• Title/Summary/Keyword: 열싸이클

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Hydrogen Production with High Temperature Solar Heat Thermochemical Cycle using CeO2/ZrO2 Foam Device (CeO2/ZrO2 Foam Device를 이용한 고온 태양열 열화학 싸이클의 수소 생산)

  • Lee, Jin-Gyu;Seo, Tae-Beom
    • Journal of the Korean Solar Energy Society
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    • v.34 no.6
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    • pp.11-18
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    • 2014
  • Two-step water splitting thermochemical cycle with $CeO_2$ foam device was investigated by using a solar simulator composed of 2.5 kW Xe-Arc lamp and mirror reflector. The hydrogen production of $CeO_2$ foam device depending on reaction temperature of Thermal-Reduction step and Water-Decomposition step was analyzed, and the hydrogen production of $CeO_2$ and $NiFe_2O_4/ZrO_2$ foam devices was compared. As a result, the amount of reduced $CeO_2$ considerably varies according to the reaction temperature of Thermal-Reduction step. and hydrogen production was not much when the amount of reduced $CeO_2$ decreased even if the reaction temperature of Water-Decomposition step was high. Therefore, it is very important to keep the reaction temperature of Thermal-Reduction step high in two-step thermochemical cycle with $CeO_2$.

A Study on Locally Drying Underwater Welding (국부건식(물커튼식)수중용접법에 관한 연구)

  • 이규복;황선효;박영조;김종열
    • Journal of Welding and Joining
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    • v.10 no.2
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    • pp.51-62
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    • 1992
  • A torch was designed and fabricated in order to develope the technology of "locally drying underwater welding" by water curtain method. The condition for the formation of the possible local cavity, the mechanical properties and the thermal cycle of welds were investigated in the developed welding equipment compared with in-air welding. The possibility of highly reliable and practical underwater welding was found. The proper local cavity was formed above the water flowrate of 30l/min and CO$_{2}$ gas flowrate of 100l/min. The bead width and penetration depth were increased with increasing welding current. The hardness of weldments is about 160Hv in air welding, but about 210Hv in underwater welding. The elongation and the impact value of underwater weldments are 15% and 6Kg/cm$^{2}$ respectively, which are only half as much as the values of in-air welding. The cooling time in the temperature range from 800.deg.C to 500.deg.C affecting the structure and the hardness of weldments is about 22sec. in air welding while about 10sec. in underwater welding.r welding.

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Effect of Cementitious Composite on the Thermal and Mechanical Properties of Fiber-Reinforced Mortars for Thermal Energy Storage (열에너지 저장을 위한 시멘트 복합재료의 섬유보강 모르타르의 열역학 특성에 관한 영향)

  • Yang, In-Hwan;Kim, Kyoung-Chul;Choi, Young-Cheol
    • Journal of the Korea Concrete Institute
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    • v.28 no.4
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    • pp.395-405
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    • 2016
  • The thermal and mechanical properties of fiber-reinforced mortars for thermal energy storage were investigated in this paper. The effect of the combination of different cementitious composite on the thermal and mechanical characteristics of fiber-reinforced mortars was investigated. Experiments were performed to measure mechanical properties including compressive strength before and after thermal cycling and split tensile strength, and to measure thermal properties including thermal conductivity and specific heat. The results showed that the residual compressive strength of mixtures with OPC and graphite was greatest among the mixtures. Thermal conductivity of mixtures with alumina cement was greater than that of mixtures with OPC, indicating favor of alumina cement for charging and discharging in thermal energy storage system. The addition of zirconium into alumina cement increased specific heat of mixtures. Test results of this study could be used to provide information of material properties for thermal energy storage concrete.

Thermal Characteristics of Concrete Fabricated with Blast Furnace Slag Subjected to Thermal Cycling Condition (고로슬래그 혼입 콘크리트의 고온 조건에서의 열역학 성능)

  • Yang, In-Hwan;Park, Ji-Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.5 no.4
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    • pp.414-420
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    • 2017
  • The thermal characteristics of concrete fabricated with blast furnace slag were investigated in this paper. Test parameters included water-binder ratio and the content of furnace slag. Experimental program were performed to measure mechanical properties including compressive strength and split tensile strength under high-temperature thermal cycling, and to measure thermal properties including thermal conductivity and specific heat. Test results showed that the residual compressive strength of mixtures with blast furnace slag was greater than that of mixture without blast furnace slag. In addition, thermal conductivity of mixtures with blast furnace slag was greater than that of mixtures without blast furnace slag. It indicates that blast furnace slag was favorable for charging and discharging in thermal energy storage system. Test results of this study would be used to design concrete module system of thermal energy storage.

