• Title/Summary/Keyword: 에너지 흡수

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비진공법을 이용한 CIGS광흡수층의 합성과 특성평가

  • Gwon, Yeong-Eun;Park, Jun-Tae;Im, Gi-Hong;Choe, Hyeon-Gwang;Jeon, Min-Hyeon
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.312.1-312.1
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    • 2014
  • Chalcopyrite계 화합물 반도체인 $Cu(InGa)Se_2$ (CIGS)는 직접천이형 에너지 밴드갭과 전파장 영역에 대하여 높은 광흡수계수($1{\times}$[10]^5/cm)를 가지므로 두께 $1{\sim}2{\mu}m$인 박막형태으로 고효율의 태양전지 제조가 가능하다. 또한, 박막공정의 저가 가능성을 나타내면서 전세계적으로 많은 연구와 관심을 받고 있고, 현재 상용화되어 있는 결정질실리콘 태양전지를 대체할만한 재료로 주목 받고 있다. 일반적으로, CIGS박막형 태양전지 구성은는 유리를 기판으로 하여 5개의 단위 박막인 Mo 후면전극, p형 반도체 CIGS 광흡수층, n형 반도체 CdS 버퍼층, doped-ZnO 상부 투명전극, $MgF_2$ 반사방지막으로 이루어진다. 이들 중에서 태양전지의 에너지 변환효율에 결정적인 영향을 미치는 구성된다. CIGS 광흡수층의 제조는 크게 진공법과 비진공방법으로 나뉜다. 현재까지 보고된 문헌에 따르면 CIGS 박막형 태양전지의 경우에 동시증발법으로 20.3%의 에너지 변환효율을 보였지만,는데, 이는 진공장비 특성상 공정단가가 높고 대면적화가 어렵다는 단점을 가진다. 따라서, 비진공법을 이용하여 광흡수층 제작하는 것이 기술적으로 진보할 여지가 크다고 볼 수 있다. 반면 현재 상용화되어 있는 결정질실리콘 태양전지를 대체할만한 방법으로 주목 받고 있는 비진공을 이용한 저가공정은 최근 15.5%의 에너지 변환효율이 보고 되었다. 비진공법에는 전계를 이용한 증착법 및 스프레이법으로 나뉘며, 이들 광흡수층 재료의 화학적 합성은 III족 원소인 In, Ga의 함량비에 따라 광흡수층의 에너지 밴드갭(1.04~1.5 eV) 조절이 가능하다. 따라서, 본 연구에서는 비진공법에 사용되는 CIGS재료의 화학적 합성조건을 변화시켜 III족 원소의 조성비 조절을 시도하였다. CIGS 분말 시료의 입자 형태와 크기를 FE-SEM을 이용하여 관찰하였고, 화합물의 성분비를 EDX 및 XRD 분석을 통해 Ga 함량에 따른 구조적 차이를 비교해 보았다.

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Evaluation of Absorbing Energy for the Rockfall Protection Fence Using High Carbon Steel Wire Rods (경강선 적용 낙석방지울타리의 흡수에너지 평가)

  • Lee, Yongjoo
    • Journal of the Korean GEO-environmental Society
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    • v.10 no.6
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    • pp.49-60
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    • 2009
  • In order to develop a new rockfall protection fence using high carbon steel wire rod (HSWR) material instead of the conventional wire rope material, the author has conducted the laboratory strength tests of both materials and their connections, and carried out evaluation of absorbing rockfall energy through the vertical field rockfall tests. The vertical filed rockfall tests showed that the new rockfall protection fence with 12 rows of the HSWR could absorb more rockfall energy than 50 kJ which stands for the typical design criteria. In addition, when the quantity of HSWR was increased up to the 16 rows, the capacity of absorbing energy was greatly improved. The new rockfall protection fence was successfully applied to the highway rock-cut slope. As a result of the filed application, its constructability was similar to the conventional fence, but its total image was improved as simple and clean. The total construction cost was saved up to 20% in comparison with the conventional one.

