• Title/Summary/Keyword: 에틸렌 글리콜

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Regulation of Unfolded Protein Response by Ethylene Glycol in Rat (Rat에서 ethylene glycol에 unfolded protein response의 조절)

  • Lee, Eun Ryeong;Kwon, Kisang
    • Journal of Life Science
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    • v.23 no.9
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    • pp.1104-1108
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    • 2013
  • Ethylene glycol (EG) is the most commonly used for automotive antifreeze, and it's easily misuseful for human. EG poisoning occurs in suicide attempts and infrequently, either intentionally through misuse or accidentally because of sweet taste. Though EG itself is mild toxic to the human body, it becomes higher toxic organic acids by in vivo broken down that are responsible for extensive cellular damage in various tissues caused principally by the metabolites. It is already well known that various cellular stresses induce gene expression of endoplasmic reticulum (ER) chaperones and ER stress sensors. This study demonstrated that regulation of gene expression of ER chaperones and ER stress sensors was induced by EG in rat tissues, and in tissues histological changes are also detected by both staining H&E and immunofluorescent.

Properties of LiNiO2 Powders Prepared by Spray Pyrolysis Process (분무열분해 공정에 의해 합성된 LiNiO2 분말의 특성)

  • Ju, Seo-Hee;Kang, Yun-Chan
    • Journal of the Korean Electrochemical Society
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    • v.11 no.4
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    • pp.297-303
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    • 2008
  • $LiNiO_2$ cathode powders with fine size have been synthesized by spray pyrolysis from the spray solution with citric acid and ethylene glycol. The as-prepared powders with spherical shape, porous structure and micron size turned into $LiNiO_2$ powders with micron size and regular morphology after post-treatment at $800^{\circ}C$. The initial discharge capacities of the $LiNiO_2$ powders changed from 199 to 171mAh/g when the concentrations of the citric acid and ethylene glycol added to the spray solutions were changed from 0 to 1 M. The maximum initial discharge capacity of the $LiNiO_2$ powders obtained from the spray solution with citric acid and ethylene glycol was 198 mAh/g when the lithium component added to the spray solution was 6 mol% excess of the stoichiometric amount. The discharge capacities of the fine-sized $LiNiO_2$ powders dropped from 198 to 163 mAh/g by the 30 th cycle at a current density of 0.1 C.

Study on the Free CaO Analysis of Coal Ash in the Domestic Circulating Fluidized Bed Combustion using ethylene glycol method (에틸렌글리콜법을 활용한 국내 순환유동층보일러 석탄회의 Free CaO 평가 연구)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Kim, Young-Jin;Choi, Moon-Kwan;Cho, Kye-Hong;Ahn, Ji-Whan
    • Journal of Energy Engineering
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    • v.26 no.1
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    • pp.1-8
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    • 2017
  • This study was carried out to physicochemical properties and free CaO contents of coal ash in domestic circulating fludized bed combustion power plant using ethylene glycol method. Results of physicochemical properties, there are many differences in CaO contents for the region position in CFBC plant. The reason, It is considered to be reflected that regulation of exhaust concentration for oxides of sulfur and other operation characteristics of region position in CFBC plant. Free CaO contents are 1.96 ~ 10.78% of fly ash and 0.07~4.24 % of bottom ash, fly ash is higher than in the bottom ash. besides CaO contents of raw materials, particle distribution have a lot of influence Free CaO contents.

Thermosensitive Sol-gel Phase Transition Behavior of Methoxy poly(ethylene glycol)-b-poly($\varepsilon$-caprolactone) Diblock Copolymers (메톡시 폴리(에틸렌 글리콜)-폴리($\varepsilon$-카프로락톤) 공중합체의 온도감응성 솔-젤 전이 거동)

  • 서광수;박종수;김문석;조선행;이해방;강길선
    • Polymer(Korea)
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    • v.28 no.4
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    • pp.344-351
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    • 2004
  • Poly(ethylene glycol)-based diblock and triblock polyester copolymers stimulating to temperature were studied as injectable biomaterials in drug delivery system because of their nontoxicity, biocompatibility and biodegradability. We synthesized the diblock copolymers consisting of methoxy poly(ethylene glycol) (MPEG) (M$_{n}$=750 g/mole) and poly($\varepsilon$-caprolactone) (PCL) by ring opening polymerization of $\varepsilon$-CL with MPEG as an initiator in the presence of HCl . Et$_2$O. The aqueous solution of synthesized diblock copolymers represented sol phase at room temperature and a sol to gel phase transition as the temperature increased from room temperature to body temperature. To confirm the in vivo gel formation, we observed the formation of gel in the mice body after injection of 20 wt% aqueous solution of each block copolymer. After 2 months, we observed the maintenance of gel without dispersion in mice. In this study, we synthesized diblock copolymers exhibiting sol-gel phase transition and confirmed the feasibility as biomaterials of injectable implantation.n.

