• Title/Summary/Keyword: 열천이

Search Result 185, Processing Time 0.026 seconds

MO Studies on Nucleophilic Substitution Reaction (친핵성 치환반응에 대한 분자궤도론적 연구)

  • Bon Su Lee;Lee, Ik Choon;Ki Yull Yang
    • Journal of the Korean Chemical Society
    • /
    • v.25 no.3
    • /
    • pp.145-151
    • /
    • 1981
  • The intrinsic reactivity of $S_N2$reaction in the gas phase was discussed MO theoretically (CNDO/2). We investigated the changes in geometry and electronic structure by means of the partial geometry optimization for reactantes, transition states, and products with various nucleophiles and leaving groups. We found that it was possible to discuss qualitatively the reactivity of $S_N2$ reaction with CNDO/2 MO calculation and the reactivity was controlled by basicity and of induced polarizability.

  • PDF

Evaluation of the Structural Stability of Platform Screen Door (PSD) due to Train Wind Pressure (열차 진입 시 풍압에 의한 완전 밀폐형 승강장 스크린 도어(PSD)시스템의 구조 안정성 평가)

  • Lee, Jae-Youl;Ryu, Bong-Jo;Kim, Dong-Hyun;Lee, Eun-Kyu;Shin, Kwang-Bok
    • Journal of the Korean Society for Railway
    • /
    • v.9 no.5 s.36
    • /
    • pp.594-600
    • /
    • 2006
  • In this study, transient and quasi-static analysis were done for the evaluation of structural integrity of the platform screen door due to train wind pressure. Fluent 6.0 was used to calculate the train wind pressure, and Ansys 10.0 was used to evaluate the structural stability of platform screen door due to train wind pressure. Transient analysis was used to check the design requirements of platform screen door, and quasi-static analysis was introduced to save the calculating time and check quickly structural performances when compared to those of transient analysis. The results show that structural stability of the platform screen door under train wind pressure is proven and quasi-static analysis can quickly check the structural integrity of platform screen door.

A Study on the Mechanical Properties Change by Stress Aging of 2.25Cr-1Mo Steel (2.25Cr-1Mo 강의 응력 시효에 의한 기계적 특성 변화에 대한 연구)

  • Yang, Hyun-Tae;Kim, Sang-Tae
    • Proceedings of the KSME Conference
    • /
    • 2001.06a
    • /
    • pp.517-522
    • /
    • 2001
  • The purpose of this study is to investigate the thermal embrittlement and the mechanical properties of 2.25Cr-1Mo steel aged at high temperature and stress for 250 hours. Original, aged artificially material were tested to obtain the hardness and impact absorbed energy. Hardness and impact absorbed energy decreased with the increasing aging time. The carbide morphology with the thermal embrittlement was found to contribute to the mechanical property change by X-Ray diffraction method.

  • PDF

A Study on the Mechanical Strength Change by Thermal Aging of 2.25Cr-1Mo Steel (발전설비용 2.25Cr-1Mo 강의 시효에 의한 기계적 강도 특성 변화에 대한 연구)

  • Yang, Hyeon-Tae;Kim, Sang-Tae
    • Transactions of the Korean Society of Mechanical Engineers A
    • /
    • v.24 no.7 s.178
    • /
    • pp.1771-1778
    • /
    • 2000
  • The purpose of this study is to investigate the thermal embrittlement and the mechanical properties of 2.25Cr-1Mo steel aged at high temperature for the extended periods. Original, aged artificiall y and used material were tested to obtain the tensile strength, hardness and impact absorbed energy. Tensile strength, hardness and impact absorbed energy decreased with the increasing aging time. The carbide morphology with the thermal embrittlement was found to contribute to the mechanical property change by X-Ray diffraction method.

Supersonic Intake Design & Flow Control Analysis using Bleeding Condition (초음속 흡입구 형상 설계 및 Bleeding을 활용한 유동제어 연구)

  • Choe, Jae-Hwan;Cheon, So-Min;Kim, Jong-Am
    • Proceeding of EDISON Challenge
    • /
    • 2012.04a
    • /
    • pp.77-80
    • /
    • 2012
  • 초음속 흡입구는 설계점에서 안정적으로 작동하지만 설계점 밖에서는 엔진성능이 급격히 감소하거나 층 격파 불안정 문제가 발생할 수 있다. 초음속 흡입구의 일반적인 특성을 파악하기 위해 2단 꺾임각을 갖는 외부 압축식 2차원 흡입구를 설계하고 EDISON_열유체 시스템을 이용하여 최종적으로 설계 마하수 2.5에서 작동하는 형상을 얻었다. 그러나 설계 마하수 이하의 영역에서는 충격파-경계층, 충격파간 상호작용으로 인해 유동에서 박리가 발생하고 최종적으로 흡입구 목을 질식시켜 아임계 상태로 천이된다. 이를 해결하기 위해 유동 제어 방법 중 하나인 bleeding을 이용하여 경계층을 제거하거나 유동의 박리를 방지하여 충격파를 cowl lip 전방에 안정하게 고정시킬 수 있었으며, 결과적으로 목적하였던 마하수 2.0에서 2.5에 이르는 작동 영역에서 강건하게 운용될 수 있는 초음속 흡입구를 설계하였다.