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Study on Obstacle Deflector of a Railway Vehicle Using Tension-type Energy Absorbers (인장형 에너지흡수부재를 이용한 철도차량용 장애물제거기 연구)

  • Kim, Hongeik;Kim, Jinsung;Kwon, Taesoo;Jung, Hyunseung
    • Journal of the Korean Society for Railway
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    • v.20 no.2
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    • pp.173-181
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    • 2017
  • The obstacle deflector sweeps obstacles off the track or absorbs crash energy with an energy absorber to prevent derailment of a train and to minimize damage and casualties after an accident. In this study, an obstacle deflector and its operational mechanism were designed with a tension-type energy absorber and a 4-bar linkage system. Also, a test method was suggested and verified with FEA (Finite Element Analysis) and UTM (Universal Test Machine) for testing of the static load and energy absorbing ability according to EN 15227 regulations. Through this study, an obstacle deflector that meets the EN 15227 standard was designed and a test method was suggested to adjust the collapse load easily and to verify it experimentally according to the design and verification procedure of the obstacle deflector.

Effects of Reinforced Fibers on Energy Absorption Characteristics under Quasi-static Compressive Loading of Composite Circular Tubes (강화섬유에 따른 준정적 하중하에서 복합소재 원형튜브의 에너지 흡수특성 평가 연구)

  • Kim, Jung-Seok;Yoon, Huk-Jin;Lee, Ho-Sun;Choi, Kyung-Hoon
    • Composites Research
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    • v.22 no.6
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    • pp.32-38
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    • 2009
  • In this study, the energy absorption capabilities and failure modes of four different kinds of circular tubes made of carbon, Kevlar and carbon-Kevlar hybrid composites with epoxy resin have been evaluated. In order to achieve these goals, these tubes were fabricated with unidirectional prepregs and compressive tests were conducted for the tubes under 10mm/min loading speed. From the test results, carbon/epoxy tubes were collapsed by brittle fracturing mode and showed the best energy absorption capabilities, while Kevlar/epoxy tubes were crushed by local buckling mode and worst. The hybrid [$90_C/0_K$] tubes were failed in a local bucking mode and showed good post crushing integrity, whereas [$90_K/0_C$] tubes were failed in a lamina bending mode and bad post crushing integrity.

An Experimental Study on the Absorbed Energy of Polymeric Foam According to Different Mass and Impact Velocity Based on the Constant Impact Energy (동일 에너지 조건하에 충격체 질량과 속도변화에 따른 발포 고분자의 흡수 에너지에 관한 실험적 연구)

  • Kim, Byeong-Jun;Kim, Han-Kook;Cheon, Seong S.
    • Composites Research
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    • v.27 no.2
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    • pp.42-46
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    • 2014
  • In the present study, impact tests were carried out to investigate the crashworthy behaviour of the expanded polypropylene under the constant incident energy (100 J and 200 J) with five different combinations of striker mass and velocity. Also, preliminary quasi-static test was performed to obtain basic characteristics of the expanded polypropylene. MTS 858 and Instron dynatup 9250 HV were used for the quasi-static test and impact tests, respectively. In consequence, it was found that the impact energy absorption characteristics of the expanded polypropylene was more influenced by the striker mass instead of the velocity of the striker.

Monte Carlo Simulation of Absorbed Energy by Gold Nano-Particles for Proton (양성자에 대한 금 나노입자의 밀도에 따른 흡수 에너지의 몬테카를로 전산모사)

