• Title/Summary/Keyword: 압출온도

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Preparation and characterization of isosorbide based PET/polycarbonate blends (Isosorbide가 함유된 바이오 기반 PET와 polycarbonate 블렌드의 제조 및 특성 연구)

  • Park, Ji-Soo;Nam, Byeong-Uk;Park, Jun-Seo
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.2
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    • pp.1216-1221
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    • 2014
  • Poly(ethylene-co-isosorbide terephthalate) (PEIT) is interest in polymer which has isosorbide monomer that is renewable resources such as corn. However, there is important drawback which is low mechnical properties as increasing isosorbide contents. In this study, polycarbonate used to make up for drawback of mechanical properties of PEIT. In addition, PEIT used to improve the tensile elongation of polycarbonate because PEIT has good sheet proccessability. The effect of polycarbonate on morphology, thermal and mechanical properties were investigated using FE-SEM, DMA, TGA, UTM, and notched izod impact strength tester. As a result of this study, PEIT/PC blends were in compatible system and polycarbonate can act as an improvement of thermal stability and mechanical properties in the blends.

Denaturation of Heat Treated Lysozyme under High Pressure Conditions (고압조건에서 가열 처리된 Iysozyme의 변성)

  • Cho, Rae-Kwang;Hong, Jin-Hwan
    • Korean Journal of Food Science and Technology
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    • v.23 no.3
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    • pp.366-369
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    • 1991
  • In order to elucidate texturization mechanism of extrudated protein, egg white lysozyme was heated under high pressure conditions, and its solubility and changes of molecular weight were investigated. Under high pressure conditions of $100,\;300\;and\;600\;kg/cm^2$, solubility decreased gradually with increasing temperature in the samples heated at $70,\;120\;and\;150^{\circ}C$ and decreased notably with increasing pressure at $200^{\circ}C$. Polymerization was found in the samples heated at $150\;and\;200^{\circ}C$ while a band which located below monomer(low-molecular) could be recognized. Molecular weight of the low-molecular was estimated to be about $6,000{\sim}9,000$ and no smaller peptide was recognized. The polymerization may have occured by disulfide crosslinking in the samples heated at $120^{\circ}C$ but other crosslinking may have played a role in those at $150\;and\;200^{\circ}C$.

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Processing and Mechanical, Thermal and Morphological Properties of Poly(lactic acid)/Poly(butylene succinate) Blends (폴리유산/폴리부틸렌숙시네이트 블랜드의 가공 및 기계적, 열적, 형태학적 특성)

  • Kim, Dae Keun;Cho, Donghwan
    • Journal of Adhesion and Interface
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    • v.15 no.1
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    • pp.14-21
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    • 2014
  • In the present work, PLA/PBS blends with poly(lactic acid) (PLA) and poly(butylene succinate) (PBS) at different contents were processed by using a twin-screw extruder and an injection molding machine, and then their mechanical, thermal and morphological properties were investigated. The mechanical properties such as flexural strength, flexural modulus, tensile strength and tensile modulus and thermal properties such as melting behavior, dynamic mechanical thermal properties and thermal stability significantly depended on the contents of PLA and PBS. However, the heat deflection temperature of the blends was not significantly influenced by the contents of PLA and PBS. Also, the fracture surfaces of PLA/PBS blends were changed from a brittle pattern to a ductile pattern with increasing the PBS contents.

Morphology, Thermal and Mechanical Properties of Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)/CMPS Blends (Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)/CMPS 블렌드의 형태학, 열적 및 기계적 특성)

  • Kang, Kyoung-Soo;Kim, Bong-Shik;Jang, Woo-Yeul;Shin, Boo-Young
    • Polymer(Korea)
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    • v.33 no.2
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    • pp.164-168
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    • 2009
  • The effects of chemically modified thermoplastic starch (CMPS) on the morphology, thermal and mechanical properties of the blends of poly (lactic acid)(PLA) and poly(butylene adipate-co-terephthalate)(PBAT) were studied. Blends of PLA/PBAT with the CMPS contents of 10, 20 and 30 wt% on the basis of PLA/PBAT weight were prepared by a twin screw extruder. The morphology, thermal and mechanical properties of the blends were examined by using scanning electron microscope (SEM), differential scanning calorimeter (DSC) and a tensile tester. The DSC study revealed that PLA/PBAT blends are thermodynamically immiscible, while the compatibility was much improved by addition of the CMPS.

