• Title/Summary/Keyword: 양극전압

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A Study on the Development of the Short Rate Zinc-Silver Secondary Battery (단시간 정격 아연-산화은 2차전지 개발에 관한 연구)

  • 공영경;김세웅
    • Journal of Energy Engineering
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    • v.3 no.1
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    • pp.77-83
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    • 1994
  • 아연-산화은 2차전지는 높은 에너지 밀도의 이점을 가진 반면, 짧은 사이클수명(설계 및 사용방법에 따라 10∼200 사이클)을 가진 단점이 있다. 산화은 전극의 비싼 가격 때문에 높은 에너지 밀도가 요구되는 분야에서 제한적으로 사용되고 있다. 본 논문은 수중운동체계의 추진용으로 사용하기 위한 신뢰성이 높은 아연-산화은 전지의 개발을 다루었다. 고율방전에서 양극 활물질의 양에 따른 전압 특성과 음극활물질의 첨가제에 따른 사이클 수명 비교 시험을 실시하였다. 본 연구결과 우수한 전압 특성과 고율방전에서10회 이상의 사이클 수명을 갖는 아연-산화은 2차전지를 개발하였다.

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Preparation of Titania Nanotube Thin films by Anodizing (양극산화를 이용한 Titania Nanotube(TNT) 박막 제조)

  • Lee, Young-Rok;Jung, Ji-Hoon
    • Korean Chemical Engineering Research
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    • v.49 no.1
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    • pp.28-34
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    • 2011
  • Titania nanotube(TNT), which is a tube shaped thin film manufactured by anodizing titanium under $F^-$ ion electrolyte, has photo activity. Distilled water and formamide were used as solvent, and HF, NaF, $NH_4F$ were used as main $F^-$ ions for the electrolyte. The length and the diameter of TNT increased as the voltage and anodizing time increased. TNT prepared by anodizing was a very ordered tube, and had a maximum length of 13.7 ${\mu}m$ depending on the conditions of manufacturing. Titania prepared by anodizing was amorphous, and became an anatase crystal after heat treatment.

Enhancement of Corrosion Resistance of Lubricant-Infused Nanoporous Aluminum Anodic Oxide by Controlling Pore Shapes (알루미늄 양극산화피막의 기공 형상 제어를 통한 윤활유가 침지된 표면의 내식성 향상)

  • Lee, Jeong-Hun;Cho, Chang-Hwan
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2018.06a
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    • pp.27-27
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    • 2018
  • 알루미늄은 취약한 내식성을 보완하기 위하여 나노다공성의 산화물 피막을 형성하는 양극산화 처리를 주로 활용한다. 이러한 나노다공성 산화물 피막에 소수성 처리와 불용성의 윤활유를 침지하면 표면에 접촉하는 물을 비롯한 다른 유체들의 젖음성을 크게 감소시킬 수 있으며, 이로 인하여 부식성 물질이 다공성 구조물로 침입하는 것을 억제할 수 있다. 따라서 양극산화 피막에 윤활유 침지를 이용하여 알루미늄의 부식에 대한 저항성을 크게 향상시킬 수 있으며, 추가적으로 외부의 물리적인 손상에 대한 치유 능력을 얻을 수 있다. 이러한 성능뿐만 아니라 침지된 윤활유의 내구성은 나노다공성 산화피막의 물리적 형상에 따라 차이가 날 수 있다. 본 연구에서는 나노다공성의 양극산화 피막의 기공 구조를 다양하게 변화시켜 그 형상에 따라서 윤활유를 침지 후 알루미늄 소재의 내식성 및 자기 치유 특성의 차이에 대하여 알아보았다. 기공의 형상은 한쪽 끝이 막혀있는 기둥형, 후처리를 통한 확장된 기둥형 및 침상형의 기공 구조를 제조하였고, 전압제어를 통한 병목 형상의 기공 구조를 구현하여 그 특성 차이를 비교하였다. 기공들이 서로 고립된 형태를 가질수록 윤활유가 안정적으로 산화물에 침지될 수 있으며, 기공의 공간이 클수록 더 많이 윤활유를 포함하여 우수한 자기 치유 특성을 보여주었다. 병목 형상의 가공 구조는 내부의 충분한 크기의 기공 공간과 표면에 작은 기공을 가지고 있기 때문에 우수한 내구성과 자기 치유 특성을 보여준다.

