• Journal of the Korean Ceramic Society
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• v.35 no.3
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• pp.231-238
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• 1998

Cr3C2 -dispersed TiC composites were prepared via HPCS(high pressure-self combustion sintering) pro-cess using mixtures of Ti, Cr and a carbon source for the purpose of increasing the facture toughness and sinterability of TiC. In this study the microstructure and properties of the composites were investigated in terms of relation to the carbon source the particle size of Ti and the amount of Cr. It was found that car-bon black was the most effective carbon source among the various carbon sources tested and the reaction was more effective as the particle size of Ti decreased. Among the sintered composites of Ti-C-Cr system the one with 30wt% Cr showed the best physical properties with 0.5% in apparent porosity 98.8% in re-lative density 18.2 GPa in hardness and 4.46 MPa.m1/2 in fracture toughness. In addition it was observed that the lattice constant of TiC decreased gradually with increasing the amount of Cr.

• Journal of Powder Materials
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• v.11 no.4
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• pp.294-300
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• 2004

This study for preparation of aluminum nitride (AlN) with high purity was carried out by self-propagating high-temperature synthesis method in two different systems, $Al-N_{2}$ and $Al-N_{2}$-AlN, with the change of nitrogen gas pressure and dilution factor. On the occasion of $Al-N_{2}$ system, unreacted aluminum was detected in the product in spite of high nitrogen pressure, 10 MPa, This may be caused by obstructing nitrogen gas flow to inner part of molten and agglomerate of aluminum, formed in pre-heating zone. In $Al-N_{2}$-AlN system, AlN with a purity of 95% or ever can be prepared in the condition of $f_{Dil}\geq0.5$, $P_{N_{2}}\geq$ 1 MPa, and the purity can be elevated to 98% over in the condition of $f_{Dil}$ = 0.7 and $P_{N_{2}}$ = 10 MPa.

• Proceedings of the KIEE Conference
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• 2006.07d
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• pp.1815-1816
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• 2006

소음은 환경 오염원의 하나로서 사람에게 육체적, 정신적 피해를 발생시킨다. 이에 소음 제어 기술의 필요성이 증대하였고, 그 중에서 제어가 까다롭고 고비용을 요구하는 저주파 소음 제어 기술의 개발이 확대되고 있다. 따라서 본 연구에서는 저주파의 주기적인 특성을 가지는 1차원 평면파 소음에 대한 능동 제어를 위해 기존의 적응 피드포워드 방법의 단점을 보완하는 적응 피드백 방법을 이용한 능동 소음 제어 시스템을 구성하고 능동 소음 제어 실험을 수행하였다. 이를 위해 소음원과 제어 음원을 가지는 덕트 형상의 실험 장치를 구성하였다. 제어기 설계를 위해 전파 소음을 예측하는 선형 예측법을 적용한 적응 디지털 필터를 구성하였으며 적응 알고리즘으로 Filtered-X LMS 알고리즘을 이용하였다. 제어기는 제어 알고리즘을 프로그램화하여 DSP에 입력함으로써 구성하였다. 실험에 사용된 소음은 500[Hz] 이하의 단일 주파수의 정현파 소음을 사용하였으며, 실험결과 음압 감소의 효과를 볼 수 있었다. 능동 소음 제어의 기술을 개발하여 하드웨어(덕트)의 모양 및 구조, 제어기의 종류 및 처리 속도, 주파수나 크기와 같은 특성이 급격히 변하는 소음의 경우에 능동적으로 소음을 제어할 수 있으며, 저주파 소음을 발생시키는 관형 연소기와 같은 장치 및 여러 분야에 응용이 가능하도록 하였다.

• Proceedings of the Korean Society of Propulsion Engineers Conference
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• 2009.05a
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• pp.196-199
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• 2009

The most important thing is to analyze the Fast Cook Off problem of the solid motor case exposed to direct flame is a heat transfer analysis. Heat causes degradation and ignition of the propellant. To archive an acceptable reaction level in Fast Cook Off, the rocket motor case generally must fail structurally prior to propellant ignition. We investigate the responses of the solid motor case exposed to Fast Cook Off by using finite element method for the thermal analysis.

• Journal of the Korean Ceramic Society
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• v.43 no.1 s.284
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• pp.16-21
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• 2006

The preparation of $TiB_2$ by SHS in $B_2O_3-Mg-TiO_2$ system was investigated in this study. In the preparation of $TiB_2$, the effect on reactivity and reaction products of the initial pressure of inert gas in reactor, the content of Mg and $TiO_2$ in mixture was investigated. The minimum initial pressure of inert gas in reactor for SHS reaction in this system was 5atm, and as the pressure increased, the concentration of unreacted Mg decreased and combustion temperature increased. At the initial inert gas pressure in reactor of 50atm, the optimum composition for the preparation of pure $TiB_2$ was $B_2O_3+5Mg+TiO_2$. The $TiB_2$ synthesized in this condition had an irregular shape and the particle size of $1\~3{\mu}m$.

