• Title/Summary/Keyword: 에멀전

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Evaluation of Dispersion Stability and Absorption Performance Enhancement of Binary Nanoemulsion Fluids (이성분 나노에멀전 유체의 분산안정성 및 흡수성능 촉진실험)

  • Lee, Jin-Ki;Kim, Young-Jin;Shin, Myung-Chul;Kim, Se-Won;Kang, Yong-Tae
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.9
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    • pp.895-900
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    • 2012
  • This paper aims to examine the effect of nanodroplets on pool-type absorption heat transfer enhancement and to find the relationship between the dispersion stability and the absorption performance. The concentrations of oil and surfactant are considered as the key parameters. $C_{12}E_4$ and Tween20 are used as the surfactants and N-decane oil is added to the $NH_3/H_2O$ solution to make the binary nanoemulsion fluids. Binary nanoemulsion fluids are dispersed by the ultrasonic vibrator and the stirrer under specific conditions. The dispersion stability of binary nanoemulsion fluids for each oil concentrations is evaluated from the droplet size and Tyndall effect analysis. The absorption performance of binary nanoemulsion fluids is compared with the result of dispersion stability. In addition, it is found that the binary nanoemulsion fluid is a strong candidate as a new working fluid for absorption applications.

Preparation of α-Al2O3 Nanoparticles by flame Spray Pyrolysis (ESP) of Microemulsion (마이크로에멀전의 화염분무열분해(ESP)에 의한 α-알루미나 나노입자의 제조)

  • 이상진;전병세
    • Journal of the Korean Ceramic Society
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    • v.41 no.3
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    • pp.242-246
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    • 2004
  • Nano-sized a-alumina with a narrow distribution was prepared by using Flame Spray Pyrolysis (FSP). The microemulsion of water in oil (W/O) was prepared to make ultrafine droplets for FSP process. Kerosene (fuel) as a continuos phase and Al(NO$_3$)$_3$$.$9$H_2O$ (oxidizer) aqueous solution as a dispersed phase were prepared for microemulsification. The microemulsion with dispersion stability was obtained by adjusting the composition of 80 vol% kerosene, 10 vol% aqueous solution, and 10 vol% emulsifying agent. Microemulsion was sprayed onto the flame by using two-fluid nozzle spray gun under the condition of 0.03 ㎫ air pressure. The synthesized products were $\alpha$-alumina phase with the size of 20 to 30 nm.

Encapsulation of ZnSe Quantum Dots within Silica by Water-in-oil Microemulsions (마이크로에멀전을 이용한 실리카에 담지된 ZnSe 양자점 제조)

  • Lee, Areum;Kim, Ji Hyeon;Yoo, In Sang;Park, Sang Joon
    • Applied Chemistry for Engineering
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    • v.22 no.3
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    • pp.328-331
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    • 2011
  • ZnSe quantum dots (QDs) were prepared by employing water-containing Dioctyl sodium sulfosuccinate (AOT) reversed micelles (microemulsions) and the silica-encapsulated ZnSe QDs were obtained by a direct injection of tetraethyl orthosilicate (TEOS) into the microemulsion system. When the QDs were coated by silica, well-defined spherical shapes were formed and the average size of the QDs was near 7 nm. In addition, the photoluminescence (PL) efficiency of the QDs was reduced from 8.0 to 1.1% as they were encapsulated by silica. However, the solid layers of the silica-encapsulated ZnSe QDs on gold surfaces showed the excellent photostability. In particular, they are cadmium free and thus, less toxic. Moreover, the present method does not require a hot reaction temperature or extremely toxic H2Se gas as a Se precursor. Accordingly, the method can be a safer and more economical process for producing silica-encapsulated ZnSe QDs, which may be a potential media for biosensors.

Relative Viscosity of Emulsions in Simple Shear Flow: Temperature, Shear Rate, and Interfacial Tension Dependence (전단유동에서 온도, 전단속도, 계면장력 변화에 따른 에멀전의 유변학적 특성)

  • Choi, Se Bin;Lee, Joon Sang
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.8
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    • pp.677-682
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    • 2015
  • We simulate an emulsion system under simple shear rates to analyze its rheological characteristics using the lattice Boltzmann method (LBM). We calculate the relative viscosity of an emulsion under a simple shear flow along with changes in temperature, shear rate, and surfactant concentration. The relative viscosity of emulsions decreased with an increase in temperature. We observed the shear-thinning phenomena, which is responsible for the inverse proportion between the shear rate and viscosity. An increase in the interfacial tension caused a decrease in the relative viscosity of the decane-in-water emulsion because the increased deformation caused by the decreased interfacial tension significantly influenced the wall shear stress.

The effect of osmotic pressure in W/O/W multiple emulsion (다상 에멀전 형성에 있어 삼투 현상이 미치는 영향)

  • 신중진;이근수;강기춘;표형배
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.26 no.1
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    • pp.139-148
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    • 2000
  • The osmotic pressure is a one of the most important factor affecting stabilization of multiple emulsion in a law hours after experiment. To understand and decrease osmotic pressure between Wl phase and W2 phase, a kinds of humectants were introduced in outer water phase. As a result, Betaine and Glucose had an excellent effect reducing osmotic pressure and NaCl made W/O/W emulsion more stable than MgSO4 did when introduced in inner water phase.

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Antioxidant Activity of Ethanol-Extracts from a Maillard Browning Mixture and Some Antioxidants in Soybean Oil and Soybean Oil-Water Emulsion Systems (콩기름 및 콩기름-물 에멀젼기질(基質)에서의 마이얄형(型) 갈색화반응생성물(褐色化反應生成物)과 일부(一部) 산화방지제(酸化防止劑)의 산화억제효과(酸化抑制效果))

  • Maeng, Young-Sun;Kim, Dong-Hoon
    • Korean Journal of Food Science and Technology
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    • v.13 no.4
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    • pp.273-282
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    • 1981
  • The antioxidant actilvity of ethanol-extracts (M-2 and M-30), which had been obtained from a Maillard-type browning mixture after 2 and 90 hr browning, and BHA, BHT, TBHQ, and ascorbyl palmitate It·as investigated in soybean oil and soybean oil-water emulsion systems. The activity of the extracts and antioxidants was estimated by comparing the POV and TBA value development of the corresponding substrates with that of controls. The substrates and controls were stored at $45.0{\pm}0.5^{\circ}C$ for 25 days. The activity of the extracts (10 ml each) and antioxidants (0.02%) based mainly on the POY development of the corresponding anhydrous substrates was, in decreasing order, as follows ; As. palmitate, TBHQ > M-30, M-2 > BHT, BHA The actilvity of the extracts and antioxidants in tile oil-water emulsion substrates was, in decreasing order, as follows : As. palmitate > M-30, M-2 > BHT, TBHQ, BHA The activity of the extracts appeared to be more effective in the oil-water emulsion system than in the anhydrous system, and it f·as greater than that of the phenolic antioxidants such as BHA, BHT, and TBHQ in the oil-water emulsion system.

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