• Title/Summary/Keyword: 열수 반응

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Hydrothermal Behaviors and Long-term Stability of Bentonitic Buffer Material (벤토나이트 완충재의 열수거동 및 장기건전성 연구)

  • Lee, Jae-Owan;Cho, Won-Jin
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.5 no.2
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    • pp.145-154
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    • 2007
  • In hydrothermal reaction tests, smectite-to-illite conversion was identified using a domestic bentonite which is favorably considered as a buffer material, and its dependency on various hydrothermal conditions was investigated. The analysis results of the XRD and Si concentration indicated that the smectite-to-illite conversion was a major process of bentonite alteration under the hydrothermal conditions. The temperature, potassium concentration in solution, and pH were observed to significantly affect the smectite-to illite conversion. A model of conversion reaction rate was suggested to evaluate the long-term stability of smectite composing a major constituent of bentonitic buffer. It was expected from the evaluation results that the smectite would keep its integrity for very long disposal time under a normal condition, whitens it might be converted to illite by 50 percent after over $5{\times}10^4$ year of disposal time under a conservative condition and consequently lose its swelling capacity as a buffer material of a repository.

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Optimization of Production and Antioxidant Effects of Beverage Prepared using Hot-water Extracts of Polygonatum odoratum, Houttuynia cordata, and Lycium chinensis (둥굴레, 어성초, 구기자 혼합 음료의 배합비 최적화 및 항산화 효과)

  • Kang, Min-Kyung;Kim, Il-Chul;Chang, Kyung-Ho
    • Food Science and Preservation
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    • v.17 no.6
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    • pp.835-846
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    • 2010
  • The manufacture of beverages prepared using hot-water extracts of Polygonatum odoratum var. pluriflorum, Houttuynia cordata, and Lycium chinensis was statistically optimized using response surface methodology. The total polyphenol content, electron donation activity, and reducing power of optimized beverages were measured to evaluate antioxidant properties. The coefficients of determination, the $R_2$ values, were 0.9887~0.9957 for color, taste and overall acceptability. Analysis of variance showed that the model fit was a statistically significant (p<0.05). The optimized compositions of processed beverages were: Polygonatum odoratum var. pluriflorum extract, 2.15%; Houttuynia cordata extract, 1.74%; and Lycium chinensis extract, 0.19% (all w/w). Total polyphenol content, electron donation activity, and reducing power of beverages of optimized composition were 3.61 mg/L, 23.78%, and 0.26, respectively.

The High temperature stability limit of talc, $Mg_3Si_4O_{10}(OH)_2$ (활석 $Mg_3Si_4O_{10}(OH)_2$의 고온 안정영역에 관한 실험적 연구)

  • 조동수;김형식
    • The Journal of the Petrological Society of Korea
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    • v.6 no.2
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    • pp.123-132
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    • 1997
  • In the system $MgO-SiO_2-H_2O$, Talc[$Mg_3Si_4O_{10}(OH)_2$] has been synthesized hydrothermally at 200 MPa, $600^{\circ}C$ from the oxide mixture of the bulk composition of talc. The oxide mixture of the bulk composition of anthophyllite$[Mg_7Si_8O_{22}(OH)2]$ converted to talc, enstatite $(MgSiO_3)$, quartz at 200 MPa, $750^{\circ}C$ with excess of $H_2O$. In low to medium pressure metramorphism, enstatite-talc assemblage is metastable relative to anthophyllite with the reaction talc + 4 enstatite=anthophyllite (Greenwood, 1963). The high temperature stability of talc is bounded with the dehydration reaction to anthophyllite rather than that to enstatite(Greenwood, 1963; Chernosky et al., 1985). Therefore our experiment result assemblage, enstatite-talc-quatz at 200 MPa, $750^{\circ}C$ from oxide mixture of bulk compostion of anthophyllite is metastable assemblage. The hydrothermal experiment performed at 41 to 243 MPa, 680 to $760^{\circ}C$ with the starting material composed of synthetic talc, enstatite and quartz. Talc or enstatite grows during the runs and no extra phases including anthophyllite nucleated. Based on the increase or decrease of the each phase from run products, one of the possible reactions is talc=3 enstatite+quartz+H_2O$. The reversal bracket of the reaction is 699 to $700^{\circ}C$ at 100 MPa. Talc is stable up to $740^{\circ}C$ at 200 MPa and enstatite grow at $680^{\circ}C$, 40 MPa and at $760^{\circ}C$, 250 MPa. Though the high temperature limit of talc around 200 MPa is bounded thermodynamically by the reaction, 7 talc=3 anthophyllite+4 quartz+4 H_2O$, talc persisted throughout the previous reaction up to the reaction, talc=3 enstatite+quartz+$H_2O$.

