• Title/Summary/Keyword: 액체-액체 평형

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Numerical Formulation of Axisymmetric Shell Element and Its Application to Geotechnical Problems (축대칭 쉘 요소의 유한요소 수식화와 지반공학적 활용)

  • Shin, Hosung;Kim, Jin-Wook
    • Journal of the Korean Geotechnical Society
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    • v.36 no.12
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    • pp.27-34
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    • 2020
  • Use of axisymmetric shell element for the structure increases the efficiency and accuracy in finite element analysis of the interaction between the ground and the structure. This paper derived the force balance equation and the moment balance equation for an axisymmetric shell element based on Kirchhoff's theory. The governing equation for the axial deformation used the isoparametric shape function in the Galerkin formulation, and the governing equation for the shell bending used the higher-order shape function. The developed axisymmetric shell element was combined with Geo-COUS, a geotechnical finite element program for the coupled analysis with the ground. The accuracy of the developed element was confirmed through the example analyses of the circular plate and the liquid storage tank. And the energy balance equation for the axisymmetric shell element is presented.

Measurement of Langmuir Adsorption Equilibrium by Elution-curve Method and Frontal Analysis (용출곡선법과 Frontal Analysis를 이용한 Langmuir 흡착평형식의 측정)

  • Choi, Yong Seok;Lee, Chong Ho;Row, Kyung Ho
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.672-676
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    • 1999
  • Adsorption isotherm is the most fundamental information in adsorption separation-process. Directly from the elution profile of a peak, the elution-curve method and frontal analysis(FA) were utilized to measure the adsorption isotherm in this work. Using RP-HPLC, sample and the buffer added in mobile phase were 5'-GMP and sodium phosphate, respectively. In this experimental condition, the retention time was decreased with increase in the injected mass of sample. And the front part of a peak was very stiff, so Langmuir adsorption isotherm might be applied. By the elution-curve method, the parameters used in the isotherm were obtained by optimization method, while by the FA, the concentrations of stationary phase were measured from the elution curve and the isotherm was determined by regression analysis. Compared to FA, the consumption of sample was less, and only one or two injections were needed by the elution-curve method. Finally, the effect of concentration of sodium phosphate in mobile phase on the parameters of the isotherm was investigated.

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Nonlinear Adsorption Isotherm of Single and Multi-Components of 2'-Deoxyribonucleosides (2'-deoxyribonucleosides의 단일 및 다성분계의 비선형 흡착평형식)

  • Jin, Long Mei;Han, Soon Koo;Choi, Dae-Ki;Row, Kyung Ho
    • Korean Chemical Engineering Research
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    • v.43 no.2
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    • pp.230-235
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    • 2005
  • Reversed-phase high-performance liquid chromatography (RP-HPLC) was used to determine the equilibrium isotherm of single and multi-components of dUrd(2'-deoxyuridine), dGuo(2'-deoxyguanosine), and dAdo(2'-deoxyadenosine) of 2'-deoxyribonucleosides by dynamic method. The composition of mobile phase was 90/10 vol.% (water/MeOH). With an increase in the injection volumes, the retention times were shorter and the peak shapes were triangle-shaped, so Langmuir-type isotherm was assumed. The Langmuir adsorption parameters were estimated by PIM (pulsed-input method), and the competitive Langmuir adsorption isotherm was further utilized. For the sample of the dUrd and dGuo whose retention times were relatively short, the agreement of between the calculated value and experimental data was fairly good in both single and multi-components, but for the dAdo, the last eluting component, some deviations were caused by non-linear and non-ideal properties.

