• Title/Summary/Keyword: 액상법

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Characterization on the electrochemical and structural properties of polyanion cathode material Li2MnSiO4/C depending on the synthesis process (합성 방법에 따른 Li2MnSiO4/C 다중음이온 양극활물질의 구조 및 전기화학적 성질)

  • Lee, Young-Lim;Chung, Young-Min;Song, Min-Seob;Ju, Jeh-Beck;Cho, Won-Il
    • Journal of Energy Engineering
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    • v.20 no.2
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    • pp.103-108
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    • 2011
  • $Li_2MnSiO_4$/C was synthesized by solid state reaction and solution synthesis with sucrose for carbon source. The X-ray diffraction patterns of solid state reaction indicates small amount of impurities. By FE-SEM and HR-TEM, solution synthesis comprised several tens of nanometer comparing to 500~600 nm of $Li_2MnSiO_4$/C prepared by solid state reaction. The $Li_2MnSiO_4$/C prepared by solution synthesis show better electrochemical performance than solid state reaction. The first charge-discharge capacity are 236, 189 mAh/g respectively by solution synthesis. But its cycle performance was poor as yet and its capacity retention was 62% after 10 cycles.

Liquefaction Evaluation by One-Dimensional Effective Stress Analysis Using UBC3D-PLM Model (UBC3D-PLM 모델을 이용한 1차원 유효응력해석에 의한 액상화 평가)

  • Jung-Hoe Kim;Hyun-Sik Jin
    • The Journal of Engineering Geology
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    • v.33 no.1
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    • pp.151-167
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    • 2023
  • This study compares the revised method in loose saturated sandy ground where the LNG storage tank will be installed with an evaluation method by one-dimensional effective stress analysis using the UBC3D-PLM model. Various laboratory and field tests were conducted to establish the parameters necessary for evaluation. The revised liquefaction evaluation method using the seismic response analysis result and N value from standard penetration testing evaluated the possibility of liquefaction as high, but assessment using effective stress analysis, which can consider various liquefaction resistance factors, found the site to be somewhat stable against liquefaction. One-dimensional finite element analysis using UBC3D-PLM modeling facilitated easier assessment of stability against liquefaction than the other methods and minimized the area required for reinforcement against liquefaction. In addition, it is expected that two-and three-dimensional numerical analysis considering the foundation of the LNG storage tank can identify the seismic design and behavior when liquefaction occurs.

New Methods for Assessing Liquefaction Potential Based on the Characteristics of Material (재료의 역학적 거동특성에 기초한 액상화 평가방법)

  • Kim, Gyeong-Hwan;Park, In-Jun;Kim, Su-Il
    • Geotechnical Engineering
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    • v.14 no.5
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    • pp.205-218
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    • 1998
  • The purpose of this study is to develop and utilize new assessment of liquefaction potential based on DSC(disturbed state concept) and dissipated energy concept. The term liquefaction has suddenly loses its shear strength and behaves like a fluid. Liquefaction has been a source of a major damage during severe earthquake. In this study, the cyclic undrained behavior of Joomoonjin strand is investigated by using an automates triaxial testing device(C. K. Chan type). In order to assess liquefaction potential of saturated strand, DSC method and energy method are applied for the experimental data. The use of DSC method and energy method to define the liquefaction potential is verified through laboratory testis of cyclic triaxial test on saturated sand specimens. Based on the analytical results of DSC method, the relationship between the factor affecting liquefaction characteristics(Dr) and physical properties of the saturated santa(fs and D.) is found. Based on the analytical results of energy method, it is found that the initial liquefaction of rand is related to the significant change in the dissipated energy. Finally, it is shown that the DSC method and energy method can capture the liquefaction mechanism.

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A New Methodology for the Assessment of Liquefaction Potential Based on the Dynamic Characteristics of Soils (II) : Verification (지반의 동적특성에 기초한 액상화 평가법 (II) : 타당성 검토)

  • 최재순;홍우석;박인준;김수일
    • Journal of the Korean Geotechnical Society
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    • v.18 no.1
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    • pp.101-112
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    • 2002
  • In this study, a new methodology fur the assessment of liquefaction potential is proposed and characteristics of the proposed methodology are verified. The experimental parameter of this methodology, that is, the plastic shear strain trajectory, is compared with the dissipated energy. It is shown that this parameter can express the liquefaction behavior which is generated by excess pore water pressure. This methodology takes advantage of the shear strain time history determined from the site response analysis based on the real time history of earthquake. In this site response analysis, shock type and vibration type records of similar predominant frequency are inputted. The liquefaction safely factors based on the proposed methodology and Korean detailed assessment related to the classical method are calculated from the results of the site response analysis and laboratory dynamic tests. Through this study, it is found that the proposed methodology can not only simulate the liquefaction behavior of saturated soils hut also express the seismic characteristics reasonably : leading type, predominant frequency, maximum acceleration, duration time.

