• Title/Summary/Keyword: 열전 특성

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Preparation of High Energy Density Lithium Anode for Thermal Batteries and Electrochemical Properties Thereof (열전지용 고에너지 밀도 리튬 음극 제조 및 이의 전기화학적 특성)

  • Im, Chae-Nam;Yu, Hye-Ryeon;Yoon, HyunKi;Cho, Jang-Hyeon
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.35 no.4
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    • pp.398-406
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    • 2022
  • In order to increase the electrochemical performance of thermal battery anode, LIFT anode having the same weight but a larger lithium content in electrodes was fabricated by mixing lithium, iron and titanium. By applying these electrodes, a single cell and a thermal battery were prepared, and the effect of LIFT anode on electrochemical performance was evaluated. The LIFT-applied single cell presented a better cell performance than LIFe-applied single cell at 500℃ and 550℃. The discharge performance of LIFT-applied single cell, which included the operating time (787s), specific capacity (1,683 Asg-1), and electrode utilization (80.7%), was improved collectively compared to the LIFe applied single cell (736s, 1,245 As g-1, and 74.6%) at 500℃. As the discharge progressed, the internal resistance of LIFT anode decreased, because the lithium migration path was formed due to the presence of large titanium particles among iron particles. These results were analyzed in terms of the microstructure of electrode using SEM. Energy density of LIFT-applied single cell also increased by 10% to 142.1 Wh kg-1 compared to that of LIFe-applied single cell (127.4 Wh kg-1). In addition, the LIFT-applied single cell presented a stable discharge performance for 6,500s without a short circuit which could occur by molten lithium under an open circuit voltage condition with a high pressure (4 kgf cm-2). As observed in the high temperature thermal battery performance tests, the voltage and specific capacity of LIFT-applied thermal battery are superior to those of LIFe-applied thermal batteries, indicating that the energy density of LIFT-applied thermal batteries should remarkably increase.

Defect Inspection and Physical-parameter Measurement for Silicon Carbide Large-aperture Optical Satellite Telescope Mirrors Made by the Liquid-silicon Infiltration Method (액상 실리콘 침투법으로 제작된 대구경 위성 망원경용 SiC 반사경의 결함 검사와 물성 계수 측정)

  • Bae, Jong In;Kim, Jeong Won;Lee, Haeng Bok;Kim, Myung-Whun
    • Korean Journal of Optics and Photonics
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    • v.33 no.5
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    • pp.218-229
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    • 2022
  • We have investigated reliable inspection methods for finding the defects generated during the manufacturing process of lightweight, large-aperture satellite telescope mirrors using silicon carbide, and we have measured the basic physical properties of the mirrors. We applied the advanced ceramic material (ACM) method, a combined method using liquid-silicon penetration sintering and chemical vapor deposition for the carbon molded body, to manufacture four SiC mirrors of different sizes and shapes. We have provided the defect standards for the reflectors systematically by classifying the defects according to the size and shape of the mirrors, and have suggested effective nondestructive methods for mirror surface inspection and internal defect detection. In addition, we have analyzed the measurements of 14 physical parameters (including density, modulus of elasticity, specific heat, and heat-transfer coefficient) that are required to design the mirrors and to predict the mechanical and thermal stability of the final products. In particular, we have studied the detailed measurement methods and results for the elastic modulus, thermal expansion coefficient, and flexural strength to improve the reliability of mechanical property tests.

Grain-Based Distinct Element Modeling of Thermoshearing of Rock Fracture: DECOVALEX-2023 Task G (입자기반 개별요소모델을 이용한 암석 균열의 Thermoshearing 거동 해석: 국제공동연구 DECOVALEX-2023 Task G)