The Thickness of Recrystallization Layer and Mechanical Properties According to Extrusion Exit Temperature (압출 출구 온도에 따른 Al 6061 합금의 표면 재결정층 두께 변화 및 기계적 특성 변화)

  • Kim, S.B.;Park, T.H.;Kim, H.G.;Lee, S.M.;Kim, H.K.
    • Transactions of Materials Processing
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    • v.30 no.5
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    • pp.219-225
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    • 2021
  • When extruding Al6061 alloys, deformation energy is deposited inside the extruded alloy depending on the deformation and the temperature of extrusion. This creates a Peripheral Coarse Grain (PCG) on the surface, where relatively more deformation energy. of the extruded alloy has been accumulated. Furthermore, since the deformation of materials continues while the materials recrystallize, it is important to examine the effect of deformation energy on dynamic recrystallization in the process of extruding Al alloys along with their microstructure. Prior studies explain the theory behind PCG growth though quantitative analysis on PCG growth of Al alloys during extrusion processes has not yet been addressed. This study aims to measure the generated PCG thickness which determines the correlation between extrusion outlet temperature and its effect on mechanical properties. Surface structure observations were performed using Optical Microscope (OM) and mechanical properties were evaluated through tensile strength and hardness measurement. Throughout this study, we endevoured to find the optimum condition of extrusion exit temperature of Al6061 and confirmed improved d reliability. This study describes the effect of the complex process variables such as exit temperature on the thickness of PCG layer for the Al6061 alloy using the 200 tons extrusion press. We therefore, discovered that the PCG layer thickness was 117 ㎛ at temperatures between 460 ℃ to 520 ℃.

The Design of Application Model using Manufacturing Data in Protection Film Process for Smart Manufacturing Innovation (스마트 제조혁신을 위한 보호필름 공정 제조데이터의 활용모델 설계)

  • Cha, ByungRae;Park, Sun;Lee, Seong-ho;Shin, Byeong-Chun;Kim, JongWon
    • Smart Media Journal
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    • v.8 no.3
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    • pp.95-103
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    • 2019
  • The global manufacturing industry has reached the limit to growth due to a long-term recession, the rise of labor cost and raw material. As a solution to these difficulties, we promote the 4th Industry Revolution based on ICT and sensor technology. Following this trend, this paper proposes the design of a model using manufacturing data in the protection film process for smart manufacturing innovation. In the protective film process, the manufacturing data of temperature, pressure, humidity, and motion and thermal image are acquired by various sensors for the raw material blending, stirring, extrusion, and inspection processes. While the acquired manufacturing data is stored in mass storage, A.I. platform provides time-series image analysis and its visualization.

Study on the biodegradable PLA sheet with multiple functionalities (복합기능성 생분해 PLA 시트에 관한 연구)

  • Lee, KyuDong;Kim, JongKyun;Lee, KyuDeug;Zun, Hyungdo;Kim, ChiGon;Yoon, KyungBae
    • The Journal of the Convergence on Culture Technology
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    • v.5 no.1
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    • pp.341-346
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    • 2019
  • The study aims to provide a study on the mixing ratios and manufacturing methods of biodegradable PLA sheets for mid - term introduction, A 3-layer process was introduced to produce a multifunctional multi-layer structure sheet having improved heat resistance, impact resistance and transparency while having anti-fogging functionality as a biodegradable PLA sheet used for the purpose of anti-fogging function. Inner layer, core layer and outer layer were mixed and extruded. The inner layer and core layer were studied for a biodegradable PLA multi-layer sheet structure having inner hardness and high heat resistance and outer layer for imparting antifogging function. By applying the results of this study, plastic PLA properties and heat-resistant temperature can be improved to replace and expand plastics.

