• Title/Summary/Keyword: 열적열화

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Preparation and Thermal Degradation Behavior of WO3-TiO2 Catalyst for Selective Catalytic Reduction of NOx (NOx 제거용 WO3-TiO2 계 SCR 촉매 제조 및 열적열화거동연구)

  • Shin, Byeongkil;Kim, Janghoon;Yoon, Sanghyeon;Lee, Heesoo;Shin, Dongwoo;Min, Whasik
    • Korean Journal of Metals and Materials
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    • v.49 no.8
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    • pp.596-600
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    • 2011
  • Thermal degradation behavior of a $WO_3-TiO_2$ monolithic catalyst was investigated in terms of structural, morphological, and physico-chemical analyses. The catalyst with 4 wt.% $WO_3$ contents were prepared by a wet-impregnation method, and a durability test of the catalysts were performed in a temperature range between $400^{\circ}C$ and $800^{\circ}C$ for 3 h. An increase of thermal stress decreased the specific surface area, which was caused by grain growth and agglomeration of the catalyst particles. The phase transition from anatase to rutile occurred at around $800^{\circ}C$ and a decrease in the Brønsted acid sites was confirmed by structural analysis and physico-chemical analysis. A change in Brønsted acidity can affect to the catalytic efficiency; therefore, the thermal degradation behavior of the $WO_3-TiO_2$ catalyst could be explained by the transition to a stable rutile phase of $TiO_2$ and the decrease of specific surface area in the SCR catalyst.

Numerical Analysis on Thermal-Induced Degradation of n-i-p Structure Perovskite Solar Cells Using SCAPS-1D (SCAPS-1D 시뮬레이션을 이용한 n-i-p 구조 페로브스카이트 태양전지의 열적 열화 원인 분석)

  • Kim, Seongtak;Bae, Soohyun;Jeong, Younghun;Han, Dong-Woon;Kim, Donghwan;Mo, Chan Bin
    • Current Photovoltaic Research
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    • v.10 no.1
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    • pp.16-22
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    • 2022
  • The long-term stability of PSCs against visual and UV light, moisture, electrical bias and high temperature is an important issue for commercialization. In particular, since the operation temperature of solar cell can rise above 85℃, a study on thermal stability is required. In this study, the cause of thermal-induced degradation of PSCs was investigated using the SCAPS-1D simulation tool. First, PSCs of TiO2/CH3NH3PbI3/Spiro-OMeTAD/Au structure were exposed to a constant temperature of 85℃ to observe changes in conversion efficiency and quantum efficiency. Because the EQE reduction above 500 nm was remarkable, we simulated PSCs performance as a function of lifetime, doping density of perovskite and spiro-OMeTAD. Consequently, the main cause of thermal-induced degradation is considered to be the change in the perovskite doping concentration and lifetime due to ion migration of perovskite.

Design of Face with Mask Detection System in Thermal Images Using Deep Learning (딥러닝을 이용한 열영상 기반 마스크 검출 시스템 설계)

  • Yong Joong Kim;Byung Sang Choi;Ki Seop Lee;Kyung Kwon Jung
    • Convergence Security Journal
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    • v.22 no.2
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    • pp.21-26
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    • 2022
  • Wearing face masks is an effective measure to prevent COVID-19 infection. Infrared thermal image based temperature measurement and identity recognition system has been widely used in many large enterprises and universities in China, so it is totally necessary to research the face mask detection of thermal infrared imaging. Recently introduced MTCNN (Multi-task Cascaded Convolutional Networks)presents a conceptually simple, flexible, general framework for instance segmentation of objects. In this paper, we propose an algorithm for efficiently searching objects of images, while creating a segmentation of heat generation part for an instance which is a heating element in a heat sensed image acquired from a thermal infrared camera. This method called a mask MTCNN is an algorithm that extends MTCNN by adding a branch for predicting an object mask in parallel with an existing branch for recognition of a bounding box. It is easy to generalize the R-CNN to other tasks. In this paper, we proposed an infrared image detection algorithm based on R-CNN and detect heating elements which can not be distinguished by RGB images.

A Study on the Establishment of Urban Life Safety Abnormalities Detection Service Using Multi-Type Complex Sensor Information (다종 복합센서 정보를 활용한 도심 생활안전 이상감지 서비스 구축방안 연구)

  • Woochul Choi;Bong-Joo Jang
    • Journal of the Society of Disaster Information
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    • v.20 no.2
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    • pp.315-328
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    • 2024
  • Purpose: The purpose of this paper is to present a service construction plan using multiple complex sensor information to detect abnormal situations in urban life safety that are difficult to identify on CCTV. Method: This study selected service scenarios based on actual testbed data and analyzed service importance for local government control center operators, which are main users. Result: Service scenarios were selected as detection of day and night dynamic object, Detection of sudden temperature changes, and Detection of time-series temperature changes. As a result of AHP analysis, walking and mobility collision risk situation services and fire foreshadowing detection services leading to immediate major disasters were highly evaluated. Conclusion: This study is significant in proposing a plan to build an anomaly detection service that can be used in local governments based on real data. This study is significant in proposing a plan to build an anomaly detection service that can be used by local governments based on testbed data.

