• Title/Summary/Keyword: 에틸렌 글리콜

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The Variation of Density and Settlement for Contaminated Sediments During Electrokinetic Sedimentation and Remediation Processes (오염퇴적토에 대한 동전기적 침전 및 정화 공정에서의 시료 밀도 및 침하 변화 특성)

  • Chung, Ha-Ik
    • Journal of the Korean Geotechnical Society
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    • v.22 no.9
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    • pp.5-14
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    • 2006
  • Generally, the sediments contain significant water, clay, colloidal fraction and contaminants, and can result in soft strata with high initial void, and its potential hazards in subsurface environments exist. Electrokinetic technique has been used in sedimentation for volume reduction of slurry tailing wastes and in remediation for extraction of contaminants from contaminated soils. In this research, the coupled effects of sedimentation and remediation of contaminated sediments are focused using electrokinetic sedimentation and remediation techniques from experimental aspects. A series of laboratory experiments including variable conditions such as initial solid content of the specimen, concentration level of the contaminant, and magnitude of applied voltage are performed with the contaminated sediment specimens mixed with ethylene glycol. Commercially available high specification Kaolin was used to simulate slurried sediment. From the test results, the settlement of specimen increases with increasing of applied voltage and decreasing of solid content and contamination level. The density of specimen increases due to settlement of specimen in the process of electrokinetic sedimentation and decreases due to extraction of organic contaminant in the process of electrokinetic remediation.

Ballistic Resistance Performance of Kevlar Fabric Impregnated with Shear Thickening Fluid (전단농화유체가 함침된 Kevlar 재료의 방탄특성)

  • Song, Heung-Sub;Yoon, Byung-Il;Kim, Chang-Yun;Park, Jong-Lyul;Kang, Tae-Tin
    • Composites Research
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    • v.20 no.3
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    • pp.1-7
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    • 2007
  • Manufacturing process of the shear thickening fluid(STF) and evaluation of the ballistic penetration resistance performance of the Kevlar-STF composites were studied. STF was made from silica and ethylene glycol, and the Kevlar-STF composite was made by impregnating the STF into the Kevlar fabric. Specimens including neat Kevlar woven fabrics and Kevlar-STF composites with two types of silica were prepared and carried out the ballistic tests. From the results STFs represented shear thickening behavior irrespective of the silica type, and Kevlar-STF composite with spherical silica showed best ballistic penetration resistance performance among them. Especially the specimens of Kevlar-STF composites with spherical silica showed radial fiber deformation by the projectile during the tests, that was somewhat different deformation behavior from those of the neat Kevlar fabrics shown fiber pull-out phenomena or fracture.

Analysis of Properties of Water-Dispersed Bio-Polyurethane Based on Caster Oil for Lamb Leather Surface (Lamb Leather용 Caster Oil 기반 수분산 바이오 폴리우레탄필름의 제조)

  • Lee, Joo-Youb
    • Journal of the Korean Applied Science and Technology
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    • v.39 no.2
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    • pp.161-168
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    • 2022
  • Unmodified castor oil (CO) was used to obtain a castor-based aqueous polyurethane (CPUD) and isophorone diisocyanate (IPDI) was used to obtain a transparent film. The mixing effect of polypropyleneglycole (PPG) was analyzed to increase flexibility. In addition, ethylenediamine (EDA) was used as a chain extender. Tensile strength, elongation, and abrasion resistance were measured according to the change according to the castor oil content and the change in the chain extender, respectively. The tensile strength of the sample containing a lot of castor oil was 1.112 kgf/㎟, and the elongation was 88%. The tensile strength of the sample containing a lot of chain extender was 3.33kgf/㎟, and the elongation was 99%. The surface strength was visually confirmed through SEM. The surface strength was visually confirmed through SEM.

Quantitative Evaluation of Free CaO in Electric Arc Furnace Reduction Slag using the Ethylene Glycol Method (에틸렌 글리콜법을 이용한 전기로 환원슬래그의 Free CaO 정량 평가에 관한 연구)

  • Kwon, Seung-Jun;Lim, Hee-Seob;Lee, Han-Seung
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.4
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    • pp.321-327
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    • 2018
  • Blast furnace slag has been actively used as a substitute for cement in the construction field with high value-added through resource recycling research. However, most of the slag cannot find a clear recycling purpose. This is because some slags contain unstable materials and are used for road-use asphalt and embankment, which are low value-added materials. Electric arc furnace reduction slag(ERS) has been reported to contain a large amount of unstable free CaO due to deoxidation and component adjustment. In this study, free CaO of ERS which is generated in Korean steelmakers is quantitatively evaluated by using ethylene glycol method. As a result of free CaO quantitative evaluation of ERS, it was confirmed that there is a big difference according to the location of each field. In addition, ERS generally existed in powder form as undifferentiated characteristics, but it was confirmed that free CaO content was different due to hydration product in aggregate form due to water treatment. In addition, free CaO is an amorphous material and its crystallization characteristics are different due to the influence of temperature when it is cooled. ERS requires a long-term aging period as it contains a lot of free CaO.

