• 한국자동차공학회논문집
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• 제13권6호
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• pp.21-30
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• 2005

Heat release analysis is a very importent method in understanding the combustion phenomena inside an engine cylinder. In this study, one-zone heat release analysis was used with the mesured cylinder pressures of an IDI(indirect injection), a HSDI(high speed direct injection) and a SI(spark ignition) engine. It has benefits of simple equation, fast speed, reliability. The object of the study is to compare the combustion characteristics among an IDI, a HSDI and SI engine. Result of analysis, the maximum heat release rate of a HSDI is higher than an IDI because of long ignition delay period. The heat release curve of a IDI is more linear than an HSDI, so the combustion characteristics of a IDI is similiar to that of an SI engine. There is a suggestion here that the combustion efficiency of a HSDI is highest of that of all engines because of the smallest heat transfer loss of all engines.

• 한국수소및신에너지학회논문집
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• 제21권2호
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• pp.123-128
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• 2010

Hydriding combustion synthesis (HCS) can produce full hydrides of alloys and in a short time. The conventional process based on ingot metallurgy cannot produce Mg-based alloy easily with the desired composition and the cast product needs a ling activation process for the practical use of hydrogen storage. In this study, the hydriding properties of Mg-xNi (x=5, 13.5, 54.7wt.%) alloys prepared by hydriding combustion synthesis were evaluated. The hydrogen storage capacity and kinetics of HCS Mg-xNi alloys were strongly dependent on the content of Ni. The HCS Mg-13.5wt.%Ni alloy shows the hydriding behavior to reach the maximum capacity within 30 min. and the reversible $H_2$ storage of 5.3wt.% at 623 K.

• 한국수소및신에너지학회논문집
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• 제27권5호
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• pp.562-570
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• 2016

At the carbon dioxide capture process using the aqueous amine solution, degradation of absorbents is main factor to reducing the process performance. Also, degradation mechanism of absorbent is important for understanding the environmental risk, route of degradation products, health risk etc. In this study, the degradation products of MEA were studied to clarify mechanism in thermal degradation process. The degradation products were analyzed using a $^1H$ NMR (nuclear magnetic resonance) and $^{13}C$ NMR. The analysis methods used in this study provide guidelines that could be used to develop a degradation inhibitor of absorbent and a corrosion inhibitor.

• 한국자동차공학회논문집
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• 제14권5호
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• pp.172-180
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• 2006

This study was to analyze the effect of mixed fuel composition and mass fraction on the characteristics of evaporating diesel spray and combustion under the various ambient conditions. The characteristics of vaporization distribution and combustion were visualized by laser induced fluorescent method and direct photography. The experiments were conducted in the constant volume vessel and rapid compression expansion machine with optical access. Multi-component fuels mixed i-octane, n-dodecane and n-hexadecane were injected the vessel and rapid compression expansion machine with electronically controlled common rail injector. Experimental results show that fuel vapor formed stratified distribution. And vaporization and diffusion are become actively increasing in mass fraction of low boiling point component. Consequently multi-component fuels were expected to control the evaporating behavior according to their suitable mass fraction.

• 한국전기전자재료학회논문지
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• 제23권1호
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• pp.14-17
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• 2010

$ZnGa_2O_4$ powder were prepared by combustion method and $Mn^{2+}$ ions, a green luminescence activator, and $Cr^{3+}$ ions, a red luminescence activator were separately doped into $ZnGa_2O_4$. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various $ZnGa_2O_4$ peaks, with the (311) main peak, appeared at all sintering temperature XRD patterns. The PL specctrums of $ZnGa_2O_4$ powder showed main peak of 425 nm, and maximum intensity at the sintering temperature of $1200^{\circ}C$. SEM images shown that nano sized particles(about 200 nm) were of spherical shape. The characteristics of $ZnGa_2O_4$ containing 0.004 mol $Mn^{2+}$(505 nm, green) and $ZnGa_2O_4$ containg 0.002 mol $Cr^{3+}$ (696 nm, red) were shown to be the best.

• 한국재료학회지
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• 제24권5호
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• pp.249-254
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• 2014

Due to their unique properties, tungsten borides are good candidates for the industrial applications where certain features such as high hardness, chemical inertness, resistance to high temperatures, thermal shock and corrosion. In this study, conditions were investigated for producing tungsten boride powder from tungsten oxide($WO_3$) by self-propagating high-temperature synthesis (SHS) followed by HCl leaching techniques. In the first stage of the study, the exothermicity of the $WO_3$-Mg reaction was investigated by computer simulation. Based on the simulation experimental study was conducted and the SHS products consisting of borides and other compounds were obtained starting with different initial molar ratios of $WO_3$, Mg and $B_2O_3$. It was found that $WO_3$, Mg and $B_2O_3$ reaction system produced high combustion temperature and radical reaction so that diffusion between W and B was not properly occurred. Addition of NaCl and replacement of $B_2O_3$ with B successfully solved the diffusion problem. From the optimum condition tungsten boride($W_2B$ and WB) powders which has 0.1~0.9 um particle size were synthesized.

