• Title/Summary/Keyword: 열분석적 특성

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The effect of MgO content on highly active Ni-MgO-$Al_2O_3$ catalysts prepared by homogeneous precipitation method (균일용액침전법으로 제조한 MgO 함량에 따른 고활성 Ni-MgO-$Al_2O_3$ 촉매에 대한 연구)

  • Jung, Youshick;Rhee, Youngwoo;Koo, Keeyoung;Jung, Unho;Youn, Wanglai;Seo, Yongseog
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.155-155
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    • 2011
  • 용융탄산염 연료전지(MCFC)는 $650^{\circ}C$에서 작동하는 고온형 연료전지 시스템이다. 이 시스템은 천연가스 등을 개질하여 생산된 수소를 바로 전기로 생산할 수 있는 시스템으로 열효율이 높으며, 현재 대체 발전시스템으로 각광을 받고 있다. MCFC는 개질방식에 따라 내부개질 방식과 외부개질 방식이 있다. 내부개질 방식은 수소를 생산하는 개질기가 스택내부에 장착된 형식으로 천연가스를 스택내부에서 개질하여 바로 전기를 생산하는 방식이다. 이 내부개질반응에 사용되는 촉매로는 알루미나에 고함량 (약 50 wt.%)으로 담지된 니켈(Ni) 계열촉매이 주로 쓰이고 있다. 이 고함량으로 담지된 촉매는 대부분 높은 활성을 보인다. 비교적 낮은 온도 운전조건 (약 $580{\sim}620^{\circ}C$)을 가지는 MCFC 내부개질에 적용하기 위해서는 활성점인 니켈을 최대한 담지체에 고르게 분산 시켜야한다. 이를 위해서 MgO를 이용하여 촉매의 활성점을 높게 분산시키는 연구를 진행 하였다. 촉매를 제조하는 방법으로 요소(urea)를 이용한 균일용액침전법을 이용하였다. 니켈함량은 50 wt.%로 고정을 한 다음, MgO 양과 $Al_2O_3$ 양을 각각 0 ~ 45 wt.%와 5 ~ 50 wt.%로 조절하면서 촉매를 제조하여 그 특성들을 분석하였다. 물성을 비교하기 위해서, X-선 회절분석 (XRD) 및 TPR, 물리화학흡착 실험을 하였다. 촉매의 활성을 살펴보기 위해서, fresh 상태 및 피독 상태에서 메탄수증기 개질활성 실험을 실시하였다. MgO 함량이 없거나 적은 촉매에서는 높은 BET surface area와 작은 NiO, metallic Ni 결정 크기가 나타났다. 반면 MgO 함량이 높은 촉매에서 낮은 BET surface area와 비교적 큰 NiO, metallic Ni 결정 크기가 나타났다. 또한 XRD 분석에서 MgO 함량이 증가할 수 록 MgO 결정 피크가 명확히 나타났으며, $MgAl_2O_4$ 피크는 나타나지 않았다. TPR 분석에서 촉매들의 환원 피크를 측정한 결과, 저함량의 MgO를 포함한 촉매는 $700^{\circ}C$ 부근에 환원 피크가 관찰되었고 MgO가 고함량인 촉매는 환원 피크가 $400^{\circ}C$ 부근에서 관찰되었다. 촉매의 초기 fresh 상태에서의 활성은 고함량 MgO를 포함한 Ni-90M10A 샘플을 제외하고 모든 촉매가 거의 비슷하게 나타났다. 그러나 $K_2CO_3$ 피독 상태에서는 MgO 함량이 증가할 수 록 활성이 좋지 않았음을 알 수 있었다. 따라서 MgO가 소량 포함된 촉매의 경우 fresh 상태에서는 우수한 물성과 활성을 보이지만, 피독상태에서는 MgO가 포함되지 않은 Ni-$Al_2O_3$ 촉매가 우수한 활성을 보였다.