An analysis on the characteristics of regasification system for LNG-FSRU depending on the changes in performance with vaporization and temperature of the heat source (LNG-FSRU용 재기화 시스템의 열원 온도 및 기화성능의 변동에 따른 시스템 특성분석)

  • Lee, Yoon-Ho;Kim, You-Taek;Kang, Ho-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.6
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    • pp.625-631
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    • 2014
  • In this study, according to increase of thermoelectric power plants that use LNG, LNG-FSRU(Floating-Storage and Regasification Unit) appeared and it is installed on the Topside in order to deliver in a gaseous state to consumers who are in the shore. This study about the study on the characteristics analysis of the system depending on changes in performance with the vaporization and temperature of the heat source. For the characteristics analysis of the system, we devided vaporization method into Ethylene glycol water vaporization method and sea water as a heat source. Then the system that can vaporize 200ton per hour of LNG of $-157.9^{\circ}C$ and 10,400kPa was configured, and according to the temperature of supplied sea water, required minimum flow rate value was calculated. Also in case of using Ethylene glycol Water as a vaporization method, providing for regional and seasonal factors such as decrease of temperature of water. The system is configured by adding a steam boiler of $174.5^{\circ}C$, 775kPa as heat source. The generation amount of the steam required according to the performance of the vaporizer compared to the water temperature changes in the steam boiler and the amount of required evaporative performance due to changes in the quantity of steam and Ethylene glycol Water was confirmed.

Chemical Structure Study on Copolyterephthalates Based on Ethylene Glycol and 1, 4-Cyclohexane Dimethanol by High Resolution NMR Analysis (고분해능 NMR 분석법에 의한 에틸렌글리콜과 1, 4-시클로헥산디메탄올의 테레프탈산 공중합체의 화학구조 연구)

  • Yoo, Hee-Yeoul;Kim, Sang-Wook;Okui, Norimasa
    • Applied Chemistry for Engineering
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    • v.4 no.4
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    • pp.770-775
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    • 1993
  • Chemical structure of poly(ethylene terephthalate-co-1, 4-cyclohexylene dimethylene terephthalate), P(ET-CT) copolyesters was investigated by High Resolution NMR analysis. The copolymer composition and isomeric ratio were determined by methylene resonance peaks which were separated into three peaks corresponding to ET, trans CT and cis CT units, respectively. The copolymer sequence distribution was evaluated from the carbon resonance peaks connected to carbonyl groups in benzene, indicating died distribution. According to statistics model, these copolyesters are almost random copolymers. The copolymer sequence distribution could be simulated and its averaged length was calculated by random copolymer statistics.

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Synthesis of Silver Nano-Particles using Alcohol Reducing Process and Antibacterial Properties of its Ag/PET Master Batch (알코올환원법을 이용한 은나노입자 제조 및 이를 함유한 Ag/PET 마스터배치칩의 항균특성에 관한 연구)

  • Son, Eun-Jong;Hwang, Young-Gu;Shin, Yu-Shik;Jung, Gi-Hoon;Jung, Hae-Rim;Jeong, Sung-Hoon
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.56-56
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    • 2011
  • 알코올 환원법(alcohol reducing process)은 화학적 환원제가 필요하지 않은 화학합성법으로 메탄올, 에탄올, 프로판올, 이소프로판올, 부탄올 등 C1-C4의 알코올류, 에틸렌 글라이콜, 디에틸렌 글라이콜, 프로필렌 글라이콜과 같은 글리콜류 등이 용매이자 환원제로써 사용된다. 전형적으로 금속 전구체를 상기의 알코올류나 글리콜류에 용해 또는 분산시킨 후 그 용액을 환류 조건하에서 가열하게 되면 금속 이온과 용매간의 산화, 환원반응에 의하여 금속이온이 금속원자로 환원되며, 환원된 금속 입자들은 핵 행성과 성장 과정을 거쳐서 입자를 형성하게 된다. 본 연구에서는 알코올환원법을 이용하여 나노크기의 은입자제조를 시도하였고, 이를 PET 칩과의 마스터배치 제조을 시도하였으며, 이의 항균성능을 연구 고찰하였다. 30 ~ 80 nm의 은파우더를 제조할 수 있었으며, 우수한 항균성능을 갖는 Ag/PET 마스터배치를 제조할 수 있었다. 이를 활용하여 나노은입자기반의 항균섬유을 제조하여 이를 활용한 기모경편성물 제조의 기초데이타로 활용이 가능하리라고 사료된다.

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Synthesis of Dendrimer with PEG Core by Click Chemistry (클릭 화학에 의한 PEG 핵을 갖는 덴드리머의 합성)

  • Han, Seung-Choul;Jin, Sung-Ho;Lee, Jae-Wook
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.295-301
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    • 2012
  • Efficient stitching methods for the synthesis of Fr$\acute{e}$chet-type dendrimers with linear PEG units at a core were elaborated. The synthetic strategy involved an inexpensive 1,3-dipolar cycloaddition reaction between an alkyne and an azide in the presence of Cu(I) species which is known as the best example of click chemistry. The linear core building blocks, two diazido-PEG units, were chosen to serve as the azide functionalities for dendrimer growth via click reactions with the alkyne-dendrons. These two building blocks were employed together with the alkyne-functionalized Fr$\acute{e}$chet-type dendrons in a convergent strategy to synthesize two kinds of Fr$\acute{e}$chet-type dendrimers with different linear core units.

Dielectric Characteristics of Alumina by Surface Etching Effects (표면에칭효과에 의한 산화알루미늄 유전체의 정전용량 특성)

  • Oh Han-Jun;Park Chi-Sun
    • Journal of the Microelectronics and Packaging Society
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    • v.11 no.4 s.33
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    • pp.61-67
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    • 2004
  • The structural, electrical properties of the electrolytic capacitors were examined. By the addition of additives to hydrochloric acid solution increased the dielectric aluminum surface layer. For etch tunnels formed in hydrochloric acid, the away and density of the tunnels was not uniform, while for those formed in hydrochloric acid with additives the distribution presented relative uniformity. When the etched surface formed in hydrochloric acid with $5\%$ ethylene glycol, the enlargement of specific surface area was more effective.

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