  • Jung-Wook, Park;Li, Zhuang;Jeong Seok, Yoon;Chan-Hee, Park;Changlun, Sun;Changsoo, Lee
    • Tunnel and Underground Space
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    • v.32 no.6
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    • pp.568-585
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    • 2022
  • In the present study, we proposed a numerical method for simulating thermally induced fracture slip using a grain-based distinct element model (GBDEM). As a part of DECOVALEX-2023, the thermo-mechanical loading test on a saw-cut rock fracture conducted at the Korea Institute of Civil Engineering and Building Technology was simulated. In the numerical model, the rock sample including a saw-cut fracture was represented as a group of random Voronoi polyhedra. Then, the coupled thermo-mechanical behavior of grains and their interfaces was calculated using 3DEC. The key concerns focused on the temperature evolution, thermally induced principal stress increment, and fracture normal and shear displacements under thermo-mechanical loading. The comparisons between laboratory experimental results and the numerical results revealed that the numerical model reasonably captured the heat transfer and heat loss characteristics of the rock specimen, the horizontal stress increment due to constrained displacement, and the progressive shear failure of the fracture. However, the onset of the fracture slip and the magnitudes of stress increment and fracture displacement showed discrepancies between the numerical and experimental results. We expect the numerical model to be enhanced by continuing collaboration and interaction with other research teams of DECOVALEX-2023 Task G and validated in further study.

Evaluation on Adiabatic Property for Vehicular Sandwich Composite Structure (차체 구조용 샌드위치 복합소재 단열 특성 평가)

  • Lee Sang Jin;Oh Kyung Won;Jeong Jong Cheol;Kong Chang duk;Kim Jeong Seok;Cho Se Hyun
    • Composites Research
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    • v.19 no.1
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    • pp.9-14
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    • 2006
  • Experimental investigation on heat transfer ratio was firstly performed with three types of sandwich panels such as the Carbon/Epoxy Skin-Aluminum Honeycomb and Balsa Core Sandwich Panel of 37mm thickness, the Carbon/Epoxy Aluminum Skin-Honeycomb Core Sandwich Panel of 57mm thickness (including insulator) and the Carbon/Epoxy Skin-Aluminum Honeycomb Core Sandwich Panel of 37mm thickness based on the KS F 2278:2003(Insulation test method of windows). In additional to this investigation, experimental tests were also done for evaluation of heat transportation ratio with the Aluminum Skin- Aluminium Honeycomb Sandwich Panels of 27mm and 35mm thickness, and Aluminum Skin-Foaming Aluminum Sandwich Panel of 27mm thickness by the KS F2277:2002 (Insulation measuring method of construction component-Calibration heat box method or protective heat box method). In this study, it was found that the larger net heat transfer cross sectional area between the skin and the sandwich core is given, the higher heat transportation ratio occurs. It was also found that the hybrid type insulation had better insulation characteristics compared to the non-hybrid type insulation.

A Study on Real-Time Monitoring for Moisture Measurement of Organic Samples inside a Drying Oven using Arduino Based on Open-Source (오픈 소스 기반의 아두이노를 이용한 건조기 내 유기 시료의 실시간 수분측정 모니터링에 관한 연구)

  • Kim, Jeong-hun
    • Journal of Venture Innovation
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    • v.5 no.2
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    • pp.85-99
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    • 2022
  • Dryers becoming commercially available for experimental and industrial use are classified to general drying oven, hot-air dryer, vacuum dryer, freezing dryer, etc. and kinds of them are various from the function, size and volume, etc. But the moisture measurement is not applied although it is important factor for the quality control and the performance improvement of products, and then now is very passive because the weight is weighed arbitrarily after dry-end. Generally the method for measuring moisture is divided by a direct measurement method and a indirect measurement method, and the former such as the change of weight or volume on the front and rear of separation of moisture, etc. is mainly used. Relatively a indirect measurement is very limited to apply due to utilize measurement apparatuses using temperature conductivity and micro-wave etc. In this research, we easily designed the moisture measurement system using the open-source based Arduino, and monitored moisture fluctuations and weight profiles in the real-time without the effect of external environment. Concretely the temperature-humidity and load cell sensors were packaged into a drying oven and the various change values were measured, and their sensors capable to operate 60℃ and 80℃ were selected to suitable for the moisture sensitive materials and the food dry. And also the performance safety using the organic samples of banana, pear, sawdust could be secured because the changes of evaporation rate as the dry time and temperature, and the measurement values of load cell appeared stable response characteristics through repeated experiments. Hereafter we judge that the reliability can be improved increasingly through the expansion of temperature-humidity range and the comparative analysis with CFD(Computational Fluid Dynamics) program.