  • Kwon Su Chon
    • Journal of the Korean Society of Radiology
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    • v.18 no.1
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    • pp.1-9
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    • 2024
  • Proton therapy is known for its superior treatment method due to Bragg peak. To enhance the therapeutic effects of protons, research has been conducted on distributing gold nanoparticles within tumors to increase the absorbed dose. While previous studies focused on handling gold nanoparticles at micrometer and nonometer scale, this study proposes a method to computationally estimate the effect of gold nanoparticles at the millimeter scale. The Geant4 toolkit was applied to computational modeling. Assuming a uniform distribution of water, similar to the human body, and gold nanoparticles, the concentration of gold nanoparticles was adjusted using density ratios. When the density ratio was 5%, the gain in absorbed energy due to gold nanoparticles was nearly twice that of the pure water phantom at the Bragg peak. As the density ratio increased, the gain in absorbed energy linearly increased. When gold nanoparticles were distributed in only one voxel at the Bragg peak, the energy of the protons affected only the neighboring voxels. However, in cases where gold nanoparticles were distributed over a wide area, the volume showing 95% of the maximum absorbed energy (9.46 keV) for the pure water phantom (9.95 keV) exhibited an improvement in absorbed energy over a region 16 times larger, and this region increased as the density ratio increased. Further research is needed to quantify the relationship between the density ratio of gold nanoparticles and the relative biological effect (RBE) in the millimeter scale.

혈관내벽에 홀뮴-166 방사선 분할 조사시 흡수선량 분포

  • 조철우;윤석남;윤준기;이명훈;탁승재;최소연;박경배
    • Proceedings of the Korean Society of Medical Physics Conference
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    • 2003.09a
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    • pp.70-70
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    • 2003
  • 경피적관상동맥성형술(CPTCA)이나 스텐트삽입술 후에 발생하는 재협착을 방지하기 위한 방사선을 조사하는 방법 중에 베타 입자를 방출하는 액체 선원을 catheter풍선 내에 넣어 일정 시간 방사선 조사 시키는 방법이 있다. 조사시킬 혈관의 길이가 길어 한번의 방사선 조사가 어려울 경우 영역을 분할하여 두 번에 나누어 조사할 경우가 있다. 조사영역의 겹치는 부근의 흡수선량이 고선량이나 저선량이 되는가를 알기 위하여 두 풍선간의 접근 거리에 따른 혈관내벽의 흡수선량 분포를 알아보았다. 풍선내의 액체 선원은 Ho-l66을 이용하였고 Ho-l66의 물리적 반감기는 26.8시간이고 최대에너지 1.85 MeV, 평균에너지 0.69 MeV와 최대에너지 1.77 MeV, 평균에너지 0.65 MeV를 갖는 베타 입자를 방출한다. Ho-l66 의 방사선 흡수선량을 측정하기 위하여 GafChromic 필름(Nuclear Associates, Carle Place, NY, USA)을 이용하였고, 방사선이 조사된 필름의 optical density는 videodensitometer(Wellhofer, Schwarzen-bruck, Germany)를 이용하여 값을 읽었다. Catheter 풍선은 직경이 3 mm 이고 길이가 20 mm인 것을 이용하였다. 혈관 내벽의 최대 흡수선량을 표준화하여 겹치는 부분의 흡수선량 분포를 접근 거리에 따라 구하였다. 또한 몬테카를로 시abf레이션으로 확인하였다. 두 풍선의 겹치는 부근의 선량 분포는 풍선 중앙에서 중앙사이의 거리가 21 mm 일 때 중앙에서 20% 증가하였고, 거리가 22 mm일 때와 23 mm일 때 각각 10%와 40%의 감소를 보였다. 풍선 도자의 풍선 안에 베타입자 방출 액체 선원을 넣어 혈관내벽에 방사선 조사하는 방법은 비정거리가 짧아 혈관 내벽 부근에만 방사선을 조사시키고 그 외 중요 장기에는 영향을 덜 미치는 장점이 있다. 그러나 혈관 내벽 표면으로 부터의 거리에 따라 흡수선량이 급격히 떨어지는 분포를 이루기 때문에 두 개의 풍선이 겹치는 부근의 흡수선량은 아주 작은 접근 거리에서도 급격한 변화를 보였다. 따라서 시술 중에 겹치는 부분을 아주 적게 분할하여 정확하게 차례차례로 조사시키기 위해서는 신중한 거리 조정을 하여야 한다.

