• Title/Summary/Keyword: 연료물성

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Development of Polymer composites Materials for DMFC Bipolar plates (고분자 복합소재를 이용한 DMFC용 분리판 개발)

  • Son, Dong-Un;Shim, Tae-Hee;Song, Ha-Young;Jung, Eun-Mi;Shin, Yong;Hwang, Sang-Moon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.11a
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    • pp.160-165
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    • 2009
  • 연료전지 분리판은 연료전지 스택을 구성하는 부품 중에서 가장 많은 수량이 사용되는 부품의 하나로서 연료전지의 출력밀도(Power Density, W/L), 비출력(Specific Power, W/kg) 및 가격($/kWe) 관점에서 가능한 저가의 소재 및 제조공정으로 경량, 박형화가 이루어져야 하는 핵심 부품이다. 이러한 저가의 경량, 박형화 분리판 개발의 전제조건은 연료전지 스택에서 요구하는 다양한 물성, 장기수명 및 신뢰성은 나타내는 내구성을 만족해야 하는 것이다. 이렇듯 연료전지 분리판은 다음과 같은 요구 조건을 만족해야 한다. 높은 전기전도도, 전기화학적 부식 저항성, 화학적 안전성, 가스 기밀성, 기계적 강도 및 가공성 등이라 하겠다. 본 연구에서는 분리판의 요구 조건을 만족할 수 있는 분리판을 제작하기 위하여 고분자 복합소재(PCB; Printed Circuit Board)를 이용하여 전기도금을 통해 Cu/Au(1st PCB 분리판)과 Cu/Ni/Au(2st PCB 분리판)을 코팅하여 분리판을 제작하였다. 제조된 분리판을 이용하여, 접촉저항, 부식특성, 가스 기밀성, 기계적 강도를 분석하였으며, 단위전지를 제작 하여 상용 Graphite 분리판과 성능을 비교분석하였다.

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Spray Characteristics of the Simplex Atomizer with Working Fluids (작동 유체에 따른 단순 압력식 연료노즐의 분무특성)

  • Choi, Chea-Hong;Lim, Byeong-Jun;Choi, Seong-Man
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.6
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    • pp.41-47
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    • 2009
  • This paper presents the spray characteristics of the simplex fuel nozzle with different working fluids for the gas turbine engine. Spray characteristics can be changed with viscosity, surface tension and density. In this research, water and test fluid type 2 which has similar characteristics of the kerosene are used as a working fluid. Spray visualization was performed by using ND-Yag laser and droplet size was measured by using PDPA(Phase doppler particle analyzer) system. The test results show that spray shapes and SMD distributions of two working fluids are similar at main spray region.

Modeling of Non-Equilibrium Kinetics of Fuel Rich Combustion in Gas Generator (농후 연소 가스발생기의 비평형 연소 화학반응 모델링)

  • 유정민;이창진
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.34 no.7
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    • pp.89-96
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    • 2006
  • The combustion temperature in gas generator should be kept below around 1,000K to avoid any possible thermal damages to turbine blade by adopting either fuel rich or oxidizer rich combustion. Thus, non-equilibrium chemical reaction dominates in the gas generator. Meanwhile, Kerosene is a compounded fuel mixed with various types of hydrocarbon elements and difficult to model the chemical kinetics. This study focus to model the non-equilibrium chemical reaction of kerosene/LOX with detailed kinetics developed by Dagaut using PSR(Perfectly stirred reactor) assumption. Also, droplet evaporation time is taken into account by calculating for the residence time of droplet and by decoupling reaction temperature from the reactor temperature. In Dagaut’s surrogate model for kerosene, chemical kinetics of kerosene consists of 1592 reaction steps with 207 chemical species. The comparison of calculation results with experimental data could provide very reliable and accurate numbers in the prediction of combustion gas temperature, species fraction and other gas properties.

