• Transactions of the Korean Society of Mechanical Engineers B
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• v.39 no.6
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• pp.505-511
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• 2015

Solid oxide fuel cell operate at high temperature ($800{\sim}1000^{\circ}C$). High temperature have an advantage of system efficiency, but a weak durability. In this study, linear state space controller is designed to handle the temperature of solid oxide fuel cell system for proper thermal management. System model is developed under simulink environment with Thermolib$^{(R)}$. Since the thermally optimal system integration improves efficiency, very complicated thermal integration approach is selected for system integration. It shows that temperature response of fuel cell stack and catalytic burner are operated at severe non-linearity. To control non-linear temperature response of SOFC system, gain scheduled linear quadratic regulator is designed. Results shows that the temperature response of stack and catalytic burner follows the command over whole ranges of operations.

• 한국신재생에너지학회:학술대회논문집
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• 2011.05a
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• pp.73.2-73.2
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• 2011

석탄 합성가스 중에는 $H_2S$, HCl, $NH_3$와 같은 불순물이 포함되어 있다. 이러한 가스들은 오염가스 배출과 관련한 환경기준 준수와 터빈과 같은 설비의 보호를 위해 제거되어야 한다. 석탄 합성가스 중 HCl 농도는 탄종에 따라 다르기는 하지만 많게는 1000 ppmv 수준까지 존재한다. 합성가스를 이용하여 발전을 하는 경우 가스터빈 보호를 위해 HCl은 <3 ppmv 이하로 정제되어야 하고, 합성가스를 연료전지에 사용하고자 하는 경우에는 HCl을 <0.5 ppmv 수준까지, 화학원료로 사용하고자 하는 경우에는 <10 ppbv 수준까지 정제하여야 한다. 또한 HCl은 고온 탈황공정에 사용되는 흡수제의 활성에도 장기적으로 부정적인 영향을 주기 때문에 고온에서 HCl을 정제할 수 있는 흡수제가 필요하다. 본 연구에서는 알칼리금속을 활성물질로 사용하여 분무건조법으로 제조한 HCl 흡수제에 대해 물성 및 HCl과의 반응성을 살펴보았다. $300-500^{\circ}C$ 영역에서 K-계 및 Na-계 흡수제에 대해 고정층반응기에서 HCl 가스를 함유한 모사 합성가스를 이용하여 상압 조건에서 Cl 흡수능을 측정한 결과 15wt% 이상의 흡수능을 나타내었으며 반응온도가 높을수록 흡수능이 증가함을 알 수 있었다. XRD 분석을 통하여 Cl은 K 및 Na와 반응하여 KCl과 NaCl을 형성하면서 흡수됨을 알 수 있었다. 20 bar 조건에서 실험한 결과에서도 동일한 경향의 반응성을 나타내었으며 반응온도가 낮을수록 흡수능은 감소하지만 Cl을 더 낮은 농도로 정제할 수 있었다. 본 실험에 사용된 Na 및 K계 흡수제는 모두 연소 후 배가스 중 $CO_2$를 제거하기 위한 흡수제로 사용되는 고체 흡수제이다. 석탄화력발전소 배가스에 연계되어 $CO_2$ 회수실험에 사용되었던 사용 후 $CO_2$ 흡수제에 대해 HCl 흡수 실험을 수행한 결과에서도 우수한 HCl 제거 성능을 보여 주었다. 이로부터, 폐 $CO_2$ 흡수제의 HCl 흡수제로서의 활용가능성을 확인 하였다.

• Journal of the Korean Society for Nondestructive Testing
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• v.16 no.1
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• pp.29-33
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• 1996

The eddy current test(ECT) probe of differential encircling coil type was designed and fabricated, and the optimum condition of ECT was derived for the examination of the irradiated fuel rod. The correlation between ECT test frequency and phase & amplitude was derived by performing the test of the standard rig that includes inner notches, outer notches and through-holes. The defect of through-hole was predicted by ECT at the G33-N2 fuel rod irradiated in the Kori-1 nuclear power reactor. The metallographic examination on the G33-N2 fuel rod was Performed at the defect location predicted by ECT. The result of metallographic examination for the G33-N2 fuel rod was in good agreement with that of ECT. This proves that the evaluation for integrity of irradiated fuel rod by ECT is reliable.

