• Journal of the Korean Applied Science and Technology
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• v.36 no.4
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• pp.1143-1152
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• 2019

In order to study the solubilization of aniline by cationic surfactants (DTAB, TTAB and CTAB), the solubilization constant (K_s) and thermodynamic functions were measured and calculated by using the UV-Vis method. The solubilization constants of aniline with the change of temperature were measured, and the effects of addition of ionic salts and organics on the solubilization constants were investigated. These effects of additives and temperature changes were compared and analyzed for each type of surfactant, and the solubilization of aniline was analyzed microscopically by comparing and evaluating the thermodynamic functions obtained from the solubilization constants. As a result, the Gibbs free energy and enthalpy changes were both negative and the entropy changes were positive within the measured range for the solubilization of aniline by cationic surfactants. The solubilization constant value decreased with increasing temperature and increased with increasing carbon chain length of the surfactant. As the concentration of ionic salts increased, the Gibbs free energy change increased at first and then decreased. In n-butanol solution, the Gibbs free energy change tended to increase continuously with increasing the concentration of n-butanol.

• Journal of the Korean Chemical Society
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• v.54 no.2
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• pp.192-197
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• 2010

The spinel compound was obtained by the thermal decomposition of Zn-Co and Zn-Ni gel prepared by sol-gel method using oxalic acid as a chelating agent. The formation of spinel compound has been comfirmed by thermogravimetric analysis (TGA), x-ray powder diffraction (XRD) and infrared spectroscopy (IR). The particle size of 13 nm~16 nm was calculated by Scherrer's equation. The sol-gel method provides a practicable and effective route for the synthesis of the spinel compound at low temperature ($350^{\circ}C$). The kinetic parameters such as activation energy (Ea) and pre-exponential factor (A) for each compound were found by means of the Kissinger method and Arrhenius equation. The decomposition of spinel compound has an activation energy about 155 kJ/mol. Finally, the thermodynamic parameters (${\Delta}G^{\varphi}$, ${\Delta}H^{\varphi}$, ${\Delta}S^{\varphi}$) for decomposition of spinel compound was determined.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.1A
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• pp.11-18
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• 2012

This paper deals with the numerical determination of the stress intensity factors of cracked aluminum plates under the mixed mode of $K_I$ and $K_{II}$ in glass-epoxy fiber reinforced composites. For the stress intensity factors, two different models are reviewed such as VCCT and two-step extension method. The p-convergent partial layerwise model is adopted to determine the fracture parameters in terms of energy release rates and stress intensity factors. The p-convergent approach is based on the concept of subparametric element. In assumed displacement field, strain-displacement relations and 3-D constitutive equations of a layer are obtained by combination of 2-D and 1-D higher-order shape functions. In the elements, Lobatto shape functions and Gauss-Lobatto technique are employed to interpolate displacement fields and to implement numerical quadrature. Using the models and techniques considered, effects of composite laminate configuration according to inclined angles and adhesive properties on the performance of bonded composite patch are investigated. In addition to these, the out-of-plane bending effect has been investigated across the thickness of patch repaired laminate plates due to the change of neutral axis. The present model provides accuracy and simplicity in terms of stress intensity factors, stress distribution, number of degrees of freedom, and energy release rates as compared with previous works in literatures.

• Journal of the Korean Wood Science and Technology
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• v.29 no.1
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• pp.9-15
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• 2001

Specific energy curves for water removal in vacuum-press drying of different thick softwoods of red pine (Pinus densiflora), white pine (Pinus koraiensis), larch (L. leptolepis) and Western hemlock (Tsuga heterophylla) were split into three sections: increased slowly, fairly constant, and increased rapidly. Calculated specific energy for 3, 5, 7, 9 and 11cm thick lumber was a value of 0.483, 0.649, 0.814, 0.977 and 1.138kWh/kg of water, respectively. Specific energy almost linearly increased as lumber thickness increased, and specific energy for severe schedule was less than that for mild schedule. Average specific energy was 0.712kWh/kg and vacuum-press drying consumed less energy as compared with any other drying methods.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.27 no.5
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• pp.295-303
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• 2015

The eigenfunction expansion method is appled for the wave scattering by a vertical slotted, where both the inertial and quadratic drag terms are involved. Quadratic drag term representing the energy loss is linearized by the application of socalled equivalent linearization. The drag coefficient, which was empirically determined by Yoon et al.(2006) and Huang(2007) is used. Analytical results are verified by comparison to the experimental results conducted by Kwon et al.(2014) and Zhu and Chwang(2001). Using the developed design tool, the effect of energy loss by a vertical slotted wall is estimated with various design parameters, such as porosity, submergence depth, shape of slits and wave characteristics. It is found that the maximum value of energy loss across the slotted wall is generated at porosity value less than P = 0.1. The present solutions can provide a good predictive tools to estimate the wave absorbing efficiency by a slotted-wall breakwater.