PBAT Compound Films with Improved Hydrolysis Resistance and its Application (내가수분해성이 향상 된 PBAT의 컴파운드 필름 및 이의 응용)

  • Sim, Jae-Ho;Shim, Jae-Hoon
    • The Journal of the Convergence on Culture Technology
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    • v.8 no.5
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    • pp.553-559
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    • 2022
  • The film mulching technology is useful for controlling soil temperature and moisture by covering the soil surface, and for suppressing weeds. In this study, in order to improve the hydrolysis resistance and mechanical properties of the biodegradable mulching film, PBAT(Poly butylene adipate-co-terephthalate) and PLA(Poly lactic acid) were modified using a twin-screw extruder and then the physical and biodegradable properties of the film were investigated. After landfill the mulching film in soil, the weight reduction of the film was confirmed by period, and plant growth was observed after mulching in the dry paddy field for rice farming. Mulching films with improved hydrolysis resistance showed excellent crop growth properties, and biodegradable mulching films can offer potential as a new alternative for environmentally friendly, efficient and sustainable agricultural practices.

Study on miscibility, morphology, thermal and mechanical properties of elastomeric impact modifier reinforced Poly(lactide)/Cellulose ester blends (충격보강제로 강인화된 PLA와 cellulose ester 블렌드의 상용성 및 모폴로지, 열적, 기계적 특성에 관한 연구)

  • Park, Jun-Seo;Nam, Byeong-Uk
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.7
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    • pp.4081-4086
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    • 2014
  • Cellulose acetate butyrate (CAB) is a biodegradable resin with excellent optical properties, but it is difficult to apply film process. In this study, an attempt was made to improve the processability of CAB using polyactic acid and the mechanical properties using an impact modifier. Polylacitc acid (PLA)/Cellulose acetate butyrate (CAB) blends with an impact modifier were prepared using a twin screw extruder. The temperature range was $140^{\circ}C$ to $200^{\circ}C$, and the screw speed was fixed to 200 rpm. To evaluate the miscibility of impact modified CAB/PLA, the glass transition behavior and morphology were observed by DSC and FE-SEM. The mechanical properties were investigated by dynamic mechanical analysis (DMA) and a Universal Testing Machine (UTM). In addition, the effect of an impact modifier in the polymer matrix was determined using a notched Izod impact strength tester. Finally, the PLA/CAB/impact modifier 75/25/10 ratio was found to be a compatible system. In the 10wt.% impact modifier, the sample had a 4 times higher izod impact strength than the non-toughening composition.

Preparation and Characterization of Cellulose Acetate/Poly Ethylene Glycol Blend Having High Melt Processibility (우수한 용융특성을 갖는 Cellulose acetate/Poly ethylene glycol 조성물의 제조 및 특성 해석)

  • Lee, Hae Sung;Lee, Sung Jun;Jung, Sang Won;Kim, Hyun-Chul;Kim, Eunjoo;Go, Young Jun;Lee, Se Guen
    • Journal of Korean Ophthalmic Optics Society
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    • v.17 no.1
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    • pp.1-10
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    • 2012
  • Purpose: Cellulose acetate (CA) was blended with polyethyleneglycol (PEG) having different molecular weight at various mixing conditions to enhance melt-processibility of CA, which might prevent the harmful effect resulted from the introduction of phthalic plasticizer. Methods: To establish optimal plasticizing conditions, CA/PEG blends were examined under various plasticizing conditions: PEG concentration, molecular weight of PEG, and plasticzing temperature. Mechanical properties of the CA/PEG blends, as well as migration and exudation of the PEG, were performed in order to evaluate the efficiency of plasticization. Results: Compared to industrial CA resin plasticized by diethyl phthalate, CA/PEG blends exhibited similar thermal plasticization. It was established that the optimum condition was to blend 30~40 phr PEG with molecular weight 400 at $175{\sim}180^{\circ}C$. CA/PEG blend showed superior glassness, PEG stability, and mechanical properties. Conclusions: CA/PEG blends would be a eco-friendly glasses frame to substitute traditional CA glasses frame prepared phthalate plasticizers.