• Korean Chemical Engineering Research
• /
• v.57 no.3
• /
• pp.438-443
• /
• 2019

A new measurement method is suggested to quantify the phosphate poisoning of cathodic Pt catalyst for HT-PEMFC. To do that, hydrogen peroxide was used as an indicator to reduce the error which has been occurred in conventional electrochemical measurement such as CV or ORR RDE with high concentration of phosphate ions. As a result, the current density induced from the reaction of hydrogen peroxide decomposition increased proportionally to the concentration of phosphate ion while the conventional methods show has a significant error with high concentration of phosphate ion. Thus, it is confirmed that the suggested way is superior to the conventional measurement method for the quantification of phosphate ion poisoning in an atmosphere similar to the actual operation condition of HT-PEMFC.

• Corrosion Science and Technology
• /
• v.20 no.6
• /
• pp.451-465
• /
• 2021

In this investigation, electrochemical characteristics and damage behavior of 316L stainless steel polymer electrolyte membrane fuel cell(PEMFC) were analyzed by potentiodynamic and potentiostatic tests in cathode operating condition of PEMFC. As the result of potentiodynamic polarization test, range of passive region was larger than range of active region. In the result of potentiostatic test, damage depth and width, pit volume, and surface roughness were increased 1.57, 1.27, 2.48, and 1.34 times, respectively, at 1.2 V compared to 0.6 V at 24 hours. Also, as a result of linear regression analysis of damage depth and width graph, trend lines of damage depth and width according to applied potentials were 16.6 and 14.3 times larger, respectively. This demonstrated that applied potential had a greater effect on pitting damage depth of 316L stainless steel. The damage tendency values were 0.329 at 6 hours and 0.633 at 24 hours with applied potentials, representing rapid growth in depth direction according to the test times and applied potentials. Scanning electron microscopy images revealed that surface of specimen exhibited clear pitting damage with test times and applied potentials, which was thought to be because a stable oxide film was formed by Cr and Mo.

• Korean Chemical Engineering Research
• /
• v.61 no.2
• /
• pp.202-207
• /
• 2023

In the case of driving water electrolysis by receiving surplus electricity from solar and wind power generation, operation and stopping must be repeated according to weather fluctuations. When the PEMWE(Polymer Electrolyte Membrane Water Electrolysis) is driven and stopped, the PEM fuel cell is in the same state as the PEM fuel cell due to the residual hydrogen and oxygen, and the high potential of the water electrolysis formed during operation is highly likely to cause degradation of the electrode and membrane even during stopping. In this study, in order to check how much degradation of the electrode and membrane progresses during the repeated driving/shutdown process of PEM water electrolysis, the performance decrease was measured by changing the number of driving/shutdown for 144 hours. Changes in electrode catalyst active area, hydrogen permeability and fluorine emision rate of membranes were analyzed to measure changes in the properties of electrodes and polymer membranes. Overall, the PEMWE performance decreased as the number of stops increased. When stopped 5 times in 144 hours, the IrO_x catalyst activity decreased by more than 30%, and the hydrogen permeability increased by 80%, confirming that both the electrode and the membrane were deteriorated.

• Journal of Hydrogen and New Energy
• /
• v.34 no.2
• /
• pp.178-186
• /
• 2023

Three activation methods (constant voltage, current cycling, and hydrogen pumping) were applied to investigate the effects on the performance of the membrane electrode assembly (MEA) loaded with PtCo/C catalyst. The current cycling protocol took the shortest time to activate the MEA, while the performance after activation was the worst among the all activation methods. The constant voltage method took a moderate activation time and exhibited the best performance after activation. The hydrogen pumping protocol took the longest time to activate the MEA with moderate performance after activation. According to the distribution of relaxation time analysis, the improved performance after the activation mainly comes from the decrease of charge transfer resistance rather than the ionic resistance in the cathode catalyst layer, which suggests that the existence of water on the electrode is the key factor for activation.

• Composites Research
• /
• v.22 no.1
• /
• pp.22-31
• /
• 2009

Recently the wind energy has been alternatively used as a renewable energy resource instead of the mostly used fossil fuel due to its lack and environmental issues. This work is to propose a structural design and analysis procedure for development of the 500W class small wind turbine system which will be applicable to relatively low speed region like Korea and for the domestic use. The wind turbine blade was performed structural analysis including stress, deformation, buckling, vibration and fatigue. In addition, the blade should be safe from the impact damage due to FOD(Foreign Object Damage) including the bird strike. MSC.Dytran was used in order to analyze the bird strike penomena on the blade, and the applied method Arbitrary Lagrangian-Eulerian was evaluated by comparison with the previous study results. Finally, the structural test was carried out and its test results were compared with the estimated results for evaluation of the designed structure.