Evaluation of 226Ra analysis methods using a gamma-ray spectrometer and a liquid scintillation counter (감마선분광분석기와 액체섬광계수기를 이용한 226Ra 분석법 비교 연구)

  • Ju, Byoung Kyu;Kim, Moon Su;Kim, Hyun Koo;Kim, Dong Su;Cho, Sung Jin;Yang, Jae Ha;Park, Sun Hwa;Kim, Hyoung Seop;Kwon, Oh Sang;Kim, Tae Seung
    • Analytical Science and Technology
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    • v.28 no.3
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    • pp.228-235
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    • 2015
  • The efficiency and applicability of the solid phase extraction disk method in a 226Ra analysis were examined by the gamma ray spectrometer (GRS) method using a Marinelli beaker and the liquid scintillation counter (LSC) method for groundwater. The recovered 226Ra, which was filtered by the solid phase extraction disk, was analyzed using gamma ray spectrometer The disks, which were pretreated for caulking the daughter nuclide, were sealed with polyethylene film. Distilled water was used for the blank value of the 226Ra activity. The recovery values of 214Bi and 214Pb in the solid phase extraction disk, which used 226Ra standard material, were 80% (295.21 Kev) and 104% (351.92 Kev), respectively, which were higher than 75% determined by the LSC. The injection of nitrogen gas into the measuring chamber reduced the interference values by about 10%. The detection limits of the 226Ra activity in a blank sample of 5 L were 0.17~0.40 pCi/L after 80,000 seconds of measuring time. The relationship of the 226Ra activity in the solid phase extraction disk method and in the LSC method in seven groundwater samples showed a correlation coefficient value 0.987, which implies the applicability of the solid phase extraction disk method. The results showed that 226Ra activity in groundwater using the solid phase extraction disk method has the following benefits: simple pretreatment, time saving, high recovery values, a low detection limit, and so on. Compared with the LSC method and the GRS method using the Marinelli beaker for the 226Ra analysis, the solid phase extraction disk method could be useful in groundwater samples with low levels of activities of radionuclides because the method is not restricted by the volume of the sample.

Helium Quantity Estimation for LOx Tank Pressurization of a Restartable Pressure-fed Propulsion System (재 점화가 있는 가압식 추진기관의 액체산소 탱크 가압 헬륨량 산정)

  • Cho, Gyu-Sik;Jung, Young-Suk;Oh, Seung-Hyub
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.3
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    • pp.77-81
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    • 2012
  • In a cryogenic propellant tank the pressurant is contracted due to heat loss and the propellant itself evaporates. On a restartable propulsion system such phenomena are more intensive because the propellant contacts with the pressurant on the larger surface during the coast flight. Such heat and mass transfer phenomena should be considered for estimating the amount of pressurant. On the hypothesis that the heat and mass transfer quasi-equilibrium is achieved during the coast flight, the calculation process of the equilibrium pressure is presented. On the process the amount of loaded helium on the Falcon-1 second stage is calculated.

Helium Quantity Estimation for LOx Tank Pressurization of a Restartable Pressure-fed Propulsion System (재 점화가 있는 가압식 추진기관의 액체산소 탱크 가압 헬륨량 산정)

  • Cho, Gyu-Sik;Jung, Young-Suk;Oh, Seung-Hyub
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.201-205
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    • 2011
  • In a cryogenic propellant tank the pressurant is contracted due to heat loss and the propellant itself evaporates. On a restartable propulsion system such phenomena are more intensive because the propellant contacts with the pressurant on the larger surface during the coast flight. Such heat and mass transfer phenomena should be considered for estimating the amount of pressurant. On the hypothesis that the heat and mass transfer quasi-equilibrium is achieved during the coast flight, the calculation process of the equilibrium pressure is presented. On the process the amount of loaded helium on the Falcon-1 second stage is calculated.

