• Title/Summary/Keyword: 열분석적 특성

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A Study on Properties of Pb-free Solder Joints Combined Sn-Bi-Ag with Sn-Ag-Cu by Conditions of Reflow Soldering Processes (리플로우 솔더링 공정 조건에 따른 Sn-Bi-Ag와 Sn-Ag-Cu 복합 무연 솔더 접합부 특성 연구)

  • Kim, Jahyeon;Cheon, Gyeongyeong;Kim, Dongjin;Park, Young-Bae;Ko, Yong-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.29 no.3
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    • pp.55-61
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    • 2022
  • In this study, properties of Pb-free solder joints which were combined using Sn-3.0Ag-0.5Cu (SAC305) Pb-free solder with a mid-temperature type of melting temperature and Sn-57Bi-1Ag Pb-free solder with a low-temperature type of melting temperature were reported. Combined Pb-free solder joints were formed by reflow soldering processes with ball grid array (BGA) packages which have SAC305 solder balls and flame retardant-4 (FR-4) printed circuit boards (PCBs) which printed Sn-57Bi-1Ag solder paste. The reflow soldering processes were performed with two types of temperature profiles and interfacial properties of combined Pb-free solder joints such as interfacial reactions, formations of intermetallic compounds (IMCs), diffusion mechanisms of Bi, and so on were analyzed with the reflow process conditions. In order to compare reliability characteristics of combined Pb-free solder joints, we also conducted thermal shock test and analyzed changes of mechanical properties for joints from a shear test during the thermal shock test.

A Study on Mineralogical Characteristic and Accelerated Weather Test of Red and Yellow Color Natural Inorganic Pigments (적색 및 황색 계열의 천연 무기안료의 광물학적 특성 및 촉진내후성 평가 연구)

  • Park, Ju Hyun;Jeong, Hye Yeong
    • Journal of the Mineralogical Society of Korea
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    • v.32 no.4
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    • pp.259-271
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    • 2019
  • We evaluated mineralogical, physical property and accelerated weather resistance of cinnabar, realgar and orpiment used as cultural heritages and traditional paintings. JB and JS are sample names of cinnabar and JH and UH are sample names of orpiment and Realgar, respectively. As a result of mineralogical property evaluation, Jinsa was identified cinnabar (HgS) and there was no difference in chemical composition according to the grade. UH and JH were confirmed realgar (AsS) and orpiment (As2S3), respectively. The polarization characteristics such as shape and color indicate that pigments using our test were natural mineral pigment observed by polarization microscope. Especially, in the case of cinnabar, it is not easy to distinguish between natural mineral pigment and synthetic pigment. But the results of polarization microscope said that cinnabar is natural occurring mineral which have authentic mineral particle and unevenly fracture. As a result of thermal analysis, JH has a higher glass transition temperature and heat stability than UH. After accelerated weather test, cinnabar, realgar and orpiment were striking result in color change because of light degradation. Red color of cinnabar turn into black and the color of realgar and orpiment became brighter than before. JB (meta-cinnabar) is more photosensitivity and faster becoming dark than JB (cinnabar). Finally light transforms realgar (red, As4S4) in arsenolite (As2O3).

Characterization of Charcoals prepared by Korean Traditional Kiln (우리나라 전통 숯가마로부터 생산된 숯의 특성분석)

  • An, Ki Sun;Kwak, Lee Ku;Kim, Hong Gun;Ryu, Seung Kon
    • Korean Chemical Engineering Research
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    • v.60 no.2
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    • pp.208-216
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    • 2022
  • Surface morphology and adsorption characteristics of black and white charcoals prepared from Korean traditional kiln were quantitatively analyzed. TGA and elemental analysis of charcoals were different from produced kiln, and thermal degradation temperature and carbon content of white charcoals were apparently higher than those of black charcoals. Surface morphology shows the activation progressed through the longitudinal direction of woods and new micropores were developed to radial direction on the surface of macropores as the furthermore activation resulting in the pore connection. BET adsorption isotherms show that there are low-pressure hysteresis due to the no desorption of adsorbates, which resulted in unique Type of charcoals overlapping Type I and Type IV. Such a low-pressure hysteresis is occurred from expansion of adsorbates, which were embedded in the micropore entrances and did not get out during the desorption run. The characteristics of charcoals such as specific surface area and pore size distribution did not show correct values depending on not only produced company but also sampling sites of one piece of charcoal. Therefore, it is not easy to suggest the quantitative characteristics of charcoals prepared from Korean traditional kiln. On the other hand, preparation the quality standard of charcoal is necessary for their special uses such as adsorbent.

