• Title/Summary/Keyword: 에틸렌 생성

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Dielectric Characteristics of Alumina by Surface Etching Effects (표면에칭효과에 의한 산화알루미늄 유전체의 정전용량 특성)

  • Oh Han-Jun;Park Chi-Sun
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.61-67
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    • 2004
  • The structural, electrical properties of the electrolytic capacitors were examined. By the addition of additives to hydrochloric acid solution increased the dielectric aluminum surface layer. For etch tunnels formed in hydrochloric acid, the away and density of the tunnels was not uniform, while for those formed in hydrochloric acid with additives the distribution presented relative uniformity. When the etched surface formed in hydrochloric acid with $5\%$ ethylene glycol, the enlargement of specific surface area was more effective.

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Effects of 2. 4-Dichlorophenoxyacetic Acid on the Growth Response and Fruit Quality of Strawberry (2. 4-Dichlorophenoxyacetic Acid 처리가 딸기의 생장반응 및 과실품질 향상에 미치는 영향)

  • 강양순;양의석;정연태
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.32 no.3
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    • pp.353-356
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    • 1987
  • To find out the effect of 2.4-D on growth response and fruit quality of strawberry, by leaf treatment (spray) of 120l/10a of 2.4-D(amine salt 40%) 10 ppm solution at flowering stage of 1st cluster, the experiment was carried out in the P-E film covered green-house. The strawberry plant showed the epinastic growing response with long petiole and petide and increased the evolution of ethylene from leaves and fruits after 2.4-D spraying. Therefore, the peak of picking time was accerated about 15 days according to the higher amount of ethylene evolution from strawberry plants, and the yield of fruit increased about 18% by improving the average weight of a fruit.

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Hydrogen production by catalytic decomposition of propane over carbon black catalyst in a fluidized bed (유동층 반응기에서 카본블랙 촉매를 이용하는 프로판 분해에 의한 수소 생산)

  • Yoon, Yong-Hee;Lee, Seung-Chul;Han, Gui-Young
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.11a
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    • pp.109-112
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    • 2007
  • 유동층 반응기를 이용한 프로판의 촉매 분해는 $CO_2$를 방출하지 않고 수소를 생성하는 새로운 방식이다. 카본블랙을 이용한 프로판 분해는 메탄보다 상대적으로 분해가 잘되며, 같은 온도에서 전환률이 높기 때문에 수소 생성량이 더 많다. 촉매로 사용된 카본블랙은 반응 중 생성되는 탄소의 침적에도 불구하고 8시간 이상 촉매의 활성이 유지되어 전환율이 일정하게 유지되었다. 프로판 촉매 분해 실험은 상압에서 600 ${\sim}$ $800^{\circ}C$ 온도 변화 실험을 수행하였고, 가스 유속 변화는 2.0 ${\sim}$ $4.0U_mf$에서 실험 조건 변화에 따른 실험을 하였다. 온도, 유속 변화에 따른 생성 가스의 몰분율과 프로판 전환율을 분석하였다. 프로판 분해에 의해 생성된 기체는 수소뿐만 아니라 메탄, 에틸렌, 에탄, 프로필렌과 분해되지 않은 프로판이 배출되었다. 수소를 제외한 여타 가스들은 고온에서 실험을 할수록 몰비가 줄어들었다. 고온에서 프로판의 전환율과 수소 수득률이 증가하였다. 프로판 분해 실험 전후의 카본블랙 표면의 변화는 FE-TEM으로 관측하였다.

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A numerical study on soot formation in ethylene diffusion flames under 1g and 0g (1g와 0g에서의 에틸렌 확산화염 내 매연 생성 특성에 관한 수치적 연구)

  • Choi, Jae-Hyuk;Park, Sang-Kyun
    • Journal of Advanced Marine Engineering and Technology
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    • v.37 no.8
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    • pp.807-815
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    • 2013
  • A numerical study on soot formation in a laminar ethylene diffusion flame at atmospheric pressure was conducted to obtain a better understanding of the effects of buoyancy on sooting flames under 0g and 1g using a gas-phase reaction mechanism and thermal and transport properties. A simple model was employed to predict soot formation, growth and oxidation with interactions between the gas phase chemistry and the soot chemistry taken into account. Results showed that the flames in 0g are much wider than that of 1g because of the thicker diffusion layer and reduction in axial velocity. The reduction in the axial velocity in 0g results in longer residence times, and resulting in greatly enhanced soot volume fraction. And, under zero-gravity, due to the lack of a buoyancy-induced instability, flame instability disappears.

Effect of N2 Diluent on Soot Formation Characteristics in Ethylene Diffusion Flames (에틸렌 확산화염 내 질소 혼합이 매연 생성 특성에 미치는 영향)

  • Jun-Soo Kim
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.29 no.4
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    • pp.356-362
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    • 2023
  • The risk of climate change has been long acknowledged, and ongoing efforts to overcome this issue, within the shipping sector, with the international maritime organization playing a central role. Conducting research on characteristics of soot formation is crucial to control its occurrence within the combustion process. In this study, the laser extinction method and chemical reaction numerical analysis were employed to examine the alterations in the state of chemical species associated with flame temperature, flame visual, and soot formation by mixing nitrogen, an inert gas, in the counterflow diffusion flame based on ethylene gas. The findings of the study suggest that as the mixing ratio of nitrogen increased, both the flame temperature and soot volume fraction decreased. Additionally, the area in which soot particles were distributed also decreased, and the volume fraction decrease rate declined when the mixing ratio increased by more than 30%. The mole fraction of the chemical species involved in soot growth also decreased. the chemical species associated with the HACA reaction were affected by variations in the hydrocarbon fuel ratio, and the chemical species related to the odd carbon path were confirmed to be affected by the flame temperature as well as the hydrocarbon fuel ratio.