• Journal of Korean Society for Atmospheric Environment
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• v.14 no.4
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• pp.273-280
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• 1998

The investigation on the removal of 502 gas fro.In flue gas which causes serious air pollution was made by using a semi dry flue gas desulfurization method. Experiments were carried out as a function of process variables which would affect SO2 removal efficiency. Process variables inclilded SO2 inlet concentration, inlet temperature of simulated flue gas, sorbent weight fraction, and volume flow rate of sorbent slurry. In this study, used sorbent was Ca(OH), and simulated flue gas was prepared by mixing pure SO2 gas with air. Experimental conditions were varied at 140~18$0^{\circ}C$ of inlet temperature of the simulated flue gas, 500~2000ppm of inlet SO2 concentration, 0.4~1.0% of sorbent concentration, and 10~25 mL/min of flow rate of sorbent slurry. Among process variables, inlet concentration of SO2 was found to be the most significant factor to affect SO2 removal efficiency. The concentration of Ca(OH2) had a lower effect on SO2 removal than SO2 inlet concentration removal amount was 0.108, 0.141, 0.153 g SO2/g Ca(OH)2 respectively- As 200 mmol of HNO3 was added into slurry to improve removal efficiency, initial pH was maintained and solubility of slurry increased, so that removal efficiency elevated. Adding over 200 mmol of HNO3 into slurry caused removal efficiency lower. Therefore it could be concluded the optimum was 200 mmol of HNO3 input.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.32 no.4
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• pp.53-60
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• 2004

Optimal design of the hybrid motor has been performed for the first stage of nanosat air launch vehicle using F-4E Phantom as mother plane. Selected design variables are number of ports, the initial oxidizer flux, the combustion chamber pressure, and the nozzle expansion ratio. GBM(Gradient Based Method) and GA(Genetic Algorithm) are simultaneously used to compare the versatility of each algorithm for optimal design in this problem. Also, two objective functions of motor weight, and length are treated separatedly in the optimization to study how the objective function can affect the optimal design. The design results show that the optimal design can be successfully achieved either using GBM or GA regardless of the choice of the objective function; motor weight or length. And nanosat air launch vehicle which has total mass of 704.74kg, and length of first stage 3.74m is designed.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.31 no.6
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• pp.88-95
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• 2003

The weighted sum of gray gas model(WSGGM) is applied to arbitrary mixtures of CO$_2$ and H$_2$0 gases. To evaluate this model, the spectral and total intensities are obtained for two different problem types. One has uniform, parabolic and boundary layer type temperature profiles with uniform partial pressure, and the other has nonuniform partial pressure and temperature profile. The results obtained from the two different problem types show fairly good agreements with the results obtained by the statistical narrow band model(SNB model) which is regarded as the reference solutions. The WSGGM and its data base provided by this study can be used for analysis of radiative transfer by combustion gases with different thermal loadings and chemical compositions.

• 기계와재료
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• v.24 no.2
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• pp.38-46
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• 2012

