• Applied Chemistry for Engineering
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• v.20 no.4
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• pp.375-380
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• 2009

Polyepichlorohydrin rubber was treated with sodium azide (Na$N_3$) to replace its chlorine by azide ($N_3$). Then, the azidated polyepichlorohydrin rubber (Az-PECH) was blended with thermoplastic styrene-acrylonitrile copolymer with the rubber/plastic ratio of 80/20, 70/30 and 60/40 (wt/wt). The miscibility, mechanical and dynamic mechanical properties as well as elastic recovery properties of the blends were evaluated by DMA (Dynamic Mechanical Analyzer) and tensile tests. When azidation level in azidated PECH was upto 50%, the blends exhibited excellent miscibility, manifested by a single $T_g$, and fairly good elastic recovery. When azidation level was 75%, the blends showed phase separation. The miscible Az-PECH/SAN blends exhibited typical thermoplastic elastomer like properties, ie. melt processibility and high extensibility as well as good elastic recovery rate. It was also observed from combustion test that higher energy is released with the increase in the azidation level of the Az-PECH in the blends.

• Journal of the Korean Society for Nondestructive Testing
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• v.18 no.1
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• pp.1-9
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• 1998

The attenuation of acoustic emission (AE) waves was evaluated for injection-molded short-fiber-reinforced thermoplastic composites employing simulated AE waves. Values of attenuation coefficient (${\alpha}$) decreased more with increasing fiber volume fraction ($V_f$) than that expected from a simple linear relation between ${\alpha}$ and $V_f$. The effect of wave attenuation was taken into account in a quantitative analysis of the AE peak amplitude distribution which was obtained from each zone partitioned in a specimen gage portion. The amplitude distribution compensated for the measured attenuation loss was exhibited almost similar in every zone of the specimen. Consequently, it was, shown that the AE amplitudes obtained from fiber/plastic composites were considerably affected by the attenuation.

• Elastomers and Composites
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• v.36 no.3
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• pp.188-194
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• 2001

Thermoplastic elastomers based on dynamically vulcanized NR/TOR/PP (rubber/PP=70/30) blends were prepared in a Haake banbury mixer. Effect of TOR content on the mechanical, dynamic mechanical and thermal stability of the rubber/plastic blends was characterized by UTM, DMTA, and TGA. On the addition of trans-polyoctylene rubber(TOR) to the rubber phase, there was a decrease in compression set and increase in tensile properties, hardness and dynamic properties as well as thermal stability or the elastomeric blends. Improvements in the properties were believed to be due to an increase in crosslink density of the rubber phase and increase in homogeneity of the blends.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.1
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• pp.914-920
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• 2015

In this paper, the crystal structure and the crystallinity of PLA(PolyLactic Acid) were studied. PLA is a eco-friendly thermoplastic which completely decomposed by microorganisms, but has low thermal stability and low degree of crystallinity. The low crystallization rate makes the cycle time of injection molding longer and the degree of crystallinity lower. It is a very big disadvantage comparing the other thermoplastics. We improved the degree of crystallinity and the crystallization rate by introducing nucleating agents and plasticizer, and discussed the mechanism.

• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.52-52
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• 2012

Poly(phenylene sulfide)(PPS)는 내열성 및 내화학성이 뛰어난 고분자 소재로, 대표적인 엔지니어링 플라스틱 중 하나이다. PPS는 벤젠 링에 황원자가 파라 치환 형태로 교대로 존재하는 결정성 고분자이며, 다른 대부분의 고성능 섬유고분자가 용융되지 않는 것과는 달리 용융되는 열가소성 소재이다. PPS는 높은 내약품성과 열에 대한 장기적인 안정성을 나타내고, 방염제 첨가 없이도 방염화가 가능하며, 전기 절연성이 뛰어나고, 형태안정성도 우수하다. 또한 $200^{\circ}C$ 이하에서는 어떤 용매에도 용해되지 않으며, $200^{\circ}C$ 이상에서도 몇 가지 방향족 화합물에만 제한된 범위 내에서 용해되는 우수한 내약품성을 나타낸다. PPS의 내열성을 더욱 우수하게 하기 위해 고분자 사슬을 가교할 수 있다. 가교에는 열처리 또는 감마선, 전자선, 자외선 조사를 이용할 수 있는데 열에 의한 가교는 균일한 열전달과 고온이 필요하며 감마선 및 전자선 조사는 설비의 고비용과 방사선 노출 위험으로 인해 비친환경적이다. 반면에 자외선 조사법은 다루기 쉽고 비용이 적게 들고 친환경적인 장점을 가진다. 본 연구에서는 PPS film의 열안정성을 향상시키기 위해 자외선 조사를 이용하여 PPS film의 광가교를 수행하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2010.06a
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• pp.29-29
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• 2010