• Journal of the Korean Ceramic Society
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• v.41 no.5
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• pp.388-394
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• 2004

LiCoO$_2$ as the cathode activity material for lithium secondary battery was prepared from a homogeneously mixed powder of LiNO$_3$/Co by SHS process under argon gas. The characteristics of powder including electrochemical properties were investigated according to various reaction conditions. The reaction temperature/velocity and the size of LiCoO$_2$ were controlled by Li/Co molar ratio and a cooling rate of the specimen, respectively. The maximum discharge capacity was 145 mAh/g on 1.05 Li/Co molar ratio and the relatively stable cycling characteristic with 6.4% of capacity fading was obtained after 10th charging-discharging test.

• Journal of the Korean Ceramic Society
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• v.34 no.5
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• pp.473-482
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• 1997

Titanium carbide(TiC) has a poor sinterability due to the strong covalent bond. Thus, it is generally fabricated by either hot pressing or pressureless-sintering at elevated temperature by the addition of sintering aids such as nickel(Ni), molybdenum(Mo) and cobalt(Co). However, these sintering methods have the following disadvantages; (1) the complicated process, (2) the high energy consumption, and (3) the possibility of leaving inevitable impurities in the product, etc. In order to reduce above disadvantages, we investigated the optimum conditions under which dense titanium carbide bodies could be synthesized and sintered simultaneously by high pressure self-combustion sintering(HPCS) method. This method makes good use of the explosive high energy from spontaneous exothermic reaction between titanium and carbon. The optimum conditions for the nearly full-densification were as follows; (1) The densification of sintered body becomes high by increasing the pressing pressure from 400kgf/$\textrm{cm}^2$ upto 1200 kgf/$\textrm{cm}^2$. (2) Instead of adding the coarse graphite or activated carbon, the fine particles of carbon black should be added as a carbon source. (3) The optimum molar ratio of carbon to titanium (C/Ti) was unity. In reality, titanium carbide body which were prepared under optimum conditions had relatively dense textures with the apparent porosity of 0.5% and the relative density of 98%.

• Journal of the Korean Ceramic Society
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• v.33 no.11
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• pp.1285-1291
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• 1996

Using Cr2O3 Al and graphite powders as starting materials Cr3C2 was synthesized by combustion synthesis process according to the following reaction : 3Cr3C2 +4C+6Allongrightarrow2Cr3C2 +3Al2O3. The synthesis was conducted at 2 atm in an argon atmosphere. in this study main-product was monolithic phase of Cr3C2 /Cr7C3 mixture and sub-product was slag state of $\alpha$-Al2O3. Single phase of Cr3C2 was obtained when crushed main-product was heat-treated at 120$0^{\circ}C$ for 3h in vacuum state with addition of 2.5wt% C. The obtained Cr3C2 powder can be used as plasma-arc deposit material because the flowability index of powder with the size of 9-50${\mu}{\textrm}{m}$ was 66.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2008.11a
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• pp.406-407
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• 2008

For this study, Yttrium aluminum garnet (YAG) particles doped $Eu^{3+}$ ions were prepared via the combustion process using the 1:1 ratio of metal ions to reagents. The characteristics of the synthesized nano powder were investigated by means of X-ray diffraction (XRD), Scanning Electron Microscope (SEM), and photoluminescence (PL). The various YAG peaks, with the (420) main peak, appeared at all sintering temperature XRD patterns. The YAG phase crystallized with results that are in good agreement with the JCPDS diffraction file 33-0040. The SEM image showed that the resulting YAG:Eu powders had larger sizes with the increse in the sintering temperature. The grain size was about 50nm at $1000^{\circ}C$. The PL intensity of $Eu^{3+}$ has the line peaks of 598, 610, 632nm and has main peak at 591nm.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.24 no.3
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• pp.435-442
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• 2000

The present study is conducted to investigate the local heat/mass transfer characteristics for flow through perforated plates. A naphthalene sublimation method is employed to determine the local heat/mass transfer coefficients on the effusion plate. Two parallel perforated plates are arranged for the two different ways: staggered and shifted in one direction. The experiments are conducted for hole pitch-to-diameter ratios of 6.0, for gap distance between the perforated plates of 0.33 to 10 hole diameters, and for Reynolds numbers of 5,000 to 12,000. The result shows that the high transfer region is formed at stagnation region and at the mid-line of the adjacent impinging jets due to secondary vortices and flow acceleration to the effusion hole. For flows through the perforated plates, the mass transfer rates on the surface of the effusion plate are about six to ten times higher than for effusion cooling alone (single perforated plate). More uniform and higher heat/mass transfer characteristic is obtained in overall region with small gap between two perforated plates.