인구의 증가와 급속한 산업화 그리고 편안함을 추구하고자 하는 문명의 이기로 인한 에너지 사용량 증가는 환경오염을 가속화시키는 문제를 유발하고 있어 전 세계적으로 심각한 사회문제로 대두되고 있다. 이에 반해 삶의 질의 향상에 따라 보다 쾌적한 환경에 대한 욕구와 인식의 변화로 환경보호에 대한 관심이 증가하는 추세이며, 이에 따라 각 국의 환경규제는 날로 강화되고 있다. 이러한 환경문제를 해결하기 위한 국제협력이 활발해지면서 무역과 연계된 국제 환경규제가 가속화되고 있으며, 환경선진국은 이러한 환경규제를 무역장벽으로 이용하고 있어 국가의 대외경쟁력에도 직 간접적으로 영향을 미치고 있다. 환경오염물질 중 질소산화물(NOx), 황산화물(SOx), 일산화탄소(CO), 이산화탄소($CO_2$) 및 휘발성유기화합물(VOCs), 다이옥신 그리고 입자상물질(PM)과 같은 대기오염물질은 대기 중으로 쉽게 확산되는 특성에 의해 인접한 지역까지 영향을 미치기 때문에 국제적인 규제대상의 초점이 되고 있으며, 경제협력개발기구(OECD, Organization for Economic Cooperation and Development), 유엔산하 국제해사기구(IMO, International Maritime Organization) 및 국제연소기구협회(CIMAC, International Council on Combustion engines)등 여러 국제기구를 중심으로 각종 규제수단을 개발하여 적용하고 있다. 특히, 국제해사기구(IMO)에서는 선박에서 발생되는 오염물질 등에 대한 규제강화를 위하여 새로운 국제해양오염방지협약(MARPOL)을 채택, 발효하여 그 규제 범위를 넓혀감에 따라 선박에 대한 각종 환경규제가 대폭 강화되고 있어 친환경 선박 및 관련 기술 개발이 활발히 진행 중에 있다. 이 글에서는 선박에서 배출되는 대기오염물질 중 그 자체로도 인체에 유해하며, 산성비, 광화학스모그 등 다양한 환경문제를 유발시키는 대표적인 물질인 질소산화물(NOx)과 질소산화물 배출규제에 대한 대응기술인 선택적촉매환원법(SCR, Selective Catalytic Reduction)과 SCR 탈질시스템에 사용되는 SCR 촉매에 대해 소개하고자 한다.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.42 no.3
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• pp.191-198
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• 2014

During multi-physics or multi-phase simulations accompanying fluid- structure- thermal interaction, data transfer problems always arise along non- matching interfaces caused by different computational meshes for each physical domain. Common- refinement scheme, among many available methods, is attractive since it is known to yield conservative and accurate data transfer for non- matching interface cases. This is particularly important in simulating compressible unsteady fluid- structure- thermal interaction inside solid propellant rockets, where grid size along solid- fluid interfaces is substantially different. From this perspective, we examine performances of common- refinement- based data transfer scheme between structured quadrilateral (structure part) and unstructured triangular (fluid part) meshes by comparing computed results with other data transfer methods.

• Journal of the Earthquake Engineering Society of Korea
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• v.3 no.1
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• pp.41-54
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• 1999

For free vibration of non-symmetric thin-walled circular arches including restrained warping effect, the elastic strain and kinetic energy is derived by introducing displacement fields of circular arches in which all displacement parameters are defined at the centroid axis. The cubic Hermitian polynomials are utilized as shape functions for development of the curved thin-walled beam element having eight degrees of freedom. Analytical solution for in-plane free vibration behaviors of simply supported thin-walled curved beams with monosymmetric cross-sections is newly derived. Also, a finite element formulation using two noded curved beams element is presented by evaluating elastic stiffness and mass matrices. In order to illustrate the accuracy and practical usefulness of this study, analytical and numerical solutions for free vibration of circular arches are presented and compared with solutions analyzed by the straight beam element and the ABAQUS's shell element.

• Journal of the Korean Ceramic Society
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• v.33 no.11
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• pp.1209-1216
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• 1996

MoSi2-Al2O3 composites were prepared by thermal explosion mode of self-propagating high temperature syn-thesis (SHS) using element powders of MoO3 Mo Si and Al. The combustion products of MoSi2 which have 10, 20, 30 and 40 wt% Al2O3 showed the molten state in the range of Mo to MoO3 6:1-9.5:1, 2:1-8:1, 1:1-5:1, and 1:1-3:1 (molar ratio) respectively. The combustion products which made least seperation the molten phase from the slag phase were in Mo/MoO3=9, 5:1, 8:1, 5:1 and 3:1 (molar ratio) respectively. Particles size of MoSi2 and Al2O3 in the combustion product were decreased as the molar ratio of Mo to MoO3 increase. By XRD analysis only MoSi2 and $\alpha$-Al2O3 peaks were identified in the combusion products, In case of MoSi2 containing 20wt% Al2O3 5.1wt% Al existed into MoSi2 grains and 30.7wt% Si and 7.7wt% Mo existed into Al2O3 grains. The relative density of MoSi2 containing 10, 20, 30 and 40 wt% Al2O3 were 82.7, 85.2, and 81.9% respectively. The fracture strength of MoSi2-Al2O3 composites increased with increasing Al2O3 and that of MoSi2-20wt% Al2O3 composite was 195 MPa.