• Title/Summary/Keyword: 액상형

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A Simulation Study on the Removal Process of the Heavy Metal Ion in Aqueous Solution by the Functionalized Silica Beads (기능화된 실리카 비드를 이용한 수용액상의 중금속 이온의 제거공정에 대한 모사 연구)

  • Woo, Yoon-Hwan;Choo, Chang-Upp
    • Clean Technology
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    • v.17 no.2
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    • pp.150-155
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    • 2011
  • The removal process of heavy metal ion in aqueous solution by the functionalized silica bead was simulated using the finite difference method. Equilibrium model and non-equilibrium model were proposed and the effects of dimensionless groups and various parameters were investigated. Freundlich isotherm was used in equilibrium model and 1st order adsorption rate expression was assumed in non-equilibrium model. The comparison results by the predictions of equilibrium and non-equilibrium models showed good agreement. The predictions of equilibrium model were compared with experimental results reported in literature and showed the marginal agreement.

Synthesis of Aluminum Nitride Whisker by Carbothermal Reaction I. Effect of Fluoride Addition (탄소환원질화법을 이용한 AIN Whisker의 합성 I. 불화물 첨가의 영향)

  • 양성구;강종봉
    • Journal of the Korean Ceramic Society
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    • v.41 no.2
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    • pp.118-124
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    • 2004
  • The properties of AlN made by carbothermal reaction depend on the starting materials, quantity of liquid, the liquid-vapor phase reaction, the N$_2$ flow rate, and the reaction temperature. AlN whisker was synthesized by the VLS and VS methods. Solid ${\alpha}$-A1$_2$O$_3$(AES-11) was carbothermally reduced with carbon black in a high-purity N$_2$ atmosphere with AlF$_3$ to cause whisker grown and additional aluminum liquid to increase whisker yield. Aluminum nitride was perfectly formed at reaction temperatures of 1600$^{\circ}C$. At reaction temperature higher than 1600$^{\circ}C$ the aluminum nitride was completely formed, while the composition remains unaffected. Needle-shaped whiskers formed best at 1600$^{\circ}C$ while higher temperatures disrupted whisker formation. Adding 0 to 15 wt% aluminum to the synthesis favorably affects the microstructure for formation of needle-shaped AlN whisker. Additions over 15 wt% degraded formation of AlN whisker.

A study on solidification of silicon by floating technique (부상응고법에 의한 실리콘 응고에 관한 연구)

  • 이근희;이진형
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.30-35
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    • 2000
  • A floating solidification technique is a process applied extensively to the production of glass plates. We used the technique for fabrication of Si plate. We used the proper liquid substrate material of 50 wt% $SiO_2$- 21 wt% $A1_2$$O_3$-29 wt% MnO, after studying ternary phase diagram of various oxides systems. The liquid substrate material has proper properties in the aspects of temperature, density and reactivity. But results showed some problems in fluidity and surface tension of the liquid substrate material.

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Improvement Scheme of Simplified Liquefaction Potential Evaluation for a Dredged and Reclaimed Ground (준설매립지반의 액상화 간편예측 개선에 관한 연구)

  • Jung, Min-Hyung;Kim, Ju-Hyun;Jeong, Sang-Guk;Lee, Song
    • Journal of the Korean Geotechnical Society
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    • v.23 no.8
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    • pp.47-57
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    • 2007
  • In this study, the analysis of density characteristics of some dredged and reclaimed ground sites, which is necessary for liquefaction evaluation of a dredged and reclaimed ground, was conducted. From analyzing a simplified liquefaction potential evaluation using SPT-N values which have been applied as domestic earthquake-resistant design criterion, improvement scheme is suggested. Based on the analysis result of density characteristics, it was found out that the relative density and the intial N-value ranged respectively $40{\sim}50%\;and\;5{\sim}8$. In the case of applying Liao & Whitman's equation to correct effective overburden pressure, liquefaction resistance of the upper ground that is relatively weaker than that of lower ground is overestimated. So, Skempton's equation is recommended. And the N value with depth which is applied for design process should be estimated by the exponential equation, $N=1.35{\sigma}'^{0.75}$.

Use of Jumbo Formulation for Paddy-applicable Pesticides (농약 살포작업의 생력화를 위한 투척처리용 점보제의 연구개발에 관하여)

  • Yu, Ju-Hyun;Lim, He-Kyoung;Cho, Kwang-Yun
    • Korean Journal of Environmental Agriculture
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    • v.15 no.1
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    • pp.116-127
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    • 1996
  • Recent development in Japan on jumbo formulation of pesticides for paddy application by hand throw was reviewed. In addition, the diffusion of liquid formulations in water was examined to establish the research strategy for the jumbo formulation. Research on jumbo formulation in Japan has been focused on gas-generating formulations and self-emulsifiable formulations. Although continuous efforts to minimize the problem of pesticide deposit on the treated site have been made for the gas-generating formulations, much work is still needed to establish a generally acceptable formulation method and to commercialize a herbicide formulation. The self-emulsifiable jumbo formulations have recently been investigated. These formulations could simply be processed and showed relatively high biological efficacy. The emulsifiable concentrate was more diffusible than the suspension concentrate in water. The diffusion of the emulsifiable concentrate was not greatly disturbed by floating obstacles. And the diffusion rate was high when the specific grabity was lower than one.

