• Title/Summary/Keyword: 연소안정성평가

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다공성 금속 합금 폼 표면의 향상된 촉매 분산을 위해 원자층 증착법을 이용한 inter-layer의 도입

  • Lee, Yu-Jin;Gu, Bon-Yul;Baek, Seong-Ho;Park, Man-Ho;An, Hyo-Jin
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.97-97
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    • 2015
  • 전 세계적으로 화석연료의 고갈 및 환경오염 문제를 해결하기 위해 신재생에너지에 대한 관심이 급증하고 있다. 이러한 신재생에너지에는 수소 에너지, 자연 에너지(태양열, 지열 등), 바이오 매스 에너지 등이 포함된다. 이 중 수소 에너지는 지구상에 풍부하게 존재하고 있는 물과 탄화수소로부터 얻어지며, 연소 시에도 다시 물을 형성하여 오염 물질을 배출하지 않는 차세대 무공해 에너지원으로써 주목을 받고 있다. 수소 제조를 위한 공정에는 수증기 개질 공정(steam reforming), 부분 산화(partial oxidation) 및 자열개질(autothermal reforming) 등이 있으며 실제로 생산되는 대부분의 수소는 탄소/수소비(1:4)가 높은 메탄($CH_4$) 가스를 이용한 메탄 수증기 개질 공정(steam methane reforming)을 통하여 제조된다. 이 때 수소 제조의 고효율화 및 저비용화를 위해서는 반응물에 대한 높은 선택도, 고활성도 및 높은 안정성을 갖는 촉매가 반드시 필요하며, 대표적으로 Ni, Pt, Ru 등이 보고되고 있다. 이러한 촉매들은 대부분 세라믹 pellet 형태로 제작되어 왔으나 열전도도가 낮고 물리적 충격에 취약하다는 단점이 존재한다. 따라서 우리는 이러한 단점을 극복하고, 촉매의 활성을 높이기 위하여 다공성 금속 합금 폼을 촉매 지지체로 도입하였다. 또한, 다공성 금속 합금 폼 표면에 촉매의 분산 및 안정성을 향상시키기 위해 지지체와 촉매 사이에 원자층 증착법을 이용하여 inter-layer를 도입하였다. 이들의 구조, 형태, 및 표면의 화학적 상태는 주사전자현미경, EDS (energy dispersive spectroscopy)가 탑재된 주사전자현미경, X-선 회절, 및 X-선 광전자 분광법을 이용하여 규명하였다. 더하여 정전압-전류 측정법 및 유도 결합 플라즈마 분광 분석기을 이용하여 전기 화학 반응을 유도하고, 반응 후 전해질의 성분분석을 통해 촉매와 지지체 간의 안정성을 평가하였다. 따라서 본 결과들은 한국진공학회 하계정기학술대회를 통해 좀 더 자세히 논의될 것이다.

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A Research on Control Method Design for the Intake Flow of a Dual Combustion Ramjet Engine using Multiple Control Inputs (다중의 제어입력을 이용한 이중연소 램제트 엔진의 흡입구 유동 제어기법 연구)

  • Park, Jungwoo;Park, Iksoo;Kim, Junghoe;Hwang, Kiyoung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.5
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    • pp.49-58
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    • 2018
  • This paper introduces a research on the control method design for the subsonic intake flow of a dual-combustion ramjet engine. To design the control method, the intake flow dynamic response characteristics, based on a designated flow condition and intake geometry, are investigated, and a control method concept considering the intake flow characteristics is established. Using a dynamic simulation model of a dual-combustion ramjet, control input/output linearized models are obtained such that a control loop design based on linearized models can be accomplished. Finally, from various control loop simulations, the performance of the control method, including its control loop stability, is evaluated.

Combustion Properties of Woods for Indoor Use (II) (실내 사용 목재의 연소 특성 분석 (II))

