years (1985~2014); the simulation period is 300 years, the management period regulated by institutional provisions. As a result of the evaluation of the basic scenario, in which the integrity of both of the containers and the covers is maintained, it was confirmed that penetration of rainfall does not completely saturate the inside of the disposal facility. It is revealed that the multiple cover layers and concrete containers effectively play the role of barrier against the permeation of rainfall.

The Effect of Silicone Oil on Preventing Deterioration of Oil for Frying Potatoes (감자튀김시 Silicone Oil의 튀김유 산화방지효과에 관한 연구)

  • Kim, Ki-Hong;Chung, Byoung-Sang;Sim, Joong-Hwan;Bae, Jae-Oh
    • Journal of the Korean Applied Science and Technology
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    • v.10 no.2
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    • pp.7-10
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    • 1993
  • This study was carried out to investigate the effect of silicone oil on preventing deterioration of oil in frying potatoes. The results obtained are summarized as follows: 1. Frying potatoes in oil, the oil added silicone oil slowly increased acid value, dielectric constant and decreased smoke point as compared with the oil without silicone oil. In the early stage of frying, there was on difference in deterioration degree of the frying oil between 1ppm and 10ppm addition of silicone all. But as frying time prolonged, the higher silicone oil was added. the more stable in deterioration of frying oil. 2. When silicone oil was added at the level of $1{\sim}10ppm$ into the oil for frying potatoes. it was possible to prevent deterioration of the frying oil.

Passivation properties of SiNx and SiO2 thin films for the application of crystalline Si solar cells (결정질 실리콘 태양전지 응용을 위한 SiNx 및 SiO2 박막의 패시베이션 특성 연구)

  • Jeong, Myung-Il;Choi, Chel-Jong
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.24 no.1
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    • pp.41-45
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    • 2014
  • We have investigated the passivation property of $SiN_x$ and $SiO_2$ thin films formed using various process conditions for the application of crystalline Si solar cells. An increase in the thickness of $SiN_x$ deposited using plasma enhanced chemical vapor deposition (PECVD) led to the improvement of passivation quality. This could be associated with the passivation of Si dangling bonds by hydrogen atoms which were supplied during PECVD deposition. The $SiO_2$ thin films grown using dry oxidation process exhibited better passivation behavior than those using wet oxidation process, implying the dry oxidation process was more effective in the formation of high quality $SiO_2$ thin films. The relative effective life time gradually decreased with increasing dry oxidation temperature. Such a degradation of passivation behavior could be attributed to the increase in interface trap density caused by thermal damages.

A fundamental study on the sulphate-resistant mortar using waste glass fine powder and meta-kaolin according to various fine aggregates (잔골재 종류에 따른 폐유리 미분말 및 메타카올린을 사용한 내황산염 모르타르에 관한 기초적 연구)

  • Jeong, Dongwhan;Park, Junhui;Ahn, Taeho;Park, Yeongsik;Sho, Kwangho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.27 no.3
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    • pp.115-121
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    • 2017
  • The degradation of the concrete due to deterioration factors, such as corrosion of steel bars, cracks and structural strength of reinforced concrete structures, is a social problem. Especially, concrete structures constructed in seawater, underground water, waste water treatment facilities and sewerage are subject to chemical attack by acid and sulphate. Therefore, this study was conducted to compare sulfated glass and fine aggregate of slag using waste glass fine powder and meta kaolin. The results showed that the slag fine aggregate showed better sulfate resistance than the river sand, and the fine powder of waste glass showed the best performance at 3 % displacement.