Study of Manufacturing Process and Properties of C/C Composites with Recycled Carbon Fiber Reinforced Plastics (리싸이클 CFRP 적용 C/C 복합재료 제조 및 특성 연구)

  • Kim, Seyoung;Han, In Sub;Bang, Hyung Joon;Kim, Soo-hyun;Seong, Young-Hoon;Lee, Seul Hee
    • Composites Research
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    • v.35 no.4
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    • pp.242-247
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    • 2022
  • This study has a different direction from the existing technology of applying recycled carbon fiber obtained by recycling waste CFRP to CFRP again. A study was conducted to utilize recycled carbon fiber as a raw material for manufacturing a carbon/carbon (C/C) composite material comprising carbon as a matrix. First, it was attempted to recycle a commonly used epoxy resin composite material through a thermal decomposition process. By applying the newly proposed oxidation-inert atmosphere conversion technology to the pyrolysis process, the residual carbon rate of 1~2% was improved to 19%. Through this, the possibility of manufacturing C/C composite materials utilizing epoxy resin was confirmed. However, in the case of carbon obtained by the oxidation-inert atmosphere controlled pyrolysis process, the degree of oxygen bonding is high, so further improvement studies are needed. In addition, short-fiber C/C composite material specimens were prepared through the crushing and disintegrating processes after thermal decomposition of waste CFRP, and the optimum process conditions were derived through the evaluation of mechanical properties.

Evaluation on Reliability of High Temperature Lead-free Solder for Automotive Electronics (자동차 전장 보드용 고온 무연 솔더의 신뢰성 평가)

  • Ko, Yong-Ho;Yoo, Se-Hoon;Lee, Chang-Woo
    • Journal of the Microelectronics and Packaging Society
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    • v.17 no.4
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    • pp.35-40
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    • 2010
  • In this study, the reliability of thermal shock, thermal cycle, and complex vibration test at high temperature were examined for 3 types of lead-free solder alloys, Sn-3.5Ag, Sn-0.7Cu and Sn-5.0Sb. For the reliability test, daisychained BGA chips with ENIG-finished Cu pad was assembled with the three lead-free solders on OSP-finished PCBs. Among the 3 types solder alloys, Sn-3.5Ag solder alloy showed the highest degradation rate of electrical resistance and joint strength. On the other hand, Sn-0.7Cu solder alloy had high stability after the reliability tests.

Ti-50.4 at% Ni 합금의 형상기억특성에 미치는 냉간가공률의 영향

  • Go, Won-Gi;Kim, Jae-Il;Park, Su-Ho;Kim, So-Jin;Kim, Hyeon;Lee, Gi-Yeong
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2012.05a
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    • pp.106.2-106.2
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    • 2012
  • Ti-Ni합금은 CsCl구조의 B2상, monoclinic 구조의 B19'(M)상과 rhombohedral 구조의 R상(R)이 나타난다고 알려져 있고, 이들 상의 변태에 의해 열탄성 마르텐사이트와 응력유기 마르텐사이트에 의한 형상기억효과와 초탄성 효과를 가지고 있다. 또한 Ti-Ni 합금은 우수한 형상기억특성을 가질 뿐만 아니라 생체적합성, 가공성 및 내식성 등이 뛰어나 공업분야 및 생체분야에서 폭 넓게 활용되고 있다. Ti-Ni합금의 형상기억특성은 냉간가공 후 어닐링 처리의 온도와 시간에 따른 matrix 내 Ni의 농도, 석출물의 밀도와 크기, 전위밀도와 전위주위의 응력장에 의해 영향을 받는다고 알려져 있다. 본 연구에서는 Ti-Ni합금의 형상기억 특성 및 변태온도에 미치는 영향을 조사하기 위해 다양한 냉간가공률의 시료를 제작하여 다양한 온도에서 Annealing 처리를 하여 냉간가공률 및 Annealing 온도가 형상기억특성에 미치는 영향을 조사하였다. Ti-50.4 at.% Ni 합금은 진공 아크 용해로에서 용해 하였으며, 용해된 Ingot는 열간단조 및 열간 압출한 후 냉간 인발과 중간온도에서 어닐링을 반복하면서 직경 0.5mm의 선재로 만들었다. 최종적으로 제작한 선재의 냉간가공률은 9.5%, 18.2%, 34.5%, 45% 이었다. 각 시편은 5X10-5torr의 진공으로 석영관에 진공 봉입하여 각각 673K, 723K, 783K에서 1hr 열처리 하였다. 합금의 형상기억특성과 변태온도는 DSC에 의해 조사되었다. DSC 측정 결과, 냉간가공률이 증가함에 따라 마르텐사이트 변태 온도는 감소하였고, 어닐링 온도가 증가함에 따라 마르텐사이트 변태 온도는 증가하였다. 또한 가공률이 증가하여도 R상 변태온도는 큰 변화가 없었고, Annealing온도가 증가함에 따라 R상 변태온도는 감소하였다. 또한, 형상기억특성은 인장시험기를 이용한 정하중 열싸이클 테스트를 이용하여 평가 하였다. 냉간 가공률이 증가함에 따라 안정한 형상기억특성을 나타내었다.

