• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.26-26
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• 2012

The hydrophobic nature of the wool surface give rise to difficult penetration of dye molecules. Among all the methods of modification, graft polymerization is an attractive method to impart a variety of functional groups to a polymer. Grafting has been made by irradiating the light on the polymer in the presence of a solvent containing monomer. The energy source commonly used are high-energy electrons, X-rays, UV and visible light. UV irradiation is a relatively low-energy radiation in comparison with others since it has the least possibility to change bulk properties. In the present paper, a photo-reactive dye was synthesized from quinizarin by the reaction with methacryloyl chloride. The synthesized dye was continuously grafted onto wool fabric at room temperature by UV irradiation. Several key parameters including UV energy, dye concentration and pH have been examined to understand their influence on the photoreactive coloration.

• Proceedings of the Korean Fiber Society Conference
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• 1998.10a
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• pp.145-148
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• 1998

1821년경 최초로 "loess"라는 이름으로 사용된 황토는 산화철을 함유하는 황갈색의 광물성 염료이며, 이것은 일반적으로 황토가 포함된 원토를 채에 담아 물 속에서 선별하거나 바람에 날려 분리시켜 얻어지며, 분리되어진 황토는 불투명한 황갈색의 색조와 항균성이 있는 것으로 알려져 왔다[1]. 그러나 황토는 물기름, 유기용제 등에 불용성이며 섬유와 친화력이 없어 염색후 내세탁성이 낮아 황토 염색시 고착제인 콩즙을 이용하는 전통적인 방법이 알려지다가 최근에 Kim[2]은 고착제 없이 황토의 입자 크기를 5 $mu extrm{m}$ 이하로 하여 9$0^{\circ}C$에서 5~10 분간 교반하는 방법으로 면직물에 염색해 내세탁성과 항균성이 있는 염색물을 얻고자 하였으나 입자 크기가 5$\mu\textrm{m}$이하 수준에서도 친화력이 부족하여 내세탁성에는 크게 영향을 미치지 못하였으며 항균 효과도 낮게 나온 것으로 보고되었다. (중략)

• Textile Coloration and Finishing
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• v.20 no.4
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• pp.53-59
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• 2008

For the modification of wool surface, wool fabrics treated with oxygen low-temperature plasma(LTP) and dichloroisocyanuric acid(DCCA) were dyed with milling type acid dye. The difference of dyeing properties on modified and control wool fabric were investigated. DCCA treated wool showed that saturation dye uptake and dyeing desorption ratio were higher than LTP treated wool. Dyeing transition temperatures of DCCA and LTP treated wool fabrics were 20$^{\circ}C$ degree lower than control wool fabric. In light color fastness test, DCCA treated wool fabric was 1 grade lower than LTP or control wool fabric.

• Textile Coloration and Finishing
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• v.20 no.4
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• pp.43-52
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• 2008

Wool fabric was treated with oxygen low-temperature plasma (LTP) and dichloroisocyanuric acid. The effect of dimensional stability (relaxation shrinkage, hygral expansion, felting shrinkage), tensile strength and elongation, crease recovery, and hand of wool fabric between LTP, DCCA treated wool fabrics and control wool fabric were investigated. SEM photograph showed that a little micro crack was formed on the fiber surface by plasma treatment with hard condition and epicuticle scale was damaged by DCCA treatment. Felting shrinkage, tensile strength and total hand value were much different in each samples.

• Textile Coloration and Finishing
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• v.16 no.1
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• pp.10-17
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• 2004

Wool fabrics were treated with deep UV for 10 to 30min and then dyed with C.I. Acid Yellow 99, C.I, Acid Red 57 and C.I. Acid Blue 62. FT-IR and XPS have been used to prove the chemical composition of wool fiber surfaces. The mechanical property and colorfastness were also studied. The intencities of the peaks of C=O group at $1700^cm^{-1}$ were increased with increasing irradiation time. Relative $O_{1s},\; N_{1s}\; and\; S_{2p}$ intensities increased considerably and oxygen was incorporated in the form of CO and COO on the fiber surface. The dye uptakes of wool fabrics dyed with three acid dyes were proportional to irradiation times and in inversely proportional to irradiation distances. It was found that the tensile strength of wool fabrics were gradually deteriorated with the UV irradiation times. The colorfastness, such as washing, light and rubbing, of UV irradiated wool fabrics dyed with acid dyes were good.

