• Title/Summary/Keyword: 액정구조

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Phase Separation Structure of (PVC/Liquid Crystal) Composite Membrane ((Polyvinylchloride/액정) 복합막의 상분리 구조)

  • 이미선;최성부;이한섭;박관선;김병식
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.68-69
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    • 1998
  • 1. 서론 : 고분자/액정 복합막은 액정의 높은 분자운동성이 물질의확산에 기여하여 우수한 투과성을 나타낸다. 이 막은 3차원의 망상구조를 갖는 매트릭스 고분자내에 액정이 연속상으로 안정하게 분산된 상분리 구조를 가지고 있다. 이 복합막은 그러한 상분리 구조에 기인하여 자기지지형(self support LC) 복합막이라고도 한다. 복합막 중에 액정은 탄화수소가스에 대하여 높은 선택성을 나타내어 막속으로 흡착을 촉진하고 액정물질이 결정에서 액정으로 변화는 전이온도에서 투과계수가 100-200 증가한다고 보고하였다. (생략)

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A Study on Entrapment Efficiency of Rosmarinic Acid Using Liquid Crystal Phosphatidylcholin (포스파티딜콜린의 액정형성을 이용한 로즈마린산 포집 효율연구)

  • Kang, Ki-Chun
    • Applied Chemistry for Engineering
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    • v.24 no.2
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    • pp.132-137
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    • 2013
  • The liquid crystal form with phosphatidylcholine contents containing in the hydrogenated lecithin was confirmed. Composition ingredients of the liquid crystal vesicle were phospholipid, ethanol and water and the rosmarinic acid was encapsulated as index material. The mean particle size of the liquid crystal vesicle appeared to form various particles form 480 nm to $3{\mu}m$ depending upon the lipid composition and ultrasonic handling time. The liquid crystal vesicle compared with the liposome showed a very high encapsulation efficiency. The quantity of liquid crystal vesicle increased with respect to the increased quantity of lipid contents in the hydrogenated lecithin. The result from release experiments of the liquid crystal vesicle containing rosmarinic acid showed that the liquid crystal vesicle releases much less than that of liposome.

Liquid Crystalline Aromatic Polyesters (액정성 전방향족 폴리에스테르)

  • Kwon Young-Wan;Choi Dong Hoon;Jin Jung-Il
    • Polymer(Korea)
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    • v.29 no.6
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    • pp.523-535
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    • 2005
  • Linear aromatic polyesters are representative examples of thermotropic liquid crystalline polymers (TLCPs), which have been the subject of many researches. This article reviews the structure-LC properties relationship in wholly aromatic CLCPs mostly based on the results obtained for the past quarter of a century. Especially, this review deals with the structural details of aromatic polyester TLCPs that influence the liquid crystalline and thermal properties. In the last part of this article the liquid crystalline properties of combined type and hyperbranched polyester also are discussed. Introduction to various synthetic methods are included in the last section.

Influence of Ceramide III on the Structure of a Phospholipid Lamellar Liquid Crystalline Phase Hydrated in Glycerin : Structural and Thermal Behaviors (Glycerin에 수화된 인지질 라멜라 액정상의 구조에 미치는 Ceramide 3의 영향 : 구조적 및 열적거동)

  • Jeong, Kwan-Young;Lee, Dong-Kyu
    • Applied Chemistry for Engineering
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    • v.21 no.6
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    • pp.603-609
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    • 2010
  • This paper aims to investigate the lyotropic behaviors of DSPC and CER3 when they are swollen by GLY as a solvent. The analyses were carried out on DSC, XRDs, PM, and Cryo-SEM. CER3 which has its high crystallinity and structural similarity with DSPC was well arranged up to 7.0 wt% in comparison to 20 wt% DSPC without any separation, but it was separated from the liquid crystalline (LC) phase to form another crystalline phase with the expression of its characteristic peak in XRDs and eutectic thermal behavior in DSC. Introducing CER3, two types of patterns were shown in XRD spectra; one is SPP expressed in a normal LC and another is LPP expressed in human skin SC. Therefore, it was confirmed that the incorporation of CER3 makes LC structure more similar to human skin. In Cryo-SEM study, it was shown that CER3 makes LC structure thicker and denser.