An analysis on the characteristics of regasification system for gas fuelled ship depending on the mixing ratio of eglycol and water (Gas Fuelled Ship용 재기화 시스템의 Eglycol Water 혼합비율에 따른 시스템 특성분석)

  • Lee, Yoon-Ho;Kim, You-Taek;Kang, Ho-Keun
    • Journal of Advanced Marine Engineering and Technology
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    • v.38 no.7
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    • pp.799-805
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    • 2014
  • Recently, the regulations of the Local and Global for a variety of air pollution prevention has been enhanced by the steep rise in fuel oil prices. So, the appearance of Gas Fuelled Ships became necessary. In this study, we configured a regasification system which uses Eglycol water as a heating medium to evaporate before being supply fuel to the DF engine, then we analysed the system properties according to the Eglycol water mixing ratio. The results were as follows. When pressure, temperature, and flux of natural gas(NG) which are supplied to DF engines are uniformly kept, the higher mixing ratio of Eglycol is, the lower mixing specific heat of Eglycol water. And the cycle flux and electric power were 1.65 and 1.54 times more required. respectively, than water was used as the heating medium. Basic variables including mass flux according to the mixing ratio of Eglycol water, required electric power of operating fluid pumps, the temperature of natural gas which is supplied to the engine, and the heat exchanger's capacity were drawn from the gotten results.

Comparison of Vitrification and Slow Freezing for the Cryopreservation of Chicken Primordial Germ Cell (Ogye) (한국재래닭 (오계) 원시생식세포의 완만동결과 급속동결의 비교)

  • Kim, Sung Woo;Ko, Yeoung-Gyu;Byun, Mijeong;Do, Yoon Jung;Han, Jae Yong;Kim, Dong Hun;Seong, Hwan-Hoo;Kim, Hyun
    • Journal of Animal Science and Technology
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    • v.55 no.5
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    • pp.417-425
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    • 2013
  • We sought to provide a method for freezing and preserving primordial germ cells, or an avian germ cell of a bird, as a material for developmental engineering or species preservation. The aim of this study was to compare the efficacy of slow freezing with a vitrification method for the cryopreservation of chicken primordial germ cells (PGCs). PGCs obtained from the germinal gonad of day 5.5-6 day (stage 28) cultured chick embryos, using the MACS method, were classified into two groups: slow freezing and vitrification. We examined the viability of PGCs after Cryopreservation. Four freezing methods were compared with each other, including the following: Method 1: The PGCs were frozen by a programmed freezer in a plastic straw, including 2.0 M ethylene glycol (EG) as cryoprotective additive (slow freezing) Method 2: The PGCs were vitrified in a plastic straw, including 8.0 M EG, plus 7% polyvinylpyrrolidone (PVP) (rapid freezing). Method 3: The slow freezing was induced with a cryotube including 2.0 M EG Method 4: The PGCs were frozen in a cryotube including 10% dimethyl suloxide (DMSO) (rapid freezing). After freezing and thawing, survival rates of the frozen-thawed PGCs from Method 1 to 4were 76.4%, 70.6%, 80.5% and 78.1% (p<0.05), respectively. The slow freezing ($-80^{\circ}C$ programmed freezer) method may provide better survival rates of frozen-thawed PGCs than the vitrification method for the cryopreservation of PGCs. Therefore, these systems may contribute to the cryopreservation of a rare avian species.

The Study on Decomposition of Metal-working Fluids Against Microbes (미생물을 이용한 절삭유제의 부패성능 평가에 관한 연구)

  • Kim, Young-Wun;Hong, Kwang Min;Chung, Kunwo;Park, Chan-Jo
    • Korean Chemical Engineering Research
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    • v.44 no.4
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    • pp.350-355
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    • 2006
  • Growth curves of microbes were examined to evaluate decomposition of metal-working fluids and decomposition properties of metal-working fluids were experimented using controled microbes such as E. coli and K. pnemoniae. According to the results of growth curve of microbes, the growth period depended on species of microbes, 2 h of E. coli, 3 h of K. pneumoniae, 4 h of P. aeruginosa and 3 h of P. oleovarans after incubation. The colony count of E. coli and K. pneumoniae controled to OD of 0.5 ranged from $4.4{\sim}10.0{\times}10^5CFU/mL$ and $1.8{\sim}9.5{\times}10^7CFU/mL$, respectively. The decomposition of metal-working fluids was excellently progressed in the range of pH 6~8 than below pH 4 and above pH 10. In the case of controled fluids to pH 6~8, the decomposition of the fluid containing ester group was more accelerated than that of the fluid containing ethylene glycol.

