• Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
• /
• 1999.11a
• /
• pp.164-168
• /
• 1999

• Transactions of the Korean hydrogen and new energy society
• /
• v.7 no.2
• /
• pp.121-128
• /
• 1996

A direct cooling equipment for hydrogen liquefaction has been developed and tested. A direct cooling equipment consists of a liquefaction vessel, a radiation shield, a cryostat and a GM refrigerator. The cool-down and warm-up characteristics of the liquefaction apparatus have been investigated in detail. It is found that the hydrogen starts to be liquefied in the liquefaction vessel after 45 minutes of cool-down. The cool-down and warm-up tests of helium gas are also performed. The cool-down and warm-up characteristics of helium gas are found to be very different from those of hydrogen gas, since helium is not liquefied under the present operating conditions. When the liquefaction vessel is evacuated, natural convection phenomena of charged gas in liquefaction vessel can be removed. It is seen that the cool-down time of liquefaction vessel is substantially increased in vacuum environment.

• 한국신재생에너지학회:학술대회논문집
• /
• 2010.06a
• /
• pp.107.2-107.2
• /
• 2010

고온건식탈황기술은 고온고압에서 석탄가스에 함유된 황화합물을 제거하는 기술로 석탄가스화에 의해 생성된 고온의 석탄가스의 열손실을 최소화하여 열효율이 높은 기술이다. 본 연구에서는 석탄으로부터 합성원유를 생산하는 0.3 배럴/일 규모 석탄액화(CTL)공정의 연계운전을 통하여 건식탈황공정의 성능을 평가하였다. 0.3 배럴/일 규모 석탄액화공정은 석탄가스화기, 건식탈황공정, 액화공정으로 구성되어 있으며 30 atm의 고압에서 운전된다. 건식탈황공정은 석탄가스화기와 액화공정 사이에 위치하여 석탄가스화로부터 생성된 석탄가스에 함유된 황화합물을 아연계 건식탈황제에 의해 제거한 후 액화반응기로 공급하여 황화합물에 의한 촉매의 피독을 막아주는 역할을 수행한다. 본 연구에서는 기존에 개발된 두 개의 기포유동층 반응기로 구성된 탈황장치를 30 atm에서 운전이 가능하도록 수정/보완하여 실제 운전압력인 30 atm의 고압에서 연속운전을 수행하였다. 실험 결과 탈황효율은 99% 이상이며 탈황반응기 출구 황화합물의 농도는 1 ppmv 이하로 유지하였다.

• Journal of Energy Engineering
• /
• v.10 no.4
• /
• pp.370-378
• /
• 2001

Characteristics and synergistic effects of the coliquefaction of Alaskan subbituminous coal, wasted tire, and polypropylene were investigated in a tubing-bomb reactor at 41$0^{\circ}C$, and the coliquefaction reactions were performed at 37$0^{\circ}C$~45$0^{\circ}C$ to evaluate the coliquefaction mechanism. The coliquefaction kinetic model based on the free-radical theory was proposed and simulated by the non-linear parameter estimation method. Simulated results represented experimental ones successfully with the correlation coefficient of 0.99. When a catalyst was not used, the conversions were decreased as tetralin increase due to the decrease of liquefaction of polypropylene. When naphthenate catalysts of Mo, Co, and Fe were used, the coliquefaction conversions were increased with the increase of the liquefaction of polypropylene. When Co-naphthenate catalyst was used, the increase of the coliquefaction conversion were as high as 21~23%.

• Journal of Korean Tunnelling and Underground Space Association
• /
• v.18 no.2
• /
• pp.175-181
• /
• 2016

In this paper, the liquid air was selected as the refrigerant in artificial ground freezing to be used for rapid ground freezing and to reduce the risk of suffocation and the applicability of liquid air was verified. In order to evaluate the stability of the liquid air, the oxygen concentration of mixtures with liquid nitrogen and liquid oxygen was experimentally examined to meet the oxygen concentration criteria in the Occupational Safety and Health Act. In addition, the effects of the mixture ratio of liquid nitrogen and liquid oxygen, pressure and flow rate change in the storage vessel on the oxygen concentration in the liquid air were investigated. As a result, the ratio of liquid nitrogen and liquid oxygen 8: 2 was shown to meet the oxygen concentration standards. Pressure and flow rate change in the storage vessel did not have significant effects on the oxygen concentration in the liquid air.