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Thermochemical Performance Analysis of Liquid Rocket Nozzle (액체로켓 노즐의 열화학적 성능 해석)

  • Choe,Jeong-Yeol;Choe,Hwan-Seok
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.31 no.1
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    • pp.85-96
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    • 2003
  • For a design of rocket engine nozzle, chemical equilibrium analysis which shares the same numerical characteristics with frozen flow analysis can be used as an efficient design tool for predicting maximum thermodynamic performance of the nozzle. 10 this study, a chemical equilibrium flow analysis code was developed for the design of hydrocarbon fueled rocket engines. 10 oder to understand the thermochemical characteristics occurring in a nozzle through the expansion process, such as recombination of chemical components and the accompanying energy recovery, chemical equilibrium flow analysis was carried out for the KSR-III rocket engine nozzles together with frozen flow and non-equilibrium flow analyses. The performance evaluation based on the present KSR-III nozzle flow analyses has provided an understanding of the thermochemical process in the nozzle and additionally, it has confirmed that the newly designed nozzle shape modified to have a reduced exit area ratio is an adequate design for obtaining an increased ground thrust.

Optimization of ejector for swirl flow using CFD (CFD를 이용한 회전 운동을 하는 이젝터의 최적화)

  • Kang, Sang-Hoon;Park, Young-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.2
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    • pp.31-37
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    • 2017
  • This paper investigates the effect of the rotational motion of a driving fluid generated by a rotational motion device at the inlet of a driving nozzle for a gas-liquid ejector, which is the main device used for ozonated ship ballast water treatment. An experimental apparatus was constructed to study the pressure and suction flow rate of each port of the ejector according to the back pressure. Experimental data were acquired for the ejector without rotational motion. Based on the data, a finite element model was then developed. The rotational motion of the driving fluid could improve the suction efficiency of the ejector based on the CFD model. Based on the CFD results, structure optimization was performed for the internal shape of the rotation induction device to increase the suction flow rate of the ejector, which was performed using the kriging technique and a metamodel. The optimized rotation induction device improved the ejector efficiency by about 3% compared to an ejector without rotational motion of the driving fluid.

A Preliminary Configuration Design of Methane/Oxygen Bipropellant Small-Rocket-Engine through Theoretical Performance Analysis (이론성능해석에 의한 메탄/산소 이원추진제 소형로켓엔진의 예비형상설계)

  • Bae, Seong Hun;Jung, Hun;Kim, Jeong Soo
    • Journal of the Korean Society of Propulsion Engineers
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    • v.19 no.3
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    • pp.47-53
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    • 2015
  • Design parameters required for Methane/oxygen bipropellant small-rocket-engine were derived through a theoretical performance analysis. The theoretical performance of the rocket engine was analyzed by using CEA and optimal propellant mixture ratio, characteristic length, and optimal expansion ratio were calculated by assuming chemical equilibrium. A coaxial-type swirl injector was chosen because of its outstanding atomization performance and high combustion efficiency compared to other types of injector and also a bell nozzle with 80% of its full length was designed. The rocket engine configuration with 1.72 MPa of chamber pressure, 0.18 kg/s in total propellant mass flow, and O/F ratio of 2.7 was proposed as a ground-firing test model.

개 동결정액 희석액에 Pentoxyfilline 첨가가 융해 후 정액성상에 미치는 영향

  • 지달영;이장희;김창근;방명걸;박성재;류일선;류재원;이주형;장유민
    • Proceedings of the KSAR Conference
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    • 2004.06a
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    • pp.280-280
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    • 2004
  • 본 연구는 개 동결정액 희석액에 pentoxyfilline을 첨가하여 융해 후 정액성상에 미치는 영향을 조사하였다. 공시견은 2∼3세의 Beagle, English cockers spania, Collie, Grey hound, Shihtzu 5두를 공시하였다. 정액은 수압법 또는 인공질법으로 채취하였고 채취된 정액은 Rota 등(EYT : Egg-yolk Tris extender, 1995)의 방법에 따라 동결정액을 제조하였다. Pentoxyfilline은 동결 보호제가 들어 있는 2차 희석액에 0 mM, 1 mM, 3 mM 농도로 첨가하였으며, 5℃에서 2시간 glycerol 평형을 한 후에 액체질소에 10분간 예비 동결하여 동결정 액을 제조하였다. (중략)

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