액상법에 의한 단분산 ZnS입자 및 피복형복합입자의 합성

  • 김영도;신건철
    • Proceedings of the Korea Association of Crystal Growth Conference
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    • 1997.10a
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    • pp.27-31
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    • 1997
  • 액상법에 의한 단분산 ZnS입자의 합성을 60~9$0^{\circ}C$에서 행하여, 반응조건이 ZnS입자의 형태에 미치는 효과를 검토했다. ZnS입자의 형태는 반응 시간의 경과와 더불어 단분산으로부터 다분산 혹은 응집체로 변화하였다. 반응 온도 60~9$0^{\circ}C$에서 초기 농도적이 중간값이고, 반응시간이 짧을 경우 입경 0.2~0.8$\mu\textrm{m}$의 구상 단분산 입자를 얻었다. 또한 Ag$_2$NO$_3$, EtOH용액, $0^{\circ}C$에서, Ag$_2$S에 의한 ZnS의 균일 피복이 가능하였다.

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The Liquefaction Assessment for Large-sized Waste Landfill Site (대형폐기물 매립지반 액상화 평가)

  • Park, lnn-Joon;Choi, Seung-Ho;Yoo, Byung-Joon;Mha, Ho-Seong
    • Journal of Korean Society of societal Security
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    • v.2 no.2
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    • pp.69-74
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    • 2009
  • The purpose of this research is to assess the aseismic safety for the large-sized waste landfill site based on the results from liquefaction potential analysis. For successful achievement of research, the simplified liquefaction analysis and detailed liquefaction analysis using data from lab test and seismic response analysis are executed. Based on the simplified liquefaction analysis, the possibility of liquefaction is occurred at only BH-14 with maximum acceleration 0.169 g. Therefore, liquefaction possibility of BH-14 is evaluated by the detailed liquefaction analysis again. The safety factor greater than 1.0 from the result of analysis at BH-14 guarantees safety of liquefaction.

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A Study on the Applicability of Arias Intensity Liquefaction Assessment (Arias Intensity 액상화 평가기법의 적용성에 관한 연구)

  • Hwang, Jungtae;Lee, Jongkeun;Shin, Eunchul
    • Journal of the Korean GEO-environmental Society
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    • v.14 no.6
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    • pp.13-19
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    • 2013
  • In this study, the target ground was selected for the assessment of liquefaction, for which energy-based Arias intensity liquefaction assessment method was applied, The results of evaluation by simplified method using conventional in-situ test were compared. The result of the assessment of liquefaction revealed that the safety factor of the Arias Intensity using the actual records of the Hachinohe and Ofunato earthquake showed generally similar trends with the simplified method, However, the Arias Intensity factor of safety for the artificial earthquake created from the design response spectrum showed some difference from the factors of safety of the simplified method. The shear stress ratio and the occurrence strength of the Arias Intensity are differently calculated between stress and energy, but the resistance stress ratio of the simplified method and the resistance strength of the Arias Intensity use the empirical chart of the results of the standard penetration test for the actual liquefaction areas by the earthquake, which seems the reason for the similar results between Arias Intensity assessment and stress concept simplified method for Hachinohe and Ofunato earthquakes. Therefore, it was found that the energy-based Arias Intensity liquefaction assessment could represent the dynamic changes of the ground caused by seismic characteristics such as acceleration, magnitude, duration and amplitude.

On the transient liquid phase diffusion bonding (천이액상화접합에 대하여)

  • 강정윤
    • Journal of Welding and Joining
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    • v.7 no.2
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    • pp.12-24
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    • 1989
  • 천이액상확산접합법은 접합계면에 일시적으로 액상이 형성되기 때문에, 고상확산접합법과 비교 하여 비교적 쉽게 금속결합을 이룰 수 있을 뿐만 아니라, 정밀하게 표면을 가공할 필요가 없으 며, 접합압력이 거의 필요 없다는 것이 잇점이라고 할 수 있다. 도한, 접합온도에서 등온응고되 기 때문에, 브레이징법과 비교하여 접합계면에 취약한 금속간화합물(Metallic Compound)이 생 성되지 않으므로, 기계적성질 및 내식성이 우수한 접합이음부를 얻을 수 있다는 잇점이 있다. 따라서, 본 접합법은 원리적으로 모재(Base Metal)와 거의 같은 정도의 물리적, 화학적, 기계적 성질을 갖는 접합이음부(Joint or Bonded Interlayer)를 얻을 수 있는 접합법이라고 생각되어진 다. 본 해설에서는 천이액상확산접합법의 기본원리, 접합기구, 접합인자 및 실용된 예에 대해서 서술하고자 한다.

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Evaluation of Liquefaction Potential for Marine Silty Sand Deposits during Earthquake (서해안 사질토지반의 지진시 액상화 예측)

  • 이희명;정두영
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.6 no.1
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    • pp.23-33
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    • 1994
  • Liquefaction characteristics of the reclaimed marine sand deposits is studied by means of the dynamic response analysis and the cyclic triaxial compression test. 1) From the result of the dynamic response analysis. it was found that the amplification of ground surface maximum acceleration varied with input earthquake motions and soil data, and earthquake coefficients were proposed to be applicable in evaluating liquefaction potential by simplified prediction methods. 2) For upper and soft sand deposits with small N-value, liquefaction strengths estimated by Seed and Idriss's simplified method were lower than those by the cyclic triaxial test while those by Iwasaki & Tatsuoka's or Vs-method were not lower. 3) Simplified methods were inclined to overestimate liquefaction potential in comparison with the dynamic response analysis and the cyclic triaxial compression test Allowable depths of liquefaction(safety factor 1) were estimated to be 7-14m for 0.1 -0.2g of input maximum acceleration.

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