• Title/Summary/Keyword: 열분석적 특성

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Amorphous-to-crystalline phase-change properties of $(Ag_{5.5}In_{6.5}Sb_{59}Te_{29})_{1-x}(Ag)_x$ (x = 0, 0.1, 0.2) thin films ($(Ag_{5.5}In_{6.5}Sb_{59}Te_{29})_{1-x}(Ag)_x$ (x = 0, 0.1, 0.2) 박막의 비정질-결정질 상변화 특성)

  • Seo, Jae-Hee;Kim, Sung-Won;Lee, Hyun-Yong
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.229-230
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    • 2008
  • 본 논문에서는 비정질-결정질간 가역적 상변화 기록 매질로 이용되고 있는 $(Ag_{5.5}In_{6.5}Sb_{59}Te_{29})$ 합금 박막의 Ag 조성 증가에 따른 원자구조와 상변화 특성간의 상관관계를 연구하였다. 실험에 사용된 AgInSbTe 조성은 5N의 금속 파우더를 용융-냉각법으로 벌크를 제작하였고 열증착 방법으로 Si (100) 및 유리(corning glass, 7059) 기판위에 200 nm 두께로 박막을 증착하였다. 비정질 박막의 결정화속도를 평가하기 위해서 658 nm의 LD가 장착된 나노-펄스 스캐너를 이용하여 power; 1~17mW, pulse duration; 10~460 ns의 범위에서 각 조성의 상변화에 따른 반사도 차이를 측정, 비교 분석하였다. 또한 각각의 박막을 $100^{\circ}C$ 에서 $300^{\circ}C$까지 $50^{\circ}C$ 간격으로 $N_2$ 분위기에서 1시간동안 열처리 한 후 XRD와 UV-Vis-NIR spectrophotometer를 사용하여 각 상의 구조분석 및 광학적 특성을 분석하였으며, 4-point probe로 면저항을 측정하였다.

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A Study on Pyrolytic and Anatomical Characteristics of Korean Softwood and Hardwood (국산 침·활엽수재의 열분해 및 해부학적 특성에 관한 연구)

  • Kim, Dae-Young;Kang, Sung-Ho;Jeong, Heon-young
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.6
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    • pp.31-42
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    • 2007
  • To investigate the pyrolytic and anatomical characteristics of Korean softwood, Pinus densi-flora, Pinus rigida and Larix leptolepis, and hardwood, Acer palntatum, Fraxinus rhynchophylla and Quercus variabilis, chemical components analysis, TG-DTA (Thermogravimetric Analysis & Differential Thermal Analysis), MBA (Methylene Blue Adsorption) test and SEM observation were carried out. For TG-DTA, samples were carbonized up to $800^{\circ}C$ at the heating rate of $10^{\circ}C$/min under $N_2$ flows 1 l/min using thermogravimetric analyzer. Chemical component analysis of all samples resulted in typical contents of major wood component. In TG-DTA results, softwood showed higher char yield than hardwood, and lignin displayed the highest char yield among the major wood components. All samples showed typical TGA, DTG and DTA curves for wood pyrolysis except a few differences between softwood and hardwood. Content of lignin influenced its pyrolysis characteristics, while molecular structure of lignin affected not only the weight loss but also the yield of char. In MBA test results, MBA of softwoods was higher than that of hardwoods. Char of Pinus densiflora showed the highest MBA, but its degree was lower than activated carbon or fine charcoal about 23 and 4 times, respectively. SEM observation showed carbonization process preserves wood structure and retain the micro-structure of wood fibers.

열 화학기상증착법을 이용한 BCN 박막의 합성과 전기적 특성 분석

  • Jeon, Seung-Han;Song, U-Seok;Jeong, Dae-Seong;Cha, Myeong-Jun;Kim, Seong-Hwan;Lee, Su-Il;Park, Jong-Yun
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.255-255
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    • 2013
  • 최근 그래핀 연구와 더불어 2차원 구조의 나노소재에 대한 관심이 급증하면서 육각형의 질화붕소(hexagonal boron nitride; h-BN) 박막(nanosheet)이나 붕소 탄화질화물(boron caronitride; BCN) 박막과 같은 2차원 구조체에 대한 연구가 활발히 진행되고 있다. 그 중 BCN은 반금속(semimetal)인 흑연(graphite)과 절연체인 h-BN이 결합된 박막으로 원소의 구성 비율에 따라 전기적 특성을 제어할 수 있다는 장점이 있다. 따라서 다양한 나노소자로의 응용을 위한 연구가 활발히 진행되고 있다. 본 연구에서는 폴리스틸렌(polystyrene, PS)과 보레인 암모니아(borane ammonia)를 고체 소스로 이용하여 열화학 기상증착법을 이용하여 BCN 박막를 SiO2 기판 위에 직접 합성하였다. SEM과 AFM 관측을 통해 합성된 BCN 박막을 확인하였으며, RMS roughness가 0.5~2.6 nm로 매우 낮은 것을 확인하였다. 합성과정에서 PS의 양을 조절하여 BCN 박막의 탄소의 밀도를 성공적으로 제어하였으며, 이에 따라 전기적인 특성이 제어되는 양상을 확인하였다. 또한 합성온도 변화에 따른 BCN 박막의 전기적인 특성이 제어되는 양상을 확인하였다. 추가적으로 같은 방법을 이용하여 BCN 박막을 Ni 위에서 합성하여 SiO2 기판위에 전사 하였다. 합성된 BCN 박막의 구조적 특징과 화학적 조성 및 결합 상태를 투과전자현미경(transmission electron microscopy), X-선 광전자 분광법(X-ray photoelectron spectroscopy)을 통해 조사하였다.

