• Proceedings of the KIPE Conference
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• 2015.07a
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• pp.381-382
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• 2015

배터리의 열역학적 인자, 즉, 엔탈피, 엔트로피, 깁스 자유 에너지는 배터리의 상태인 SOH (State Of Health)를 추정하는 데 있어서 매우 밀접한 관련이 있으며, 정밀한 측정을 필요로 한다. 이러한 열역학적 인자 중 엔트로피의 측정이 중요한데 ETM (Electrochemical thermodynamics measurements) 방법이 대표적으로 사용되고 있다. 본 논문에서는 기존 ETM 방법을 설명하고, 이를 보완한 새로운 엔트로피 측정 방법을 제안하며, 실험을 통해 유효성을 입증한다.

• Journal of the Korean Chemical Society
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• v.54 no.1
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• pp.125-130
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• 2010

In the present work, we have investigated the adsorption efficiency of carbon/iron oxide nanocomposite towards removal of hazardous brilliant green (BG) from aqueous solutions. Carbon/iron oxide nanocomposite was prepared by chemical precipitation and thermal treatment of carbon with ferric nitrate at $750^{\circ}C$. The resulting material was thoroughly characterized by TEM, XRD and TGA. The adsorption studies of BG onto nanocomposite were performed using kinetic and thermodynamic parameters. The adsorption kinetics shows that pseudo-second-order rate equation was fitted better than pseudo-first-order rate equation. The experimental data were analyzed by the Langmuir and Freundlich adsorption isotherms. Equilibrium data was fitted well to the Langmuir model with maximum monolayer adsorption capacity of 64.1 mg/g. The thermodynamic parameters were also deduced for the adsorption of BG onto nanocomposite and the adsorption was found to be spontaneous and endothermic.

• Journal of the korean Society of Automotive Engineers
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• v.13 no.1
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• pp.9-14
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• 1991

디젤 기관의 출력 성능을 향상시키기 위하여 실린더 내로 흡입되는 공기를 적극적인 방법으로 밀도가 높은 공기로 압입시키는 과급기는 디젤기관의 종합 성능을 결정하는 중요한 인자가 되고 있다. 이와 같은 관점에서 터보 과급기의 성능을 규명하고 과급기의 특성에 관한 사항을 열역학적 해석과 압축기 및 터빈의 성능 특성을 살펴보기로 한다. 여기서는 주로 과급기의 성능 특성을 중심으로 다루기로 한다.

• Journal of the Korean Society of Propulsion Engineers
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• v.26 no.5
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• pp.24-34
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• 2022

In order to predict the cooling performance of a regenerative cooling channel using hydrocarbon fuel operating in the supercritical region, it is essential to predict the thermodynamic properties. In this study, a comparative analysis was performed on two-parameter equations of state (SRK(Soave-Redlich-Kwong), PR(Peng-Robinson) equations of state) and three-parameter equations of state (RK-PR equations of state) to appropriately predict density and specific heat according to the critical compressibility factor of polymer hydrocarbons. Representatively, n-dodecane fuel with low critical compressibility factor and JP-10 fuel with high critical compressibility factor were selected, and an appropriate equation of state was presented when predicting the thermodynamic properties of the two fuels. Finally, the prediction results of density and specific heat were compared and verified with NIST REFPROP data.

• Journal of the Korean earth science society
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• v.25 no.2
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• pp.87-93
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• 2004

To study the effect of cloud on the variabilities of turbulent fluxes over the flat terrain, we used the gradient method to analyze the dynamic and thermodynamic data from the meteorological 9-m mast (0.75, 3 and 9 m) in Villafria airport in Spain. The decrease of the surface wind speed is governed by cooling at the surface following the evening transition. The sensible heat flux and the momentum flux are increased with the dynamic factor rather than the thermodynamic factor, and the sensible heat flux was not affected by the thermal condition. The global radiation did not play an important role in the variation of the sensible heat flux in the cloudy day, but the atmospheric surface layer was characterized rather by the wind intensity.