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An Informetric Analysis on the Notation of East Sea Recorded in Academic Journals ('동해' 표기에 대한 계량적 분석)

  • Han, Jong Yup
    • Journal of the Korean Society for information Management
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    • v.32 no.1
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    • pp.23-41
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    • 2015
  • This study worked on the qualitative analysis about nomenclature East Sea by the record type in researches related to East Sea shown in the scientific journals. Here in this study, the way of marking is classified as three: 'sole notation of East Sea', 'sole notation of Sea of Japan', and 'simultaneous notation of both'. Based on a total of 4,192 selections from Web of Science DB, the analysis was followed up for change in time series by the notation type, notation type according to the nation that authors belong to, difference in research topic, impact factor, collaboration in research, and co-authorship network. The result turned out in this work that the sole notation of Sea of Japan accounted for the largest portion. It also showed that the rates of sole notation of East Sea and simultaneous notation have kept increasing continuously since the 1990s. Hub nations regarding the research of East Sea is five including Japan, Russia, Korea, USA, and China. In the case of sole notation of Sea of Japan, active collaboration studies are performed in USA, Russia, and China with a focus in Japan. In the case of sole notation of East Sea and simultaneous use, the research rate is relatively high in USA and Japan with a focus in Korea. As to the co-authorship network in the sole notation of Sea of Japan, sort of a "giant component" among different groups has been set up and through which the collaborative works are actively underway. However, it was found that the research of sole notation of East Sea is dispersed into small groups on the base of relevant individual institution.

A Study on the Characteristics of Summer Water Temperature Fluctuations by Spectral Analysis in Coast of Korea in 2016 (스펙트럼 분석을 통한 2016년 하계 한국연안의 수온변동 특성에 관한 연구)

  • Seo, Ho-San;Jeong, Yong-Hyun;Kim, Dong-Sun
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.26 no.2
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    • pp.186-194
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    • 2020
  • In this study, spectral analysis was conducted to identify environmental factors af ecting short-term changes in water temperature in the East, West and South coasts of Korea. The data used in the spectrum analysis is the 2016 summer water temperature, air temperature, tide level and wind data provided by Korea Hydrographic & Oceanographic Agency. In power spectrum results, peaks of water temperature and tide level were observed at same periods in West Sea (Incheon, Pyeungteak, Gunsan and Mokpo) and South Sea (Wando, Goheung, Yeosu, Tongyeong and Masan) where mean tidal range was more than 100 cm. On the other hand, periodicity of water temperature did not appear in East Sea and Busan where the mean tidal range was small. Coherence analysis showed that water temperature was highly correlated with tide in West Sea and three stations(Wando, Goheung and Tongyeong) of South Sea. Especially, correlation between water temperature and tide level in Wando and Tongyeong presented 0.96 at semi-diurnal period. Water temperature in Yeosu seems to have influenced by tide and inflow of fresh water. In Masan, water temperature is influenced by south wind, tide and inflow of fresh water. In East Sea, influence of tide on water temperature is small due to current and small tidal range. As a result of comparing the time series graph, stations where the correlation between water temperature and tide is high show that relatively cold water was inputted at flood tide and flow out at ebb tide. short-term variation of water temperature was affected by tide, but long-term variation over a month was affected by air temperature.

Analysis of Factors Affecting Job Competency of Quality Management for a Construction Manager (건설사업관리자의 품질관리 직무 역량에 영향을 미치는 요인 분석)

  • Jung, Seoyoung;Yu, Jungho
    • Korean Journal of Construction Engineering and Management
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    • v.18 no.1
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    • pp.65-73
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    • 2017
  • Today, the United States, Europe and other advanced organizations are utilizing the concept of competency-based HR management. Recently, many organizations in Korea are also managing workforces by introducing the concept of job competencies in personnel management. However, in spite of the current trend, domestic human resources management methods for construction managers continues to operate by asking about work experience, licensing, education level, etc. This is a seniority system and it functions separately from an assessment of practical job competencies for the business. Moreover, construction management work has been very fragmented in terms of expertise and capacity depending on the type of management work and project progress. Therefore, it is necessary to develop a competencies management system for each business segment to effectively manage job competencies that reflect the the characteristics of a construction manager' s work. As such, the aim of this study is to analyze human resources management methods pertaining to domestic construction managers and present challenges and limitations in current practices. In particular, factors affecting the job competencies of construction managers are analyzed statistically. The results of this study will be used as the basis for future research into development of a construction manager competency management system.

