• Title/Summary/Keyword: 연마 성능

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Conditioning Effects on LSM-YSZ Cathodes for Thin-film SOFCs

  • Lee You-Kee;Visco Steven J.
    • Journal of the Korean Electrochemical Society
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    • v.2 no.4
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    • pp.202-208
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    • 1999
  • Composite cathodes of $50/50\;vol\%$ LSM-YSZ $(La_{-x}Sr_xMnO_3-yttria\;stabilized\;zirconia)$ were deposited onto dense YSZ electrolytes by colloidal deposition technique. The cathode characteristics were then examined by scanning electron microscopy (SEM) and studied by ac-impedance spectroscopy (IS). The conditioning effects on LSM-YSZ cathodes were seen and remedies for these effects were noted in order to improve the performance of a solid oxide fuel cell (SOFC). The effects of temperature on impedance, surface contamination on cathode bonding to YSZ electrolyte, changing Pt paste, aerosol spray technique applied to curved surface on microstructure and cell to cell variability were solved by testing at $900^{\circ}C$, sanding the YSZ surface, using only one batch of Pt paste, using flat YSZ plates and using consistent procedures and techniques, respectively. And then, reproducible impedance spectra were confirmed by using the improved cell and the typical spectra measured for an (air)LSM-YSZ/YSZ/LSM-YSZ(air) cell at $900^{\circ}C$ were composed of two depressed arcs. Impedance characteristics of the LSM-YSZ cathodes were also affected by experimental conditions such as catalytic interlayer, composite cathode compositions and applied current.

진공 장비용 코팅부품의 내플라즈마 특성 평가 방법

  • No, Seung-Wan;Sin, Jae-Su;Lee, Chang-Hui;Gang, Sang-U;Kim, Jin-Tae;Sin, Yong-Hyeon;Yun, Ju-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.329-329
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    • 2010
  • 반도체 및 디스플레이의 진공부품은 알루미늄 모제에 전해연마법(electrolytic polishing), 양극산화피막법(Anodizing), 플라즈마 용사법(Plasma spray) 등을 사용하여 $Al_2O_3$ 피막을 성장시켜 사용되고 있다. 반도체 제조공정 중 30~40% 이상의 비중을 차지하는 식각(etching) 및 증착(deposition) 공정은 대부분 플라즈마를 사용하고 있다. 플라즈마에 의해 화학적, 물리적 침식이 발생하여 코팅막에 손상을 일으켜 코팅막이 깨지거나 박리되면서 다량의 Particle을 생성함으로써 생산수율에도 문제를 야기 시킨다고 알려져 있다. 하지만 이들 코팅막을 평가하는 방법은 거의 전무하여 산업계에서 많은 애로를 겪고 있다. 이러한 코팅부품의 내플라즈마 성능평가 방법과 기준이 없어 적절한 교체시기를 파악하기 위한 코팅부품의 손상정도를 정량화 및 평가 방법의 표준화를 구축하는 연구를 수행하였다. 본 연구에서는 이러한 소재의 특성평가를 위해 공정에서 사용 중 손상되어 교체된 샘플의 모폴로지 관찰하고 내전압 측정으로 전기적 특성을 분석하여 손상 전, 후의 변화를 관찰하였다. 또한 플라즈마의 영향에 따른 코팅 막 형태 변화 및 전기적 특성의 변화를 알아보기 위하여 양극산화피막법(Anodizing)으로 $Al_2O_3$를 성장시킨 평가용 샘플을 제작한 후, Plasma chamber 장비를 이용하여 플라즈마 처리에 따른 코팅막의 내전압, 식각율, 표면 미세구조의 변화를 측정하였고 이를 종합적으로 고려하여 진공 장비용 코팅부품의 공정영향에 의한 내플라즈마 특성평가방법 개발에 관하여 연구하였다. 이러한 실험을 통해 플라즈마 처리 후 코팅 막에 크랙이 발생되는 것을 확인할 수 있었고 코팅 막의 손상으로 전기적 특성이 감소를 것을 확인할 수 있었다. 또한 ISPM 장비를 이용하여 진공 장비용 코팅부품이 플라즈마 공정에서 발생하는 오염 입자를 측정할 수 있는 방법을 연구하였다. 이러한 결과를 이용하여 진공공정에서 사용되는 코팅부품이 플라즈마에 의한 손상정도를 정량화 하고 평가방법을 개발하여 부품 양산업체의 진공장비용 코팅부품 개발 신뢰성 향상이 가능할 것으로 본다.

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Integrated Superstructure Design of Elastic Components to Improve the Track Performance (궤도의 성능향상을 위한 탄성구성요소로 통합된 상부구조 설계)

  • Kang, Bo Soon
    • Journal of the Korean Society for Railway
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    • v.18 no.6
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    • pp.578-585
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    • 2015
  • Track elastic components can be technically and economically efficient when integrated well into track superstructure of a railway network. In such cases, the elastic rail pad is larger than a 800m radius curve provides smooth rail branching and allows for high-speed operation ($V{\geq}160km/h$). High track resistance causes the tamping intervals to stand out because the constantly increasing share of the sleeper pad further extends the increase of the tamping interval and the long grinding period; the engineering and construction of the small curve radius track provides some measures for reducing the solid sounds. Installation of elastic mats under the ballast can have a good effect, particularly in the context of protection against dust during construction or extensive renovation measures when laying new lines. However, such a process requires special attention and proper installation.