• Textile Coloration and Finishing
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• v.10 no.1
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• pp.33-37
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• 1998

It is rather important in the water and oil repellent finishing for wool fabric what kind of water-repellent agents will be used. In many cases, Fluorocarbon-based water-repellent agents(eg.Oleophobol-S), the surface tensions of which very low, were recom-mended on account of good water and oil repellencies. In repellent finishing, fabrics were padded in a bath which contained aqueous solution of water-repellent agents, and wetting agents, followed by drying and curing. The most suitable treating condition for excellent repellency was as follows Fabrics were padded at liquor pick-up ratio of 50%, with aqueous solution which contained $30g/\ell$ of water-repellent agents, and $40g/\ell$ of wetting agents. And the padded fabrics were dried at $110^\circ{C}$ for 1 minute, and cured at $160^\circ{C}$ for 2 minutes. For the fabrics, water and oil repellencies and durability to repeated dry-cleanings are observed.

• Fashion & Textile Research Journal
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• v.3 no.4
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• pp.344-350
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• 2001

Wool fabrics were treated with dichloro isocyanuric acid (DCCA) and dyed with acid dyes (C.I. Acid Red 18), and then, they were treated by sputter etching. Wool fabrics had been sputtered with aluminium under various conditions such as sputter etching time and discharge power in the presence of argon gas. We compared mechanical properties, colour difference and fastness properties of these samples one another: Mechanical properties and colour difference of sputtered wool fabrics changed by sputter etching time, discharge power and DCCA concentration. Light fastness showed a rising tendency but rubbing fastness showed a downward tendency when sputter etching time was 7 minutes.

• Textile Coloration and Finishing
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• v.13 no.4
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• pp.227-233
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• 2001

Wool fabrics were pre-treated with corona prior to treating with enzyme for shrinkage resistance. Commercial protease and cellulase were used for degradation of wool and the treatment conditions such as enzyme amount, treating time, and assistant chemicals. Friction coefficient and zeta-potential were measured to certificate an effect of treatment condition on the handle of wool fabric. Corona pretreatment make the wool fabric soft, which result in the decrease of friction coefficient and zeta-potential. Scale removal of wool surface was observed by scanning electron microscope. Amino acid analysis shows the effectiveness of enzyme, and corona pretreatment does not cause severe internal damage.

• Journal of the Korean Society of Clothing and Textiles
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• v.38 no.1
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• pp.110-122
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• 2014

This study examined hwangbek dyeability for cotton, silk, and wool from different tree species and origin as well as their berberine and palmatine content. A total of 12 different hwangbek were examined, six purchased directly from different locations of China and six purchased from the Seoul Medicine Market. Hwangbek purchased from China were 3 Kwanhwangbek (Phellodendron amurense Rupr.) from Jilin, Liaoning, Heilongjiang and 3 Chunhwangbek (Phellodendron chinense Schneid.) from Sichuan, Yunnan, and Guangxi. Hwangbek purchased from the Seoul Medicine Market included 3 hwangbek that originated from Korea and 3 hwangbek imported from China. We extracted 2.5g of each hwangbek into 500mL of water for 60 min at $80^{\circ}C$. Dyeing was conducted using the IR dyeing machine for 30min at $55^{\circ}C$ using a 1:100 liquor ratio. Cotton was mordanted using tannic acid followed by potassium antimonyl tartrate trihydrate treatment before dyeing. Berberine and palmatine pigments in hwangbek were identified with the HPLC-DAD-MS instrument and the amount of pigment was quantified using an ion chromatogram. The results indicated that the K/S values of dyed fabrics were highly related to the amount of pigment in hwangbek used for dyeing.

• Textile Coloration and Finishing
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• v.20 no.2
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• pp.9-18
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• 2008

Wool has excellent properties, such as heat retention, absorbency, and elasticity, but it has a disadvantage in washability because the fabric will felt and shrink greatly. Felting causes the interlocking of the fiber surface scales with one another. Therefore, the studies on wool finishing have been focused on shrink proofing. Precedent researches on wool shrink proofing are mostly on eco-friendly method. using enzyme. The purpose of this study is to examine the effect of L-cysteine, EDTA in papain treatment of wool fabrics. The specific contents of study are as follows. Depending on pH, temperature, treatment time, enzyme concentration and L-cysteine, EDTA concentration, weight loss, tensile strength, whiteness, SEM were examined. Each papain treatment conditions depending on L-cysteine, EDTA were optimized from these properties. Papain had very low activation without activators. The optimum conditions of papain treatment were pH 7.5, temperature $75^{\circ}C$, time 30minutes(L-cysteine), 180minutes(EDTA) and papain concentration 5%(o.w.f.). In the use of papain 5%(o.w.f.), the activators optimum concentration was L-cysteine 2%(o.w.f.), EDTA 7%(o.w.f.)