Correlation Analysis of Cutter Acting Force and Temperature During the Linear Cutting Test Accompanied by Infrared Thermography (선형절삭시험과 적외선 열화상 측정을 통한 픽커터 작용력과 발생 온도의 상관관계 분석)

  • Soo-Ho Chang;Tae-Ho Kang;Chulho Lee;Hoyoung Jeong;Soon-Wook Choi
    • Tunnel and Underground Space
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    • v.33 no.6
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    • pp.519-533
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    • 2023
  • In this study, the linear cutting tests of pick cutters were carried out on a granitic rock with the average compressive strength over 100 MPa. From the tests, the correlation between the cutter acting force and the temperature measured by infrared thermal imaging camera during rock cutting was analyzed. In every experimental condition, the maximum temperature was measured at the rock surface where the chipping occurred, and the temperature generated in the rock was closely correlated with the cutter acting force. On the other hand, the temperature of a pick cutter increased up to only 36℃ above the ambient temperature, and the correlation with the cutter force was not obvious. This can be attributed to the short cutting distance under laboratory conditions and the high thermal conductivity of the tungsten carbide inserts. However, the relatively high temperature of the tungsten carbide inserts was found to be maintained. Therefore, it is recommended that a reinforcement between the insert and the head of a pick cutter or the quality improvement of silvering brazing in the production of a cutter is necessary to maintain the high cutting performance of a pick cutter.

Investigation of Tensile Properties in Edge Modified Graphene Oxide(E-GO)/Epoxy Nano Composites (측면 치환 그래핀/에폭시 나노복합재료의 인장 특성 평가)

  • Donghyeon Lee;Ga In Cho;Hyung Mi Lim;Mantae Kim;Dong-Jun Kwon
    • Composites Research
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    • v.37 no.3
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    • pp.209-214
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    • 2024
  • Graphene oxide (GO), known for its high stiffness, thermal conductivity, and electrical conductivity, is being utilized as a reinforcement in nanocomposite materials. This study evaluates the mechanical properties of epoxy nanocomposites incorporating GO and edge modified GO (E-GO), which has hydroxyl groups substituted only on its edges. GO/E-GO was uniformly dispersed in epoxy resin using ultrasonic dispersion, and mechanical properties were assessed through tensile testing. The results showed that the addition of nanoparticles increased both tensile strength and toughness. The tensile strength of the epoxy without nanoparticles was 74.4 MPa, while the highest tensile strength of 90.7 MPa was observed with 0.3 wt% E-GO. Additionally, the modulus increased from 2.55 GPa to 3.53 GPa with the addition of nanoparticles. Field emission scanning electron microscopy of the fracture surface revealed that the growth of cracks was impeded by the nanoparticles, preventing complete fracture and causing the cracks to split in multiple directions. E-GO, with surface treatment only on the edges, exhibited higher mechanical properties than GO due to its superior dispersion and surface treatment effects. These results highlight the importance of nanoparticle surface treatment in developing high-performance nanocomposite materials.

Climatological Characteristics in the Variation of Soil temperature in Korea (우리나라 지중온도 변동의 기후학적 특성)

  • Kim Seoung-Ok;Suh Myoung-Seok;Kwak Chong-Heum
    • Journal of the Korean earth science society
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    • v.26 no.1
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    • pp.93-105
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    • 2005
  • Climatological characteristics in the variation of soil temperatures in Korea were investigated using Korea Meterological Administration's observation data. And the impacts of soil moisture on the variation of soil temperature were examined using observed precipitation data. The climatological averages of soil temperatures are ranged from 14.4 to $15.0^{\circ}C$ regardless of depths. And they showed an latitudinal gradient with a warm temperature at the southern region and 'U' shape as in the air temperature with a high value along the coastal region. The relatively higher heat capacity and low conductivity of soil compared to those of the air resulted in the significant delay of the maximum and minimum date with depth. As a results, soil acts as a heat source during winter while a heat sink during summer. Global warming and urban heat island have increased the soil temperatures with an average rate $0.3\~0.5^{\circ}C/10-year$ as in the air temperature during last 30 years $(1973\~2002)$. However, the warming rate is maximized during spring contrary to the winter in the air temperature. The temporal variation of soil temperatures is strongly affected by that of soil moisture through an modification of the heat capacity and heat convection. In general, the increased soil moisture clearly decreased the temporal variations and increased the deep layer soil temperatures during cold season.