Characteristics of Concrete Sidewalk Block Manufactured Using Stone Powder Sludge and photocatalytic agent (석분슬러지와 광촉매제를 사용한 콘크리트 보도블록의 특성)

  • Jung, Yong-Wook;Lee, Seung-Han;Choi, Jong-Oh
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.6
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    • pp.4237-4244
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    • 2015
  • This study examined the efflorescence characteristics of a concrete sidewalk block manufactured using recycled stone powder sludge and photocatalytic generated by surface polishing during the sidewalk block manufacturing process. The study evaluated the characteristics of the sidewalk block in terms of its quality, based on the amount of stone powder sludge used, efflorescence, and further based on the mixing ratio and number of applications of the photocatalytic. The experimental results indicated that heavy metals such as lead, hexavalent chrome, cadmium, and mercury were not present in the concrete sidewalk block, thereby confirming the effectiveness of the recycled stone powder sludge. The optimum mixing ratio of used in the concrete sidewalk block (for satisfying KS standard values such as water absorption ratio and flexural strength) was found to be 20%. The concrete sidewalk block incorporating the stone powder sludge and photocatalytic exhibited a water absorption ratio of 5.4% and flexural strength of 5.2 MPa, thereby satisfying the quality standards. Additionally, when the photocatalytic was used, efflorescence did not occur even at the low temperature of $-5^{\circ}C$, and the by the sidewalk block was found to be 70% under normal conditions and 68% when subjected to an accelerated weathering test.

Improvement of Cycle Performance of Graphite-Silicon Monoxide Mixture Negative Electrode in Lithium-ion Batteries (흑연과 실리콘 일산화물의 혼합물로 구성된 리튬이온 이차전지용 음극의 사이클 성능개선 연구)

  • Kim, Haebeen;Kim, Tae Hun;Ryu, Ji Heon
    • Journal of the Korean Electrochemical Society
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    • v.22 no.4
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    • pp.155-163
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    • 2019
  • Mixture electrodes of a graphite having a good cycle performance and a silicon monoxide (SiO) having a high capacity are fabricated and their cycle performances are evaluated as negative electrodes for lithium-ion batteries. The electrode prepared by mixing the natural graphite and carbon-coated SiO in a mass ratio of 9:1 shows a reversible capacity of $480mAh\;g^{-1}$, 33% higher than that of graphite. However, the capacity deteriorates continuously upon cycling due to the volume change of silicon monoxide. In this study, the factors that can improve the cycle performance have been discussed through the change in the configurations of the electrode and the electrolyte. The electrode using the carboxymethyl cellulose (CMC) binder shows the best cycle performance compared to the conventional binders. The electrode sing the CMC and styrene-butadiene rubber (SBR) binder not only has almost the similar cycle characteristics with the electrode using the CMC binder but also has the better rate capability. When the fluoroethylene carbonate (FEC) is used as an electrolyte additive, the cycle life is improved. However, the electrolyte with 5 wt% of FEC is appropriate because the rate capability decreases when the content of FEC is increased to 10 wt%. In addition, when the mass loading of the electrode is lowered, the cycle performance is greatly improved. Also, enhanced cycle performance is achieved using the roughened Cu current collector polished by abrasive paper.

Development of a Silicon Carbide Large-aperture Optical Telescope for a Satellite (SiC를 이용한 대구경 위성용 망원경 제작)

  • Bae, Jong In;Lee, Haeng Bok;Kim, Jeong Won;Lee, Kyung Mook;Kim, Myung-Whun
    • Korean Journal of Optics and Photonics
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    • v.33 no.2
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    • pp.74-83
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    • 2022
  • The entire process, from the raw material to the final system qualification test, has been developed to fabricate a large-diameter, lightweight reflective-telescope system for a satellite observation. The telescope with 3 anastigmatic mirrors has an aperture of 700 mm and a total mass of 66 kg. We baked a silicon carbide substrate body from a carbon preform using a reaction sintering method, and tested the structural and chemical properties, surface conditions, and crystal structure of the body. We developed the polishing and coating methods considering the mechanical and chemical properties of the silicon carbide (SiC) body, and we utilized a chemical-vapor-deposition method to deposit a dense SiC thin film more than 170 ㎛ thick on the mirror's surface, to preserve a highly reflective surface with excellent optical performance. After we made the SiC mirrors, we measured the wave-front error for various optical fields by assembling and aligning three mirrors and support structures. We conducted major space-environment tests for the components and final assembly by temperature-cycling tests and vibration-shock tests, in accordance with the qualifications for the space and launch environment. We confirmed that the final telescope achieves all of the target performance criteria.