• Journal of Advanced Marine Engineering and Technology
• /
• v.36 no.6
• /
• pp.756-761
• /
• 2012

Natural gas is converted in to LNG by chilling and liquefying the gas to the temperature of $-162^{\circ}C$, when liquefied, the volume of natural gas is reduced to 1/600 of its standard volume. This gives LNG the advantage in transportation. In this study, the effects of the pressure drop of refrigerant and natural gas in the LNG heat exchanger of cryogenic cascade refrigeration cycle were investigated and then the design criteria for the pressure drop of refrigerant and natural gas of the LNG heat exchanger were proposed. The pressure drop of the cascade liquefaction cycle was investigated and simulated using HYSYS software. The simulation results showed that the pressure drop in the LNG heat exchanger is set to 50 kPa considering the increase in the compressor work and COP of cryogenic cascade liquefaction cycle.

• Journal of the Korean Institute of Gas
• /
• v.7 no.4 s.21
• /
• pp.1-6
• /
• 2003

Freon gas has been replaced with LPG in the cosmetic industry because of its bad effects on environment. In this paper, skincare product with a cooling effect was developed using LPG as propellant. A cooling effect is obtained by the ice which is formed through spraying. Ice formation is affected by the composition of LPG and most of all, the high content of propane gas in the LPG results in the irregular surface of ice formed because of its high vapor pressure. Also the ratio of LPG to skincare solution affects the formation of ice.

• Journal of Welding and Joining
• /
• v.13 no.3
• /
• pp.1-7
• /
• 1995

1992년 9월 현재 전 세계적으로 운전 중(건설포함)인 액화 및 인수기지의 LNG 저장탱크는 지상식-이중벽 금속 탱크, 지상식-맴브레인 PC 탱크, 지상식-자립식 내부탱크/PC 외부탱크, 피드식-RC(Reinforced Concrete) 보강둑 탱크, 피트식-이중벽 금속탱크, 피트식-자립식 내부탱크/PC 외부탱크 및 지하식 탱크의 7가지 유형으로 나 타낼 수 있다. 또한 액화천연가스를 저장하는 내부탱크 소재에 따라 9%Ni강 및 MEMBRANE(SUS304) 형식으로 대별할 수 있다. MEMBRANE 저장탱크 형식의 핵심기술인 MEMBRANE은 -162.deg.C의 LNG에 의한 열수축팽창에 견딜 수 있도록 스테인레스강판 (SUS304)을 사용하여 기하학적으로 특이한 주름진 형상을 갖도록 설계되었으며 주름 형상에 따라 프랑스의 테크니가즈(Technigaz), 일본의 가와사끼(Kawasaki). 미쓰비시 (Mitsubishi), 이시가와지마하리마(Ishikawajima-Harima)사의 멤브레인과 세계에서 3번째로 한국가스공사 연구개발원이 개발한 링디식 멤브레인으로 구별할 수 있다. 본 해설에서는 국내의 전국 천연가스 공급사업계획 및 건설현황을 검토하고 최근 전 세계적으로 널리 사용되고 있는 액화천연가스 저장탱크의 종류를 용량별, 년도별로 분석하여 전세계의 액화천연가스 저장탱크에 관해 소개 하겠다.

• 월간 기계설비
• /
• s.228
• /
• pp.43-54
• /
• 2009

석탄가스화 액화기술은 기후변화협약, 환경규제 등에 대응할 수 있고 석유나 천연가스의 고갈에 대비한 에너지의 안정적 확보 차원에서 저공해 고효율화 기술로 평가되고 있다. 석탄가스화 기술은 환경 친화적이고 미분탄 발전과 비교하면 이산화탄소 발생량이 20% 이상 감소돼 향후 기후변화협약 발효에 따른 탄소배출권이 현실화 될 경우를 고려하면 경제적 파급효과는 클 것으로 예상되고 있다. 최근 주요 선진국들은 석탄가스화 액화 실증플랜트 건설 운영을 위해 민간과 정부가 공동 으로 노력 중이며 차세대 발전기술 분야의 수출전략 산업으로 육성하고 있다. 그러나 현재 국내에서는 상용급 IGCC 발전소 건설 경험이 없고 관련 기반 기술이 선진국에 비해 열세이다. 이에 따라 석탄가스화 및 액화기술, 설비제작, 엔지니어링 등 관련 국내기업간의 협력을 통한 기술 및 시장경쟁력 제고방안이 마련돼야 한다는 지적이다. 이번 호에서는 석탄가스화 액화기술에 대해 알아본다.

• KSBB Journal
• /
• v.7 no.1
• /
• pp.73-78
• /
• 1992

The solubilizations of Australian lignite by the fungus Poria cocos, Trichodermareesei, Candide tropicalis, and niger were investigated. Three different types of chemical pretreatment methods were used for increasing biosolubility of lignite. Nitric acid and hydrogen peroxide were proven to be proper chemical pretreatment materials of Australian lignite. Poria cocos showed much better solubilization ability than other strains. Interpretation of the nature of coal solubilization by Poria cocos was based primarily on infrared, ultraviolet and nuclear magnetic resonance spectrum analyses.