• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
• /
• 2006.04a
• /
• pp.415-418
• /
• 2006

회동저수지를 중심으로 수영강 일대 하상퇴적물에 대한 PAHs(Polycyclic Aromatic Hydrocarbons) 오염특성 연구가 진행되었다. 하상퇴적물의 화학분석결과, 16 EPA PAHs 중 naphthalene 등 총 15개 성분이 검출되었으며, benzo(a)anthracene과 chrysene의 검출빈도가 가장 높고, 총 PAHs는 최대 7,116 ppb가 검출되었다. 한편 퇴적물 내 PAHs의 심도별 함량 변화는, 대체로 하부 시료에 비해 상부 시료에 PAHs 함량이 높게 나타나며, 특히 상부의 점토질 토양과 하부의 현지 토양이 함께 산출되는 시료의 경우, 하부 현지 토양에서의 PAHs 함량에 비해 상부 점토질 토양에서의 PAHs 함량이 높으며, 이는 PAHs가 수영강 으로부터 유입되어 주로 상부 점토질 퇴적물에 축적된 결과로 판단된다. PAHs의 기원은 전반적으로 수영강 상류지역에서는 연소 기원을 보이며, 수영강 하류에서는 교량 및 도심지역에서의 차량통행과 관련이 있는 석유류의 특징을 나타내며, 회동저수지의 경우 석유류와 연소 기원의 특징을 복합적으로 보여주고 있다.

• Journal of Korean Society of Environmental Engineers
• /
• v.39 no.3
• /
• pp.118-123
• /
• 2017

This study investigated the feasibility of a statistical approach for the prediction of BaP and total PAHs as pyrogenic sources. As results of regression, excellent linear and multiple correlations ($r^2$ > 0.94) were observed between BaP (or ${\Sigma}PAH$) and Pyr concentrations. When a developed prediction equation was applied to other investigations as validation and application studies, outstanding prediction results were obtained. The predictive model showed very good correlation between the measured and calculated ${\Sigma}PAH$. From this equation, Pyr was an apparently important hydrocarbon for the prediction of PAH. This model might provide a potentially useful tool for the calculation of average BaP and ${\Sigma}PAH$ in a certain region without additional tests.

• Proceedings of the Materials Research Society of Korea Conference
• /
• 2007.11a
• /
• pp.129.1-129.1
• /
• 2007

• Proceedings of KOSOMES biannual meeting
• /
• 2007.11a
• /
• pp.83-86
• /
• 2007

광양만권 개발에 따른 광양만의 매립과 준설로 인해 광양만의 급격한 지형변화가 일어나고 있다. 또한. 오염에 대한 우려가 있어 해양수산부에서는 특별관리해역으로 지정하여 관리하고 있다. 본 연구는 광양만 중앙의 묘도를 중심으로 5개의 정점을 선정하여 2005년 겨울부터 2007년 8월까지 총 8차례에 걸친 조사를 통해 장기적인 모니터링을 실시하여 환경변화에 따른 오염도를 조사하였다. 광양만의 중금속의 경우 농도의 변동양상으로 볼 때 오염원의 증가에 의한 변동보다는 계절적인 영향에 의한 변동양상으로 판단할 수 있다. 광양만에서 검출되는 중금속의 농도수준은 As를 제외한 전 항목이 US EPA 의 ERL을 초과하지 않은 것으로 조사되었다. 표층퇴적물 중 PAHs의 분석결과를 비교해 보면 지점별 농도변동양상이 뚜렷하지 않으며, 지점별 농도변화도 미약하다. PAHs 오염원의 추정의 결과 조사시기별 전 지점에서 분석한 결과, 몇 지점에서는 유류기원에 의한 오염의 경향이 보이는 반면 그 외의 대부분의 조사지점에서는 연소기원에 의한 PAHs 물질의 분포를 보였다.

• Journal of Wetlands Research
• /
• v.15 no.4
• /
• pp.441-451
• /
• 2013

Samples for estimating concentrations of polycyclic aromatic hydrocargons(PAHs), total petroleum hydrocarbons(TPHs), and benzene-toluene-ethylbenzene-xylene(BTEX) were collected at the tidal flat sediments of 8 coastal sites in Incheon, at seventy-two sampling stations for the surface sediment and twenty-four stations for the sediment core, twice in the spring and fall in 2011. This study was performed to evaluate the distributions of seasonal and spatial concentrations of PAHs, TPHs, and BTEX in the tidal flat sediments. The source origin of PAHs were carried out. The total average concentration of PAHs in the tidal flat sediment was $95.62{\mu}g/kg$. The characteristic of PAHs concentration distributions was observed that the average concentration in the autumn was lower than that in the spring, and higher concentration in the sediment core than the surface sediment, and greater vertical concentration at the top rather than the bottom in the sediment core. The total average concentration of TPHs at all sampling sites was in the value of 46 mg/kg. The characteristic of the TPHs concentration distribution was observed that the average concentration in the fall was much higher than that in the spring, and higher concentration in the surface sediment than the sediment core. The possible source of PAHs inputs were mainly derived from both pyrogenic and petrogenic origin at the surface sediment at Janghwari site and the sediment cores of both Sorae and Okyeon sites, while the rest sites of study areas originated with pyrogenic combustion.

