• Applied Chemistry for Engineering
• /
• v.28 no.5
• /
• pp.576-580
• /
• 2017

In the present paper, the thermal deactivation characteristics of plate-type commercial $V_2O_5-WO_3/TiO_2$ SCR catalyst were investigated. For this purpose, the plate-type catalyst was calcined at different temperatures ranging from $500^{\circ}C$ to $800^{\circ}C$ for 3 hours. Structural and morphological changes were characterized byXRD, specific surface area, porosity, SEM-EDS and also NOx conversion with ammonia according to the calcine temperature. The NOx conversion decreased with increasing calcine temperature, especially when the catalysts were calcined at temperatures above $700^{\circ}C$. This is because the crystal phase of $TiO_2$ changed from anatase to rutile, and the $TiO_2$ grain growth and $CaWO_4$ crystal phase were formed, which reduced the specific surface area and pore volume. In addition, $V_2O_5$, which is a catalytically active material, was sublimated or vaporized over $700^{\circ}C$, and a metal mesh used as a support of the catalyst occurred intergranular corrosion and oxidation due to the formation of Cr carbide.

• Proceedings of the Korea Air Pollution Research Association Conference
• /
• 2003.11a
• /
• pp.173-174
• /
• 2003

PAN은 1950년 중반 스모그 챔버연구원에서 'Compound X'라고 규정된 광화학 2차 오염물질로 강한 햇빛, NMHCs과 NOx의 존재하에서 이들 반응에 의해 형성된 물질이다 (Stephen, 1969) PAN은 눈을 자극하고, 식물에 대해 독성을 나타내며, 변이성과 발암을 유발할 가능성도 가지고 있다. 또한 PAN은 열적으로 불안정하여 상온에서 쉽게 NO2와 Peroxyaceyl radical로 분해 되며, 저온에서는 안정되게 존재하여 특히 상층 대류권을 통한NO2의 장거리 수송과 NO2의 reservoir역할을 한다. (중략)

• Journal of the Korean Institute of Gas
• /
• v.23 no.6
• /
• pp.8-16
• /
• 2019

One of the methods for low-pollution combustion, flue gas recirculation(FGR) is effective to reduce nitrogen oxides and it was applied in CH₄/air premixed counterflow flames to identify the change of flame characteristics and NOx mechanisms. Considering that the mole fraction of the products varied depending on the strain rates, the major products: CO₂, H₂O, O₂ and N₂ were recirculated as a diluent to reflect the actual combustion system. With the application of the FGR technique, a turning point of maximum flame temperature under certain strain rate condition was found. Furthermore as the recirculation ratio increased, the tendency of NO was changed before and after the turning point and the analysis on thermal NO and Fenimore NO production was conducted.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.8 no.1
• /
• pp.1-9
• /
• 2007

The performance of the small scale cyclone incinerate system (100kg/hr) to process the sewage sludge containing high moisture is evaluated. The incinerate system design is based on properties of the domestic sewage sludge. The combustion characteristics of the incinerate system is tested and analyzed with the various operation conditions of the moisture level, the sludge feed rate and the auxiliary fuel feed rate. The pressure loss of the whole system is appeared relatively small of 700mmAq under the normal operating condition and the temperature distribution of the incinerator internal combustion is maintained less than 1000C. Auxiliary fuel of 4.7 1/hr is required to incinerate 100kg sludge which include 87% moisture. Because the inside temperature of the incinerator is maintained less than $1000^{\circ}C$, it is predicted that the most NOx measured is produced not from the heat during the combustion process but from the oxidation of the N ingredient in the sludge. From the component analysis of ash, the organic matter is not entirely detected. Accordingly, it is estimated that the complete combustion has been accomplished in the incinerator.

• Journal of Advanced Marine Engineering and Technology
• /
• v.38 no.9
• /
• pp.1064-1069
• /
• 2014

The use of emulsified fuel and EGR (Exhaust gas recirculation) system are effective methods to reduce NOx emission from diesel engines. In general, it is considered that EGR method influences diesel engine combustion in three different ways: thermal, chemical and dilution effect. Among others, the thermal effect is related to the increase of specific heat capacity due to the presence of $CO_2$ and $H_2O$ in inlet air. Meanwhile, emulsified fuel method of utilizing latent heat of vaporization and miro-explosion has been recognized as an effective technique for reducing diesel engine emissions. In this paper, an author studied on combustion and emission characteristics by using emulsified fuel (EF, Light oil : 80% + Water : 20%) and EGR (30% EGR ratio) system. And the effect of fuel injection pattern control was investigated.

