• Title/Summary/Keyword: 열적열화

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Selection of Artificial Sand Suitable for Manufacturing Steel Castings through Evaluation of Various Foundry Sand Properties (각종 주물사의 특성과 주강품 주조에 적합한 인공사 선택)

  • Gwang-Sik Kim;Jae-Hyung Kim;Myeong-Jun Kim;Ji-Tae Kim;Ki-Myoung Kwon;Sung-Gyu Kim
    • Journal of Korea Foundry Society
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    • v.43 no.3
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    • pp.107-136
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    • 2023
  • Natural silica sand was commonly used for sand casting of cast steel products, and chromites sand was used to suppress seizure defects due to the lack of thermal properties of silica sand. However there are disadvantages such as deterioration by repeated use, system sand mixing problem, difficulty separating and removing, increased during mold according to high density and to being waste containing chrome. Recently, industrial waste reduction and atmospheric environment improvement have been highlighted as important tasks in the casting industry. In order to solve the problems that occur when using foundry Sand and to improve the environment of casting factories, various artificial sands that can be applied instead of natural silica sand have been developed and introduced. Artificial sands can be classified into artificial sand manufactured by the electric arc atomization or gas flame atomization, artificial sand manufactured by the spray drying & sintering process, artificial sand manufactured by the sintering & crushing process and exhibit different physical properties depending on the type of raw-minerals and manufacturing method. In this study, comparative evaluation tests were conducted on the physical properties of various foundry sands, mold strength, physical durability, thermal durability, and casting test pieces. When comprehensively considering the actual amount of molding sand used according to density, the mold strength according to the shape of sand, the physical and thermal durability of foundry sand, and the heat resistance characteristics of foundry sand, 'Molten artificial sand A1' or 'Molten artificial sand B' is judged to be the most suitable spherical artificial sand for casting of heavy steel castings.

The Deterioration Properties and Actual Conditions of Insulation Cover used at 22.9 kV Transformer Bushing (22.9 kV용 변압기 부싱 절연 커버의 실태 조사 및 열화 특성)

  • Choi, Chung-Seog;Kim, Hyang-Kon;Han, Woon-Ki;Lee, Ki-Yeon
    • Fire Science and Engineering
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    • v.20 no.3 s.63
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    • pp.35-41
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    • 2006
  • In this study, we presented the problems in the insulation cover of 22.9kV transformer bushing through investigating actual conditions. After thermal stress applied to the insulation cover, deterioration patterns, thermogravimetric and infrared characteristics were analyzed, and the results were applied to the cause analysis of accidents and judgement of safety. The insulation covers are used to protect exposed terminals of transformer, but they had improper size and length. Therefore, they could not show efficient insulation function. In case that thermal stress of $150^{\circ}C$ was applied to the insulation covers, plastic insulation covers(A, B, D, E) damaged severely, whereas rubber insulation cover(C) showed normal shapes. In the result of thermogravimetric analysis, the thermal gravity of plastic covers(A) decreased about 33.3% at $307.8^{\circ}C\;to\;405.9^{\circ}C$. and he thermal gravity of rubber covers (C) decreased about 53.7% at $258.8^{\circ}C\;to\;32.9^{\circ}C$. In the result of FT-IR analysis, plastic covers showed peaks characteristic of $CH_2,\;CH_3$, C=O and C=C bonds, whereas rubber covers showed peaks characteristic of OH, $CH_2,\;CH_3$, C=O, C=N and C=C bonds.

Effect of Containing Promoter on SCR Catalysts (SCR 촉매에 포함된 조촉매 영향)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.9
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    • pp.474-481
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    • 2018
  • The policy-making and technological development of eco-friendly automobiles designed to increase their supply is ongoing, but the internal combustion engine still accounts for approximately 95% of automobiles in use. To meet the stricter emission regulations of internal combustion engines based on fossil fuels, the proportion of after-treatments for vehicles and (ocean going) vessels is increasing continuously. As diesel engines have high power and good fuel economy in addition to less CO2 emissions, their market share is increasing not only in commercial vehicles, but also in passenger cars. Because of the characteristics of the diesel combustion, however, NOx is generated in localized high-temperature combustion regions, and particulates are formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for the after-treatment of exhaust gas to reduce NOx in diesel vehicles. This study examined the effect of a containing promoter on SCR catalysts to cope with the severe exhaust gas regulation. The de-NOx performance of the Mn-SCR catalyst was the best, and the de-NOx performance was improved as the ion exchange rate between Mn ion and Zeolyst was good and the activation energy was low. The de-NOx performance of the 7Cu-15Ba/78Zeoyst catalyst was 32% at $200^{\circ}C$ and 30% at $500^{\circ}C$, and showed the highest performance. The NOx storage material of BaO loaded as a promoter was well dispersed in the Cu-SCR catalyst and the additional de-NOx performance of BaO was affected by the reduction reaction of the Cu-SCR catalyst. Among the three catalysts, the 7Cu-15Ba/Zeolyst SCR catalyst was resistant to thermal degradation. The same type of CuO due to thermal degradation migrates and agglomerates because BaO reduces the agglomeration of the main catalyst CuO particles.

