• Title/Summary/Keyword: 열분석적 특성

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Temporal and Spatial Variations in Sea Surface Temperature Around Boryeong off the West Coast of Korea From 2011-2012 (2011-2012년 서해 보령연안 수온의 시공간적 변동)

  • Choo, Hyo-Sang;Yoon, Eun-Chan
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.23 no.5
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    • pp.497-512
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    • 2017
  • Temporal and spatial variations in surface water temperature were studied using data from temperature monitoring buoys deployed at 47 stations around Boryeong from 2011-2012 off the west coast of Korea. Temperature fluctuations are predominant at diurnal and semidiurnal periods for all seasons, and their amplitudes are large in spring and summer but small in autumn. The maximum annual change in air temperature takes place on August 2nd and August 22th for water temperature, which means the phase for air temperature precedes water temperature by 20 days. The diurnal period of water temperature fluctuation is predominant around Daecheon and Muchangpo Harbors, with the semidiurnal period around Wonsan Island, and the shallow water constituent period on the estuary around Daecheon River. On the whole, air and water temperatures fluctuate with wind. Spectral analyses of temperature records show significant peaks at the 0.5, 1 and 15 day marks with 7-10 day periods of predominant fluctuations. Cross-correlation analyses for the temperature fluctuation show that the waters around Boryeong can be classified into four areas: a mixed water zone around the southeast side of Wonsan Island, an off-shore area to the west, an off-shore area to the south and a coastal area along the shore from Song Island to Muchangpo Harbor.

Synthesis of Lithium Manganese Oxide by a Sol-Gel Method and Its Electrochemical Behaviors (졸-겔 방법에 의한 LiMn2O4의 합성 및 전기화학적 거동)

  • Jeong, Euh-Duck;Moon, Sung-Wook;Lee, Hak-Myoung;Won, Mi-Sook;Yoon, Jang-Hee;Park, Deog-Su;Shim, Yoon-Bo
    • Journal of the Korean Electrochemical Society
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    • v.6 no.4
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    • pp.229-235
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    • 2003
  • A precursor of lithium manganese oxide was synthesized by mixing $(CH_3)_2CHOLi\;with\;Mn(CH_3COO)_2{\cdot}4H_2O$ in ethanol using a sol-gel method, then heat-treated at $400^{\circ}C\;and\;800^{\circ}C$ in air atmosphere. The condition of heat treatment was determined by thermogravimetric analysis/differential thermogravimetric analysis (TGA/DTA). The characterization of the lithium manganese oxide was done by X-ray diffraction (XRD) spectra and scanning electron microscopy (SEM). The electrochemical characteristics of lithium manganese oxide electrode for lithium ion battery were measured by cyclic voltammetry (CV), chronoamperometry and AC impedance method using constant charge/discharge process. The electrochemical behaviors of the electrode have been investigated in a 1.0M $LiClO_4/propylene$ carbonate electrolyte solution. The diffusivity of lithium ions, $D^+\;_{Li}\;^+$, as determined by AC impedance technique was $6.2\times10^{-10}cm^2s^{-1}$.

A study on the fabrication of $Pb(Fe^{0.5},Nb^{0.5}O_3$ thin films by a Co-sputtering technique and their characteristics properties (동시 스퍼터링법에 의한$Pb(Fe^{0.5},Nb^{0.5}O_3$박막의 제조 및 특성 평가에 대한 연구)

  • 이상욱;신동석;최인훈
    • Journal of the Korean Vacuum Society
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    • v.7 no.1
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    • pp.17-23
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    • 1998
  • $Pb(Fe_{0.5}Nb_{0.5}O_3(PFN)$ thin films were prepared by rf magnetron co-sputtering method on $SiO_2/Si$, ITO/glass, and $Pt/Ti/SiO_2/Si$ substrates and post-annealed at the $N_2$ atmosphere by RTA(rapid thermal annerling). The degree of crystallinity of PFN films was identified on various substrates. Electrical properties of PFN films was characterized for $Pt/PFN/Pt/Ti/SiO_2/Si$ structure. The composition of PFN films was estimated by EPMA (electron probe micro analysis). PFN films would be crystallized better to perovskite phase on ITO/glass substrate than $SiO_2/Si$ substrate. This may be induced by the deformation of Pb deficient pyrochlore phase due to Pb diffusion into $SiO_2/Si$ substrate. PFN films on $Pt/Ti/SiO_2/Si$ substrate. PFN films with 5-10% Pb excess were crystallized to perovskite phase from $500^{\circ}C$ temperature. In summary, we show that Pb composition and annealing temperature were critically influenced on crystallinity to perovskite phase. When PFN film with 17% Pb excess was annealed at $600^{\circ}C$ at the $N_2$ atmosphere for 300kV/cm and 88. Its remnant polarization coercive field $2.0 MC/cm^2$ and 144kV/cm, respectively.