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Analysis of dried Asian lacquer by pyrolysis/GC/MS (열분해/GC/MS에 의한 한국산 건조 옻 분석)

  • Park, Jongseo;Ahn, Sun Ah
    • Analytical Science and Technology
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    • v.31 no.2
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    • pp.78-87
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    • 2018
  • Asian lacquer has been used as an adhesive and coating material in Asian countries, such as China, Japan, and Korea, and other southeast Asian countries. In this study, the changes in the chemical structure of lacquer with drying was analyzed using pyrolysis/GC/MS (which is useful in analyzing polymeric material) to understand its drying procedures. Upon increasing temperature, the dried lacquer was fully pyrolyzed above the pyrolysis temperature of $500^{\circ}C$. The repeatability was good at the pyrolysis temperature of $500^{\circ}C$ (rsd = 2.6-22.3 %); however, there were differences in the pyrogram patterns when the difference in sample quantity was large. The characteristic peaks of Asian lacquer components, such as those corresponding to 1,2-benzenediol and 3-methyl-1,2-benzenediol, were detected and the compound of each peak was assigned according to the mass library. As the lacquer dried, the composition of pyrolysis products with urushiol derivatives bearing 3 C=C bonds was severely reduced compared with the ones with no C=C bonds, indicating that the polymerization is related to C=C bonds. These results can be applied to confirm the presence of lacquer in excavated relics and to monitor the changes in the composition of raw lacquer with drying.

A Study on Management Issues Based on User Attitudes of Electronic Academic Journals (전자학술저널의 이용행태 분석에 의한 관리방안 연구)

  • Jeong Dong-Youl
    • Journal of the Korean Society for Library and Information Science
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    • v.33 no.3
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    • pp.5-21
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    • 1999
  • This study assesses user attitudes towards electronic academic journals and suggests management issues for users and information managers. To reveal academic scholars' user attitudes, this paper is an attempt to survey the concepts of electronic journals, thoughts, perceptions and experiences of a sample of university faculty. Based upon various aspects of user attitudes, this study derives effective management techniques for electronic academic journals in library and information center.

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Evaluation of satellite precipitation prediction using ConvLSTM (ConvLSTM을 이용한 위성 강수 예측 평가)

  • Jung, Sung Ho;Le, Xuan-Hien;Nguyen, Van-Giang;Choi, Chan Ul;Lee, Gi Ha
    • Proceedings of the Korea Water Resources Association Conference
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    • 2022.05a
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    • pp.62-62
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    • 2022
  • 홍수 예보를 위한 강우-유출 분석에서 정확한 예측 강우량 정보는 매우 중요한 인자이다. 이에 따라 강우 예측을 위하여 다양한 연구들이 수행되고 있지만 시·공간적으로 비균일한 특성 또는 변동성을 가진 강우를 정확하게 예측하는 것은 여전히 난제이다. 본 연구에서는 딥러닝 기반 ConvLSTM (Convolutinal Long Short-Term Memory) 모형을 사용하여 위성 강수 자료의 단기 예측을 수행하고 그 정확성을 분석하고자 한다. 대상유역은 메콩강 유역이며, 유역 면적이 넓고 강우 관측소의 밀도가 낮아 시·공간적 강우량 추정에 한계가 있으므로 정확한 강우-유출 분석을 위하여 위성 강수 자료의 활용이 요구된다. 현재 TRMM, GSMaP, PERSIANN 등 많은 위성 강수 자료들이 제공되고 있으며, 우선적으로 ConvLSTM 모형의 강수 예측 활용가능성 평가를 위한 입력자료로 가장 보편적으로 활용되는 TRMM_3B42 자료를 선정하였다. 해당 자료의 특성으로 공간해상도는 0.25°, 시간해상도는 일자료이며, 2001년부터 2015년의 자료를 수집하였다. 모형의 평가를 위하여 2001년부터 2013년 자료는 학습, 2014년 자료는 검증, 2015년 자료는 예측에 사용하였다. 또한 민감도 분석을 통하여 ConvLSTM 모형의 최적 매개변수를 추정하고 이를 기반으로 선행시간(lead time) 1일, 2일, 3일의 위성 강수 예측을 수행하였다. 그 결과 선행시간이 길어질수록 그 오차는 증가하지만, 전반적으로 3가지 선행시간 모두 자료의 강수량뿐만 아니라 공간적 분포까지 우수하게 예측되었다. 따라서 2차원 시계열 자료의 특성을 기억하고 이를 예측에 반영할 수 있는 ConvLSTM 모형은 메콩강과 같은 미계측 대유역에서의 안정적인 예측 강수량 정보를 제공할 수 있으며 홍수 예보를 위한 강우-유출 분석에 활용이 가능할 것으로 판단된다.