  • Seo, Hyun Jeong;Kang, Mee Ran;Son, Dong Won
    • Journal of the Korean Wood Science and Technology
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    • v.43 no.4
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    • pp.478-485
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    • 2015
  • The aim of this study is to analyze the combustion and thermal properties in order to establish baseline data for the fire safety evaluation of domestic timbers. The combustion properties such as heat release rate, total heat release, gas yield, and mass loss were analyzed by the method of cone calorimeter test and thermogravimetry (TGA). Thermal decomposition temperatures of the specimens by TGA were recorded as $359.83^{\circ}C$ for White pine, $359.80^{\circ}C$ for Red-Leaved Hornbeam, $363.14^{\circ}C$ for Carolina poplar, $358.59^{\circ}C$ for Konara oak, and $362.11^{\circ}C$ Sargent cherry. Red-Leaved Hornbeam showed the highest value of heat release rate, but, Carolina poplar wood showed the lowest value. In case of the total heat release, Red-Leaved Hornbeam wood showed the highest value and Carolina poplar wood showed the lowest one. The gas analysis results showed that Sargent cherry wood had the lowest value of 0.021, and Konara oak had the highest at 0.031 in the $CO/CO_2$. The minimum value of mass reduction was recorded as 87.57% for Sargent cherry, but, on the other hand, it was 95.03% for Konara oak. There was a correlation between the gas generation of CO and $CO_2$, and combustion behavior of woods. These results are expected to be usful for providing a fundamental guideline with the fire safety of wood use in interior applications.

On Design of Half-Wave Resonators for Acoustic Damping in a Model Combustion Chamber (모형 연소실내 음향 감쇠를 위한 반파장 공명기의 설계에 관한 연구)

  • Park, Ju-Hyun;Sohn, Chae-Hoon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.05a
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    • pp.18-21
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    • 2008
  • Acoustic design parameters of a half-wave resonator are studied experimentally for acoustic stability in a model combustor. According to standard acoustic-test procedures, acoustic-pressure signals are measured. Quantitative acoustic properties of damping factor and sound absorption coefficient are evaluated and thereby, the acoustic damping capacity of the resonator is characterized. The diameter and the number of a half-wave resonator, its distribution are selected as design parameters for optimal tuning of the resonator. Acoustic damping capacity increases as the resonators with diameter increases. The optimum number of resonators or the optimum open-area ratio decreases as boundary absorption decreases.

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Numerical Study on Heat Transfer Characteristic in Combustor Nozzle (추진기관 노즐의 열전달 특성에 관한 수치적 연구)

  • Namkoung, Hyuck-Joon;Han, Poong-Gyoo;Lee, Kyoung-Hoon;Kim, Young-Soo;Jeong, Hae-Seung
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.11a
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    • pp.275-281
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    • 2007
  • For a cooling performance research of the combustor operated in a extreme environment of a high temperature and high pressure, we accomplished a cooling performance analysis. Generally a heat transfer characteristic in cooling passage is known well experimentally and theoretically, however heat flux in the combustion chamber isn't. In this study, fluid flow combined with heat transfer analysis is accomplished about a combustor nozzle. We tried to analyze the cooling performance with a heat transfer characteristic of a gas and coolant side in the view point of quantity on the mass flow rate to be supplied to the cooling channel. And finally, evaluation on the thermal safety of nozzle wall material was accomplished.

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Study on Torrefaction Characteristics of Solid Biomass Fuel and Its Combustion Behavior (바이오매스 고형연료의 반탄화 특성 및 반탄화물의 연소특성에 관한 연구)

  • Lee, Weon Joon
    • Journal of the Korea Organic Resources Recycling Association
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    • v.23 no.4
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    • pp.86-94
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    • 2015
  • Torrefaction is a thermochemical process proceeded at the temperature around $250^{\circ}C$ in an inert gas condition. By torrefaction, the hemicellulose portions contained in biomass are broken down to change into the volatile gas which is removed from biomass eventually. The main purpose of biomass torrefaction is to improve the energy density of the biomass to minimize the transport energy consumption, though the flammability can be elevated for transportation. In this study two types of solid biomass fuel, waste wood and rice straw, were torrefied at various temperature range from $200^{\circ}C$ to $300^{\circ}C$ to evaluate the torrefied biomass characteristics. In addition torrefied biomass were tested to evaluate the combustion characteristics using TGA (Thermogravimetric Analysis). After the torrefaction of biomass, the C/H (carbon to hydrogen ratio) and C/O (carbon to oxygen ratio) were measured for aquisition of bio-stability as well as combustion pattern. Generally C/H ratio implies the soot formation during combustion, and the C/O ratio for bio-stability. By torrefaction temperature at $300^{\circ}C$, C/H ratio and C/O ratio were increased by two times for C/H and three times for C/O. The torrefied biomass showed similar TGA pattern to coal compared to pure biomass; that is, less mass decrease at lower temperature range for torrefied biomass than the pure biomass.