A Study on the Worst Stress Condition Test Evaluation of Blowers for Small Stationary Fuel Cell System (소용량 건물용 연료전지시스템 블로워의 가혹조건 평가에 관한 연구)

  • Kim, Kangsoo;Lee, Deokkwon;Lee, Jungwoon;Kim, Eunjung;Kim, Inchan;Kim, Younggyu;Shin, Hunyong
    • Journal of the Korean Institute of Gas
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    • v.16 no.6
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    • pp.34-40
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    • 2012
  • The fuel cell is one of the renewable energy sources. And it is a new source of energy that can be applied to various fuels and continuously supported by the excellent city-gas infrastructure. It is important to improve performances and reliabilities, and reduce the cost of fuel cell systems for commercialization. And, some safety performances of blower domestically produced are evaluated and some improvements are researched to save the cost of fuel cell systems. In this paper, the performance and worst stress condition of blowers are evaluated in operating environment similar to the fuel cell systems. Actually, the correlation of flow, leakage and thermal behavior are evaluated in the worst stress condition at $70^{\circ}C$ and, some major factors of blower degradation such as a motor deterioration, material and structures of the outlet are examined.

Comparison of Optimum Drilling Conditions of Aircraft CFRP Composites using CVD Diamond and PCD Drills (CVD 다이아몬드 및 PCD이 드릴을 이용한 항공용 CFRP 복합재료의 홀 가공성 비교)

  • Kwon, Dong-Jun;Wang, Zuo-Jia;Gu, Ga-Young;Park, Joung-Man
    • Composites Research
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    • v.24 no.4
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    • pp.23-28
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    • 2011
  • Recently CFRP laminate joints process by bolts and nets are developed rapidly in aircraft industries. However, there are serious drawback during jointing process. Many hole processes are needed for the manufacturing and structural applications using composite materials. Generally, very durable polycrystalline crystalline diamond (PCD) drill has been used for the CFRP hole process. However, due to the expensive price and slow process speed, chemical vapor deposition (CVD) diamond drill has been used increasingly which are relatively-low durability but easily-adjustable process speed via drill shape change and price is much lower. In this study, the comparison of hole process between PCD and CVD diamond coated drills was done. First of all, CFRP hole processbility was evaluated using the equations of hole processing conditions (feed amount per blade, feed speed). The comparison on thermal damage occurring from the CFRP specimen was also studied during drilling process. Empirical equation was made from the temperature photo profile being taken during hole process by infrared thermal camera. In addition, hole processability was compared by checking hole inside condition upon chip exhausting state for two drills. Generally, although the PCD can exhibit better hole processability, hole processing speed of CVD diamond drill exhibited faster than PCD case.

Compressive Properties of Ultra High Strength Concrete Exposed to High Temperature (고온에 노출된 초고강도 콘크리트의 압축특성)

  • Kang, Yong-Hak;Kang, Choong-Hyun;Choi, Hyun-Guk;Shin, Hyun-Jun;Kim, Wha-Jung
    • Journal of the Korea Concrete Institute
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    • v.26 no.3
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    • pp.377-384
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    • 2014
  • Recently, the trend toward larger architectural structures continues and accelerates demand for Ultra High Strength Concrete (UHSC) which satisfies structural performance. However, UHSC has weakness in fire and the performance tests are required. In this paper, the change of mechanical properties of 100 MPa grade UHSC exposed to high temperatures ($20^{\circ}C{\sim}800^{\circ}C$) was observed to develop high temperature material model of UHSC: residual compressive strength, modulus of elasticity, property of stress-strain on monotonous loading and property of stress-strain on cyclic loading. In addition, TG/DTA and SEM Images analyses were performed to investigate chemical and physical characteristics of UHSC, and the results of this research were compared with those of previous studies. As a result, UHSC at the heating temperature of $300^{\circ}C$ showed a sharp decrease of residual compressive strength and modulus of elasticity. And It was shown that UHSC had a plastic behavior at more than $400^{\circ}C$ on the cyclic loading and revealed a same tendency in both monotonous and cyclic loading of all heating temperatures. In addition, through TG/DTA and SEM images analyses compared with those from previous studies, it was shown that the deterioration of concrete inner tissue, water evaporation and chemical reaction caused the decrease of residual compressive strength and modulus of elasticity.