Saccharification of lignocellulosics by Supercritical Water (초임계수를 이용한 목질바이오매스의 당화 가능성)

  • Choi, Joon-Weon;Lim, Hyun-Jin;Han, Gye-Sung;Choi, Don-Ha
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.11a
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    • pp.525-528
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    • 2006
  • 아임계 및 초임계수에 의한 목질바이오매스의 당화특성을 분석하기 위하여 분해공정 동안 압력을 23MPa(물의 임계압력)로 고정하고 물의 아임계 온도$(325^{\circ}C,\;350^{\circ}C)$와 초임계 온도$(380^{\circ}C,\;400^{\circ}C,\;425^{\circ}C)$에서 현사시나무 목분을 각각 60초 동안 처리하였다. 생성된 현사시나무의 분해산물에는 액상과 고형분의 분해산물이 섞여 있었다. 각 처리조건에 따른 목질바이오매스의 분해율은 온도가 상승함에 따라 증가하였으며 초임계 온도인 $425^{\circ}C$에서 최고 83.1%의 분해율을 나타냈다. 아임계 및 초임계수에 의해서 생성된 단당류는 고성능 음이온 교환 크로바토그래프(HPAEC)를 이용하여 분석하였다. 목질바이오매스의 초임계수 분해과정에서 처리 온도가 높아지면서 단당류 수율은 증가하는 경향을 보였으며, $425^{\circ}C$에서 가장 높은 7.3%의 단당류 수율을 나타내었다. 아임계 온도 범위에서는 현사시나무의 섬유소 성분 중에서 자일란이 우선적으로 분해되어 자일로스의 생성비율이 비교적 높았으며, 처리온도가 높아지면서 셀롤로오스의 분해에 의한 글루코오스 생성율이 급격히 상승하였다. 이렇게 생성된 단당류 성분들은 고온의 반응조건하에서 열분해 반응에 의해서 더욱 분해되어 퓨란계 화합물로 변형되었다.

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Basic Design and Structural and Optical Glass Characteristic Study of Chalcogenide Aspheric Lens (칼코게나이드계 비구면 성형렌즈의 기초설계 및 구조적, 광학적 글래스 특성 연구)

  • Ko, Jun-Bin;Kim, Jeong-Ho;Byun, Dong-Hae
    • Journal of the Korean Society for Precision Engineering
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    • v.27 no.5
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    • pp.69-74
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    • 2010
  • An increasing interest towards the investigations of chalcogenide glasses has been observed in the past years. This interest is due to their specific properties, as well as to the possibilities for their application in different fields of science. The optical devices, working on the basis of photoinduced phase transition between amorphous and crystalline state in the chalcogenide glasses, are a perspective for the micro- and nano-electronics. Here we were analysis basic physical properties for Ge-As-Se and As-Se chalcogenide glasses samples for characteristic for a planning of chalcogenide aspheric lens. From differential DTA/TG results, activation energies of the crystallizations of $Ge_{10}As_{40}Se_{50}$ and $As_{40}Se_{60}$ were approximately 3.6 eV and 3.3 eV, respectively.

A Study on the Long-Run Equilibrium Between KOSPI 200 Index Spot Market and Futures Market (분수공적분을 이용한 KOSPI200지수의 현.선물 장기균형관계검정)

  • Kim, Tae-Hyuk;Lim, Soon-Young;Park, Kap-Je
    • The Korean Journal of Financial Management
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    • v.25 no.3
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    • pp.111-130
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    • 2008
  • This paper compares long term equilibrium relation of KOSPI 200 which is underling stock and its futures by using general method fractional cointegration instead of existing integer cointegration. Existence of integer cointegration between two price time series gives much wider information about long term equilibrium relation. These details grasp long term equilibrium relation of two price time series as well as reverting velocity to equilibrium by observing difference coefficient of error term when it renounces from equilibrium relation. The result of this study reveals existence of long term equilibrium relation between KOSPI200 and futures which follow fractional cointegration. Difference coefficient, d, of 'two price time series error term' satisfies 0 < d < 1/2 beside bandwidth parameter, m(173). It means two price time series follow stationary long memory process. This also means impulse effects to balance price of two price time series decrease gently within hyperbolic rate decay. It indicates reverting speed of error term is very low when it bolts from equilibrium. It implies to market maker, who is willing to make excess return with arbitrage trading and hedging risk using underling stock, how invest strategy should be changed. It also insinuates that information transition between KOSPI 200 Index market and futures market does not working efficiently.