Optimization of a Process for Extraction of Petasin from Petasites japonicus Leaves by Response Surface Methodology (반응표면분석법에 의한 머위 잎의 petasin 추출공정 최적화)

  • Lee, Dong Wan;Lee, Se Yeul;Chung, Hun Sik;Choi, Young Whan;Im, Dong Soon;Lee, Young Guen
    • Journal of Life Science
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    • v.23 no.11
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    • pp.1360-1364
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    • 2013
  • Petasin extracted from Petasites japonicus leaves has been well known to be effective in the treatment of allergic asthma. This study was carried out to optimize the extraction process of petasin from P. japonicus leaves by response surface methodology (RSM). The dried powder of P. japonicus leaves was extracted at ethanol concentrations ranging from 40% to 80%, extraction rpm ranging from 125 rpm to 225 rpm, and extraction time ranging from 1 to 3 hours. The effects of the extraction conditions on the dry yield and petasin content of the extracts were investigated using a second-order Box-Behnken design. The petasin content was significantly affected by ethanol concentration, extraction rpm, and extraction time, tending to increase more with increasing ethanol concentration. The optimum condition for petasin extraction from Petasites japonicus leaves was 79.92% in ethanol concentration, 178.10 rpm in extraction rpm, and 2.06 hours in extraction time, respectively.

Locations and Topographical Character of the MAEULSOOP in the Southwestern and the Eastern Region (마을숲의 분포 위치와 지형적 공간특성 유형화 방안 - 경북 의성, 전북 진안 및 전남 함평지역을 대상으로)

  • Kwon, Jino;Oh, Jeong-Hak;Lee, Jeong-Youn;Park, Chan-Ryul;Choi, Myoung-Sub
    • Journal of the Korean Association of Geographic Information Studies
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    • v.11 no.4
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    • pp.85-93
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    • 2008
  • The MAEULSOOP, Korean traditional village groves have been installed and survived since 7th Century to serve local village dwellers as a community forest. The common sense of their reasons for being is related to the surroundings such as hills, waterways and wind-ways. To understand the roles in a local community, spatial characteristics of distribution, locations and shapes were tested at the two-characterized regions, the Southwestern Flat Region and the Eastern Hilly Region. Approximately more than 500 written evidences related to trees and forests were surveyed, for example village names, folk tales and lists of designated trees for protection. Twenty sites in each region were selected and tested for the spatial analysis. Aerial photographs, DEM and the ArcGIS with a modified AML for slope analysis are applied based on the criteria of the KLCIS(Kwon, 2002; 권진오, 2008). The major factors in the role of the MAEULSOOP based on the spatial character of two regions are; the array and locations of hills for encircling or exposure, locations against corridors and waterway or not, locations of the community to serve, the conservation of energy. Although locations and shapes of the MAEULSOOP are slightly different, it seems that one of the prime roles is what makes their everyday life difficult the most in the community.

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A Study on Real-Time Defect Detection Using Ultrasound Excited Thermography (초음파 서모그라피를 이용한 실시간 결함 검출에 대한 연구)

  • Cho, Jai-Wan;Seo, Yong-Chil;Jung, Seung-Ho;Jung, Hyun-Kyu;Kim, Seung-Ho
    • Journal of the Korean Society for Nondestructive Testing
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    • v.26 no.4
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    • pp.211-219
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    • 2006
  • The UET(ultrasound excited thermography) for the ,eat-time diagnostics of the object employs an infrared camera to image defects of the surface and subsurface which are locally heated using high-frequency putted ultrasonic excitation. The dissipation of high-power ultrasonic energy around the feces of the defects causes an increase In temperature. The defect's image appears as a hot spot (bright IR source) within a dark background field. The UET for nondestructive diagnostic and evaluation is based on the image analysis of the hot spot as a local response to ultrasonic excited heat deposition. In this paper the applicability of VET for fast imaging of defect is described. The ultrasonic energy is injected into the sample through a transducer in the vertical and horizontal directions respectively. The voltage applied to the transducer is measured by digital oscilloscope, and the waveform are compared. Measurements were performed on four kinds of materials: SUS fatigue crack specimen(thickness 14mm), PCB plate(1.8 mm), CFRP plate(3 mm) and Inconel 600 plate (1 mm). A high power ultrasonic energy with pulse durations of 250ms Is injected into the samples in the horizontal and vertical directions respectively The obtained experimental result reveals that the dissipation loss of the ultrasonic energy In the vertical injection is less than that in the horizontal direction. In the cafe or PCB, CFRP, the size of hot spot in the vortical injection if larger than that in horizontal direction. Duration time of the hot spot in the vertical direction is three times as long as that in the horizontal direction. In the case of Inconel 600 plate and SUS sample, the hot spot in the horizontal injection was detected faster than that in the vertical direction

Mineralogical and Physical Properties of Lime Plaster used in Wall Repair in Temple of Bagan, Myanmar (미얀마 바간지역 사원 벽체 보수에 사용되는 석회 플라스터의 광물학적 및 물리적 특성)