Degradation of perchloroethylene by ferrate(VI) (Ferrate(VI)를 이용한 퍼클로로에틸렌의 분해특성 연구)

  • Kim, Il-Kyu
    • Journal of Korean Society of Water and Wastewater
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    • v.29 no.1
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    • pp.39-46
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    • 2015
  • The degradation characteristics of perchloroethylene by ferrate(VI) oxidation have been studied. The degradation efficiency of perchloroethylene in aqueous solution was investigated at various values of ferrate(VI) dosage, pH, initial concentration of perchloroethylene and aqueous solution temperature. GC-ECD has been used to analyze the changes of perchloroethylene concentration. The optimum conditions of perchloroethylene degradation were obtained at pH 7.0 and $25^{\circ}C$ of aqueous solution temperature. Also, the experimental results showed that perchloroethylene removal efficiency increased with the decrease of initial concentration of perchloroethylene. Lastly intermediate products were identified by GC-MS techniques. Trichloroethylene and chloroform were identified as reaction intermediates.

Continuous Mediated Electrochemical Oxidation of Ethylene Glycol by Co(III)/Co(II) and Fe(III)/Fe(II) Redox Systems (Co(III)/Co(II) 및 Fe(III)/Fe(II) 산화환원계에 의한 에텔렌글리콜의 연속 매개전해 산화)

  • Kim, Ik-Seong;Park, Seung-Cho
    • Applied Chemistry for Engineering
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    • v.16 no.5
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    • pp.635-640
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    • 2005
  • Mediated electrochemical oxidation (MEO) is an aqueous process which oxidizes organics electrochemicallly at low temperatures and pressures. The useful process can be used to treat mixed wastes containing hazardous organics. This paper have studied MEO of ethylene glycol (EG) in nitric acids by Fe(III)/Fe(II) and Co(III)/Co(II) system. It investigated current density, supporting electrolyte concentration, hydraulic retention time, removal efficiency of EG by MEO. Removal efficiency of EG by MEO was superior in Co(III)/Co(II) redox system than Fe(III)/Fe(II) redox system, where MEO removal efficiency was 100 percent. In case of EG, the reactions were fast and good yields of carbon dioxide formation was observed.

A Recombinant Soil Bacterium Which Efficiently Degrades Trichloroethylene (삼염화에틸렌을 분해하는 유전자재조합 토양세균에 관한 연구)

  • Kim, Young-Jun;Han, Gee-Bong;Chung, Jae-Chun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.11 no.4
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    • pp.49-56
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    • 2003
  • The strain Ralstonia eutopha JMP134 (formerly Alcaligenes eutrophus JMP134) can degrade trichloroethylene(TCE) through a chromosomal phenol-dependent pathway. The phenol hydroxylase was previously found to be a single responsible enzyme for TEC degradation. Here, we demonstrate that a recombinant bacterium, R. eutopha AEK301, one of Tn5-induced mutants of JMP134 containing a recombinant plasmid pYK3011, degrades TCE in the absence of inducer, phenol and in the presence of various carbon sources. Complete removal of TCE ($50{\mu}M$) was observed in minimal medium containing only 0.05% ethanol as a carbon source within 24 hours. The bacterium removed $200{\mu}M$ of TCE to below detectable level within two days under non-selective pressure. When TCE concentration was increased up to $400{\mu}M$, the degradation had been continued until two days, then ceased with removal of 70% of detectable TCE.

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Insensitivity of the ageotropum Pea Mutant Roots to Gravity (완두 돌연변이체 ageotropum 뿌리의 중력불감성)

  • Kim, Jeong-Im;Bin G. Kang
    • Korean Journal of Plant Tissue Culture
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    • v.22 no.6
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    • pp.345-350
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    • 1995
  • Root gravitropism was investigated in the pea (Pisum sativum L.) mutant ageotropum lacking normal gravitropic response. Exogenous ethylene treatment inhibited gravitropic response in the normal (wild type) pea rook, but had no significant effect to restore the unresponsiveness in the mutant Neither inhibitors of ethylene biosynthesis nor antagonists of ethylene action were able to bring about the development of gravioopic curvature in the ageotropum roots. Auxin action seems to be normal since asymmetric application of agar blocks containing auxin to the mutant roots caused normal gravitropic response to occur. Endogenous as well as auxin-induced ethylene production in tissue segments of the mutant root was about equal to that of the wild type. However no appreciable lateral transport of labeled auxin was observed in glavistimulated mutant roots whereas typical auxin asymetry was apparent in the wild type roots under the same conditions. It is concluded that the mutant has a defect in either gravity perception or its transduction, but not in the effector system involving auxin action.

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