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Quantitative Analysis of Damage Impacts in case of Bunkering NH3 from Tank Lorry to Fishing Vessel (어선-탱크로리 간의 NH3 이적 시 누출에 따른 정량적 피해영향분석)

  • Lim, Sang-Jin;Choi, Bu-Hong;Lee, Yoon-Ho
    • Journal of the Korean Institute of Gas
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    • v.26 no.3
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    • pp.10-20
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    • 2022
  • About 21% of domestic chemical accidents are caused by transport vehicles for the past 10 years in Korea. Also, ammonia is a chemical substance with the largest number of accidents, 82 out of 672. In this study, supposed seasonal alternative scenario and worst scenario in case of releasing ammonia during bunkering it from tank lorry to fishing vessel and interpreted seasonal impact and range through Python, ALOHA, Probit analysis. Radiation impact range of possibility for 2nd burn and for maximum radiation in winter scenario, which is one of the alternative scenarios, was the highest(range: 41m, radiation: 5.01kW/m2) while overpressure impact was less than minimum standard of impact. And toxicity impact range(EPRG-2) of the summer scenario was the widest(5.0km) and took a very high death rate near accident area(port area, tourist area) according to Probit analysis. the wort scenario had a similar impact and range of summer scenario.

LNG Gas Demand Forecasting in Incheon Port based on Data: Comparing Time Series Analysis and Artificial Neural Network (데이터 기반 인천항 LNG 수요예측 모형 개발: 시계열분석 및 인공신경망 모형 비교연구)

  • Beom-Soo Kim;Kwang-Sup Shin
    • The Journal of Bigdata
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    • v.8 no.2
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    • pp.165-175
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    • 2023
  • LNG is a representative imported cargo at Incheon Port and has a relatively high contribution to the increase/decrease in overall cargo volume at Incheon Port. In addition, in the view point of nationwide, LNG is the one of the most important key resource to supply the gas and generate electricity. Thus, it is very essential to identify the factors that have impact on the demand fluctuation and build the appropriate forecasting model, which present the basic information to make balance between supply and demand of LNG and establish the plan for power generation. In this study, different to previous research based on macroscopic annual data, the weekly demand of LNG is converted from the cargo volume unloaded by LNG carriers. We have identified the periodicity and correlations among internal and external factors of demand variability. We have identified the input factors for predicting the LNG demand such as seasonality of weekly cargo volume, the peak power demand, and the reserved capacity of power supply. In addition, in order to predict LNG demand, considering the characteristics of the data, time series prediction with weekly LNG cargo volume as a dependent variable and prediction through an artificial neural network model were made, the suitability of the predictions was verified, and the optimal model was established through error comparison between performance and estimates.

Development of EST-SSR Markers and Analysis of Genetic Diversity Using Persimmon (Diospyros kaki Thunb) Cultivars Collecting from Domestic (국내 수집 감 품종을 이용한 EST-SSR marker 개발과 유전적 다양성 분석)

  • Seo, Dong Hywi;Jung, Kyung Mi;Kim, Se Jong;Kim, Kyung-Min
    • Korean Journal of Plant Resources
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    • v.26 no.4
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    • pp.491-502
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    • 2013
  • Persimmon (Diospyros kaki Thunb) fruit is one of the most important fruit and have been cultivated from ancient times in Korea. In this study, we found 16 EST-SSR markers that contained one or more EST-SSR sites from 246 cDNA sequences. The developing of EST-SSR marker analysis from 42 persimmon cultivars was compared by genetic relationships and morphological relationships using 6 qualitative traits (fruit related 6 traits) and 19 quantitative traits (flower related 19 traits). In this study, 25 primer sets were tested to identify PCR polymorphism and 14 potential EST-SSR primer pairs were selected. The result of morphological relationship EST-SSR marker analysis showed that the coefficient 0.02 was difficult to categorize in several groups. And then, coefficient 0.77 of genetic relationship showed that the group was classified as four groups. The result of correlation distance between genetic relationship and morphological relationship were investigated was low significance (-0.03). Our results also provided an optimized method for improvement of breeding efficiency and introduce of superior character at persimmon cultivars using EST-SSR markers which was useful for further investigation.

Analysis of RCSTP Wastewater Characteristics and Installed Treatment Process in Bong-Hwa Gun (봉화군에 도입된 마을하수도 하수 특성 및 처리 공법 분석)

  • Im, Jiyeol;Gil, Kyungik
    • Journal of Wetlands Research
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    • v.15 no.4
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    • pp.453-460
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    • 2013
  • Rural area sewage distribution rate is 40 % less than urban area. Previous research results announced that one of the reason in water resource pollution was caused of low rural area sewage distribution rate. Analysis on operation result of 11 RCSTP in Bong-hwa area which is located at the upper region of An-dong Dam and Im-ha Dam. Based on operation result, an analysis on characteristics of wastewater in Bong-hwa and treatment efficiency of installed treatment process was conducted. The wastewater influent of Bong-hwa contained high organic matter and nutrient than those of urban area. Treatment process showed totally stable treatment efficiency. But, The treatment efficiency for nutrient showed high fluctuation. This result means which is need to operation condition control of nutrient treatment when operating RCSTP.