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Study on Degradation Characteristic of Plastic Artwork for Conservation (플라스틱 작품 보존을 위한 열화 특성 연구)

  • Yu, Ji A;Cho, Ha Jin;Han, Ye Bin;Lee, Hyun Ju;Lee, Sang Jin;Chung, Yong Jae
    • Journal of Conservation Science
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    • v.31 no.2
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    • pp.87-94
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    • 2015
  • Plastic artwork can be appeared crack, change of color and whitening event by various environment conditions. A large scale plastic artwork often exhibits in outside it will be directly degraded by physical and chemical degradation factor such as strong sunlight, high humidity and rainfall. We should know degradation characteristic of plastics to prevent these damages. In this study, we studied degradation characteristic of plastics (5 types of wide use plastics; polypropylene, polystyrene, polyethylene, polyvinyl chloride, polyurethane) depending on various artificial degradation conditions such as high temperature, ultraviolet and these complex conditions (high temperature and ultraviolet). As a result, polypropylene, polystyrene and polyethylene show the most visible change especially polypropylene, polystyrene. Polypropylene didn't show a great change degree of tensile strength and contact angle, on the other hand polystyrene did. Polypropylene and polystyrene weakened by photo degradation, polyvinyl chloride and polyurethane had relatively good light stability. Also the high temperature and complex conditions were most degradation characteristic. High temperature worked for degradation catalyst because its energy can not enough worked for cut off binding energy of plastics while ultraviolet condition effected as directly degradation condition. Though following results, we expect it can be applied to investigation of degradation factor depending on plastic artwork materials and basic result of plastic artworks conservation.

A Study on the Mutual Influence of Indicators of the Real Estate Auction Market (부동산 경매시장 지표간의 상호 영향에 관한 연구)

  • Jeong, Dae-Seok
    • The Journal of the Korea Contents Association
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    • v.19 no.12
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    • pp.535-545
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    • 2019
  • If the real estate auction market indicators are relevant and meaningful, they can be meaningful information to the real estate market in connection with general real estate. The purpose of this study is to examine whether time-supply logic is applied in auction market by identifying time series correlations for the number of auctions, the auction rate, and the auction price rate, which are major indicators of real estate auction market. The real estate types were classified into three categories: residential real estate, land, and commercial real estate. The monthly time series of auctions in the metropolitan real estate were compiled for 96 months. Based on this data, the auction market model for each type was established and the mutual influences between the indicators were analyzed. As a result, the supply and demand indicators, the number of auctions and the auction rate, showed the nature of supply and demand according to the supply and demand logic of the market. However, the correlation was high for residential real estate and relatively low for commercial real estate. the auction rate has a long-term impact on price indicators, especially residential real estate, which is quantitatively explanatory and significant. The three auction-related indicators differ in degree, but there is a correlation, especially for residential real estate, which can be useful information for policy making.

A Study on Sea Water and Ocean Current in the Sea Adjacent to Korea Peninsula - Expansion of Coastal Waters and Its Effect on Temperature Variations in The South Sea of Korea - (한반도 근해의 해류와 해수 특성 -남해연안수 확장과 수온변화-)

  • NA Jung-Yul;HAN Sang-Kyu;CHO Kyu-Dae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.23 no.4
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    • pp.267-279
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    • 1990
  • The temporal and spatial distribution of the coastal cold waters which was formed due to winter colling in the South Sea of Korea was analyzed by IR images from satellite and in situ data from shipboard observations. The coastal waters are known to be consisted of the Yellow Sea Coastal Waters(YSCW) and the South Korean Coastal Waters(SKCW). The former is driven around the Chuja-do and drifted into the Cheju Strait by residual currents, while the latter expands toward offsea by southward wind forcing. The expansion patterns of the SKCW were observed as sinking expansion or drifting expansion such that both were strongly dependent on the surface heat flux conditions. Under the condition of positive heat flux(warmer sea surface) or when the sea surface heat is lost to the atmosphere, the surface water started sinking and eventually expanded toward the open sea causing the cooling of the water column. For the negative heat flux the surface water was just drifted horizontally and expanded seaward and in this case only the surface layer of water was cooled.

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Effect of Amylose Content on the Physical Properties of Resistant Starches (효소저항전분의 물리적 성질에 대한 아밀로오스 함량의 효과)

  • Mun, Sae-Hun;Baik, Moo-Yeol;Shin, Mal-Shick
    • Korean Journal of Food Science and Technology
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    • v.29 no.3
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    • pp.516-521
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    • 1997
  • Effect of amylose content on the physical properties of resistant starches (RS) from autoclaved maize starches (with starch:water=1:3.5, at $121^{\circ}C$) which were repeated up to 4 times heating-cooling cycles, were investigated by water uptake, scanning electron microscope (SEM) and differential scanning calorimetry (DSC). Amylose content of waxy maize starch (Amioca), common maize starch (PFP), high amylose starch(Amaizo, Amylomaize VII) were 0%, 29%, 50%, and 72%, respectively. Yield of RS increased as amylose content increased. Water uptake of all kinds of native starch was higher than that of RS, but lower than that of autoclaved starch. By SEM, RS showed some small particles on surface but the size of particles was different with amylose content. Single endothermic transition peak exhibited at $40{\sim}70^{\circ}C$ in autoclaved Amioca and PFP (crystalline melting of amylopectin) and at $132{\sim}169^{\circ}C$ in autoclaved Amaizo and Amylomaize VII(crystalline melting of amylose) by DSC. RS from all kinds of autoclaved starches except Amioca showed single endothermic peak over $155^{\circ}C$ but the enthalpy was not related to amylose content.