Properties of Al Doped LiMn2O4 Powders Prepared by Spray Pyrolysis Process (분무열분해 공정에 의해 합성된 Al이 치환된 LiMn2O4 분말의 특성)

  • Ju, Seo Hee;Jang, Hee Chan;Kang, Yun Chan
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.84-88
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    • 2009
  • Al doped $LiMn_2O_4$ cathode powders with fine size were synthesized by an ultrasonic spray pyrolysis method from the spray solution with citric acid and ethylene glycol. The as-prepared powders with spherical shape, porous structure and micron size turned into $LiMn_{11/6}Al_{1/6}O_4$ powders with micron size and regular morphology after post-treatment above $800^{\circ}C$. The $LiMn_{11/6}Al_{1/6}O_4$ powders had low initial discharge capacity of 94 mAh/g at a post-treatment temperature of $700^{\circ}C$. As the post-temperature increased from $750^{\circ}C$ to $1,000^{\circ}C$, the initial discharge capacities of the $LiMn_{11/6}Al_{1/6}O_4$ powders changed from 103 to 117 mAh/g. The $LiMn_{11/6}Al_{1/6}O_4$ powders had the maximum discharge capacity at a post-treatment temperature of $750^{\circ}C$. However, the $LiMn_{11/6}Al_{1/6}O_4$ powders post-treated at a temperature of $900^{\circ}C$ had the good cycle properties. The discharge capacities of the $LiMn_{11/6}Al_{1/6}O_4$ powders dropped from 107 to 100 mAh/g (93% capacity retention) by the 70th cycle at a current density of 0.1 C.

Control of YAG($Y_{3}Al_{5]O_{12}$) Particle Shape prepared by Sol-Gel Process (솔-젤 공정(工程)을 이용(利用)하여 제조(製造)된 YAG($Y_{3}Al_{5}O_{12}$) 분말 입형제어)

  • Park, Jin-Tae;Kim, Chul-Joo;Yoon, Ho-Sung;Sohn, Jung-Soo
    • Resources Recycling
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    • v.17 no.5
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    • pp.52-59
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    • 2008
  • Sol-gel process applied in this study was carried out by chelation of metal ions and citric acid. From the results of thermal gravimetric analysis and XRD analysis of gel powder obtained through sol-gel and heat treatment, gel powders are mostly amorphous, and crystallize completely at $900^{\circ}C$, and the crystalline structure of YAG increases with increasing calcinations temperature. Since YAG prepared by sol-gel & calcinations process was porous, and the sape and size was irregular and nonuniform, the shape and size of YAG powder had to be controlled. Therefore the effects of organic materials such as ethylene glycol and surfactant on the crystalline structure of YAG powder were investigated. Polyesterification of ethylene glycol and citric acid separated reaction area of metal ions in the solution and decreased the size of YAG primary particles. The addition of Igepal 630 as surfactant formed the droplet in the solution, and increased the size of primary particles which forms the aggregate of YAG In order to obtain monodispersed YAG particles of uniform size, gel powder prepared with organic materials had to be milled before calcination. And milling process was very important for obtaining YAG of uniform size.

Study on expandability and X-ray coherent scattering domain size of bentonite from Gampo and Yonil area, Korea (감포와 연일 지역 벤토나이트의 팽창성 및 X-선 부합성 산란영역 크기에 관한 연구)

  • 강일모;박석찬;문희수;유장한
    • Economic and Environmental Geology
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    • v.36 no.1
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    • pp.1-8
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    • 2003
  • This study was performed to measure expandabilities and coherent scattering domain sizes (CSDs) of bentonite samples from Campo and Yonil area, Korea, using X-ray powder diffraction (XRD), and to compare their experimental data with those of international standard bentonite samples (SAz-1, STx-1, and SWy-2). Most of Gampo and Yonil bentonite samples comprised randomly interstratified illite-smectite (R0 I-S), and their expandabilities ranged over 77-100%S$_{XRD}$ from the saddle/001 method. The interstratification deformed 001 peaks of EG-solvated samples (Mering's first principle), which prohibited us from adopting these peaks to measure CSDs using BWA (Bertaut-Warren-Averbach) method. CSDs of the bentonite samples with R0 I-S could be measured through dehydration at 30$0^{\circ}C$ after K-saturation, where the deformation originated from the interstratification could be removed effectively. Campo and Yonil bentonite samples showed that their mean CSDs ranged over 3.8-5.4 interlayers, and that their CSDs distributions were similar to those of Gonzales (STx-1) and Wyoming (SWy-2) bentonite samples.