Influences of changes in the Thermal Properties on Pyrolysis of Solid Combustibles (열물성의 변화가 고체 가연물의 열분해에 미치는 영향)

  • Hong, Ter-Ki;Lee, Jong Won;Park, Seul-Hyun
    • Fire Science and Engineering
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    • v.31 no.3
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    • pp.41-48
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    • 2017
  • In order to investigate the influence of changes in the thermal properties of solid combustibles on thermal decomposition, a series of solid pyrolysis experiments were performed using a cone calorimeter specified in KS F ISO 5660-1. In the present study, Poly Methyl Methacrylate (PMMA) which does not produce Char during pyrolysis process was used as solid fuel. Results obtained from cone calorimeter experiments were compared to ones obtained from numerical analysis of Fire Dynamics Simulator (FDS) 1D pyrolysis model adopted with thermal properties of solid fuel as input parameters. Comparisons between experimentally calculated and model-predicted mass loss rate were then made to elucidate the effect of changes in the thermal properties on pyrolysis of PMMA.

A Study on the Estimation of Homogeneous Physical Properties of Molten Carbonate Fuel Cell Stacks (용융탄산염형 연료전지 스택의 균질 물성치 추정에 관한 연구)

  • Lee, Sang-Wook;Suh, Yong-S.
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.12 no.7
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    • pp.2939-2944
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    • 2011
  • The performance and efficiency of a Molten Carbonate Fuel Cell system will improve with the aids of numerical simulations such as finite element analysis. For best simulation results, the virtual model must accurately reflect the actual model including the material properties. It is very difficult, however, to make a detailed numerical model of the stack that consists of hundreds of layers of unit cells composed of various materials like metal, ceramics, polymer, etc. Instead, a practical approach is to find a homogenized material property of the stack as a whole as an approximate replacement. In this paper, the compression ratio of a unit cell is introduced, and a new method is proposed to estimate the homogeneous material properties for both the active and the manifold regions of the stack under the assumption that the compressive deformation occurs only at the separators and matrices in the unit cells. The estimated properties are applied successfully to simulating an actual stack.

Modeling of Thermodynamic Properties of Saturated state Hydrogen using Equation of State (상태방정식을 이용한 포화상태 수소의 열역학적 물성 모델링)

  • Bong-Seop Lee;Hun Yong Shin;Choong Hee Joe
    • Korean Chemical Engineering Research
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    • v.61 no.4
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    • pp.550-554
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    • 2023
  • Fossil energy sources are limited in their sustainable use and expansion due to global warming caused by carbon dioxide emissions. Hydrogen is considered as a promising alternative to traditional fossil fuels. To ensure the stable long-term storage, it is necessary to accurately predict its thermodynamic properties at cryogenic temperatures. Therefore, this study aimed to investigate thermodynamic properties, such as saturated vapor pressure and density, enthalpy, and entropy of liquid and gas, using cubic equations of state that demonstrate relatively simple relationships. Among the three types of equations of state (Redlich-Kwong (RK), Soave-Redlich-Kwong (SRK), and Peng-Robinson (PR)), the SRK model exhibited relatively accurate prediction results for various physical properties.

A feasibility study on Introducing Reference Fuel(Diesel) for Testing Vehicles in South Korea (국내 차량 인증시험용 표준연료(경유) 도입 필요성 검토 연구)

  • Hwang, Inha;Kang, Hyungkyu;Seong, Sangrae;Song, Hoyoung;Ha, Jonghan;Na, Byungki
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.4
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    • pp.974-985
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    • 2017
  • Although the number of registered cars in South Korea is about 22million but, there is no national standard for automobile reference fuel in South Korea. Reference fuel is the fuel used for certificating vehicle performance, emissions and fuel economy. Now, domestic market fuels are used as reference fuel. However, the quality of domestic market fuel is constantly changing by seasonal and fuel manufacturers. It may effect vehicle performance, emissions and fuel efficiency test result. On this study, market diesel fuel quality was monitored and reference fuel standard(draft) was set by reflecting market fuel monitoring result. Reference fuel standard(draft) was applied to CRDI engine.

