• Title/Summary/Keyword: 에너지 물질

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Conceptual Design of 50 kW thermal Chemical-Looping Combustor and Analysis of Variables (열량기준 50kW급 매체순환식 가스연소기의 개념설계 및 변수해석)

  • 류호정;진경태
    • Journal of Energy Engineering
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    • v.12 no.4
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    • pp.289-301
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    • 2003
  • To develop a chemical-looping combustion technology, conceptual design of 50 kW thermal chemical-looping combustor, which is composed of two interconnected pressurized circulating fluidized beds, was performed by means of mass and energy balance calculations. A riser type fast fluidized bed was selected as an oxidizer and a bubbling fluidized bed was selected as a reducer by mass balance for the chemical-looping combustor. Calculated values of bed mass, solid circulation flux, and reactor dimension by mass and energy balance calculations were suitable for construction and operation of chemical-looping combustor. It is concluded from the comparison of the design results and operating values of commercial circulating fluidized bed that the process outline is realistic. Moreover, the previous results support that oxygen carrier particle, NiO/bentonite, fulfills the conversion rates needed for the proposed design. The effects of system capacity, metal oxide content in a oxygen carrier particle, amount of steam input, gas velocity, and solid depth on design values were investigated and the changes in the system performance can be estimated by proposed design tool.

Kinetic Analysis of Energetic Materials Using Differential Scanning Calorimetry (DSC를 이용한 고에너지 물질의 반응속도식 추출과 활용)

  • Kim, Yoocheon;Park, Jungsoo;Yang, Seungho;Park, Honglae;Yoh, Jai-Ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.1
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    • pp.33-41
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    • 2015
  • The kinetic analysis of energetic materials using Differential Scanning Calorimetry (DSC) is proposed. Friedman Isoconversional method is applied to DSC experiment data and AKTS software is used for analysis. The proposed kinetic scheme has considerable advantage over the standard method based on One-Dimenaionl Time to Explosion (ODTX). Reaction rate and product mass fraction simulation are conducted to validate extracted kinetic scheme. Also a slow cook-off simulation is implemented on $B/KNO_3$ for validating the applicability of the extracted kinetics scheme to a practical thermal experiment.

Fundamental Aspects of Energy Recovery Systems based on Municipal Solid Waste Characteristics and Its Biodegradability (도시폐기물의 성상과 생분해정도에 따른 에너지회수공정의 비교)

  • Choi, Eui So;Park, Hoo Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.11 no.2
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    • pp.99-105
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    • 1991
  • This study was carried out to provide basic data to be necessary for the selection of an energy recovery process based on the characteristics of municipal solid wastes(MSW). The samples were collected at Kangdong-Ku in Seoul and conducted ultimate and proximate analyses. Laboratory scale anaerobic digesters were operated to determine the non biodegradable fractions of the wastes. The results indicated that carbon and hydrogen contents, and lower heating values could be calculated from the volatile contents of MSW by the following equations : C = 0.57 VS, H =0.084 VS, and HL=49.5 VS-(6-0.045VS) W. Nonbiodegradable fractions were respectively 58.9% of volatile matters and 77.7% of MSW. Incineration and refuse derived fuel(RDF) processes appeared to be the most efficient processes in terms of weight reduction and energy recovery, But determining the energy recovery processes, the fluctuations of heating values of MSW throughout a year and available landfill site and secondary pollution should be considered.

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An Extraction of Detailed Isoconversional Kinetic Scheme of Energetic Materials using Isothermal DSC (등전환법과 등온 DSC를 이용한 고에너지 물질의 정밀 반응모델 개발)

  • Kim, Yoocheon;Park, Jungsu;Kwon, Kuktae;Yoh, Jai-ick
    • Journal of the Korean Society of Propulsion Engineers
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    • v.20 no.2
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    • pp.46-55
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    • 2016
  • The kinetic analysis of a heavily aluminized cyclotrimethylene-trinitramine(RDX) is conducted using differential scanning calorimetry(DSC), and the Friedman isoconversional method is applied to the DSC experimental data. The pre-exponential factor and activation energy are extracted as a function of the product mass fraction. The extracted kinetic scheme does not assume multiple chemical steps to describe the complex response of energetic materials; instead, a set of multiple Arrhenius factors is constructed based on the local progress of the exothermic reaction. The resulting reaction kinetic scheme is applied to two thermal decomposition tests for validating the reactive flow response of a heavily aluminized RDX. The results support applicability of the present model to practical thermal explosion systems.