An Experimental Study on Filling Material for Bored Pile Using High Calcium Ash (고칼슘 연소재를 이용한 매입말뚝의 주면고정액에 관한 실험적 연구)

  • Song, Sang-Hwon;Lim, Yang-Hyun;Seo, Se-Gwan;Cho, Dae-Sung
    • Journal of the Korean Geosynthetics Society
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    • v.16 no.4
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    • pp.13-20
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    • 2017
  • In this study, laboratory tests were performed to evaluate for new filling materials (ZA-Soil) for bored pile that were developed using by high calcium ash. As a result of laboratory test, the uniaxial compression strength of 2 types of ZA-Soil are shown 68.0% and 64.6% compared to ordinary portland cement. And it have a suitable flowability and environmental stability. Also, after 28days, uniaxial compression strength of material mixed with soil and high strength filling material (ZA-Soil) for bored pile is 1.10-1.23 times bigger than material mixed with ordinary portland cement.

Effect on Properties of Epoxy Composite as the Kind of Flame Retardation (난연제 종류에 따른 Epoxy Composite 특성 연구)

  • Kim, Sang-Hyun;Lee, Woo-Sung;Kang, Nam-Kee;Yoo, Myong-Jae
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.212-212
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    • 2008
  • 에폭시 수지는 화학적 열적 안정성과 절기 절연성 및 기계적 특성 등 여러 가지 우수한 특성에도 불구하고 난연성은 그 단독으로 만족시킬 수 없기 때문에 난연제를 첨가함으로써 난연효과를 얻어왔다. 기존에 할로겐 화합물인 브롬계 난연제는 우수한 난연효과에도 불구하고 연소시 유해물질이 발생되어진다. 그리하여 인계 난연제를 첨가하는 것이 고분자 시스템에 난연성을 부여하는 효과적인 수단으로 대두되어지고 있다. 이 실험에서는 인계 난연제와 브롬계 난연제를 10, 20, 30, 40wt% 첨가하여 epoxy composite 제작하였다. 제작된 epoxy composite를 UL-94V 방법으로 난연성 평가하여 브롬계 난연제 20wt%에서 V-0를 획득할 수 있었으나 인계난연제 40wt%에서도 V-0를 만족할 수 없었다. 난연제 함량에 따른 Dielelctric constant 및 loss는 브롬계 난연제를 첨가시 감소하였고, 인계난연제의 경우 증가하였다.

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3D Finite Element Simulation of Pellet-Cladding Mechanical Interaction (3차원 유한요소를 이용한 핵연료와 피복관 기계적 거동 해석)

  • Seo, Sang Kyu;Lee, Sung Uk;Lee, Eun Ho;Yang, Dong Yol;Kim, Hyo Chan;Yang, Yong Sik
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.40 no.5
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    • pp.437-447
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    • 2016
  • In a nuclear power plant, the fuel assembly, which is composed of fuel rods, burns, and the high temperature can generate power. The fuel rod consists of pellets and a cladding that covers the pellets. It is important to understand the pellet-cladding mechanical interaction with regard to nuclear safety. This paper proposes simulation of the PCMI. The gap between the pellets and the cladding, and the contact pressure are very important for conducting thermal analysis. Since the gap conductance is not known, it has to be determined by a suitable method. This paper suggests a solution. In this study, finite element (FE) contact analysis is conducted considering thermal expansion of the pellets. As the contact causes plastic deformation, this aspect is considered in the analysis. A 3D FE module is developed to analyze the PCMI using FORTRAN 90. The plastic deformation due to the contact between the pellets and the cladding is the major physical phenomenon. The simple analytical solution of a cylinder is proposed and compared with the fuel rod performance code results.

Characteristics of Vitrification Process for Mixture of Simulated Radioactive Waste Using Induction Cold Crucible Melter (유도가열식 저온용융로를 이용한 혼합모의 방사성폐기물의 유리화 공정 특성)

  • 김천우;양경화;박병철;박승철;황태원;박종길;신상운;하종현;송명재
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.2 no.3
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    • pp.165-174
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    • 2004
  • In order to simultaneously vitrify the ion exchange resin(IER) and combustible dry active waste(DAW) generated from Korean nuclear power plants, a vitrification pilot test was conducted using an induction cold crucible melter(CCM) . The energy necessary for startup of the glass using a Ti-ring was evaluated as about 290 kWh. The power supplied from a high frequency generator to melt the glass properly was ranged from 160 to 190 kW without any interruption. When the mixture of the IER and DAW was fed into the CCM, the concentration of CO was lowered up to 1/40 compared to feeding the IER solely. It may be caused by the DAW which can produce about 1.8 times higher heat compared to the IER. When the swelling phenomenon occurred in the glass melt, the concentration of $NO_2$, oxidizing gas, was higher than NO, reducing gas. Total feed amounts of the IER and DAW were 368 and 751 kg, respectively. And then, about 74 of volume reduction factor was achieved.

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