• Polymer(Korea)
• /
• v.32 no.3
• /
• pp.290-294
• /
• 2008

Induction mechanism of molecular orientations for a rubbed polymer film as an alignment layer was investigated using polarized UV/Vis spectroscopic experiments for polyimide and polyvinylcinnamate whose conjugated electrons are located along main chain and side chain, respectively. By determining anisotropy formed in the rubbed film, LC director formed in the LC cell, and orientation direction of deposited pentacene molecules, it was found that LC orientation was induced mainly by molecular interactions whereas surface microgrooves formed by the rubbing process affect the orientation direction of deposited pentacene molecules.

• Proceedings of the KIEE Conference
• /
• 2001.11a
• /
• pp.41-42
• /
• 2001

본 연구에서는 빠른 응답특성과 넓은 시야 각 특성을 갖는 Optically Compensated Bend Mode Liquid Crystal Displays(OCB LCDs)의 전기광학 특성을 계산하였다. 액정의 운동방정식을 시뮬레이션하여 얻은 분자배열 분포로부터 광학적 투과 특성을 계산하였으며, 누설광 차단과 수평 및 수직 방향의 넓은 시야각을 확보하기 위하여 보상필름으로써 Wide View Film을 적용하였다. 이러한 결과를 이축성 필름을 사용한 기존의 OCB LCDs와 비교함으로써 Wide View Film을 적용한 OCB LCDs의 시야의존 특성이 향상됨을 확인하였다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
• /
• 2004.07a
• /
• pp.196-199
• /
• 2004

본 연구에서는 최초로 TFT-LCD의 단위 화소 내에 존재하는 화소 및 각종 전극간 저항 성분을 총 소비전력으로부터 엄정하게 계산하였다. 단위 화소 내의 총 소비전력은 3차원적 액정의 분자배열 분포에 대하여, 전류 연속방정식을 만족하는 전위 분포로부터 얻어졌으며, 전위 분포의 시뮬레이션에 있어서는 유한한 크기의 복수 전극에 의한 측면 전장 효과가 고려되었다. 그 결과, 3차원적인 방법으로 계산된 정확한 화소 저항은 기존의 접근방법으로부터 얻어진 값에 비하여 무려 15% 가량 작은 것이 확인되었으며, 또한 데이터-공통 전극 및 화소-데이터 전극 간 저항 또한 무시할 수 없을 정도의 값이 나타남을 확인하였다.

• Polymer(Korea)
• /
• v.31 no.1
• /
• pp.37-46
• /
• 2007

Fully or nearly fully 6- [4- (4'- (nitrophenylazo)phenoxycarbonyl)]pentanoated polysaccharide derivatives were synthesized by reacting cellulose, amylose, chitosan, chitin, alginic acid, pullulan or amylopectin with 6- [4- (4'- (nitrophenylazo)phenoxy) ] pentanoyl chloride (NA6C) and their thermotropic liquid crystalline behaviors were investigated. Like in the case of NA6C, all the polysaccharide derivatives formed monotropic nematic phases, suggesting that the mesophase structure of the polysaccharide derivatives is dertermined by the mesogenic side groups and not by the polysaccharide backbone. This is the first report of polysaccharide derivatives, except cellulose derivative, that form thermotropic nematic phases. The thermal stability and degree of order of the nematic phases observed for poly saccharide derivatives were significantly different from those reported for the polymers in which the azobenzene groups are attached to flexible or rigid backbones through flexible spacers. The results were discussed in terms of the difference in the arrangement of the main and side chains and the flexibility of the main chain.

• Proceedings of the KSME Conference
• /
• 2004.11a
• /
• pp.1098-1103
• /
• 2004

In this study, the effect of channel flow in the concave surface on local heat transfer characteristics of array jets was investigated experimentally. A TLC method is employed to determine local heat transfer coefficients on the target plate and also flow visualization has been conducted to investigate the behavior of a row of impinging jets and array of impinging jets. Two different array patterns of impinging array jets devices are tested for Reynolds number(Re=10,000). In a row of impinging jets, secondary vortex is strongly maintained by main vortex at nozzle-to-plate distance of H/d=2. Therefore, the Nusselt number slowly decreased at the mid-way region between adjacent jets. In array jets, the local maximum Nusselt number region move further in the downstream direction due to the increase of channel flow velocity.

• Journal of the Korean Chemical Society
• /
• v.20 no.2
• /
• pp.118-128
• /
• 1976

The significant structure theory of liquids and the Bragg-Williams approximation of phase transition theory have been applied to the calculation of the thermodynamic properties of p-azoxyanisole which exhibits a liquid crystal phase of the nematic type. The isotropic phase was treated as a normal liquid; and for the nematic phase, in addition to its liquidity, the effect due to the arrangement of molecular-dipoles was considered. The liquidity of the p-azoxyanisole was described by the significant structure theory of liquids, and the Bragg-Williams approximation was used to consider the effect due to the arrangement of molecular-dipoles. The molar volume, vapor pressure, heat capacity at constant pressure, thermal expansion coefficient, compressibility, entropy and enthalpy change at the nematic-isotropic phase transition point, absolute entropy, and absolute Helmholtz free energy were calculated over the temperature range of the nematic and isotropic phases. The calculated results of the thermodynamic properties were compared with the experimental data.

• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.8 no.5
• /
• pp.979-983
• /
• 2007

In this thesis, a strip layout drawing of LCD S/C (shield case) was prepared. In the press die, strip layout drawing is a major factor that decides the mass production of a product. The 3D CAD/CAM system was applied for the easy correction of the interference factor with other parts to be mounted. The material use ratio was enhanced to 60.17% by optimizing the blank layout and strip layout in double width array. Furthermore, the flatness of the product was made to fit the requirements by adding the bidding process intensively on the notching part where the occurrence of the change in shape is expected owing to the thin material. For the 3D CAD/CAM software, Unigraphics NX3.0 was used. The strip layout drawing was prepared in 12 processes.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.43 no.1
• /
• pp.79-86
• /
• 2017

This study is related to a lamellar liquid crystal make-up cleansing formulation with a hologram-like unique appearance between two polarizing plates. Make-up cleansing formulations with a lamellar liquid crystal phase have been extensively studied for a long time, but there have been limitations in practical commercialization because of increasing turbidity and viscosity. In this study, to solve this problem, alkyl chains of surfactants were modified to increase the fluidity of the liquid crystal phase, and electrostatic repulsion force was increased by introducing anionic surfactant. The lamellar liquid crystal make-up cleansing formulation which introduced anionic surfactants can easily inhibit crystallization through electrostatic repulsion force, thereby showing excellent stability overtime, maintaining transparent appearance and viscosity. In addition, we have newly introduced an in vitro cleansing evaluation method using fluorescent material and in vivo imaging system (IVIS) for objective and quantitative cleansing ability evaluation. The excellent cleansing ability of lamellar liquid crystal cleansing formulation has been confirmed by newly developed evaluation method. On the other hand, when lamellar liquid crystal make-up cleansing formulation was placed between orthogonally arranged two polarizing plates, a specific pattern like a hologram can be observed. This phenomenon is presumably interpreted as the interference between the visible light passing through the liquid crystal formulation and the lamellar structure. The lamellar structure of cleansing formulation was confirmed by SAXS analysis, exhibiting Bragg spacing ratio of 1 : 2. The lamellar liquid crystal make-up cleansing formulation prepared in this study would be useful for future application in make-up cleansing due to its excellent stability, cleansing ability, and unique hologram-like pattern placed between two polarizing plates.

• Transactions of the Korean Society of Mechanical Engineers B
• /
• v.28 no.3
• /
• pp.304-314
• /
• 2004

An experimental study has been conducted to measure the temperature fields and the local film cooling effectiveness for two and three staggered rows of the rectangular shaped-holes with various blowing rates. The hydraulic diameter of rectangular-shaped hole is 10mm. To compare with the film cooling performance of rectangular-shaped hole, two kinds of circular holes are tested. One has the same hydraulic diameter as the rectangular hole and the other has the same cross sectional area. Also, rectangular holes with expanded exit with same inlet area as rectangular ones are tested. Temperature fields are measured using a thermocouple rake attached on three-axis traversing system. Adiabatic film cooling effectiveness on the surface are obtained based on experimental results of thermochromic liquid crystals. The film cooling effectiveness is measured for various blowing rates and compared with the results for the cylindrical holes. In case of 2 rows, the rectangular holes has better performance than circular holes due to its slot-like geometry. In case of 3 rows, the effecta of hole shape is not clear.

• Polymer(Korea)
• /
• v.34 no.2
• /
• pp.116-125
• /
• 2010

The thermotropic liquid crystalline behavior of the homologous series of combined-type liquid crystalline polymers, tri-O-{4-(4'-cyanophenylazo)phenoxy}alkyl celluloses (CACETn, where n, the number of methylene units in the spacer, is 2~10) have been investigated. The CACETn with n of 5 and 7 exhibited enantiotropic nematic phases, while other polymers showed monotropic nematic phases. The isotropic-nematic transition temperature($T_{iN}$) increased when n is increased up to 4, but it decreased with increasing n more than 5. The entropy change at $T_{iN}$ also reaches a minimum at n=5, before it increases again for n=6. The sharp change at n=5 may be attributed to the difference in arrangement in the side groups. The nematic-crystalline transition temperatures, in contrast with $T_{iNS}$, exhibited a distinct odd-even effect, suggesting that the average shape of the side chains in the crystalline phase is different from that in the nematic phase. The mesophase properties of CACETn were significantly different from those reported for tri-O-alkyl celluloses and poly[1-{4-(4'-cyanophenylazo)phenoxyalkyloxy}ethylene]s. The results were discussed in terms of the difference in the chemical structures of the main and side chains and the number of the mesogenic units per repeating unit.