Thermal Behavior of (Co0.5 Mn0.5)Fe2O4 for Hydrogen Generation by Thermochemical Cycle (열화학 사이클 H2 제조를 위한 (Co0.5 Mn0.5)Fe2O4의 열적 거동)

  • Shin, H.C.;Choi, S.C.;Kim, C.S.;Kim, J.W.;Joo, O.S.;Jung, K.D.
    • Transactions of the Korean hydrogen and new energy society
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    • v.13 no.2
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    • pp.143-150
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    • 2002
  • The thermal behavior of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ prepared by a co-precipitation wasinvestigated for Hz generation by the thermochemical cycle. The reduction reaction of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ started from $480^{\circ}C$, and the weight loss was 1.6 wt% up to $1100^{\circ}C$. At this reaction, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ was reduced by release of oxygen bonded with the $Fe^{3+}$ ion in the B site of ($CO_{0.5}$ $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. In the $H_2O$ decomposition reaction, $H_2$ was generated by oxidationof reduced $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$. The crystal structure of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ for reduction reaction maintained spinel structure and the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ ($8.41\AA$) was enlarged to $8.45\AA$. But the lattice constant of $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ after $H_2O$ decomposition reaction did not change to $8.45\AA$. Then, $(Co_{0.5}\;Mn_{0.5})Fe_2O_4$ is excellent material in the thermochemical cyclic reaction due to release oxygen at low temperature for the reduction reaction and produce $H_2$ maintaining crystal structure for redox reaction.

A Study on the Development of Super Low-loss Type Pole Transformer Using the Hybrid Insulation (혼합절연을 이용한 초저손실급 주상변압기 개발에 관한 연구)

  • Min, Yun-Hong;Shin, Dae-Chul
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.7
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    • pp.84-93
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    • 2007
  • The pole transformer is one of the most important facility to insure the stability of electric power supply. which distributes electricity to customers directly. However there are a lot of defects which are caused by manufacturing fails(in 3 years) or deterioration (in 13 years), so we need a more improved transformer which insures quality. This thesis talks about the development of the new-type transformer using the hybrid insulation that is durable thermally, mechanically, and electrically. It would show how to lay out and produce the transformer using the hybrid insulation. And finally we are sure that we could increase the utilization rate of a transformer by 160% as compared with its own capacity through the overload test. Also, we carried out the examination about the short-circuit and insulation with a 100[kVA] model transformer, so that we expound the analysis of magnetic-mechanical forces intensity and the measure for improving short-circuit efficiency.

Thermal Stability and the Effect of Substrate Temperature on the Structural and Magnetic Properties of Pd/Co Multilayer Films (Pd/Co 다층박막의 구조 및 자기적 특성에 미치는 기판온도 및 열적안정성에 관한 연구)

  • 허용철;김상록;이성래;김창수
    • Journal of the Korean Magnetics Society
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    • v.3 no.4
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    • pp.298-304
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    • 1993
  • The effects of the substrate temperature and the Pd underlayer on the structure and the magnetic properties of Pd/Co multilayer films prepared by the thermal evaporation were studied. As the substrate temperature increases up to $150^{\circ}C$, the crystallinity of sublayers, (111) texture and the interface sharpness of Pd/Co multilayers were improved due to the enhanced mobility of adatoms. As results of that, the perpendicular and surface anisotropy energies were increased but the coercivity was decreased because the pinning sites of domain wall decreased due to the grain growth. The grain size of the multilayers increased with Pd underlyer thickness. Thermal degradation was enhanced at above $200^{\circ}C$ due to interdiffusion at the Pd/Co interface. The intensity of the main diffraction peak rapidly decayed in the initial stage of aging and then decreased slowly. The rapid change of the intensity in the initial stage was speculated to be due to the structural relaxation phenomena and the later stage change was due to the interdiffusion. The activation energy for the interdiffusion in Pd4/Co1 multilayers was 14.9 KCal/mole.K.

