• Title/Summary/Keyword: 에너지갭

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The Structural and Optical Properties of ZnO : $Al_{2}O_{3}$ Compound by Reaction Sintering (Reaction Sintering에 의한 ZnO : $Al_{2}O_{3}$ 합성물의 구조 및 광학적 특성)

  • Kang, Byeong-Mo;Park, Gye-Choon;Yoo, Yong-Tek
    • Journal of Sensor Science and Technology
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    • v.7 no.3
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    • pp.218-224
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    • 1998
  • 2nO and $Al_{2}O_{3}$ powder were weighed in 1 : 1 mole ratio and ball-milled in ethanol for 3 h. Dried mixture were pressed and then sintered at $900^{\circ}C{\sim}1200^{\circ}C$ for 3 h in vacuum($3{\times}10^{-5}$ Torr). According to XRD, remnant ZnO and $Al_{2}O_{3}$ not converted to $ZnAl_{2}O_{4}$ were observed up to $1100^{\circ}C$, which were completely changed to$ZnAl_{2}O_{4}$ ternary compound at $1200^{\circ}C$. Optical bandgap is calculated at 4.75 eV. With increasing sintering temperature, PL spectrums shifted to shorter wavelengths and are appeared 430nm at $1200^{\circ}C$.

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Preparation of Cadmium-free Buffer Layers for CIGS Solar Cells (CIGS 태양전지용 Cd-Free 버퍼층 제조)

  • Moon, Jee Hyun;Kim, Ji Hyeon;Yoo, In Sang;Park, Sang Joon
    • Applied Chemistry for Engineering
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    • v.25 no.6
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    • pp.577-580
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    • 2014
  • Indium hydroxy sulfide ($In(OH)_xS_y$) as a cadmium (Cd)-free buffer layer for $CuInGaSe_2$ (CIGS) solar cells was prepared by the chemical bath deposition (CBD) and the reaction time was optimized. The band gap energy and transmittance data alongside the thickness results from the direct observation with focused ion beam system (FIB) could be a powerful tool for optimizing the conditions. In addition, X-ray diffractometer (XRD), X-ray photoelectron microscopy (XPS), and scanning electron microscope (SEM) were also employed for the layer characterization. The results indicated that the optimum reaction time for $In(OH)_xS_y$ buffer layer deposition by CBD was 20 min at $70^{\circ}C$ under the conditions employed. At the optimum conditions, the buffer layer thickness was near 57 nm and the band gap energy was 2.7 eV. In addition, it was found that there was no XPS peak shift in between the buffer layers deposited on molybdenum (Mo)/glass and that on CIGS layer.

Effect of In2O3 Doping on the Properties of ZnO Films as a Transparent Conducting Oxide (투명전도성 ZnO 박막의 특성에 미치는 In2O3 첨가에 따른 영향)

  • Lee, Choon-Ho;Kim, Sun-Il
    • Journal of the Korean Ceramic Society
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    • v.41 no.1
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    • pp.57-61
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    • 2004
  • Zinc Oxide (ZnO) have the crystal structure of wurtzite which is semiconducting oxide with band gap energy of 3.3eV. $In_2O_3$-doped ZnO films were fabricated by electron beam evaporation at $400^{\circ}C$ and their characteristics were investigated. The content of $In_2O_3$ in ZnO films had a marked effect on the electrical properties of the films. As $In_2O_3$ content decreased. $In_2O_3$-doped ZnO films was converted amorphous into crystallized films and showed a better characteristics generally as a transparent conducting oxide. As $In_2O_3$-doped ZnO films were prepared by $In_2O_3$-doped ZnO pellet with 0.2at% of $In_2O_3$ content, the value of resistivity was about $6.0 {\times} 10^{-3} {\Omega}cm$. The transmittance was higher than 85% throughout the visible range.