• Proceedings of The Korean Society of Agricultural and Forest Meteorology Conference
• /
• 2003.09a
• /
• pp.35-38
• /
• 2003

아황산가스(SO$_2$)는 일차 대기오염물질 중의 하나이며, 수용성인 무색의 자극성 가스로써 주 배출원은 황을 함유하고 있는 석탄과 석유가 연소되는 공정과 금속 제련공정, 기타 산업공정 등으로 볼 수 있다. 최근 선진국들은 배출 규제를 통하여 아황산가스 배출량을 감소시켜왔으나, 개발도상국의 아황산가스 배출은 매년 증가하여 전 세계적으로는 증가 추세에 있다 (Agrawal and Deepak, 2003).(중략)

• Journal of the Korean Society of Marine Environment & Safety
• /
• v.26 no.2
• /
• pp.206-218
• /
• 2020

Located mostly inside the megacity of Busan, the Busan Southern Port is a multifunctional port with various nearby industry activities, including a joint fish market, ship repair facilities, and fishing boat facilities. If toxic chemicals generated by the industrial activities continue to flow into and accumulate in the sediment of the port, they can affect aquatic ecosystems and humans. Therefore, in this study, distribution levels and potential influent sources of organic pollutants, including polycyclic aromatic hydrocarbons (PAHs), polychlorinated biphenyls (PCBs), and butyltin compounds (BTs), in the sediment were investigated. The sediment samples were collected from eight sampling sites in November 2013 (first phase) and November 2014 (second phase). The mean concentrations of PAHs, PCBs, and BTs in the first and second sampling phages were 4174.0 ng/g-dry wt. and 1919.0 ng/g-dry wt., 166.3 ng/g-dry wt. and 21 ng/g-dry wt., and 50.9 ng/g-dry wt. and 30.8 ng/g-dry wt., respectively. The concentrations of the organic pollutants detected in the seabed sediments were lower in the second phase than in the first phase. In this study, the inflow sources of PAHs, PCBs, and BTs were found to be combustion, land, and municipal sewage or industrial wastewater, respectively.

• Journal of the Korean Society of Combustion
• /
• v.10 no.3
• /
• pp.25-33
• /
• 2005

Fast-time instability is investigated for diffusion flames with Lewis numbers greater than unity by employing the numerical technique called the Evans function method. Since the time and length scales are those of the inner reactive-diffusive layer, the problem is equivalent to the instability problem for the $Li\tilde{n}\acute{a}n#s$ diffusion flame regime. The instability is primarily oscillatory, as seen from complex solution branches and can emerge prior to reaching the upper turning point of the S-curve, known as the $Li\tilde{n}\acute{a}n#s$ extinction condition. Depending on the Lewis number, the instability characteristics is found to be somewhat different. Below the critical Lewis number, $L_C$, the instability possesses primarily a pulsating nature in that the two real solution branches, existing for small wave numbers, merges at a finite wave number, at which a pair of complex conjugate solution branches bifurcate. For Lewis numbers greater than $L_C$, the solution branch for small reactant leakage is found to be purely complex with the maximum growth rate found at a finite wave number, thereby exhibiting a traveling nature. As the reactant leakage parameter is further increased, the instability characteristics turns into a pulsating type, similar to that for L < $L_C$.

• Particle and aerosol research
• /
• v.14 no.4
• /
• pp.135-144
• /
• 2018

Based on a two-year measurement data, major sources for the ambient carbonaceous aerosols at the Anmyeon Global Atmosphere Watch (GAW) station were identified by using the Positive Matrix Factorization (PMF) model. The particulate matter less than or equal to $2.5{\mu}m$ in aerodynamic diameter (PM2.5) aerosols were sampled between June 2015 to May 2017 and carbonaceous species including ~80 organic compounds were analyzed. When the number of factors was 5 or 6, the performance evaluation parameters showed the best results, With 6 factor case, the characteristics of transported factors were clearer. The 6 factors were identified with various analyses including chemical characteristics and air parcel movement analysis. The 6 factors with their relative contributions were (1) anthropogenic Secondary Organic Aerosols (SOA) (10.3%), (2) biogenic sources (24.8%), (3) local biomass burning (26.4%), (4) transported biomass burning (7.3%), (5) combustion related sources (12.0%), and (6) transported sources (19.2%). The air parcel movement analysis result and seasonal variation of the contribution of these factors also supported the identification of these factors. Thus, the Anmyeon Island GAW station has been affected by both regional and local sources for the carbonaceous aerosols.

• Economic and Environmental Geology
• /
• v.38 no.4 s.173
• /
• pp.463-479
• /
• 2005

The Sr and Pb isotopic ratios and chemical composition were measured for atmospheric bulk deposition samples collected in the Jeonju, Gunsan and Namweon areas over a period of one year. Acidity of deposition ranged pH $4\~7$ with little higher in dry season, and around pH 5.0 in rainy season. The EC and TDS of rainy season was low showing dilution effect, and increased during dry season. Sulfate $(SO_4)\;and\;NO_3$ are atmospheric aerosols largely of anthropogenic origin in winter. Sodium was concentrated in winter deposition, Ca was concentrated in spring to summer deposition. Namweon has lower EC and TDS than those of other, and Jeonju has higher. Namweon was concentrated in $HCO_3$ and Cunsan was concentrated in Cl. Aluminium, Cu, and Zn show good correlation index with TDS, indicating of their origin atmospheric. $^{87}Sr/^{86}Sr$ ratios of bulk deposition ranged from 0.7109 to 0.7128. The isotopic variations are correlated with mixing of isotopic compositions of local soils, road deposit and biogenic aerosol. In order to constrain further the origin of aerosols in rainwater, it will be necessary to collect additional Sr isotopic data for aerosols. Lead isotope ratios for all areas were similar and belonged to Pb isotope ratios of Seoul's aerosols, but little different with Beijing's aerosols. It showing that Pb in the Korea mainly derived from the gasoline combustion, not exclusively from the Beijing.