• Journal of Hydrogen and New Energy
• /
• v.34 no.6
• /
• pp.555-561
• /
• 2023

In this study, we proposed a standard model for the design, construction and demonstration of the technology development and substantiation of small hydrogen powered vessel in order to respond to the alternative fuel-using vessel market that requires the use of low-carbon/carbon-free fuel as a greenhouse gas reduction measure. The hydrogen fuel cell-based electric propulsion system developed through this is optimized through performance and durability tests on the land-based test site (LBTS), and the electric propulsion system applied to this result is mounted on a small hydrogen propulsion vessel and operated. Simultaneously, through the digital twin technology between the LBTS and the hydrogen-propelled vessel on the sea, the technology that can predict and diagnose the problems that can occur in the electric propulsion system of the vessel is applied to carry out the empirical study of the hydrogen-propelled vessel. In addition, we propose a commercialization model by analyzing the economic feasibility of the demonstration vessel.

• Journal of Korea Society of Industrial Information Systems
• /
• v.29 no.1
• /
• pp.31-48
• /
• 2024

The domestic automotive industry must consider a strategic shift from traditional automotive component manufacturing to align with future trends such as connectivity, autonomous driving, sharing, and electrification. This research conducted topic modeling on R&D projects in the future automotive sector funded by the Ministry of Trade, Industry, and Energy from 2013 to 2021. We found that topics such as sensors, communication, driver assistance technology, and battery and power technology remained consistently prominent throughout the entire period. Conversely, topics like high-strength lightweight chassis were observed only in the first period, while topics like AI, big data, and hydrogen fuel cells gained increasing importance in the second and third periods. Furthermore, this research analyzed the areas of concentrated investment for each period based on topic-specific government investment amounts and investment growth rates.

• The Journal of the Institute of Internet, Broadcasting and Communication
• /
• v.24 no.4
• /
• pp.141-146
• /
• 2024

Energy Storage System(ESS) have been developed to store and efficiently utilize energy, transitioning from the traditional method of producing and consuming energy immediately via fossil fuels and generators. With the advancement of this technology, Battery Management System(BMS) that manage Li-ion batteries at the cell level play a crucial role in enhancing battery performance, lifespan, and safety. Among the BMS functions, cell balancing, which aligns the imbalanced voltages of cells, is essential for optimizing capacity in devices like ESS. It ensures all cells maintain the same voltage and capacity, improving performance and output stability. Therefore, this paper examines the operational characteristics of the cell balancing method within BMS when charging an imbalanced Li-ion battery.

• Journal of the Korean Society for Aeronautical & Space Sciences
• /
• v.44 no.12
• /
• pp.1071-1086
• /
• 2016

The safety of aircraft can be threatened by environmental factors, such as icing, turbulence, and lightning strike. Due to its adverse effects on aircraft structure and electronic components of aircraft, lightning strike is one of the biggest hazards on aircraft safety. Lightning strike can inject high voltage electric current to the aircraft, which may generate strong magnetic field and extreme hot spots, leading to severe damage of structure or other equipment in aircraft. In this work, mechanism of lightning strike and associated direct and indirect effects of lightning on aircraft were studied. First, on the basis of aircraft lightning regulations provided by Aerospace Recommended Practice (ARP), we considered different lightning waveform and zones of an aircraft. A coupled thermal-electrical computational model of ABAQUS was then used for simulating flow of heat and electric current caused by a lightning strike. A study on fuel tank, with and without lightning protection system, was also conducted using the computational model. Finally, electric current flow on two full scale airframes was analyzed using the EMA3D code.

• Journal of the Korean Electrochemical Society
• /
• v.4 no.4
• /
• pp.172-175
• /
• 2001

Nanophase catalyst layer for direct methanol fuel cell has been fabricated by magnetron sputtering method. Catalyst metal targets and carbon were sputtered simultaneously on the Nafion membrane surface at abnormally higher gas (Ar/He mixture) pressure than that of normal thin film processing. They could be coated as a novel structure of catalyst layer containing porous PtRu or Pt and carbon particles both in nanometer range. Membrane electrode assembly made with this layer led to a reduction of the catalyst loading. At the catalyst loading of 1.5mg $PtRu/cm^2$ for anode and 1mg $Pt/cm^2$ for cathode, it could provide $45 mW/cm^2$ in the operation at 2 M methanol, 1 Bar Air at 80"C. It is more than $30\%$ increase of the power density performance at the same level of catalyst loading by conventional method. This was realized due to the ultra fine particle sizes and a large fraction of the atoms lie on the grain boundaries of nanophase catalyst layer and they played an important role of fast catalyst reaction kinetics and more efficient fuel path. Commercialization of direct methanol fuel cell for portable electronic devices is anticipated by the further development of such design.