A Study on The Performance and Fuel Economy of Diesel Vehicles According to Change in Fuel Properties (연료물성에 따른 경유 차량의 성능 및 에너지소비효율 연구)

  • Noh, Kyeong-Ha;Lee, Min-Ho;Kim, Ki-Ho;Lee, Jung-Min
    • Journal of the Korean Applied Science and Technology
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    • v.35 no.3
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    • pp.667-675
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    • 2018
  • Increasing emissions regulations and demand of high-efficiency cars that travels a lot of distance with less fuel, there is growing interest in Energy Consumption Efficiency. Korean energy consumption efficiency compute combined Fuel Economy by driven city & highway driving mode and present final Energy Consumption Efficiency as using 5-cycle correction formula. Energy consumption efficiency is computed Carbon-balance-method, when used burning fuel play a key role in vehicle performance & Energy Consumption Efficiency. In Korea, vehicle fuel is circulate by Petroleum and Petroleum Alternative Business Act, there is property difference in quality standard because petroleum sector's refine method or type of crude oil. It does not appear a big difference according to fuel, because it sets steady quality standard, it may affect the performance of automobile. Thus, in research We purchase a few diesel fuel which circulated in the market in summer season though directly-managed-gas station by petroleum sector, resolve property each of fuel, we compute Fuel Economy each of them. We analyze into change depend on applying for property as nowadays utilizing Energy Consumption Efficiency calculating formula of gasoline and diesel fuel. As result, Density each of sample fuel has a maximum difference roughly 0.9%, net heat value each of sample fuel has difference 1.6%, result of current Energy Consumption Efficiency each of sample fuel has a difference roughly 1% at city drive mode, 1.4% at highway drive mode. Result of use gasoline calculator formula shows less 6% result than nowadays utilizing Energy Consumption Efficiency calculating formula, each of sample's Energy Consumption Efficiency shows maximum roughly 1.4% result in city & highway drive mode.

Property changes of PEFCs at the sub-zero temperature conditions (영하조건에서 고분자전해질 연료전지의 특성 변화)

  • Lim, Soo-Jin;Park, Gu-Gon;Park, Jin-Soo;Park, Seok-Hee;Yoon, Young-Gi;Lee, Won-Yong;Lim, Tae-Won;Lee, Young-Moo;Kim, Chang-Soo
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.212-215
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    • 2007
  • 고분자전해질연료전지 시스템이 영하 조건에 노출될 경우, 셀의 성능 및 내구성에 미치는 영향을 실험적으로 확인해 보았다. -30 $^{\circ}C{\sim}70$ $^{\circ}C$ 조건을 반복 경험시키며, 성능저하 정도를 살펴보았다. 일반적인 운전조건과 동결/해동에 의한 성능저하 요인을 분리하여 확인하기 위해, 30 $^{\circ}C{\sim}70$ $^{\circ}C$ 범위의 사이클을 진행한 경우에 대해, 위와 통일한 분석을 통하여 성능 및 각종 물성 값의 변화를 비교하였다. 동결조건에서 셀의 성능저하는 형성된 얼음의 물리적 부피팽창으로 인한 계면저항의 증가가 주요 원인임을 밝힐 수 있었다.

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A Study on the Performance of EFI Engine Used Ultrasonic Energy Adding Fuel System(I) -Attaching Importance to Fuel Characteristics for Ultrasonic- (초음파연료공급장치를 이용한 EFI 기관의 성능에 관한 연구(I) -초음파에 의한 연료의 물성변화를 중심으로-)

  • 윤면근;류정인
    • Transactions of the Korean Society of Automotive Engineers
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    • v.5 no.2
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    • pp.42-49
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    • 1997
  • This experimental study was performed to find fuel property variations of the ultrasonic energy adding gasoline and improve the spray characteristics of the multipoint injector for EFI engine. The cause and effect of the characteristic improvement of the ultrasonic energy adding fuel was found out by the chemical structure analysis (NMR, IR), distillation and viscosity test. The results are obtained that the chemical property of gasoline organizition was changed aromatics to paraffins and branch index as the physical characteristics of gasoline were improved by ultrasonic energy. There were higher distillation and lower viscosity in ultrasonic energy adding gasoline.

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