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A Review on Measurement Techniques and Constitutive Models of Suction in Unsaturated Bentonite Buffer (불포화 벤토나이트 완충재의 수분흡입력 측정기술 및 구성모델 고찰)

  • Lee, Jae Owan;Yoon, Seok;Kim, Geon Young
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.17 no.3
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    • pp.329-338
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    • 2019
  • Suction of unsaturated bentonite buffers is a very important input parameter for hydro-mechanical performance assessment and design of an engineered barrier system. This study analyzed suction measurement techniques and constitutive models of unsaturated porous media reported in the literature, and suggested suction measurement techniques and constitutive models suitable for bentonite buffer in an HLW repository. The literature review showed the suction of bentonite buffer to be much higher than that of soil, as measured by total suction including matric suction and osmotic suction. The measurement methods (RH-Cell, RH-Cell/Sensor) using a relative humidity sensor were suitable for suction measurement of the bentonite buffer; the RH-Cell /Sensor method was more preferred in consideration of the temperature change due to radioactive decay heat and measurement time. Various water retention models of bentonite buffers have been proposed through experiments, but the van Genuchten model is mainly used as a constitutive model of hydro-mechanical performance assessment of unsaturated buffers. The water characteristic curve of bentonite buffers showed different tendencies according to bentonite type, dry density, temperature, salinity, sample state and hysteresis. Selection of water retention models and determination of model input parameters should consider the effects of these controlling factors so as to improve overall reliability.

Estimation on Trends of Reference Evapotranspiration of Weather Station Using Reference Evapotranspiration Calculator Software (Reference Evapotranspiration Calculator Software를 이용한 기상관측소 기준증발산 추정)

  • Choi, Wonho;Choi, Minha;Oh, Hyunje;Park, Jooyang
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.30 no.2B
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    • pp.219-231
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    • 2010
  • The Reference Evapotranspiration Calculator Software (REF-ET) supports computational guidelines for the reference evapotranspiration using seventeen FAO Penman-Monteith (PM) equations simultaneously such as the ASCE and FAO standardized forms. The REF-ET can conveniently consider missing data predictions and regional site characterizations, when reference ET is computed on monthly, daily, and hourly time steps. The applicability of the REF-ET was estimated to simulate the reference ET using hourly weather data from Seoul weather station for 29 years. The result found that the FAO24-Rd and 1957-Makk equations closely concerned with solar radiation parameter which were the most highly correlated to reference ET computed by pan coefficient. In addition, the 1957-Makk equation was identified as the most correct computational method for reference ET by analysis of bias and root mean square error. The 1957-Makk equation could predict the reference ET within the error of less than 1.06 mm/day, though all the other equations tended toward overestimation of predicting the reference ET in comparison with refecence ET of pan. The results of this study suggest that the REF-ET will be applicable to support reference ET estimation for a variety of field condition and time-scale.

Spatio-temporal Variations of Marine Environments and Phytoplankton Community in the Gochang Coastal Waters (GCW) of Southern West Sea in Korea (서해 남부, 고창연안해역의 해양환경 및 식물플랑크톤 군집의 시·공간 변동특성)

  • Yoon, Yang Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.11
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    • pp.477-493
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    • 2020
  • This study conducted a seasonal survey to analyze the spatio-temporal variations of marine environments and phytoplankton community in Gochang Coastal Waters (GCW) from August 2016 to April 2017. In the results, the water temperature ranged from 2.1℃ to 34.5℃, showing a large seasonal variation, but the salinity changed from 31.14 psu to 32.64 psu. Therefore, the seasonal variations of water types in GCW were mainly determined by water temperature. The phytoplankton community consisted of 53 genera and 86 species, showing a relatively simple distribution. The phytoplankton cell density ranged from 2.2 to 689.2 cells mL-1, with an average of 577.2 cells mL-1, which was low in autumn and high in winter. The seasonal succession of phytoplankton dominant species was mainly diatoms during the whole year, Leptocylindrus danicus, Chaetoceros curvisetus, Skeletonema costatum-ls in summer, Paralia sulcata, Eucampia zodiacus in autumn, S. costatum-ls, Thalassiosira nordenskioeldii in winter, and S. costatum-ls, Asterionella glacialis in spring. In other words, the phytoplankton community showed high diversity in GCW throughout the year. According to the PCA, GCW were easily heated and cooled by radiant energy at lower depth, and the seasonal distributions of phytoplankton were determined by the supply of nutrients by re-fuelling of surface sediments due to the seawater mixing such as tidal mixing.

High Frequency Properties of Fe93.5Si6.5 Magnetic Powder/Epoxy Composite Film (Fe93.5Si6.5 자성분말/에폭시 복합재 필름의 고주파 특성)

  • Hong, Seon-Min;Kim, Cheol-Gi
    • Journal of the Korean Magnetics Society
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    • v.18 no.5
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    • pp.195-199
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    • 2008
  • Composites of $Fe_{93.5}Si_{6.5}$ powder and epoxy were prepared using a thermal curing process. Scanning electron microscope (SEM), vibrating sample magnetometer (VSM) and network analyzer were used to analyze the structure, electromagnetic properties and microwave absorption of the composites. Results show that the saturation magnetization depends on the fraction of the $Fe_{93.5}Si_{6.5}$ powder in the composite, which affects initial permeability. It is believed that the eddy current loss is a dominant factor over 1 GHz and that the resonance frequency of the composite decreases with increasing fractions of $Fe_{93.5}Si_{6.5}$ powder. Finally, reflection loss was calculated from the permeability and permittivity of these composites. Composite with 50 wt.% $Fe_{93.5}Si_{6.5}$ powder fractions and 5 mm thickness showed reflection loss below -20 dB from 3.66 GHz to 4.16 GHz. Therefore, it is believed that thin Fe-Si/epoxy composites may be a good candidate for microwave absorption application.