Physical Properties and Apparent Thermal Diffusivity of the Soils where Soil Temperature is Measured Regularly (기상청(氣象廳) 지온(地溫) 측정(測定) 토양(土壤)의 물리적(物理的) 성질(性質)과 겉보기 열확산(熱擴散) 계수(係數) 산정(算定))

  • Song, Kwan-Cheol;Jung, Yeong-Sang;Kim, Byung-Chan;Ahn, Yoon-Soo;Um, Ki-Tae
    • Korean Journal of Soil Science and Fertilizer
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    • v.25 no.3
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    • pp.220-230
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    • 1992
  • Soil temperature is one of the important environmental factors which control all the physical, chemical and biological processes in soil including germination and root growth of plants and other organisms living in the soil ecosystem. Soil water and nutrient availability and mobility are temperature dependent. Soil temperature change is depended primarily upon energy exchange in soil surface, meteorological variance and physical properties of the soils which are closely related to heat transfer mechanism. In this study physical properties including bulk density, soil texture and organic matter content were measured and thermal diffusivity on the soils was calculated. Soil samples from the 66 meteorological stations under the Korea Meteorology were collected and the physical parameters were measured. To obtain relationship between thermal diffusivity and soil water content a heat probe thermal diffusivity measurement apparatus was designed and used in this experiment. According to the survey on soil physicsal properties on the 66 meteorological stations, the 52% of the surface soil texture were sandy loam and laomy sand or sand, 38% were loam and silty loam, and 10% were clay loam and silty clay loam. The bulk density which was closely related with thermal properties showed average of $1.41g/cm^3$ for sandy soils, $1.33g/cm^3$ for loam and silty loam soils, and $1.21g/cm^3$ for clay loam and silty clay loam soils. The apparent thermal diffusivity of the upper layer from 0 to 30cm ranged from 1.16 to $8.40{\times}10^{-3}cm^3/sec$ with average of $3.53{\times}10^{-3}cm^3/sec$. The apparent thermal diffusivities of the Jeju soils of which organic matter contents were high and the bulk densities were low were near $2{\times}10^{-3}cm^3/sec$. The thermal diffusivity of snow measured in Chuncheon ranged from 0.822 to $2.237{\times}10^{-3}cm^3/sec$. The damping depth calculated from the thermal diffusivity ranged from 5.92 to 13.65cm for daily basis and 124 to 342cm for yearly basis. The significant regression equation to estimate thermal diffusivity with bulk density and soil water content was obtained by the heat probe in laboratory.

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Effect of Package Size and Pasteurization Temperature on the Quality of Sous Vide Processed Spinach (Sous Vide 가공 시금치의 품질에 미치는 포장단위 및 살균온도의 영향)

  • 장재덕;김기태;이동선
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.195-200
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    • 2004
  • Microbial lethal value and nutrient retention of sous vide processed spinach were evaluated with mathematical model prediction and experimental trial for different package sizes and pasteurization temperatures. The package size covers 500 g, 1 kg and 2 kg, while the pasteurization temperature includes 80, 90 and 97$^{\circ}C$. The basic process scheme consists of filling blanched spinach into barrier plastic film pouch, sealing under vacuum, pasteurization in hot water with over pressure and final cooling to 3$^{\circ}C$. Pasteurization condition was designed based on attainment of 6 decimal inactivation of Listeria monocytogenes at geometric center of the pouch package by heating cycle, which was determined by general method. Heat penetration property of the package and thermal destruction kinetics were combined to estimate the retention of ascorbic acid and chlorophyll. Smaller packages with shorter pasteurization time gave better nutrient retention, physical and chemical qualities. Larger package size was estimated and confirmed experimentally to give higher pasteurization value at center, lower ascorbic acid and chlorophyll contents caused by longer heat process time. Lower pasteurization temperature with longer process time was predicted to give lower pasteurization value at center and lower ascorbic acid, while chlorophyll content was affected little by the temperature. Experimental trial showed better retention of ascorbic acid and chlorophyll for smaller package and higher pasteurization temperature with shorter heating time. The beneficial effect of smaller package and higher pasteurization temperature was also observed in texture, color retention and drip production.