  • PDF

Flow pattern characteristics in vertical two phase flow by PDF and signals from conductance probe (確率密度函數와 電導 Prode信號에 의한 垂直二相流의 流動樣式特性)

  • Son, Byung-Jin;Kim, In-Suhk;Lee, Jin
    • Transactions of the Korean Society of Mechanical Engineers
    • /
    • v.10 no.6
    • /
    • pp.814-822
    • /
    • 1986
  • Flow patterns and its transitions in vertical two phase flow of air-water isothermal flow are identified objectively by void output signals and moments computed from the Probability Density Function which is associated with the statistical measurement for time average local void fractions using conductance probe. It has been shown that the probe output signals, PDF distributions and its moments are deterministic criteria of flow pattern and transition classification.

Phase-Locked Three-Dimensional Structures in the Cylinder Wake Observed from Cinematic PIV Data (Cinematic PIV에 의한 실린더 후류의 위상평균된 3차원 구조)

  • Sung, Jae-Yong;Park, Kang-Kuk;Yoo, Jung-Yul
    • Proceedings of the KSME Conference
    • /
    • 2000.04b
    • /
    • pp.661-666
    • /
    • 2000
  • Near-wake flow field of a circular cylinder is studied by means of a cinematic PIV system with high sampling rate and large internal memory block. Experiments are conducted in a closed-cycle water tunnel system and a cross-correlation algorithm in conjunction with FFT (Fast Fourier Transform) analysis and an offset correlation technique is used for vector processing. With the help of very high sampling frequency compared to the shedding frequency, it is possible to obtain phase-averaged information of the three-dimensional wake, even though the shedding is not forced but natural. Phase-locked vortical structures observed simultaneously from the spanwise and cross-stream planes are displayed in the wake-transition regime where fine-scale secondary vortices have a spanwise wavelength or around one diameter. Spatial relations and temporal evolutions of the primary Karman vortex and the secondary vortex are also discussed schematically.

  • PDF

Measurement of Heat Transfer and Pressure Distributions on a Gas Turbine Vane Endwall (가스터빈 베인 끝벽의 열전달 특성 및 정압분포 측정)

  • Lee, Yong-Jin;Shin, So-Min;Kwak, Jae-Su
    • Journal of the Korean Society for Aviation and Aeronautics
    • /
    • v.14 no.2
    • /
    • pp.33-38
    • /
    • 2006
  • Heat transfer coefficients and static pressure distributions on a gas turbine vane endwall were experimentally investigated in a 5 bladed linear cascade. The Reynolds number based on an axial chord length and the cascade exit velocity was 500,000. Both heat transfer and pressure measurements on the vane endwall were made at the two different turbulence intensity levels of 6.8% and 10.8%. Detailed heat transfer coefficient distributions on the vane endwall region were measured using a hue detection based transient liquid crystals technique. Results show various regions of high and low heat transfer coefficients on the vane endwall surface due to several types of secondary flows and vortices. Heat transfer coefficient and endwall static pressure distributions showed similar trends for both turbulence intensity, however, the averaged heat transfer coefficients for higher turbulence intensity case was higher than the lower turbulence intensity case by 15%.

  • PDF

Adsorption on Solid Surface from Binary Liquid Solution (이성분 용액에서의 고체 표면에 대한 흡착)

  • Seihun Chang;Hyungsuk Pak;Sangyoun Park
    • Journal of the Korean Chemical Society
    • /
    • v.17 no.2
    • /
    • pp.80-84
    • /
    • 1973
  • In treating solid-liquid interfaces, it is assumed that the adsorbed layer consists of monolayer and the molecules of the adsorbed layer behave as two dimensional liquid and oscillate harmonically in the vertical direction to the adsorbent. Applying the transition state theory of significant liquid structure to the adsorbed molecules, the adsorption isotherm, entropy and heat of adsorption for cyclohexane-benzene solutions adsorbed on silica-gel G are calculated. The calculated values are in good agreements with those of the observed ones.

  • PDF

A Study on Transient Characteristics of Flow Caused by Heat Addition in Supersonic Nozzle (초음속 노즐 내부 유동장의 가열에 의한 천이 특성에 대한 연구)

  • Chung, Jin-Do;Kim, Jang-Woo
    • Transactions of the Korean Society of Mechanical Engineers B
    • /
    • v.29 no.1 s.232
    • /
    • pp.80-86
    • /
    • 2005
  • This study presents numerical solutions of the two-dimensional Navier-Stokes equations for supersonic unsteady flow in a convergent-divergent nozzle with heat addition. The TVD scheme in generalized coordinates is employed in order to calculate the moving shock waves caused by thermal choking. We discuss on transient characteristics, start and unstart phenomena, fluctuations of specific thrust caused by thermal choking and viscous effects. We prove that the control of separation of boundary layer is the most important key problem to prevent the thermal choking.