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Absorption and Regeneration Characteristics of a Sorbent for Fluidized-Bed CO2 Removal Process (유동층 CO2 회수공정을 위한 흡수제의 흡수 및 재생특성)

  • Yi, Chang-Keun;Hong, Sun-Wook;Jo, Sung-Ho;Son, Jae-Ek;Choi, Jeong-Hoo
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.294-298
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    • 2005
  • Absorption and regeneration characteristics of sorbent used in a fluidized-bed process to capture $CO_2$ from flue gas have been measured in a thermo gravimetric analyzer. A sorbent Sorb NH prepared for fluidized-bed process was faster than pure $Na_2CO_3$ in absorption and regeneration reaction rate. Activation energy of apparent absorption reaction of sorbent Sorb NH was estimated as -10,100 cal/g mol and that of pure $Na_2CO_3$ as -12,200 cal/g mol. Activation energy of apparent regeneration reaction of sorbent Sorb NH was estimated as about 12,050 cal/g mol and that of pure $Na_2CO_3$ as about 11,320 cal/g mol.

A Study on Improvement of Performance of Absorber in Absorption Heat Pump (흡수열펌프에서 흡수기의 성능 개선 연구)

  • Min, Byong-Hun
    • Applied Chemistry for Engineering
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    • v.19 no.3
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    • pp.338-344
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    • 2008
  • The improvement of energy conservation is mandatory to decrease consumption of fossil fuels and to minimize negative impacts on the environment which originates from large cooling and heating demand. The absorption heat pump technology has a large potential for energy-saving in this respect. Absorption heat pump is a means to upgrade waste heat without the addition of extra thermal energy. The higher performance of absorber is of great importance for absorption heat pump cycle. In this study, in order to improve the performance of absorber, the absorber of tangential feed of a liquid phase with spiral tube has been investigated using methanol-glycerine as a working fluid. The spiral tube and tangential feeding generate the turbulence into the liquid flow while increasing the mass and heat transfer coefficients. The simultaneous heat and mass transfer were found to take place in a liquid turbulent film in the absorber with the spiral tube during the process of gas absorption. By calculating mass and heat transfer coefficients by measurement of the concentration and the temperature of each position in the absorber, the entrance was found to be more effective in enhancing mass and heat transfer.

Cross Calibration of Dual Energy X-ray Absorptiometry Equipment for Diagnosis of Osteoporosis: between Domestic Manufacturers and Global Manufacturers (골밀도 장치의 교차분석 ; 국내 제조사와 해외 제조사 비교)

  • Kim, Jung-Su
    • Journal of the Korean Society of Radiology
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    • v.12 no.7
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    • pp.833-844
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    • 2018
  • Dual energy X-ray absorptiometry is mainly used as an X-ray test method. For equipment manufactured GE and Hologic, cross-calibration analyses (CCA) of machines from the same manufacturer and between units from different manufacturers have been conducted, but the CCA of equipment manufactured in Korea are inadequate. Through CCA, we present a formula of the intersections between the Korean medical equipment company (KEC) with GE and Hologic manufactured DXA, and among the KEC DXA. The CCA was conducted for the European Spine Phantom on DXA from four KEC and three global medical equipment company (GEC) manufacturers. We compared bone mineral density (BMD) values and calculated the CCA equation by linear regression analysis. The standard-deviations (SD) of the BMD values were highest for the Dexxum T for the low, medium, and high spine, which were 0.030, 0.029, and 0.037, respectively. The smallest SD in the low and medium vertebrae were 0.005 and 0.004 for the Horizon Ci, respectively, and 0.005 for the Osteo Pro Max in the high vertebrae. Based on the intersection equations of the KEC DXA established in this study, CCA of various KEC DXA should be established for more accurate follow-up of BMD tests in clinical environments.