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The Variation of Structure and Physical Properties of XLPE during Thermal Aging Process (가교 폴리에틸렌의 열노화에 따른 구조와 물성의 변화)

  • 이미영;김철환;구철수;김복렬;이영관
    • Polymer(Korea)
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    • v.27 no.3
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    • pp.249-254
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    • 2003
  • The variation of chemical structure and physical properties of crosslinked polyethylene (XLPE) during thermal aging process was investigated. The formation of carbonyl functional group resulting from thermal oxidation reaction of XLPE was monitored using X-ray photoelectron spectroscopy and near infrared (NIR) spectroscopy. It was observed that the intensity of carbonyl peak observed at 1715 nm linearly increased with aging time in NIR spectroscopy. The linear relationship between NIR peak absorbance and aging time confirmed that NIR spectroscopy might be used as a proper tool for monitoring the aging process of polymeric materials. Also the formation of crosslinks during the aging process was monitored using thermal mechanical analysis, stress-strain test, and Shore hardness test. The change in the physical properties, such as the increase in the glass transition temperature from 110 to 132$^{\circ}C$, the decrease in the strain from 265 to 110%, as well as the increase in the shore D hardness from 32 to 50, was observed during the aging process.

An Analysis of Relationships between Plant Growth and Temperature Characteristics Measured with Thermographic Camera (식물의 성장과 열화상카메라로 측정된 열적 특성과의 연관성 분석)

  • Park, Sang-Mi;Nam, Da-Hyun;Kim, Ji-Hyung;Jo, Geon-Young;Kim, Ha-Yang;Kim, Jeongbae
    • Journal of the Korean Solar Energy Society
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    • v.36 no.2
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    • pp.1-7
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    • 2016
  • This study was experimentally performed to analyze the growth characteristics of a plant(wax tree or privet) using the surface temperature measured from thermal images captured using a thermal camera with water and cider. To do that, this study measured every each 12 hours the surface temperature and the stem temperature of leaves attached to the plant sample until the plants wilt on summer season in the laboratory room. From the experimental results, this study revealed that the temperature of front and back of the leaves is a little different due to the pore. The mean surface temperature of a leaf in cider is $0.52^{\circ}C$ higher than that of a leaf in water. The phenomena that the leaves of plants fall could be also demonstrated using the surface temperature. Before a leaf is falling from the tree, the temperature of the stem is lowered about $2^{\circ}C$ than those of other parts in a leaf. This result can be validated from previous result performed in University of Wisconsin.

Failure Analysis of the Rate of Rise Spot Type Heat Detector on Artificially Accelerated Aging (인공 가속열화에 따른 차동식 스포트형 열감지기의 고장 원인분석)

  • Kim, Chan-Young
    • Fire Science and Engineering
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    • v.25 no.4
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    • pp.48-55
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    • 2011
  • This paper presents the failure analysis of the rate of rise spot type heat detectors on artificially accelerated aging. The failures of heat detector turned out by two reasons. The first one is the separation of binder from plastic moulding, resulting in the leakage of air from heat chamber. The second reason is the crack of plastic. The large cracks were maybe created by these reasons, thermal expansion difference, mechanical stress, or growth of microcrack. In the sound detector, the separation and the crack were not occurred or not developed to the critical size. The glass fibers which increase the mechanical strength were added in the binder of detector 2010G. The densities of binder or plastic of each detector were similar. However, the TGA result shows that the thermal characteristics of 2005A and 2005B were not similar.

The Non-destructive Inspection Using Infrared Thermal Technique on Reinforced Slopes by Shotcrete (적외선 열화상을 이용한 숏크리트 보강사면의 비파괴점검)

  • Shin, Chang-Gun;Lee, Song;Ahn, Sang-Ro
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.1
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    • pp.95-102
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    • 2007
  • It needs to Prevent damage as aging shotcrete itself exists as a dangerous component to comuting vehicles or infrastructure due to scaling, spaling, and loosening. However, it is hard to make an approach owing to a steep slope and high work, and there has been indicated a limit that it is difficult to grasp the internal condition of shotcrete on the surface. This study aimed to research internal defects that cannot be observed from the surface, by measuring a subtle thermal transfer on the shotcrete surface by using infrared thermography for overcoming such a technical limit. As a result of conducting an inspection through an analysis on measured data and fieldwork using an endoscope camera, it was impossible to accurately determine the wet part because of an excessive coating of shotcrete, yet, This study is proposed effictively extract a void part of the inside with non-destructive and non-touching method.