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Comparison of Genetic Variation between Pre-practice Mature Trees and Post-practice One-year Old Seedlings in Pinus densiflora Natural Regeneration Stands (소나무 천연갱신림내 성목과 치수의 유전변이 비교)

  • Ahn, Ji Young;Lee, Jei Wan;Lee, Seok Woo;Baek, Seung Hoon;Lim, Hyo In;Kim, Hyun Seop
    • Journal of Korean Society of Forest Science
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    • v.104 no.4
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    • pp.543-548
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    • 2015
  • We studied the genetic impact of natural regeneration practices, such as Single seed tree, Group seed tree, Patch clear cutting and Alternate strip clear cutting systems, by comparing the nuclear microsatellite(nSSR) variation of post-practice natural regeneration one-year old seedlings of Pinus densiflora to that of pre-practice mature trees. The levels of genetic diversity of seedlings (A=13.6, $A_e$=4.3, $H_o$=0.571, $H_e$=0.597) were similar to those of mature trees (A=13.4, $A_e$=4.3, $H_o$=0.596, $H_e$=0.598) and the differences in the level of genetic diversity between seedlings and mature trees for each of the practices were not statistically significant. The degree of genetic differentiation between seedlings and mature trees was very low ($F_{ST}$=0.002) and the pairwise $F_{ST}$ values between seedlings and mature trees for all practices were less than 0.01. Overall, the natural regeneration practices appeared to have only minor impacts on the genetic diversity and the genetic composition in the studied P. densiflora stands. For a better understanding of the genetic effects of natural regeneration practices, subsequent studies such as temporal genetic variation of seedlings formed by crossing among post-practice mature trees should be considered.

Preparation and Crystallization Kinetics of Glasses with Ferroelectric Fresnoite Crystal (강유전체 Fresnoite 결정을 갖는 유리의 제조 및 결정화 거동)

  • Lee, Hoi-Kwan;Chae, Su-Jin;Kang, Won-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.2 s.35
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    • pp.161-166
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    • 2005
  • Glass formation, thermal property and crystallization behavior were investigated in $xK_2O-(33.3-x)BaO-16.7TiO_2-50SiO_2(mole\%)$ with fresnoite($Ba_2TiSi_2O_8$) crystal by replacement BaO for $K_2O$. As x(0$\le$x$\le$20) contents increased, glass formation became easy, and crystallization temperature moved on to the low temperature. Crystal phase of the $Ba_2TiSi_2O_8$ was confirmed by XRD, and the replaced x was not effected on the formation of new crystals. The kinetics of crystallization of fresnoite were studied by applying the DTA measurements carried out at different heating rates. The average avrami exponent(n) and activation energy were changed $2.26 {\pm}0.1,\;2.03 {\pm}0.1,\;1.93{\pm}0.15$, $279 {\pm}12kJ/mole,\;302{\pm}7kJ/ mole,\;319{\pm}1kJ/mole$ according to x contents, respectively. The replaced x improved the orientation of crystal growth.

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Bonding Strength of Cu/SnAgCu Joint Measured with Thermal Degradation of OSP Surface Finish (OSP 표면처리의 열적 열화에 따른 Cu/SnAgCu 접합부의 접합강도)

  • Hong, Won-Sik;Jung, Jae-Seong;Oh, Chul-Min
    • Journal of the Microelectronics and Packaging Society
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    • v.19 no.1
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    • pp.47-53
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    • 2012
  • Bonding strength of Sn-3.0Ag-0.5Cu solder joint due to degradation characteristic of OSP surface finish was investigated, compared with SnPb finish. The thickness variation and degradation mechanism of organic solderability preservative(OSP) coating were also analyzed with the number of reflow process. To analyze the degradation degree of solder joint strength, FR-4 PCB coated with OSP and SnPb were experienced preheat treatment as a function of reflow number from 1st to 6th pass, respectively. After 2012 chip resistors were soldered with Sn-3.0Ag-0.5Cu on the pre-heated PCB, the shear strength of solder joints was measured. The thickness of OSP increased with increase of the number of reflow pass by thermal degradation during the reflow process. It was also observed that the preservation effect of OSP decreased due to OSP degradation which led Cu pad oxidation. The mean shear strength of solder joints formed on the Cu pads finished with OSP and SnPb were 58.1 N and 62.2 N, respectively, through the pre-heating of 6 times. Although OSP was degraded with reflow process, the feasibility of its application was proven.