• Journal of Advanced Marine Engineering and Technology
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• v.40 no.6
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• pp.476-483
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• 2016

An organic Rankine cycle for ocean thermal energy conversion system is a generating cycle using the temperature difference between surface water and deep water of the ocean. The working fluid is an important factor in the thermodynamic performance of an organic Rankine cycle. There is pinch point analysis as thermodynamic analysis of an organic Rankine cycle. This study performed a thermodynamic performance analysis according to variation in the pinch point temperature difference in heat exchangers and variation of outlet temperature of heat source and heat sink. It analyzed the thermodynamic performance by applying seven types of simple working fluids in a simple Rankine cycle for ocean thermal energy conversion that was designed according to pinch point analysis. As a result of the performance analysis, cycle irreversibility and total exergy destruction factor more decreased, and second law efficiency more increased in the lower pinch point temperature difference and temperature variation of heat source and heat sink in heat exchangers. In addition, the irreversibility changed greatly at a point that occurred in the thermodynamic variation. Among the selected working fluids, RE245fa2 showed the best thermodynamic performance, and the performance of all working fluids was observed to be similar. It needs a strict theoretical basis about diverse factors with thermodynamic performances in selecting heat exchangers and working fluids.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.38 no.6
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• pp.596-604
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• 2010

In order to investigate the operating conditions and major design parameters of a dual ramjet propulsion system, an theoretical analysis of ramjet and scramjet propulsion systems was performed. The performance characteristics of each engine are delivered by thermo-dynamical cycle analysis, considering loss effects in a real engine. The performance sensitivity analysis is conducted by investigating various performance parameters, such as an intake efficiency, combustor inlet Mach number, configuration of the combustor, fuel flow rate, and exhaust nozzle efficiency. Based on these analysis results, the processes of application to dual ramjet cycle engines are specified.

• Fire Science and Engineering
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• v.17 no.2
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• pp.43-49
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• 2003

For the inert gases of Ar, $N_2$and $CO_2$, the empirical equations of the gas mixture were correlated in terms of saturated pressure, density and viscosity. They were obtained by regression analysis based on the mixing rule. The empirical equation of saturated pressure was assumed as the first order function of temperature. The empirical form of density was expressed as compressibility factor and saturated pressure while the empirical equation of viscosity was formulated as a power function of temperature. This empirical equations of the physical properties were obtained in the composition of Ar, $N_2$and $CO_2$, 40/50/10(mol. %).

• Journal of the Korean Chemical Society
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• v.35 no.4
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• pp.308-315
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• 1991

The structure and thermodynamic properties of body centered cubic structure of simple Coulombic liquids are computed from the perturbation theory for one-component plasma. A comparison of perturbation theory (PT) and Monte Carlo (MC) simulation shows excellent agreement. The hardsphere perturbation theory is applicable to a long-range attractive system, such as the one-component plasma. A comparison of the radial distribution function (g(r)) and the structure factor (S(q)) for PT data and MC data shows agreement. Thus the perturbation theory is an applicable method to explain the structure and thermodynamic properties of Coulomb liquids.

• Proceedings of the Korea Water Resources Association Conference
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• 2006.05a
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• pp.1716-1720
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• 2006

침투는 지반이 충적토로 구성되어 있는 제방의 파괴를 야기하는 중요한 원인이다. 침투 해석 수치모형은 제방 침투와 관련된 문제 해석과 방지기법 설계에 있어 매우 유용한 방법이나, 각각의 수치모형은 적용상 한계와 문제점을 내포하고 있다. 실제 지하수 흐름은 간극률, 입자형상 및 크기, 포화도 등과 같은 토질특성, 내부침식과 같은 역학적 특성, 점성과 동결융해 같은 열역학적 특성, 그리고 화학적 특성 등 다양한 인자의 영향을 받는다. 이러한 물리적 인자 이외에도 침투 수치해석은 외력조건, 격자 크기(element size), 그리고 시간 간격(time step interval) 등 입력조건에 영향을 받기 때문에 이들 설정에 대한 검토를 시행하여야 한다. 본 연구에서는 침투 수치모형의 적절한 입력조건 범위를 검토하였으며, 격자크기는 계산시간과 해석결과 등 수치모의의 효율성을 고려하였을 때 홍수위 혹은 제방고의 1/10이하로 결정하면 타당할 것으로 판단된다. 그리고 침투수치모형의 시간 간격은 외력조건을 고려하여 1시간 이내로 설정하는 것이 바람직할 것으로 판단된다. 본 연구결과는 침투해석 수치모의의 유의사항을 검토하여 해석결과에 대한 불확실성과 위험요소를 제거하는데 도움이 될 것으로 판단된다.