An Analysis of Operating Characteristics and Management Satisfaction of Forest Museums in Korea (우리나라 산림박물관의 운영특성 및 관리 만족도 분석)

  • Ha, Sung-Gyone;Shin, Hyun-Tak;Jung, Tae-Yeol;An, Jong-Bin
    • Journal of Korean Society of Forest Science
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    • v.102 no.3
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    • pp.382-389
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    • 2013
  • The present study grasped the operation characteristics and operation management of forest museums in Korea and analyzed satisfaction with the foregoing. In the results of a survey of forest museums' operation characteristics, with regard to groups to which exhibits were helpful, over half of respondents answered that the exhibits were helpful to students and many respondents had an opinion that all age groups should be equally considered as targets of exhibition. Among matters that were considered with regards to forest museums, accessibility showed the highest rate of answers followed by museum programs. The curator was needed for the majority of respondents were exhibits prior to the survey had the highest expectations for the medium. With regard to the operation management of forest museums, the expected value of periodic and extraordinary exhibitions was shown to be high and high and satisfaction was shown by the professionalism of staff. As for matters of forest museums that must be improved, attention should be paid to the development of programs in which users can participate, diverse exhibition media should be developed, and exhibition should be planned to fit the composition of exhibits. As for operation management, since exhibits were repeated every year, environments should be changed by exhibiting new exhibits or otherwise and active methods of improvement should be devised such as the utilization of broadcasting media for public relations.

The Copper Adsorption onto 'Hwangto′ in the Okjong Area, Hadong (하동군 옥종 지역에서 산출되는 황토의 구리 흡착 특성)

  • 조현구;양도열;김영호
    • Journal of the Mineralogical Society of Korea
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    • v.16 no.4
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    • pp.321-331
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    • 2003
  • We researched the variation of mineral composition with depth and the Cu adsorption behavior of Hwangto in the Okjong area, Hadong. The 4 Hwangto samples were collected from depth 10 cm, 25 cm, 2∼3 m and under 3 m from surface, and analyzed using the X­ray Diffractometer. The Hwangto samples were mostly composed of clay minerals such as kaolinite and halloysite. Two samples from 10 cm and 25 cm contained Fe or Al hydroxide minerals, for example goethite or gibbsite. As depth increases, the content of quartz decreases but that of kaolinite increases. The amount of Cu removal was rapidly rised from pH 4, and reached about 90% at pH 6 and above 90% at pH 7. It is regarded that the trend of Cu removal was affected by the difference in mineral composition. It was relatively well matched between experimental value and calculated value by MINTEQA2 program in the case of high Cu concentration. From this study the precipitation has important role for the removal of Cu ions, particularly in the case of high Cu concentration. However, it was discord between experimental value and calculated one in the dilute concentration circumstances. The reason may be the mistake in parameters, insufficient reaction time, and inadequate consideration of reaction site in mineral surface.

Characterizing Magnetic Properties of TA (Tofua Arc) 22 Seamount (23° 34′ S) in the Lau Basin, Southwestern Pacific (남서태평양 라우분지 TA 22 해저산(23° 34′ S)에서의 지자기 특성 연구)

  • Choi, Soon Young;Kim, Chang Hwan;Park, Chan Hong;Kim, Hyung Rae
    • Geophysics and Geophysical Exploration
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    • v.21 no.2
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    • pp.67-81
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    • 2018
  • We acquired the magnetic and bathymetry data around the TA (Tofua Arc) 22 seamount in the Lau Basin for finding submarine hydrothermal deposits. From the data, we estimated the magnetic characteristics in the study area. The bathymetry shows that TA 22 seamount consists of the western and eastern summits. Each summit exhibits a caldera. The western caldera is smaller, but deeper than the eastern caldera. The slope gradients of the TA 22 are steeper around ~1000 m depth range and relatively gentle at the summit areas with the small difference of two calderas. The magnetic properties of TA 22 seamount present high anomalies at the summit and the vicinity of the caldera. Low magnetization zones appear over the outer flanks and center of the calderas. These magnetic patterns are similar to the previous studies which had represented high anomalies and low magnetization zones inside of the summit area or on the flank of the outside of the summit area. The results of the 2D magnetic forward modeling with seismic profiles show about 20 nT of RMSEs (root mean square error) between the modeled and observed values. The low RMSEs proposes a good correlation between the modeled 2D structure and the geophysical observation in this study area. Based on the modeling and magnetization distribution, hydrothermal deposits are predicted to be located at the inner area of the calderas or at small mounds around caldera rims.