Experimental Study on Wave-Induced Hydraulic Pressure subjected to Bottom of Floating Structures (부유구조체 하면에 작용하는 파압에 대한 실험적 연구)

  • Jeong, Youn-Ju;You, Young-Jun;Lee, Du-Ho
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.6A
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    • pp.425-433
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    • 2011
  • In this study, in order to investigate the wave-induced buoyancy effects, experimental studies were conducted on pontoon-type floating structures. A series of small-scale tests with various wave cases were performed on the pontoon models. A total of four small-scale pontoon models with different lateral shapes and bottom details were fabricated and tested under the five different wave cases. Six hydraulic pressure gauges were attached to the bottom surfaces of the pontoon models and the wave-induced hydraulic pressure was measured during the tests. Finally, hydraulic pressures subjected to the bottoms of the pontoon models were compared with each other. As the results of this study, it was found that whereas the waffled bottom shape hardly influenced the wave-induced hydraulic pressure, the hybrid lateral shape significantly influenced the wave-induced hydraulic pressure subjected on the bottoms of floating structures. The air gap effects of the hybrid shape contribute to decreasing the wave-induced hydraulic pressure due to absorption of wave impact energy. Compared with box type, the hydraulic pressures of the hybrid type were about 83% at the bow, 74% at the middle, and 53% at the stern.

Assessment of the Counter-Flow Thrust Vector Control in a Three-Dimensional Rectangular Nozzle (3차원 직사각형 노즐에서 역유동 추력벡터 제어 평가)

  • Wu, Kexin;Kim, Tae Ho;Kochupulickal, James Jintu;Kim, Heuy Dong
    • Journal of the Korean Society of Propulsion Engineers
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    • v.24 no.1
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    • pp.34-46
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    • 2020
  • Computational assessment of gas-dynamic characteristics is explored for a three-dimensional counter-flow thrust vector control system in a rectangular supersonic nozzle. This convergent-divergent nozzle is designed by Method of Characteristics and its design Mach number is specially set as 2.5. Performance variations of the counter-flow vector system are illustrated by varying the gap height of the secondary flow duct. Key parameters are quantitatively analyzed, such as static pressure distribution along the centerline of the upper suction collar, deflection angle, secondary mass flow ratio, and resultant thrust coefficient. Additionally, the streamline on the symmetry plane, three-dimensional iso-Mach number surface contour, and three-dimensional turbulent kinetic energy contour are presented to reveal overall flow-field characteristics in detail.

Structural, Morphological, and Optical Properties of AlN Thin Films Subjected to Oxygen Flow Ratio (산소 유량비 변화에 따른 AlN 박막의 구조, 표면 및 광학적 특성)

  • Cho, Shin-Ho;Kim, Moon-Hwan
    • Journal of the Korean Vacuum Society
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    • v.19 no.4
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    • pp.287-292
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    • 2010
  • We have investigated the effects of oxygen flow ratios on the structural, morphological, and optical properties of AlN thin films grown by using radio-frequency reactive magnetron sputtering. The AlN thin films were deposited at $300^{\circ}C$ of substrate temperature, and the reactive gas were supplied with both nitrogen and oxygen. The oxygen flow ratio was varied by controlling the amount of oxygen with respect to the total mixed gases, 0%, 10%, 15%, 20%, 25%, and 30%. The structural, morphological, and optical properties of the deposited AlN thin films were examined by using X-ray diffractometer, scanning electron microscopy, and ultraviolet-visible spectrophotometer. The AlN thin film grown at 10% of oxygen flow ratio indicated an average transmittance of 91.3% in the wavelength range of 350~1,100 nm and an optical band gap of 4.30 eV. The experimental results suggest that AlN thin films can be deposited optionally by varying the oxygen flow ratio.

Structural, Optical and Electrical Properties of ZnO Thin Films with Zn Concentration (Zn 농도변화에 따른 ZnO 박막의 구조, 광학 및 전기적 특성 연구)

  • 한호철;김익주;태원필;김진규;심문식;서수정;김용성
    • Journal of the Korean Ceramic Society
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    • v.40 no.11
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    • pp.1113-1119
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    • 2003
  • We used isopropanol which has low boiling point to prepare thin films at low temperature and changed mole concentration of zinc acetate from 0.3 to 1.3 mol/l. The structural, optical and electrical properties of ZnO thin films with Zn content were investigated. ZnO thin films highly oriented along the c-axis were obtained at Zn concentration of 0.7 mol/l. ZnO thin films with Zn concentration of 0.7 mol/l showed a homogeneous surface layer of nano structure. The transmittance of ZnO thin films by UV-vis. measurement was about 87% under the Zn concentration of 0.7 mol/l, but rapidly decreased over the 1.0 mol/l. The optical band gap energy was obtained from 3.07 to 3.22 eV which is very close to the band gap of bulk ZnO (3.2 eV). The electrical resistivity of ZnO thin films was about 150 $\Omega$-cm that shows little difference with Zn concentration. I-V curves of ZnO thin films exhibited typical ohmic contact properties.