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Antioxidant Activities of Hot Water Extract from Cornus walteri Wanger against Oxidative Stress Induced by tert-Butyl Hydroperoxide in HepG2 Cells (tert-Butyl Hydroperoxide로 산화 스트레스가 유도된 HepG2 세포에서 말채나무 열수추출물의 항산화 활성)

  • Yeon, Seong Ho;Ham, Hyeonmi;Sung, Jeehye;Kim, Younghwa;Namkoong, Seulgi;Jeong, Heon-Sang;Lee, Junsoo
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.42 no.10
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    • pp.1525-1532
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    • 2013
  • The objective of this study was to investigate the effect of hot water extract from Cornus walteri Wanger (CWE) on tert-butyl hydroperoxide (TBHP)-induced oxidative stress in HepG2 cells. Generation of reactive oxygen species (ROS), concentrations of cellular lipid peroxidation products and reduced glutathione, and antioxidant enzyme activity were used as biomakers of cellular oxidative status. Cells pretreated with CWE (25~200 ${\mu}g/mL$) showed an increased resistance to oxidative stress in a dose-dependent manner, as revealed by a higher percentage of surviving cells compared to control cells. ROS generation induced by TBHP was significantly reduced when cells were pretreated with 200 ${\mu}g/mL$ CWE for 4 h. Pretreatment with CWE (5~50 ${\mu}g/mL$) prevented the decrease in reduced glutathione and the increase in malondialdehyde and ROS evoked by TBHP in HepG2 cells. Finally, CWE pretreatments prevented the significant increase of glutathione peroxidase, catalase, glutathione reductase, and superoxide dismutase activities induced by TBHP. These results show that CWE has significant protective ability against a TBHP-induced oxidative insult and that the modulation of antioxidant enzymes by CWE may have an important antioxidant effect on TBHP-induced oxidative stress in HepG2 cells.

Quality Characteristics and Reduced Sugar Conditions of Yanggaeng Prepared with Steamed Liriopis Tuber Extract Using Response Surface Methodology (반응표면분석법을 이용한 증숙 맥문동 첨가 양갱의 품질 특성 및 당류 저감화 조건 연구)

  • Park, Chanyoung;Park, So Hae;Kim, Won Baek;Hwang, Ji Hoe;Lee, Heeseob
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.2
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    • pp.229-236
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    • 2017
  • This study was performed to optimize yanggaeng processing conditions prepared with different amounts of steamed Liriopis tuber (SLT) extract, sugar, and agar powder using response surface methodology. The experimental conditions were designed according to the central composite design with 16 experimental points, including two replicates for three independent variables. The experimental data on physicochemical properties, textural properties, and sensory evaluation were fitted to various models, and the accuracy of the equations was analyzed by ANOVA. Among the responses, pH, water content, sugar content, L-value, browning index, chewiness, gumminess, and sensory properties of appearance, color, sweetness, hardness, texture, and overall acceptability showed significant correlation with contents of SLT, sugar, and agar powder. From these results, optimum formulation of yanggaeng was calculated as follows: SLT 35 mL, sugar 55.23 g, and agar powder 3.39 g.

Changes of Physicochemical Characteristics of Acanthopanax senticosus Extract during Storage (오가피 추출액의 저장조건에 따른 이화학적 특성변화)

  • Chung Hun-Sik;Youn Kwang-Sup
    • Food Science and Preservation
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    • v.12 no.3
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    • pp.204-208
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    • 2005
  • This study was conducted to investigate the effects of temperature and packaging on the quality characteristics of hot-water extract from Acanthopanax senticosus. The herb samples, ground and sifted($8{\sim}20$ mesh), were extracted by a boiling($100^{\circ}C$) water under the atmospheric pressure for 2 hrs. The extract was packed with out nylon PE(0.08 mm) pouch and kept under the condition(40 and $60^{\circ}C$) for 10 days. The reduction of turbidity, pH, polyphenol amount and DPPH radical scavenging activity of extract were retarded by packaging under the low temperature. Titratable acidity was increased with packaging at high temperature. Soluble solid content was not affected by packaging and temperature condition. The changes of quality characteristics followed the first-order reaction rate. Arrhenius equation was applied to determine the effects of temperature on the reaction rate constant, showing high $R^2$. These results suggested that packaging under lower temperature can be utilized for maintaining the quality of A senticosus extract.