  • Ahn, Sunah;Kim, Eunkyung;Nam, Byeongjik;Hlaing, Chaw Su Su;Kang, Soyeong
    • Journal of the Mineralogical Society of Korea
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    • v.31 no.4
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    • pp.267-275
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    • 2018
  • The purposes of this study were to analyze the mineralogical characteristics of slaked lime used for wall repair of traditional buildings in Bagan, Myanmar and to evaluate the physical properties of lime plaster produced by the same method as Bagan region. In the X-ray diffraction and thermal analysis of the Myanmar slaked lime, portlandite ($Ca(OH)_2$) and brucite ($Mg(OH)_2$) were detected as main constituent minerals, and a carbonate rock mainly composed of dolomite ($CaMg(CO_3)_2$) minerals may be used as a raw material to make slaked lime. The field-emission scanning electron microscope analysis showed that the Myanmar slaked lime was composed of irregularly shaped crystals of $0.5{\mu}m$ or larger and a small amount of $0.1{\mu}m$ of plate - like crystals. The size and uniformity of crystals in Myanmar lime is different from that of Korea slaked lime. This may be attributed to the effect of the mineral composition and the lime hydration method of Myanmar, which produces slurry by immersing the burnt lime in excess water for a long period of time. The compressive strength of the lime plaster in Myanmar resulted in a mean value of $1.13N/mm^2$ for the specimens cured for 28 days. The strength of the specimens with Bale juice was $1.03N/mm^2$, respectively. The lime is an air setting material that exhibits strength through long carbonation process. Therefore, it is necessary to evaluate physical properties according to curing period through long-term curing over 28 days in the future.

Thermomechanical Characteristics of Poly(vinyl alcohol)/Chitosan Films and Its Blend Hydrogels (폴리(비닐 알코올)/키토산 블렌드와 블렌드 수화젤의 열특성)

  • Park Jun Seo;Park Jang Woo;Kim Byung Ho
    • Polymer(Korea)
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    • v.29 no.2
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    • pp.183-189
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    • 2005
  • Films of poly(vinyl alcohol)(PVA)/chitosan blends and its blend hydrogels were prepared by the solution casting method. The state of miscibility of the blends and blend hydrogels were examined over the entire composition range by differential scanning carorimetry (DSC), thermogravimetry (TGA), and dynamic mechanical analysis (DMA). DSC analysis shows the depression of melting point of PVA in the blends and the decrease of crystallization temperature of PVA in the blends were observed with increasing chitosan content in the blends. TGA analysis indicates that chitosan was thermally more stable than PVA and the thermal stability of PVA in the blends was higher than that of pure PVA, due to some interactions between two component polymers in the blend. The glass transition temperature $(T_g)$ of the chitosan and of PVA, measured by DMA, were at 160 and $90^{\circ}C$, respectively. The $T_g$ of the blends was changed with the content of chitosan in the blends. The results of thermal and viscoelastic analysis indicate some miscibility between component polymers in the blend exists. Moisture and cross linking in the blend and blend hydrogel, which strongly change thermal and physical properties of hydrophilic polymers, affected the miscibility of chitosan and PVA to a small extent.

The Mineralogical Characteristics on the Polder Soils Development from Alluvio-marine Deposits near to Sapgyo-lake (삽교천유역의 하해혼성충적층에서 발달된 토양의 광물학적 특성)

  • Zhang, Yong-Seon;Um, Myung-Ho;Jung, Pil-Kyun;Shin, Jae-Sung
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.6
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    • pp.377-383
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    • 2000
  • The composition of primary minerals of sand fractions and secondary minerals of clay fractions were investigated on the polder soils developed from alluvio-marine deposits near to Sapgyo-lake, constructed a sea dike across river estuary located in the west coast. The effects of a topographical sequence on the physico-chemical properties and mineralogical characteristics were evaluated using XRD, DTA, and TG with the chemical composition of $H^+$ saturated clays. Soils located on the seashore side were more silt fraction, higher pH and exchangeable cations than the others. The dominant minerals of soil parent materials are in the order of quartz, feldspars, micas, chlorite and amphibole. According to the greater distance from the lake, the amount of 1:1 minerals increased, but 2:1 minerals decreased. The dominant clay minerals of polder soils are kaolinite, vermiculite and illite. Hydroxy interlayer minerals are abundant in the clay fractions derived from the soil parent materials which have relatively low soil pH.

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