• Journal of Satellite, Information and Communications
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• v.11 no.2
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• pp.55-59
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• 2016

Conventional RF energy harvesting systems can harvest energy and decode information from same source as an Hybirid-AP (H-AP). However, harvesting efficiency is seriously dependent on distance between users and H-AP. Therefore, in this paper, we proposed a transmission model for RF harvesting consisting of information and power source separately called Decoupled RF Energy harvesting networks. Main purpose of this paper is to maximize energy efficiency under various constraints of transmit power from H-AP and power beacon (PB), minimum quality of service and quality of harvested power of each users. To measure proposed model's performance, we proposed optimal time scheduling algorithms for energy efficiency (EE) maximization using Lagrangian dual decomposition theory that locally maximizes the EE by obtaining suboptimal values of three arguments : transmit power of H-AP, transmit power of PB, frame splitting factor. Experiment results show that the proposed energy-efficient algorithms converge within a few iterations with its optimality and greatly improve the EE compared to that of baseline schemes.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.14 no.1
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• pp.8-18
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• 2002

In this paper, wave energy absorption of OWC(oscillating water column) device is analyzed. The analytic model consists of a partially immersed circular vertical cylinder open at its end and an air turbine connected with the air chamber. The boundary value problem is decomposed into scattering problem related to scattering by an incident wave in the absence of a pressure variation and radiation problem describing the flow due to an oscillating pressure in the absence of an incident wave. By invoking the continuity of an air flow inside the chamber, the oscillating pressure in a chamber is derived. With oscillating pressure, the mean power absorbed by OWC device and the capture width are obtained. In numerical calculation, the induced volume flux across the internal free surface of the chamber in the scattering and radiation problem and the maximum capture width are compared with various design parameters such as radius and submergence depth of chamber and wave conditions. The maximum capture width obtained by choosing the optimal value of turbine constant occurs at the first resonant mode (Helmholtz mode) among the natural frequencies of a circular cylinder chamber.

• Journal of the Korean Electrochemical Society
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• v.22 no.1
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• pp.1-12
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• 2019

The reduction of nitrogen to produce ammonia has been attracting much attention as a renewable energy technology. Ammonia is the basis for many fertilizers and is also considered an energy carrier that can power internal combustion engines, diesel engines, gas turbines, and fuel cells. Traditionally, ammonia has been produced through the Haber-Bosch process, in which atmospheric nitrogen combines with hydrogen at high temperature ($350-550^{\circ}C$) and high pressure (150-300 bar). This process consumes 1-2% of current global energy production and relies on fossil fuels as an energy source. Reducing the energy input required for this process will reduce $CO_2$ emissions and the corresponding environmental impact. For this reason, developing electrochemical ammonia-production methods under ambient temperature and pressure conditions should significantly reduce the energy input required to produce ammonia. In this review, we introduce the electrochemical nitrogen reduction reaction at ambient condition. Numerical studies on the electrochemical nitrogen reduction mechanism have been carried out through the computation of density function theory. Electrodes such as nanowires and porous electrodes have been also actively studied for further participation in electrochemical reactions.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.25 no.5
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• pp.327-334
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• 2013

The interaction of oblique incident waves with a surface-mounted horizontal porous plate is investigated using matched eigenfunction expansion method under the assumption of linear potential theory. The new boundary condition on the porous plate suggested by Zhao et al.(2010) when it is situated at the still water surface is used. The imaginary part of the first propagating-mode eigenvalue in the fluid region under a horizontal porous plate, is closely related to the energy dissipation across the porous plate. By changing the porosity, plate width, wave frequencies, and incidence angles, the reflection and transmission coefficients as well as the wave loads on the porous plate are obtained. It is found that the transmission coefficients can be significantly reduced by selecting optimal porous parameter b = 5.0, also increasing the plate width and incidence angle.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.38 no.10
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• pp.1125-1131
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• 2014

This work presents a vulnerability assessment procedure for a complex structure using vibration characteristics. The structural behavior of a three-dimensional framed structure subjected to impact forces was predicted using the spectral element method. The Timoshenko beam function was applied to simulate the impact wave propagations induced by a high-velocity projectile at relatively high frequencies. The interactions at the joints were analyzed for both flexural and longitudinal wave propagations. Simulations of the impact energy transfer through the entire structure were performed using the transient displacement and acceleration responses obtained from the frequency analysis. The kill probabilities of the crucial components for an operating system were calculated as a function of the predicted acceleration amplitudes according to the acceptable vibration levels. Following the proposed vulnerability assessment procedure, the vulnerable positions of a three-dimensional combat vehicle with high possibilities of damage generation of components by impact loading were identified from the estimated vibration responses.