• 한국화재소방학회논문지
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• 제26권4호
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• pp.18-23
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• 2012

이산화탄소 주조법에서 사용되고 있는 방법을 응용하여 목질내에 규산겔과 탄산소다, 이산화규소가 석출된 목재를 제조한 후 외부 복사열원(20, 25, 35 및 50 $kW/m^2$)에 따른 점화시간, 점화온도, 질량감소속도, 임계열유속을 측정하였다. 연구결과, 물유리와 이산화탄소를 이용한 가압함침 처리된 목재는 Pre-Flashover 단계에서의 복사열원(20 $kW/m^2$ 이하)에서 난연성능이 있음을 확인할 수 있었다. 향후 지속적인 연구를 통해 우수한 배합비율을 찾는다면 난연목재로서의 활용가능성이 있다고 판단된다.

• 한국화재소방학회:학술대회논문집
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• 한국화재소방학회 2009년도 춘계학술논문발표회 논문집
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• pp.557-563
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• 2009

FMVSS 302 수평 연소 시험법을 통과한 자동차 내장재의 열적 특성을 평가하기 위해서 콘칼로미터를 이용하여 시험을 수행하였다. 화재 위험과 관련된 착화시간(time to ignition), 열방출률(heat release rate), 질량감소율(specific mass loss rate), 감쇠계수(extinction coefficient) 그리고 연기요소(smoke factor)와 같은 여러 가지 요소들을 분석하였다. 최대 열방출률값은 시험편에 따라 232${\sim}$635kW/$m^2$으로 큰 편차를 보였으며, 연기요소 또한 99${\sim}$551MW/$m^2$로 큰 편차를 보였다. 보조매트의 최대 열방출률은 다른 시험편에 비해서 상대적으로 낮은 값을 보였지만, 총연기 발생이 다른 시험편에 비해서 상당히 높았다. 따라서 최대 열방출률과 총 연기발생을 함께 고려한 연기요소값은 상대적으로 다른 시험편에 비해서 높게 나타났다.

• 자원리싸이클링
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• 제5권2호
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• pp.45-51
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• 1996

국내산 무연탄의 경우 약 0.3∼7% 정도의 황을 포함하고 있어 연소시 대기오염은 물론 산성비의 원인이 되는 SOx 및 NOx 등을 배출한다. 환경오염 문제에 대처하기 위한 화력발전소의 SOx 방출 허용기준치는 우리나라의 경우 1995년 500ppm이지만 1999년에는 270ppm으로 강화될 전망이다. 본 연구에서는 고구배 자선기를 이용하여 습식 자력선탄과 오일 응집에 의한 탈황의 가능성을 조사하였다. 자력선별법에서는 입도의 크기, matrix 종류, 광액의 농도, 급광속도, 정선횟수 그리고 탄종변화 등을 실험한 결과 최적 실험조건에서 강릉지역산 시료의 석탄회수율은 82.1%, 황분제거율은 60.8%이었다. 오일 응집 시험에서는 pH변화, 응집제의 종류 및 첨가량, 광액의 농도, 정산 그리고 탄화도 등에 관하여 실험한 결과 마로산시료의 석탄회수율 98.0%이었으며, 회 및 황의 제거율은 각각 70.9%와 95.7%이었다.

• 한국추진공학회지
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• 제19권3호
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• pp.96-102
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• 2015

기존에 사용되고 있는 대부분의 추진물질들은 연소 시 이산화탄소, 염산가스 등의 환경유해 물질을 다량 발생시킨다. 본 연구에서는 이러한 문제점을 개선하기 위한 테트라진 계열의 저탄소 고질소 화합물인 DAAT의 합성공정을 확립하였다. 또한, 문헌에 빠져있는 구체적인 공정법 및 특성 분석 결과를 서술하였다. 그리고 분광분석(NMR, IR)을 통한 DAAT의 구조분석과 열, 충격, 마찰 안정성을 측정하였고, Gaussian 09와 EXPLO5를 이용하여 생성열과 폭발 특성(폭압, 폭속) 등을 계산하였다.