Inhibitory Activity of Advanced Glycation Endproducts (AGE) Formation of Edible Plants for Development of Anti-Wrinkle Ingredients (피부 주름개선 소재개발을 위한 식용작물의 최종당화산물 생성 억제활성)

  • Lee, Hyun-Sun;Yoon, Jin-A
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.39 no.2
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    • pp.186-192
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    • 2010
  • Skin wrinkles typically appear as a result of aging processes. One of causes may be the nonenzymatic glycation followed formation of browning products called advanced glycation endproducts (AGEs), an irreversible cross-linked protein. The accumulation of glycated collagen cross-linked in skin inhibits the formation and function of skin tightening agents such as collagen and elastin. To development for anti-wrinkle ingredients from edible plants, MeOH and hot-water extracts were prepared and evaluated for their inhibitory effects of AGEs formation. The activities of both extracts from bay laurel (Laurus nobilis), cinnamon (Cinnamomum loureirii), clove (Eugenia caryophyllate), oregano (Origanum vulgare), rosemary (Rosemarinus officinalis), savory (Satureja hortensis) and star anis (Illicium verum) of western spices, and blackberry (Rubus coreanus), dayflower (Commelina communis), Epimedium koreamun (whole), termunalia frutus (Terminalia chebula) and turkestan rose (Rosa rugosa) of medicinal plants were higher than the others. Of Korean vegetables, however, MeOH and hot-water extract from only Asters caber and green tea showed higher activities, and no activity in Korean marine plants (seaweeds).

Growth and Yield Response of Corn Hybrids with Different Canopy Types to Planting Density (옥수수 초형별 재식밀도에 따른 생육 및 수량반응)

  • 이명훈
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.39 no.4
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    • pp.353-358
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    • 1994
  • Grain yields of errect-leaved corn hybrids were reported to be increased as planting density(PD) increased compared to those of horizontal leaf type hybrids. This trial was conducted to investigate the difference between errect and horizontal-leaved hybrids in response to different PD. Grain yields of both type hybrids were decreased at the highest PD, however, that of horizontal-leaved hybrid, Ga209 ${\times}$ Ki14A, was decreased more than errect-leaved hybrids which indicated varietal difference in response to PD. Responses to PD for days to tasseling, plant height, ear height, and leaf angle were not significant, also, PD ${\times}$ hybrid interactions were not observed. Yield components were decreased as PD increased and there were no PD ${\times}$ hybrid interactions for these characters. Leaf angle was negatively correlated with grain yield and yield components except for kernel weight.

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Anti-Inflammatory and Anti-Oxidative Effect of Pinus koraiensis Cone Shell Extracts (잣피 추출물들의 항산화 및 항염증에 미치는 영향)

  • Jin, Joong Hyun;Kwon, Han Ol;Ha, Yejin;Heo, Seok Hyun;Lee, Jeongmin
    • Journal of the Korean Society of Food Science and Nutrition
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    • v.46 no.9
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    • pp.1053-1060
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    • 2017
  • The present study examined the anti-inflammatory and anti-oxidative effects of Pinus koraiensis (PK) cone shell extracts in vitro. Anti-inflammatory and anti-oxidative effects of PK cone shell extracted with hot water, 20% ethanol (EtOH), or 50% EtOH were examined using 2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid) (ABTS) radical scavenging assay, superoxide dismutase (SOD), catalase (CAT), and glutathione peroxidase (GPx) activites, as well as nitric oxide (NO) and anti-inflammatory cytokine measurements. The 20% EtOH extract of the PK cone shell decreased the NO and inflammatory cytokines secretion, and increased the ABTS radical scavenging, SOD, CAT, and GPx activities. This indicates that the 20% EtOH extract of the PK cone shell would be helpful in inflammation and oxidation systems. Therefore, the 20% EtOH extract of PK cone shell has great potential as a useful health food.

Magnetism of Ferric Iron Oxide and Its Significance in Martian Lithosphere (화성 암권의 진화해석을 위한 예비연구: 3가철 산화물의 자화특성)

  • Jeong, Doo-Hee;Yu, Yong-Jae
    • Journal of the Mineralogical Society of Korea
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    • v.24 no.3
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    • pp.189-194
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    • 2011
  • Martian satellite missions indicate that Martian equatorial plains are covered by ferric iron oxide. As a non-destructive technique, low-temperature treatment of remanent magnetization is effective in identifying magnetic minerals in rocks. In the present study, four sets of ferric iron oxides were prepared by aqueous alteration of ferrihydrite at warm conditions and four others by dehydration of goethite. As the amount of aluminous trivalent cations increases, crystallographic lattice parameters and N$\acute{e}$el temperatures decrease. Such declines originate from lattice distortion as the smaller aluminous trivalent cations substitue the larger terric irons. Whilst high remanence memory was observed for aqueously produced ferric iron oxide, low remanence memory was observed for dehydrated ferric iron oxide. In the future. magnetic remanence memory would be powerful in diagnosing the origin of ferric iron oxide.