Engineering plastics have excellent electrical properties, mechanical strength and various characteristic which include chemical resistance, environmental resistance, weatherability at a wide temperature range. It has good characteristic(light weight, good productivity) as compare with epoxy or porcelain insulators. However, engineering plastics not suited to outdoor insulator because it isn't hydrophobic. Therefore, to over come these critical problems, we improve the surface insulation characteristics of engineering plastic by coating micro-, nano- size inorganic fillers added to RTV-SIR(Room temperature vulcanized-silicone rubber) at this plastic surface. The effect is analyzed through salt-fog test, tracking test. In conclusion, the engineering plastic coated RTV with micro-$Al_2O_3$20[phr], nano-Al(OH)3 1 ~ 3[phr] improved much better than the others.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.15 no.5
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• pp.1-7
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• 2016

In the present study, a plastic surface end-milling was implemented to investigate the effects of processing parameters on surface quality. The end milling can be considered an efficient method for rapid prototyping of thermoplastic bio-systems since it exhibits several beneficial functions including short fabrication time and high dimensional accuracy. In this regard, putative biocompatible thermoplastic materials, such as PMMA, PET, and PC, were chosen as workpiece materials. Among the relevant processing parameters influencing the surface quality of the final product, depth of cut, feed rate, and spindle speed were considered in the present study. The roughness of surfaces machined under various conditions was measured to elucidate the effect of each parameter. We found that the cut depth was the most significant factor. Heat generation during machining also had a remarkable effect. From these investigations, an appropriate combination of processing conditions specific to each type of use and end-product could be found. This optimization can be useful in end-milling of thermoplastic bio-systems.

• Journal of the Korean Society of Safety
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• v.31 no.1
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• pp.61-65
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• 2016

In this study, we considered the ignition possibility for the shredded thermoplastic elastomer at the fire ground loaded the waste TPE. The average moisture content of the TPE sample was almost 0.33 wt.% at $110^{\circ}C$ and the range of ignition point was $461.9{\sim}491.9^{\circ}C$ approximately. In addition, we analyzed the change of weight and calorie the TPE sample according to temperature variations using the TG-DTA analyzer. As a result, the weight loss occurred twice in $250{\sim}420^{\circ}C$ and $420{\sim}473^{\circ}C$, and we found the second weight loss temperature range was the ignition point of TPE. Also, we conducted the spontaneous ignition tests of TPE for the wet and dry samples and we confirmed that the possibility of spontaneous ignition of TPE was very low. The elapsed time and humidity had little influence on the spontaneous ignition of TPE in this experimental conditions. In conclusion, the spontaneous of the shredded waste TPE in this study.

• Composites Research
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• v.12 no.1
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• pp.11-18
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• 1999

The compression molding is widely used in the automotive industry to produce products that are large, thin, lightweight and stiff. The molded product is formed by squeezing a fiber-reinforced plastic composites. During a molding process of fiber reinforced thermoplastic composites, control of filling patterns in mold, orientation and distribution of fibers are needed to predict the effects of molding parameters on the flow characteristics. It is the objective of this paper to develop an isothermal compression molding simulation that can handle both thin and thick charges and motion of the flow front, and can predict pressure distributions and accurate velocity gradients. The composites are treated as an incompressible Newtonian fluid. The effects of slip parameter $\alpha$ and extensional/shear viscosity ratio $\zeta$ on the mold filling parameters are also discussed.

• Elastomers and Composites
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• v.46 no.3
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• pp.257-261
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• 2011

We introduce a novel method that could modify neat asphalt. A polymer-forming monomer, dimethylphenol( DMP) was added to the neat asphalt and polymerization was occurred autonomously, without adding any external catalyst for the polymerization, only with oxygen molecules in the air. The polymer produced in the asphalt was polyphenyleneoxide( PPO) and it enhanced the mechanical properties of the asphalt. Compared with the neat asphalt, the tenacity and toughness of the DMP-modified asphalt were two and half times and three times high, respectively.