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An Experimental Study on Flexural Performance Evaluation of C-Shaped Steel-Timber Composite Beams (C형 강재-목재 합성보의 휨성능 평가에 관한 실험 연구)

  • Oh, Keunyeong;Lee, Sang-Sup;Park, Keum-Sung;Boo, Yoon-Seob
    • Journal of the Korea Institute of Building Construction
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    • v.24 no.3
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    • pp.331-341
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    • 2024
  • In this study, the flexural strength and ductility of steel-timber composite beams were evaluated to enhance the structural performance of glued-laminated timber beams. Three specimens were fabricated, including one reference glulam beam and two composite beams. The composite beams were constructed by attaching steel sections to the glulam beam using either liquid adhesive or screws. The experimental results showed that the structural performance of the steel-timber composite beams was approximately 2-3 times higher than the reference glulam beam, indicating that both flexural strength and ductility were sufficiently ensured. Notably, the specimen constructed with liquid adhesive demonstrated superior structural performance compared to the screw-attached specimen.

The Effect of Sodium Sulfate in Liquid or Solid Form on Leveling Properties of Cellulose Fibers (액상 또는 분말망초 Type에 따른 Cellulose섬유의 균염성 연구)

  • Kim, Mi-Ri;Lee, Hae-Jung;Nam, Chang-Woo
    • Proceedings of the Korean Society of Dyers and Finishers Conference
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    • 2011.03a
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    • pp.89-89
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    • 2011
  • Cellulose섬유의 염색시 섬유가 물속에 침지되면 섬유표면은 음전하가 형성되어, 용액 속에서 음이온으로 존재하는 염료와의 반발력으로 인해 염료가 섬유에 접근하기가 어려워지며 따라서 염색이 원활하게 이루어지지 않는다. 그러나 염욕에 염화나트륨(sodium chloride, NaCl)이나 망초 즉, 황산나트륨(Glauber's salt, sodium sulfate, Na2SO4)과 같은 전해질을 첨가하면, 양이온인 sodium 이온이 섬유표면과 음이온 염료사이의 반발력을 감소시킨다. 따라서 음이온의 염료는 섬유표면에 접근할 수 있고, 고유한 인력으로 염색이 가능하게 된다. 현재 Cellulose섬유의 상업적인 반응성염료 염색공정뿐만 아니라 최근 연구에서는 전해질 중 대부분 분말망초를 대부분 사용하고 있다. 그러나 분말망초는 별도의 용해과정이 필요할 뿐 아니라, 과량 사용시 용해되지 않은 분말이 섬유 표면에 흡착될 경우 불균염을 초래할 우려 등의 단점이 있다. 이와 같이 작업효율성을 향상시키고 염색을 효율적으로 진행시키기 위해 최근 액상형의 망초가 도입되고 있다. 이 연구에서는 분말 및 액상 망초를 조제로 사용하여 3종류의 Cellulose섬유를 반응성염료로 염색하였다. 담색, 중색, 농색 3가지 염료 농도에 대해 투입하는 망초의 type에 따라 각각의 Cellulose섬유별 균염성 정도에 대하여 비교해 보았다.

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High Pressure Binary Phase Equilibria Measurements of α-Tetralol with Carbon Dioxide (이산화탄소와 α-Tetralol과의 2성분계 고압상평형 측정)

  • Byun, Hun-Soo;Kim, Choon-Ho;Hwang, Young-Gi;Kwak, Chul
    • Applied Chemistry for Engineering
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    • v.7 no.1
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    • pp.67-74
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    • 1996
  • The binary phase equilibrium experiments of carbon dioxide/1,2,3,4 ${\alpha}$-tetrahydro-1-naphthol(${\alpha}$-tetralol) system were conducted to get phase equilibrium and mixture density data at 313.2K, 343.2K and 373.2K and within pressure ranges of 6.0 MPa to 35.0MPa. The phase equilibrium apparatus was type that circulated the vapor and liquid phase, the expended volume measuring system was adopted to microsampling technique for the analysis. The phase equilibrium and mixture density data were obtained for carbon dioxide/${\alpha}$-tetralol system from liquid and vapor phase. The mole fraction of carbon dioxide in liquid phase decreases and the mole fraction of ${\alpha}$-tetralol in vapor phase increases at constant pressure according to increment of temperature, and both the densities of the vapor and liquid phase approach to the mixture critical density as the pressure increases at any temperature. For she thermodynamic analysis, the experimental data were correlated with Peng-Robinson equation in cubic equation of state and compared to theoretical values of carbon dioxide/${\alpha}$-tetralol system. The AAD result was in the range of 1.08%~8.93% in the case of K(1), and was in the range of 45.71%~72.34% in the case of K(2).

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Density, Absorption and Table Flow properties of the Lower melting Point of the Modified Sulfur and General Industrial Sulfur (일반 공업용 유황과 융점을 낮춘 개질유황의 유동성, 흡수율 및 밀도 특성)

  • Kim, Heon-Tae;Lee, Yong;Lee, Sang-Soo
    • Proceedings of the Korean Institute of Building Construction Conference
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    • 2015.11a
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    • pp.45-46
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    • 2015
  • Recently, the large amount of sulfur is globally generated by the development of the petroleum refining industry every year. In this study, without the use of the sulfur with a high melting point used in the previous studies, the modified sulfur mortar with addition of a melting point of about 65℃ were tested to determine their distribution and strength properties according to the mixing method and curing conditions. This study is a test to find out the Density, Absorption and Table Flow of the modified sulfur and general sulfur. As result, general industrial sulfur flow was lower, showed a high absorption rate.

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