Design and Fabrication of APD-FET Module for 2.5 Gbps Optical Communicating System (광통신용 APD-FET 광수신모듈 설계 및 제작)

  • 강승구;송민규;윤형진;박경현;박찬용;박형무;윤태열;이창희;심창섭
    • Korean Journal of Optics and Photonics
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    • v.5 no.1
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    • pp.166-172
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    • 1994
  • The fiber optic receiver, ETRI APD-FET 1.0, is developed for the application of optical communication. This fiber optic receiver includes PD sub-module and pre-amplifier case. A single lens system is introduced for the PD sub-module. The sub-module consists of the avalenche photodiode(APD), GRIN rod lens, and a single mode fiber. The above components are enclosed into the stainless steel 304L housings. By bevelling the fiber end, the single mode fiber provides less than ~ 28 dB of optical return loss. The area of image focus is controlled by adjusting the length of spacer located in-between the fiber and the GRIN rod lens. The laser welding technique is applied to achieve the maximum coupling efficiency for the joining of each housing. In the pre-amplifier case, GaAs FET pre-amplifier workes for photocurrent amplification and the thermister is mounted to control the APD bias. The performance of ETRI APD-FET1.0 shows the sensitivity of - 30.3 dBm at $10^{-10}$ BER(bit error rate) and 2.5 Gbps optical random signal of $2^{23}-1$ word length. The fiber optic receiver is one of the essensial parts of the transmission module for B-ISDN. Also, the above optical packaging technology will be adapted for the developement of 10 Gbps transmission application 2.5 Gbps 5 Gbps

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Density and Water Absorption Characteristics of Artificial Lightweight Aggregates containing Stone-Dust and Bottom Ash Using Different Flux (폐석분 및 바텀애시를 사용한 인공경량골재의 융제(Flux) 종류에 따른 밀도 및 흡수율 특성)

  • Han, Min-Cheol;Shin, Jae-Kyung
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.3
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    • pp.49-55
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    • 2012
  • In this paper, the physical properties of lightweight aggregate such as density and water absorption according to addition ratio and type of flux were investigated. When using $Na_2CO_3$ as flux of lightweight aggregate, burnability was available at low burning temperature and water absorption increased. And as increasing addition ratio of $CaCO_3$, NaOH, $Fe_2O_3$, absorption decreased and $CaCO_3$, NaOH, $Fe_2O_3$ were considered improper to use flux of lightweight aggregate because of high dried density. $Na_2SO_4$ was proper to use flux of lightweight aggregate due to dried density $1.35{\sim}1.50g/cm^3$ and lower absorption. When using glass abrasive sludge as flux of lightweight aggregate, dried density and water absorption were in the range of $1.45{\sim}1.55g/cm^3$ and 9~12% respectively. It was indicated that as increasing addition ratio of blast furnace slag powder, density increased whereas absorption decreased. In use of oxidizing slag as flux, artificial lightweight aggregate which have dried density $1.46g/cm^3$, water absorption 8,5 % can be manufactured at 10 % of addition ratio.

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Study on the Infection Control and Dental waste Disposal in Dental Clinic Located in Seoul City (서울시 치과의원의 진료실 감염관리 및 폐기물 처리 실태 조사연구)

  • Kang, Jae-Kyoung;Kim, Eun-Sook;Kim, Kyung-Mi
    • Journal of dental hygiene science
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    • v.2 no.2
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    • pp.105-113
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    • 2002
  • This study was aimed to investigate the practice on the infection control and dental waste disposal in dental clinic. The data used in this study had been collected in 100 dental clinics located in Seoul city from August to October, 2001. It was shown that examination instruments, oral surgery instruments, and periodontal instruments were almost sterilization in dental clinic. It was high in the recognition of individual protection but it was low in the degree of practice. Therefore, the practice in infection control is very important to dental team for safety of patients and operators.

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Analysis of rock removal shape according to overlapping width of waterjet cutting (워터젯 절삭폭 중첩에 따른 암반제거 단면형상 분석)

  • Oh, Tae-Min;Park, Dong-Yeup;Park, Jun-Sik;Cho, Gye-Chun
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.23 no.3
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    • pp.167-181
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    • 2021
  • New type of rock excavation method using a waterjet system is being developed to secure economic feasibility and to reduce vibrations during excavation. In waterjet rock excavation, overlapping of cutting width is essential for high efficiency. In this study, cutting experiments for granite specimens were performed using abrasive waterjet system according to the overlapping ratio and standoff distance. Based on the experimental results, the granite cutting performance was analyzed according to the overlapping ratio. In addition, removal shapes of the cross-section were analyzed in terms of the cutting depth, width, and volume after waterjet cutting. When the overlapping ratio is less than 58%, rock specimens are partially removed due to the insufficient overlapping ratio. However, when the overlapping ratio exceeds 67%, overcutting phenomenon is observed. For the partial overlapping ratio (i.e., 25~75%), cutting efficiency is increased in the removal volume. This study is expected to be used as the important basic data for determining the optimum overlapping ratio when the waterjet system is applied for rock excavation.