• Fire Science and Engineering
• /
• v.30 no.3
• /
• pp.1-6
• /
• 2016

More than five thousands transportation fires occurannually in Korea and the resulting destruction of property and loss of life is huge and results in traffic and environmental pollution. The recent development of automobile technology such as the hybrid concept and use of bio fuels makes fire protection even more difficult due to a lack of understanding of the new adapted system including vehicle engines. In this study, a numerical simulation was performed on a PSR (perfectly Stirred Reactor) to simulate an automobile engine and to clarify the effect of gasoline/ethanol surrogates as a fuel. The temperature, NOx and soot emissions were predicted to decrease with increasing ethanol content, but that of unburned hydrocarbons was found to increase dramatically. The result will provide not only the basic thermal characteristics for engines and their after-treatment systems, but also make it possible to assess the potential for fire events in these systems when an ethanol mixed fuel is used in gasoline vehicles.

• Clean Technology
• /
• v.27 no.4
• /
• pp.332-340
• /
• 2021

With the recent reinforcement of emission standards, it is necessary to make efforts to reduce NOx from air pollutant-emitting workplaces. The NOx reduction method mainly used in industrial facilities is selective catalytic reduction (SCR), and the most commercial SCR catalyst is the ceramic honeycomb catalyst. This study was carried out to reduce the NOx emitted from steel plants by applying De-NOx catalyst coated on metallic monolith. The De-NOx catalyst was synthesized through the optimized coating technique, and the coated catalyst was uniformly and strongly adhered onto the surface of the metallic monolith according to the air jet erosion and bending test. Due to the good thermal conductivity of metallic monolith, the De-NOx catalyst coated on metallic monolith showed good De-NOx efficiency at low temperatures (200 ~ 250 ℃). In addition, the optimal amount of catalyst coating on the metallic monolith surface was confirmed for the design of an economical catalyst. Based on these results, the De-NOx catalyst of commercial grade size was tested in a semi-pilot De-NOx performance facility under a simulated gas similar to the exhaust gas emitted from a steel plant. Even at a low temperature (200 ℃), it showed excellent performance satisfying the emission standard (less than 60 ppm). Therefore, the De-NOx catalyst coated metallic monolith has good physical and chemical properties and showed a good De-NOx efficiency even with the minimum amount of catalyst. Additionally, it was possible to compact and downsize the SCR reactor through the application of a high-density cell. Therefore, we suggest that the proposed De-NOx catalyst coated metallic monolith may be a good alternative De-NOx catalyst for industrial uses such as steel plants, thermal power plants, incineration plants ships, and construction machinery.

• Journal of Energy Engineering
• /
• v.22 no.1
• /
• pp.44-50
• /
• 2013

This study was experimentally investigated NOx and CO emissions characteristics with various equivalence ratios using premixed type of burner installed small heat exchanger. The effectiveness of heat exchanger and the entropy generation number were also calculated. As results, the heat transfer rate increases with increasing equivalence ratio due to increase the flame temperature. According to the emission characteristics and the effectiveness, the optimal operating equivalence ratio is 0.75 in the range of this experiment. Consequently, the area of the heat exchanger should be increased to reduce the entropy generation number and to increase the effectiveness.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.13 no.4
• /
• pp.1923-1930
• /
• 2012

Mn-Cu catalysts were tested for selective catalytic reduction of NOx with NH3. Influence of initial reaction temperature was studied for NOx conversion in which reaction temperature was changed three patterns. NOx conversion of catalysts calcined at 200, 300 and $340^{\circ}C$ was measured during the changing temperature. Hydrogen conversion efficiency of calcined catalysts was also measured in the $H_2$-TPR system. The deactivation effect of $SO_2$ on catalyst was investigated with the on-off control of $SO_2$ supply. The catalyst which calcined above $340^{\circ}C$ was somewhat deactivated with thermal shock. The reason of deactivation was draw from the results of surface area and hydrogen conversion.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.23 no.6
• /
• pp.788-794
• /
• 1999

The swirl flame is mostly used to stabilize the flame on the burner nozzle in the industrial combustor. In the case of the weak swirl flame(S<0.4), the recirculation zone could not be formed, but in the strong swirl(S>0.6) flame, it could be formed in the center of the swirl flame. In this study, the measurement and analysis of emission species, temperature, radicals of premixed swirl flame in the combustor were performed to understand the NO formation and emission characteristics of the swirl flame of natural gas. The result of NO emission in the swirl flame is that the amount of NO emission in the strong swirl flame decreased about 60% compared with that of the weak swirl flame. The main region of NO formation of the weak swirl flame is positioned in the down stream(z=100~200mm) of the flame, but that of the strong swirl flame is positioned in the up stream(z=40mm) where the recirculation zone seems to be formed. It is supposed that the increase of flame surface and the formation of inversed flame cause the reduction of the high temperature region on the production of NO in the strong swirl flame. The result of NO-temperature relation revealed that the factor of NO formation is not only temperature but also another parameters in the weak swirl flame, but in the strong swirl flame, NO is proportional to the temperature of higher than 1200K.