• Journal of the Korean Chemical Society
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• v.22 no.1
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• pp.45-51
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• 1978

The luminescence of N-methyllutidone is studied in ethanol matrix at $77^{\circ}C$K. No fluorescence is observed but a strong phosphorescence with the quantum yield of 0.1 and the lifetime of 0.2 sec is recorded. An unusually high triplet energy of 85.1 kcal/mole is determined for the compound from the O-O band of phosphorescence. The cis ${\leftrightarrow}$ trans photoisomerization of high triplet energy olefins such as 2-hexene and trans-1,4-dichlorobutene-2 is efficiently sensitized by N-methyllutidone substantiating the high triplet energy of the compound. The negative polarization of O-O band reveals the emitting triplet state to be $({\pi},{\pi}^*)^3$ state. Alkaline metal salts such as lithium chloride enhances the phosphorescence intensity through cation-N-methyllutidone coordination widening the gap between $({\pi},{\pi}^*)^3$and $(n,{\pi}^*)^3$ states.

• Environmental and Resource Economics Review
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• v.21 no.2
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• pp.211-235
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• 2012

This paper presents an alternative decomposition technique to identify the relative importance of factors associated with changes in $CO_2$ emissions by using directional distance function to model the joint production of desirable and undesirable outputs. The key feature of the proposed approach is the introduction of fossil and non-fossil fuel energy input efficiencies, productivity change and emission intensity change. For the 27 OECD countries as a whole, the empirical results indicate that economic growth is the most important contributor to $CO_2$ emissions increase, while efficiency change is the most important component to $CO_2$ emissions reduction between 1980 and 2007. For more extensive insights, this paper divided 3 groups according to the emission growth rate and find out that high emission countries show relatively low production efficiencies and technical changes contributing $CO_2$ emissions increase. The results also provide that more strict environmental regulations are needed to improve the pollution intensity in these countries.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.40 no.6
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• pp.557-563
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• 2016

The energy absorption efficiency of a wave power generation system is calculated as the ratio of the wave power to the power of the system. Because absorption efficiency depends on the dynamic behavior of the wave power generation system, a dynamic analysis of the wave power generation system is required to estimate the energy absorption efficiency of the system. In this study, a dynamic analysis of the wave power generation system under wave loads is performed to estimate the energy absorption efficiency. RecurDyn is employed to carry out the dynamic analysis of the system, and the Morison equation is used for the wave load model. According to the results, the lower the wave height and the shorter the period, the higher is the absorption efficiency of the system.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.16 no.4
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• pp.2757-2763
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• 2015

p-Snake is an energy minimizing algorithm that applies an additional prototype energy to the existing Active Contour Model and is used to extract the contour line in the area where the edge information is unclear. In this paper suggested the creation of a prototype energy field that applies a variable prototype expressed as a combination of circle and straight line primitives, and a fudge function, to improve p-Snake's contour extraction performance. The prototype was defined based on the parts codes entered and the appropriate initial contour was extracted in each primitive zones acquired from the pre-processing process. Then, the primitives variably adjusted to create the prototype and the contour probability based on the distance to the prototype was calculated through the fuzzy function to create the prototype energy field. This was applied to p-Snake to extract the contour from 100 images acquired from various small parts and compared its similarity with the prototype to find that p-Snake made with the adaptive prototype was about 4.6% more precise than the existing Snake method.

• Journal of the Mineralogical Society of Korea
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• v.21 no.4
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• pp.415-423
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• 2008

Earth outer core is composed of iron mainly with some diluent elements, which account for the observed ca. 10% density deficit compared to the pure iron. Among candidates as the light diluents, hydrogen and oxygen were selected, and the thermodynamic stability of the following reaction was calculated; hematite + hydrogen $\to$ goethite + iron. At ambient conditions, Gibb's free energy of this reaction is 12.62 kJ/mol. On increasing pressure at room temperature, it decreases to zero at 0.068 GPa. This energy decreases at constant rate down to 200 GPa, which shows -208.26 kJ/mol at that pressure. From these results, this chemical reaction prefers the reduction environment forming the iron element and iron oxyhydroxide, so possible presence of iron oxyhydroxide with iron at proto-core can not be ruled out.

• Korean Chemical Engineering Research
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• v.49 no.6
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• pp.764-768
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• 2011

The process of $CO_2$ capture using aqueous Monoethanolamine(MEA) has been considered as one of the leading technologies for intermediate-term strategy to reduce the $CO_2$ emission. This MEA process, however, consumes relatively a large amount of energy in the stripper for absorbent regeneration. For this reason, various process alternatives are recently established to reduce the regeneration energy. This paper suggests a flue gas split configuration as one of MEA process alternatives and then simulates this process using commercial simulator. This flue gas splitting has an effect on reducing the temperature of the lower section of absorber as well as decreasing the absorbent flow rate. Compared to the base model, this optimized flue gas split process provides 6.4% reduction of solvent flow rate and 5.8% reduction of absorbent regeneration energy.