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A study on the fatigue and fracture characteristics of localized nuclear reactor vessel material (국산 원자로용기 재료의 피로 및 파괴특성 연구)

  • Jeong, Sun-Eok
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.21 no.10
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    • pp.1626-1635
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    • 1997
  • It is important to ensure the reliability of the first localized reactor vessel steel. To satisfy with this purpose, a study on the impact/hardness, low cycle fatigue(LCF), crack growth rate(da/dN) and fracture toughness( ) of base material(BM) and weld metal(WM) were performed under room temperature air and corrosion conditions. A summary of the results is as folows : (1) Charpy impact absorbed energy of BM was the highest value, heat affected zoon(HAZ) and the lowest, WM. The hardness of BM was similar to HAZ. (2) Coefficients of Manson equation using the monotonic tensile test data were obtained for the present material. (3) The effects of stress ratio and ambient (120.deg. C and NaCl) condition on da/dN were investigated, da/dN with NaCl condition expressed the highest value. (4) The results of Charpy V-notch impact test had good correlation with $K_{IC}$ characteristics and the lowest curve of $K_{IC}$ for BM was derived, more researches about WM and HAZ are required hereafter.

Long Term Operation and Improvement Reliability for SOFC System (SOFC 시스템의 장시간 운전 및 시스템 신뢰성 향상)

  • YI, YONG;SHIN, SEOCK JAE;PARK, SE JIN;KIM, MIN SOO;KIM, HYUNG JOONG;KIM, JUN HO;KIM, INHWAN;KIM, YONG SU
    • Transactions of the Korean hydrogen and new energy society
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    • v.28 no.5
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    • pp.502-511
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    • 2017
  • Design, manufacture and operate the 700W Solid oxide fuel cell system suitable for housing. Except for BOP not produced domestically, most of the domestic BOPs were applied as much as possible. Finally, the system size was 350 liter. System performance was electric efficiency 44.64%, thermal efficiency 40.99%, total efficiency 85.62% at certificate authority. The system was operated for 4,500 hours, this operation time include automatically system on/off, E-stop for emergency stop, load trip for blackout and inverter error. There were that the system on/off were 26 times. System performance remains intact after system on/off.

Rate Augmentation of Exothermic Hydration in the CaO Packed Bed (CaO 충전층의 수화발열반응 촉진)

  • Chung, Soo-Yull;Kim, Jong-Shik
    • Solar Energy
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    • v.14 no.2
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    • pp.91-101
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    • 1994
  • Heat release characteristics of a CaO packed bed reactor which is used for a chemical heat storage device has been studied. We employed Cu-plate fins to release the heat of reaction of the CaO packed bed inside the reactor fast and effectively. Two-dimensional analysis of unsteady state heat flow inside the bed was performed as a function of time and under various conditions of the Cu-plates. It is noted that the time required to release the heat of reaction with Cu fins is reduced more than twice fast compared to that without Cu fins. That was largely dependent upon the number of Cu-plate, as well.

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