Cap-Divided 방식의 VA 액정모드를 채용한 신규 반투과형 LTPS-LCD 개발

  • Gang, Seung-Gon;Kim, Seong-Ho;Song, Seok-Cheon;Park, Won-Sang;Lee, Cheong;Kim, Chi-U;Jeong, Gyu-Ha
    • Information Display
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    • v.5 no.5
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    • pp.10-12
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    • 2004
  • 우수한 화질특성을 나타내는 새로운 반투과형 액정모드를 개발했다. 단일 셀캡 구조에서 감마(Gamma) 보정없이 투과모드와 반사모드를 동시에 구동하기 위해 유기막을 이용하여 반사모드 영역의 액정 Cap을 두 가지로 분리하는 새로운 설계구조를 도입했다. 반사모드 영역의 액정 Cap을 순수한 액정 $Cap(C_{LC})$과 유기막 $Cap(C_{OL})$으로 분리함으로써 액정에 걸리는 실제 전압을 조절하게 되어 단일 셀캡 구조에서도 감마 보정없이 우수한 특성을 나타내는 반투과형 VA 액정모드를 개발하였다. 이러한 Cap-Divided 방식의 신규 VA 액정모드는 높은 콘트라스트, 광시야각 특성 및 공정 단순화의 장점이 있기 때문에 향후 반투과형 LCD에 적극적인 채용이 기대되어진다.

Properties of Blends of a Thermotropic Liquid Crystalline Polymer with Polyphenylene Sulfide (열방성 액정 고분자와 폴리페닐렌 설파이드와의 블렌드에 관한 물성)

  • 김연희
    • The Korean Journal of Rheology
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    • v.6 no.2
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    • pp.96-103
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    • 1994
  • 열방성 액정 고분자인 백트라와 폴리페닐렌 설파이드와의 블렌드를 주사전자현미경, 시차주사 열분석기, 그리고 모세관 레오미터를 이용하여 전 조성 범위에 대하여 연구하였다. 블렌드의 결정화와 용융에 관한연구결과로부터 두 고분자 사이에는 상호작용이 없음을 알수 있다. 이는 두 개의 상이 완전히 분리되기 때문이다. 폴리페닐렌설파이드를 많이 포함하고 있는 블렌드의 점도는 상당히 감소되었으며 이는 높은 전단속도에서 열방성 액정 고분자가 섬유구조를 갖기 때문이다. 열방성 액정고분자의 섬유구조는 열방성 액정 고분자가 섬유구 조를 갖기 때문이다. 열방성 액정 고분자의 섬유구조는 열방성 액정 고분자와 등방성상과의 점도비와 전단속도에 의해 영향을 받음을 알수 있다.

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An improved electrode structure of the Patterned Vertical Aligned Liquid Crystal Cell for high transmittance (새로운 전극구조를 통한 수직배향 액정 셀의 투과특성 향상)

  • Choi, Yong-Hyun;Son, Jung-Hee;Lee, Gi-Dong
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.11 no.9
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    • pp.1724-1728
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    • 2007
  • In this paper we propose a novel electrode structure for high transmittance in the Patterned Vertical Alignment (PVA) LC cell. We use the 'TechWiz LCD' for calculation of the director configuration and optical characteristics. We studied the area decreasing the transmittance through the electrode structure for wide viewing angle and proposed new electrode design to change LC director configuration in the area. We show the comparison of the calculated optical transmittance between the conventional PVA mode and the proposed PVA mode. From the results, we confirm that the optical transmittance of the proposed structure of the PVA cell becomes higher.