• Journal of the Institute of Electronics Engineers of Korea SC
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• v.46 no.6
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• pp.21-27
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• 2009

As portable electronic systems being used more often, it becomes a more important issue to lengthen the lifetime of the power battery of the system, for instance, by developing batteries of a higher efficiency. A simple as well as practical method to lengthen the lifetime is to use multiple batteries that are connected in parallel. But in this paper we present a new idea in using multiple batteries, with which the residual energy of the battery can be used in the sense of recycling. The idea is based on a usual phenomenon that a battery cell that has been used until its voltage has dropped below a reference level may still have some residual energy, due to which the voltage can recover when the cell takes a rest for a while. As a practical realization scheme of this idea, a multi-cell configuration method with a cell selection switch is introduced, and its feasibility has been examined by performing experimental observations on the behavior of battery discharge. It has been found that the lifetime of an Alkaline primary battery cell can be lengthened approximately by one or two hours with the proposed method.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2017.10a
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• pp.514-517
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• 2017

In solar photovoltaic systems, power generation is greatly affected by the weather conditions, so it is essential to predict solar energy for stable load operation. Therefore, data on weather conditions are needed as inputs to machine learning algorithms for solar energy prediction. In this paper, we use 15 kinds of weather data such as the precipitation accumulated during the 3 hours of the surface, upward and downward longwave radiation average, upward and downward shortwave radiation average, the temperature during the past 3 hours at 2 m above from the ground and temperature from the ground surface as input data to the algorithm. We analyzed the statistical characteristics and correlations of weather data and extracted the downward and upward shortwave radiation averages as a major elements of a feature vector with high correlation of 70% or more with solar energy.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.162-162
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• 2010

InAs 는 광전자 및 광통신 소자에 널리 이용되는 $In_xGa_{1-x}As_yP_{1-y}$ 화합물의 endpoint 로서, Heterojunction Field-Effect Transistors (HEMTs), Heterojunction Bipolar Transistor (HBT) 등에 중요하게 이용되고, 다양한 소자의 기판으로도 폭넓게 사용되는 물질이다. InAs 의 반도체 소자로의 응용을 위해서는 정확한 광 특성과 밴드갭 값들이 필수적이며, 분광타원편광분석법(ellipsometry) 을 이용한 상온 InAs 유전율 함수는 이미 정확히 알려져 있다. 그러나 상온에서는 $E_2$ 전이점 영역에서 여러 개의 밴드갭들이 중첩되어 있어, 밴드구조계산 등에 필수적인 InAs의 전이점을 정확히 정의하기 어렵다. 또한, 현재의 산업계에서 중요하게 여겨지는 실시간 모니터링을 위해서는 증착온도에서의 유전율 함수 데이터베이스가 필수적이다. 이와 같은 필요성에 의해, 22 K - 700 K 의 온도범위에서 InAs 의 유전율 함수와 밴드갭 에너지에 대한 연구를 수행하였다. InAs bulk 기판을 methanol, acetone, DI water 등으로 세척 한 뒤, 저온 cryostat 에 부착하였다. 분광타원분석법은 표면의 오염에 매우 민감하기 때문에, 저온에서의 응결 방지를 위해 고 진공도를 유지하며, 액체 헬륨으로 냉각하였다. 0.7 - 6.5 eV 에너지 영역에서 측정이 가능한 분광타원편광분석기로 측정한 결과, 온도가 증가함에 따라 열팽창과 phonon-electron 상호작용효과의 증가에 의해, 밴드갭 에너지 값의 적색 천이와 밴드갭들의 중첩을 관찰 할 수 있었다. 정확한 밴드갭 에너지 값의 분석을 위하여 2계 미분을 통한 표준 밴드갭 해석법을 적용하였으며, 22 K 의 저온에서는 $E_2$ 전이점 영역에서 중첩된 여러 개의 밴드갭들을 분리 할 수 있었다. 또한 고온에서의 연구를 통해, 실시간 분석을 위한 InAs 유전함수의 데이터베이스를 확립하였다. 본 연구의 결과는 InAs 를 기반으로 한 광전자 소자의 개발 및 적용분야와 밴드갭 엔지니어링 분야에 많은 도움이 될 것으로 예상한다.

• Journal of the Korean Vacuum Society
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• v.19 no.6
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• pp.489-494
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• 2010

Enhance signal-to-noise ratio, slow positron coincidence Doppler Broadening method has been applied to study of characteristics of $Nb_3Ge$ superconductor film, which were performed from 20 K to 300 K sample temperature near Tc of it. In this investigation the numerical analysis of the Doppler spectra was employed to the determination of the shape parameter, S, defined as the ratio between the amount of counts in a central portion of the spectrum and the total counts of whole spectrum. The S-parameter values between 0.598 and 0.594 were decreased while the temperature were decreasing, that indicated the voids into the samples. The temperature dependence came from specific positron trapping rate into the vacancy-type defects. It is believed that the positrons annihilate with normal-electrons instead of super-electrons in the Nb3Ge superconductor.