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Design and testing of bipolar pulsed power supply with high efficiency for mineral exploration (광물 탐사를 위한 고효율 양극성 펄스전원장치 설계 및 실험)

  • Bae, Jung-Soo;Kim, Shin;Yu, Chan-Hun;Kim, Hyoung-Suk;Kim, Jong-Soo;Jang, Sung-Roc
    • Proceedings of the KIPE Conference
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    • 2018.07a
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    • pp.48-50
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    • 2018
  • 본 논문은 광물 탐사용 25kW 양극성 펄스전원장치에 대해 기술한다. 고효율 LCC 공진형 컨버터와 풀 브리지 기반 바이폴라 펄스 스위칭부로 구성된 500V, 12.5A 단위 모듈을 설계한다. LCC 공진형 컨버터는 도전 손실을 줄이기 위해 사다리꼴 모양의 공진 전류를 갖도록 하고, 높은 전력 밀도를 달성하기 위해 변압기의 누설 인덕턴스를 공진 인덕턴스로 활용한다. 또한, 반복적인 짧은 펄스 기반으로 설계된 게이트 구동 회로는 DC에서 8kHz의 주파수 범위를 동작시키고 게이트 변압기의 사이즈를 줄이기 위해 제안된다. 개발된 양극성 펄스전원장치는 4개의 모듈이 직병렬로 결선되어 부하 조건에 따라 Grounded dipole mode (2kV, 12.5A) 또는 Loop mode (500V, 50A)로 동작한다. 네 모듈의 출력 전압 밸런싱을 충족시키기 위해 LCC 공진형 컨버터의 변압기에 보상권선이 감긴다. 본 논문에서는 양극성 펄스전원 장치의 상세설계에 대해 기술하고, 시뮬레이션 및 실험 결과를 통해 이를 검증한다.

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Superhydrophobic Engineered Surface Based on Nanohoneycomb Structures (나노허니컴 구조물을 이용한 산업용 극소수성 표면 제작)

  • Kim, Dong-Hyun;Park, Hyun-Chul;Lee, Kun-Hong;Hwang, Woon-Bong
    • Composites Research
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    • v.20 no.2
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    • pp.17-20
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    • 2007
  • Superhydrophobic polytetrafluoroethylene ($Teflon^{(R)}$, Dupont) sub-micro and nanostructures were fabricated by the dipping method, based on anodization process in oxalic acid. The polymer sticking phenomenon during the replication creates the sub-microstructures on the negative polytetrafluoroethylene nanostructure replica. This process gives a hierarchical structure with nanostructures on sub-microstructures, which looks like the same structures as lotus leaf and enables commercialization. The diameter and the height of the replicated nano pillars were 40 nm and 40 um respectively. The aspect ratio is approximately 1000. The fabricated surface has a semi-permanent superhydrophobicity, the apparent contact angle of the polytetrafluoroethylene sub-micro and nanostructures is about $160^{\circ}$, and the sliding angle is less than $1^{\circ}$.

Corrosion mitigation of photovoltaic ribbon using a sacrificial anode (희생양극을 이용한 태양광 리본의 부식 저감)

  • Oh, Wonwook;Chan, Sung-Il
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.3
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    • pp.681-686
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    • 2017
  • Degradation is commonly observed in field-aged PV modules due to corrosion of the photovoltaic ribbon. The reduced performance is caused by a loss of fill factor due to the high series resistance in the PV ribbon. This study aimed to mitigate the degradation by corrosion using five sacrificial anodes - Al, Zn and their alloys - to identify the most effective material to mitigate the corrosion of the PV ribbon. The corrosion behavior of the five sacrificial anode materials were examined by open circuit potential measurements, potentiodynamic polarization tests, and galvanic current density and potential measurements using a zero resistance ammeter. Immersion tests for 120 hours were also conducted using materials and damp heat test tests were performed for 1500 hours using 4 cell mini modules. The Al-3Mg and Al-3Zn-1Mg sacrificial anodes had a low corrosion rate and reduced drop in power, making then suitable for long-term use.