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Effects of Hydrological Condition on the Coupled Thermal-Hydrological-Mechanical Behavior of Rock Mass Surrounding Cavern Thermal Energy Storage (암반 공동 열에너지저장소 주변 암반의 수리적 조건에 따른 열-수리-역학적 연계거동 분석)

  • Park, Jung-Wook;Rutqvist, Jonny;Lee, Hang Bok;Ryu, Dongwoo;Synn, Joong-Ho;Park, Eui-Seob
    • Tunnel and Underground Space
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    • v.25 no.2
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    • pp.168-185
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    • 2015
  • The thermal-hydrological-mechanical (T-H-M) behavior of rock mass surrounding a large-scale high-temperature cavern thermal energy storage (CTES) at a shallow depth has been investigated, and the effects of hydrological conditions such as water table and rock permeability on the behavior have been examined. The liquid saturation of ground water around a storage cavern may have a small impact on the overall heat transfer and mechanical behavior of surrounding rock mass for a relatively low rock permeability of $10^{-17}m^2$. In terms of the distributions of temperature, stress and displacement of the surrounding rock mass, the results expected from the simulation with the cavern below the water table were almost identical to that obtained from the simulation with the cavern in the unsaturated zone. The heat transfer in the rock mass with reasonable permeability ${\leq}10^{-15}m^2$ was dominated by the conduction. In the simulation with rock permeability of $10^{-12}m^2$, however, the convective heat transfer by ground-water was dominant, accompanying the upward heat flow to near-ground surface. The temperature and pressure around a storage cavern showed different distributions according to the rock permeability, as a result of the complex coupled processes such as the heat transfer by multi-phase flow and the evaporation of ground-water.

Degradation characteristics of the FRP material for using as a PCB substrate (PCB 기판용 FRP 재료의 열화특성)

  • Park Jong Kwan
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.41 no.12
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    • pp.1-6
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    • 2004
  • In this study, heat and discharge treatments are arbitrary simulated for finding out the initiations and processes of surface degradation on the surface of polymer for using as a PCB substrate. Thermal-treatment changed the surface to the hydrophobic one with the increase of contact angle and surface potential decay, respectively. The XPS spectrum showed that the increased hydrophobicity in thermal treatment was originated from the continuous decrease of side-chains caused by secessions of oxygen groups and the increase of unsaturated double bond in carbon chains. Also, thermal-treatment caused the discoloration on the point of treated surface. These phenomena were attributed to the generation of ether group. In the chemical change by discharge treatment, a lot of side-chains occurred on the treated surface, and so the hydrophilicity increased as time elapsed.

Behavior Analysis in Love Model with applying Conscious and Nonconscious (사랑 모델에서 의식과 무의식을 적용한 거동 분석)

  • Shon, Young-Woo;Lee, Jeong-Gu;Bae, Young-Chul
    • The Journal of the Korea institute of electronic communication sciences
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    • v.11 no.5
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    • pp.523-530
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    • 2016
  • Human mind can be divided by conscious and nonconscious. The action that can be seen by eyes express of conscious world, but brain researchers tell us that the world of nonconscious more occupied than world of conscious. In this paper, we divide conscious and nonconscious of world in basic love model of Romeo and Juliet, and then we represent complex number for the conscious and nonconscious. We also display as time series and phase plane for their behavior. Finally, we confirms the existence of nonlinear characteristics in their behavior.

Flame detection algorithm using adaptive threshold in thermal video (적응 문턱치를 이용한 열영상 화염 검출 알고리즘)

  • Jeong, Soo-Young;Kim, Won-Ho
    • Journal of Satellite, Information and Communications
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    • v.9 no.4
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    • pp.91-96
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    • 2014
  • This paper proposed an adaptive threshold method for detecting flame candidate regions in a infrared image and it adapts according to the contrast and intensity changes in the image. Conventional flame detection systems uses fixed threshold method since surveillance environment does not change, once the system installed. But it needs a adaptive threshold method as requirements of surveillance system has changed. The proposed adaptive threshold algorithm uses the dynamic behavior of flame as featured parameter. The test result is analysed by comparing test result of proposed adaptive threshold algorithm and conventional fixed threshold method. The analysed data shows, the proposed method has 91.42% of correct detection rate and false detection is reduced by 20% comparing to the conventional method.