Evaluation of the Forest Bird Community in the Breeding Season by using the Sound Recording System (산림성 조류의 번식기 음성녹음을 이용한 조류군집 평가)

  • Yoo, Seung-Hwa;Han, Hyun-Jin;Kim, Dong-Won;Joo, Woo-Young
    • Korean Journal of Environment and Ecology
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    • v.32 no.1
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    • pp.39-46
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    • 2018
  • Breeding bird surveys provide the reference information for understanding bird community structure and function in the ecosystem and conserving biodiversity. Recent rapid change of biodiversity due to climate change and other factors has made it necessary to utilize acoustic sensors for accuracy and spatial expansion of forest bird survey data and for time-series monitoring of forest birds. The objective of this study is to investigate the possibility of using acoustic recording sensor to evaluate the diversity of forest birds at breeding season by comparing and analyzing the recorded data of bird songs and field bird survey data. We conducted the site survey and recording in 186 points in 48 areas of 4 regions of Gombaeryeong and Jochimryeong around Jeombongsan Mountain and Jugryeong and Gochiryeong around Sobaeksan Mountain from May 2nd to 16th in 2013. The analysis of the correlation between the recording result and Bird Community Index based on the field survey showed that the number of bird species, population, and the number of bird songs by recording was significantly correlated to the number of species and population by field survey. Moreover, the number of bird species and the number of bird songs by recording showed a significant correlation to species diversity and species richness but no or low significant correlation to species evenness by the field study (observation and listing in parallel). As a result, it was possible to check species composition and species diversity of bird communities by analyzing acoustic recording data on the field. The acoustic recordings of bird songs in the breeding period were more reliable than the non-breeding period in the correlation of recording result and species diversity and for utilization.

Effect of Bi and Zr addition on yellow colour properties of environment-friendly ceria-based pigments (비스무스와 지르코늄 첨가를 통한 세리아계 친환경 노란색 안료 특성에 관한 연구)

  • Kim, Tae-Ho;Hwang, Hae-Jin;Kim, Jin-Ho;Hwang, Kwang-Taek;Han, Kyu-Sung
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.25 no.4
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    • pp.153-159
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    • 2015
  • Inorganic pigments have been received a great attention for various applications including paint, glazed ceramic ink, art tile, and building exterior due to their excellent thermal and chemical stability. Traditionally, the compositions of $PbCrO_4$, CdS and CdSe have been widely used as a yellow inorganic pigment. However, the use of these compositions has been restricted in recent years, because they contain harmful elements such as Cd, Cr, Pb and Se. In this study, new environment-friendly ceria-based pigment was synthesized using solid state reaction. Crystal structure and morphology of the obtained $Ce_{1-x}Zr_xBi_yO_{2-y/2}$ yellow pigment were analyzed using XRD and SEM, respectively. Substitutional effect of Zr and Bi on the pigment color was analyzed using UV-vis. spectrophotometer and CIE $L^*a^*b^*$ analysis. The crystal structure of the obtained pigments was dependent on the calcination temperature. The color characteristics and absorption band of the pigments were dependent on the calcination temperature and Zr, Bi contents. As a result, all the obtained yellow pigments showed the effective absorption ranged from ultraviolet to visible light, and $Ce_{0.44}Zr_{0.36}Bi_{0.20}O_{0.19}$ (x = 0.36, y = 0.20) pigment showed the most brilliant yellow color.

A study on the fabrication of soda-lime glass by using refused coal ore and its properties (석탄 폐석을 이용한 소다라임계 유리의 제조 및 특성 연구)

  • Lim, Tae-Young;Jeong, Sang-Su;Hwang, Jong-Hee;Kim, Jin-Ho
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.20 no.1
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    • pp.43-52
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    • 2010
  • Glass was fabricated by using refused coal ore obtained from Dogye coal mine in Samchuk. We additionally used soda ash and calcium carbonate as raw materials to make a glass with the chemical composition of soda-lime glass. And the properties of glass were measured when limestone was used as natural raw materials instead of calcium carbonate as chemical raw materials. Transparent glass was fabricated by melting raw materials at $1550^{\circ}C$ for 1 hr in an electrical furnace. The various kinds of glass samples were fabricated according to the kinds of refused coal ore and glass cullet. The optical properties of transmittance and color chromaticity were measured by UV/VIS/NIR spectrometer and the thermal properties of thermal expansion coefficient and softening point were measured. Transparent glass with the transmittance of over 70% in visible range was fabricated by using normal refused coal ore and black colored glass with the transmittance of 0~35% was fabricated by using shel1 type refused coal ore. Therefore, it is concluded that refused coal ore can be used for raw materials to manufacture secondary glass products such as a glass tile and foamed glass panel for construction material.