Driving Properties of Diesel Injection System using the Multilayer Actuator Structured-ultrasonic Nozzle (적층액츄에이터형 초음파 노즐을 이용한 경유분사 시스템의 구동특성)

  • Kim, Do-Hyung;Kim, Hwa-Soo;Kang, Jin-Hee;Lee, Yu-Hyong;Hwang, Lark-Hoon;Yoo, Ju-Hyun;Hong, Jae-Il
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.174-174
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    • 2008
  • 초음파를 이용하여 액체 연료를 분사하면 균일한 입경과 미립화가 우수하며 에너지 절약과 공해방지등을 할 수 있다. 또한 유속과 유량에 관계없이 이용할 수 있어 반도체 분야의 웨이퍼와 평판 표시기상에 사진 석판용 화학물질의 균일도포 컴퓨터 하드 디스크의 광택제 도포등에 사용할 수 있다. 이처럼 초저의 유출 용량을 요구하는 모든 공정 및 액체연료의 분사가 요구되는 모든 산업에 적용할 수 있는 장점을 가지고 있다. 하지만 현제까지 주로 사용되고 있는 초음파노즐의 액츄에이터는 단판액츄에이터형로 높은 교류전압을 인가해주어야 하는 단점을 가지고 있다. 이 단점을 해결하기 위해 적층액츄에이터형을 사용하여 초음파 노즐 구동하면 낮은 교류 입력전압에서도 단판액츄에이터형 초음파 노즐과 같은 특성을 가질 수 있다. 또한 초음파 노즐의 구동시 기계적인 진동을 이용하므로 많은 열을 발생시켜 노즐의 온도가 상승하여 세라믹 액츄에이터에도 그 영향을 미치게 되어 열적 열화 현상이 일어날 수 있기에 높은 큐리온도를 가지는 액츄에이터가 필요하다. 본 실험에서는 $Pb(Mn_{1/3}Nb_{2/3})_{0.02}(Ni_{1/3}Nb_{2/3})_{0.12}(Zr_{0.50}Ti_{0.50})_{0.86}O_3$ 조성을 사용하여 $900^{\circ}C$의 저온에서 액상 소결하여 적층혈액츄에이터를 제작하였으며 압전 및 유전 특성을 조사하였다. 제작된 초음파노즐을 구동하기 위해서는 약 36kHz의 30V이상의 교류입력전압 할 수 있는 구동회로가 필요로 한다. 압전액츄에이터의 구동을 위해서는 정확한 정현파 입력이 필요 없다. 압전액츄에이터의 특성상 유사 정현파 입력 만으로도 임피던스 매칭이 이루어지기 때문에 설계가 쉽고 간편한 Push-Pull 방식을 이용한 PWM인버터를 사용하였고 인버터의 출력 주파수를 34~38kHz까지 가변 할 수 있게 설계하였다. 제작된 적층액츄에이터형 초음파 노즐을 PWM인버터로 실제 액체 연료인 경유를 분사하였을 때의 액츄에이터의 온도 변화에 따른 공진주파수와 온도 의존성, 전기적 특성을 조사하고 미립화 분사되는 경유의 미립자 크기 및 최대 분사량을 조사 하였다.

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Preparation and Heating Characteristics of N-doped Graphite Fiber as a Heating Element (질소가 도핑 된 흑연섬유 발열체의 제조 및 발열특성)

  • Kim, Min-Ji;Lee, Kyeong Min;Lee, Sangmin;Yeo, Sang Young;Choi, Suk Soon;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.80-86
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    • 2017
  • In this study, nitrogen functional groups were introduced on graphite fiber (GF) to modify their electrical properties, and heating properties were investigated according to the treatment conditions. GF was prepared by a thermal solid-state reaction at $200^{\circ}C$ for 2 h. Surface properties of the nitrogen doped GF were examined by XPS, and its resistance and heating temperature were measured using a programmable electrometer and thermo-graphic camera, respectively. The XPS result showed that the nitrogen functional groups on the GF surface were increased with increasing of urea contents, and the heating property of the GF was also improved as nitrogen functional groups were introduced. The maximum heating temperature of GF treated by urea was $53.8^{\circ}C$ at 60 V, which showed 55% improved heating characteristics compared to that of non-treated GF. We ascribe this effect to introduced nitrogen functional groups on the GF surface by thermal solid-state reaction, which significantly affects the heating characteristics of GF.

A Study on the Thermal Characteristics of a Coupler to Improve the Performance of Electrodeless Lamp (무전극 램프의 성능 향상을 위한 커플러의 열특성 연구)

  • Lee, Kye-Seung;Lee, Jae-Min
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.10 no.6
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    • pp.487-495
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    • 2017
  • The thermal characteristics of the electrodeless lamp are one of the main factors that determine the design and performance of the lamp. The coupler changes the impedance characteristic by heat and its use temperature is usually within about $150^{\circ}C$. In this study, we observed the phenomenon when the coupler was exposed at a temperature of $150^{\circ}C$ or higher, which has not been discussed so far. Two types of coupler A and coupler B with different spacing between the inner tube and the coupler were analyzed for electrical, thermal and optical properties and deterioration characteristics with different heat and heat shielding conditions. First, the impedance of the system is obtained and used as a criterion for analyzing the electrical characteristics through it. The diameters of the two types of couplers are 1 mm, and the experimental result shows that the coupler diameter is 1 mm, which can cancel out the loss of the magnetic field strength. Therefore, based on these results, when the coupler is exposed to high temperature of about $200^{\circ}C$, the efficient design method corresponding thereto is proposed.