Structure Analysis of Liquid Crystal Emulsions Using X-ray Scattering Analysis (X선 산란분석법을 이용한 액정에멀젼 구조분석)

  • Park, So Hyun;Kim, Su Ji;Noh, Min Joo;Lee, Jun Bae;Park, Soo Nam
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.42 no.3
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    • pp.297-302
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    • 2016
  • In this study, we prepared liquid crystal emulsions composed of $C_{12-20}$ alkyl glucoside, $C_{14-22}$ alcohol, and behenyl alcohol and performed structure analysis using various analytical equipment. First, as an important characteristic of liquid crystal emulsions, maltese cross patterns and multi-layer structure were observed by a polarized microscope and cryo-SEM. Also, formation of liquid crystal phase was confirmed by DSC and multi-layer lamellar structure having an interlayer spacing approximately $305{\AA}$ was confirmed by small angle x-ray scattering (SAXS). The alkyl chain arrangement formed orthorhombic structure of a lamellar structure of the liquid crystal emulsion was confirmed by wide angle x-ray scattering (WAXS). These results suggest that information on the various physical properties obtained through the research of liquid crystal emulsion structure is expected to be widely used in cosmetics development in the future.

Nanostructuring the Polyimide Alignment Layer and Uniform Liquid Crystal Alignment by Solvent Assisted Micromolding (Solvent Assisted Micromolding을 이용한 Polyimide 나노구조 형성 및 이를 통한 균일 액정 배향)

  • Kim, Jongbok
    • The Journal of Korea Institute of Information, Electronics, and Communication Technology
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    • v.12 no.1
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    • pp.72-77
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    • 2019
  • The display that provides information to us through the visual sense is a very important information transmission means by intuitively transmitting information, and the liquid crystal display (LCD) is the most widely used information transmission display. In this paper, we studied solvent assisted micromolding as an alternative for the rubbing that is essential to align the liquid crystals in LCD and successfully aligned the liquid crystal molecules by constructing the nanostructures on conventional polyimide alignment layer. When generating the nanostructures on the polyimide film, there was a competitive correlation between the dissolution effect of the polymer by the solvent and the capillary effect of the polyimide molecules into the nanostructures of the mold depending on the process temperature. It was possible to form nanostructures with high step by deriving the optimum temperature. These nanostructures were able to align the liquid crystal molecules uniformly and demonstrated that they could form a desirable pretilt angle.

Thermal Properties of blends of Poly and a Thermotropic Liquid Crystalline Polymer (Poly과 열방성액정 고분자 블렌드의 열적 성질에관한연구)

  • 김명섭
    • The Korean Journal of Rheology
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    • v.7 no.3
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    • pp.250-260
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    • 1995
  • 스크류 압출기로 제조한 poly(ether ether ketone) (PEEK)과 p-hydroxy benzoic acid/poly(ethylene tere-phthalate) (HBA/PET)의 공중합체인 열방성 액정 고분자의 블렌드 를 전조성에 대하여시차 주사 열분석기 (DSC)와 주사전자현미경(SEM)을 이용하여 연구하 였다. 측정된 유리전이 온도와 유리전이 온도에서의 열용량 증가분으로부터 PEEK가 액정고 분자에 녹아들어가는 양보다 액정 고분자가 PEEK에 녹아들어가는 양이 더 많음을 알수 있 었다. 고분자-고분자상호작용계수($\chi$12)값은 35$0^{\circ}C$에서 0.069$\pm$0.004이었고, 짝상에서 액정고 분자의 degree of disorder는 PEEK의 질량분율이 증가함에 따라 증가하였다. 블렌드에서 PEEK의 결정화에 액정 고분자는 거의 영향을 주지않았고 액정 고분자의 결정화 역시 PE 따에 영향을 받지 않았다. 모폴로지연구에서는 액정 고분자를 PEEK에 10%첨가시에 PEEK 의 메트릭스상에서 액정 고분자가 신장된 타원형을 형성하였으며 액정 고분자를 20% 첨가 시에는 액정 고분자가 섬유상구조를 가지고 있었다.

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