Preparation and Photocatalytic Characteristics of $TiO_2$ by Anodic Oxidation Process (양극산화법에 의한 광촉매용 $TiO_2$제조 및 특성)

  • Jang, Jae-Myeong;Kim, Seong-Gap;O, Han-Jun;Lee, Jong-Ho;Ji, Chung-Su
    • Korean Journal of Materials Research
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    • v.11 no.1
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    • pp.61-66
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    • 2001
  • $TiO_2$films for photocatalytic reaction were synthesized by anodizing process. The photocatalytic efficiencies of anodized $TiO_2$were evaluated by the rate of decomposition of aniline blue. The properties of photocatalysis on anodic $TiO_2$films have been observed, but the efficiencies of photocatalytic reaction depended on the conditions of films formation. The microstructure of the anodic film formed in $H_2SO_4$ solution differed from that of $TiO_2$films formed in $H_2SO_4+H_3PO_4$ solution. It has been shown that the appropriate applied-voltage for anodizing of titanium for photocatalysis was 180V in both aqueous solutions.

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Development of a 700 W Class Laboratory Model Hall Thruster (700 W급 홀 전기추력기 랩모델 연구개발)

  • Doh, Guentae;Kim, Youngho;Lee, Dongho;Park, Jaehong;Choe, Wonho
    • Journal of the Korean Society of Propulsion Engineers
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    • v.25 no.5
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    • pp.65-72
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    • 2021
  • 700 W class laboratory model Hall thruster, which can be used for the orbit control or station keeping of small satellites, was developed. The size of the discharge channel was determined using a scaling law, and the magnetic field was designed to be symmetric with respect to the midline of the discharge channel and to be maximized outside the discharge channel. Base pressure of a vacuum chamber was maintained below 2.0×10-5 Torr during experiments, and the thrust was measured by a thrust stand. The anode flow rate and coil current were varied with the fixed anode voltage at 300 V. Under the operation condition at 2.36 mg/s anode flow rate and 2.4 A coil current, performance was optimized as 38 mN thrust, 1,540 s total specific impulse, and 50 % anode efficiency at 620 W anode power.

Effect of the Removal of an Initial Oxide Layer and the Anodization Time on the Growth of the Porous Alumina Layer (초기 산화피막 제거와 양극산화 시간에 따른 다공성 알루미나 막의 성장)

  • Kim, Dae-Hwan;Lue, Sang-Hee;Lee, Hyo-Jin;Park, Young-Ok;Lee, Eun-Joong;Kouh, Tae-Joon
    • Journal of the Korean Magnetics Society
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    • v.20 no.5
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    • pp.191-195
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    • 2010
  • We have investigated the effect of the removal of an initial oxide layer and the anodization time on the growth of the porous alumina layer. The porous alumina layer was fabricated by two-step anodization process with phosphoric acid. We have observed the changes in the uniformity of the pore structure by varying the removing time of the initial oxide layer after the first anodization with phosphoric acid and chromic acid, and noted that its uniformity improves with the removing time. We have also determined the thickness of the alumina layer after the final anodization process and found that the thickness increases linearly with the anodization time. Under 150 V of anodization voltage with phosphoric acid, the growth rate of the porous alumina layer is determined to be 22.5 nm/min.

Design of an 8-Bit eFuse One-Time Programmable Memory IP Using an External Voltage (외부프로그램 전압을 이용한 8비트 eFuse OTP IP 설계)

  • Cho, Gyu-Sam;Jin, Mei-Ying;Kang, Min-Cheol;Jang, Ji-Hye;Ha, Pan-Bong;Kim, Young-Hee
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.14 no.1
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    • pp.183-190
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    • 2010
  • We propose an eFuse one-time programmable (OTP) memory cell based on a logic process, which is programmable by an external program voltage. For the conventional eFuse OTP memory cell, a program datum is provided with the SL (Source Line) connected to the anode of the eFuse going through a voltage drop of the SL driving circuit. In contrast, the gate of the NMOS program transistor is provided with a program datum and the anode of the eFuse with an external program voltage (FSOURCE) of 3.8V without any voltage drop for the newly proposed eFuse cell. The FSOURCE voltage of the proposed cell keeps either 0V or the floating state at read mode. We propose a clamp circuit for being biased to 0V when the voltage of FSOURCE is in the floating state. In addition, we propose a VPP switching circuit switching between the logic VDD (=1.8V) and the FSOURCE voltage. The layout size of the designed eFuse OTP memory IP with Dongbu HiTek's $0.15{\mu}m$ generic process is $359.92{\times}90.98{\mu}m^2$.