LED visible light communication and their application (LED 가시광 통신시스템과 그 응용)

  • Chung, Wan-Young;Kim, Jong-Jin;Kwon, Tae-Ha
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2010.05a
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    • pp.226-229
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    • 2010
  • LED(Light Emitting Diode) is an emitting device which energy is same to the bandgap of p-type and n-type semiconductor junction. Recently high brightness LED is used in fish-luring light and traffic signal light alternative of normal light bulb, and widely used in the area of display pannel. Moreover nowadays LED has been used as a back light of LCD display. Recently, visible light communication(VLC) using LED, that allow two-way serial data communication between LEDs over a distance of sveral centimeters or meters, has been widely studied in the area of digital information transmission along with illumination and display. In this paper, we present LED communication system and their applications.

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Non-Contact Power Supply Using the Series-Parallel Resonant Converter (직ㆍ병렬 공진형 컨버터를 이용한 비접촉전원)

  • Kong Young-Su;Kim Eun-Soo;Yang Seung-Chul;Kim Jong-Mu;Shin Byung-Chul
    • The Transactions of the Korean Institute of Power Electronics
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    • v.9 no.5
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    • pp.405-412
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    • 2004
  • In this paper, Non-contact power supply(NCPS) with the long primary cable longer than 20m and the large air-gap between the primary and secondary of Non-Contacting Transformer(NCT) is presented. The NCT has a large leakage inductance bigger than its magnetizing inductance because it has low coupling, and it is not efficient for NCPS to transfer the primary energy to the secondary one. In order to improve this problem, the voltage-gain characteristics of the series resonant converter, the parallel resonant converter, and the series-parallel resonant converter are analyzed respectively. In addition, the experimental results of 10kW prototype the series-parallel resonant converter is presented.

Growth and temperature dependence of energy band gap for $CuGaSe_2$ Single Crystal Thin Film by Hot Wall Epitaxy (Hot Wall Epitaxy(HWE)법에 의한 $CuGaSe_2$ 단결정 박막의 성장과 에너지 밴드갭의 온도 의존성)

  • Lee, Sang-Youl;Hong, Kwang-Joon
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.97-98
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    • 2007
  • A stoichiometric. mixture of evaporating materials for $CuGaSe_2$ single crystal thin films was prepared from horizontal electric furnace. Using extrapolation method of X-ray diffraction patterns for the polycrystal $CuGaSe_2$, it was found tetragonal structure whose lattice constant $a_0$ and $c_0$ were $5.615\;{\AA}$ and $11.025\;{\AA}$, respectively. To obtain the single crystal thin films, $CuGaSe_2$ mixed crystal was deposited on thoroughly etched semi-insulating GaAs(100) substrate by the hot wall epitaxy (HWE) system. The source and substrate temperatures were $610^{\circ}C$ and $450^{\circ}C$, respectively. The crystalline structure of the single crystal thin films was investigated by the photoluminescence and double crystal X-ray diffraction (DCXD). The carrier density and mobility of $CuGaSe_2$ single crystal thin films measured with Hall effect by van der Pauw method are $4.87{\times}10^{17}\;cm^{-3}$ and $129\;cm^2/V{\cdot}s$ at 293 K, respectively. The temperature dependence of the energy band gap of the $CuGaSe_2$ obtained from the absorption spectra was well described by the Varshni's relation, $E_g(T)\;=\;1.7998\;eV\;-\;(8.7489\;{\times}\;10^{-4}\;eV/K)T^2/(T\;+\;335\;K)$.

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