• Title/Summary/Keyword: 압축 수소

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Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of n-Heptane (탄화수소계 연료의 축소반응모텔과 노말-헵탄(n-Heptane)의 자발화 현상)

  • 여진구
    • Transactions of the Korean Society of Automotive Engineers
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    • v.10 no.1
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    • pp.76-83
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    • 2002
  • Mathematically and chemically simplified reaction scheme for n(heptane that simulates autoignitions of the end gases in spark ignition engines has been developed and studied computationally. The five(equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius pre-exponential constants, A, and heats of reaction for stoichiometric nheptane/air has all been optimized. Comparisons between computed and experimental autoignition delay times have validated the present simplified reaction scheme. The influences of heat loss and concentration of chain carrier at the beginning of compression upon autoignition delay times have been computationally investigated.

Parametric Study on Combustion Characteristics of CNG Fuel (연소실 매개변수에 따른 천연가스 연소 특성)

  • Lee, Seang-Wock;Song, Young-Mo;Baik, Doo-Sung
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.32 no.7
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    • pp.513-517
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    • 2008
  • A parametric study was made to understand the fundamentals of combustion of CNG fuel in a constant volume chamber in the respect of swirl effect, and the numbers of spark ignition. Optical devices were applied for the visualization of the physics of combustion, and combustion pressures and exhaust emission were measured at several equivalence ratios by controlling speeds of a swirling motor. When the speed of a swirling motor was raised the combustion conditions were improved. The corresponding maximum combustion pressure and heat release rate were increased and the speed of flame propagation was getting faster. This research may contribute to improve the performance of CNG engine and reduce emissions in future.

Simplified Reaction Scheme of Hydrocarbon Fuels and Its Application to Autoignition of Gasoline with Different Octane Numbers (탄화수소계 연료의 축소반응모델과 가솔린연료의 옥탄가 변화에 따른 자발화 지연시간)

  • 여진구
    • Transactions of the Korean Society of Automotive Engineers
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    • v.11 no.3
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    • pp.13-19
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    • 2003
  • Mathematically simplified reaction scheme that simulates autoignitions of the end gases in spark ignition engines has been studied computationally. The five equation model is described, to predict the essential features of hydrocarbon oxidation. This scheme has been calibrated against autoignition delay times measured in rapid compression machines. The rate constants, activation temperatures, Ta, Arrhenius preexponential constants, A, and heats of reaction for stoichiometric n-heptane/air, iso-octane/air, and their mixtures have all been optimised. The optimisation has been guided by Morley's correlation of the ratio of chain branching to linear termination rates with octane number. Comparisons between computed and experimental autoignition delay times have validated the Present simplified reaction scheme and the influences of octane number upon autoignition delay times have been computationally investigated. It has been found that both cool flame and high temperature direct reactions can have an effect on autoignition delay times.

An Experimental Study of the Variable Sonic/supersonic Ejector Systems (가변형 음속/초음속 이젝터 시스템에 관한 실험적 연구)

  • Lee Jun Hee;Kim Heuy Dong
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.29 no.5 s.236
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    • pp.554-560
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    • 2005
  • A new method to improve the efficiency of a hydrogen fuel cell system was introduced by using variable sonic/supersonic ejectors. To obtain the variable area ratio of the nozzle throat to ejector throat which controls the mass flow rate of the suction flow, the ejectors used a movable cylinder inserted into a conventional ejector-diffuser system. Experiments were carried out to understand the flow characteristics inside the variable ejector system. The secondary mass flow rates of subsonic and supersonic ejectors were examined by varying the operating pressure ratio and area ratio. The results showed that the variable sonic/supersonic ejectors could control the recirculation ratio by changing the throat area ratio, and also showed that the recirculation ratio increased fur the variable sonic ejector and decreased for the variable supersonic ejector, as the throat area ratio increases.

1773K 에서 dopant 첨가에 따른 (U,Ce)$O_2$ 의 크립거동

  • 나상호;김시형;정창용;김한수;이영우
    • Proceedings of the Korean Nuclear Society Conference
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    • 1998.05b
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    • pp.181-185
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    • 1998
  • 모의 혼합산화물인 (U,Ce)O$_2$ 에 dopant 인 Li$_2$O 와 SiO$_2$ 를 첨가한 소결체의 압축크립변형거동을 수소분위기, 온도 1773K 에서 응력(10-120MPa)을 변화시켜 조사하였다. Dopant 를 첨가할 경우 정상상태 크립변형속도는 첨가하지 않은 경우보다 크게 증가하는 것으로 나타났다. 증가한 원인으로는 Li$_2$O 를 첨가한 경우 우라늄 확산계수의 증가에 기인되며, SiO$_2$ 를 첨가한 경우에는 SiO$_2$ 가 glassy phase 로 입계에 위치하여 입계이동이 용이하게 되어 정상상태 크립변형속도가 증가한 것으로 사료된다. 또한 저응력구간에서 (U,Ce)O$_2$ 의 크립활성화에너지는 109.6 kcal/mol 로 $UO_2$ 의 크립활성화에너지(94.2kca1/mol)보다 더 크게 나타났다.

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Self-ignition of high-pressure hydrogen gas released into tube (튜브내 고압수소가스 누출에 따른 자발점화 현상 유동가시화 연구)

  • Kim, Yeong Ryeon;Lee, Hyoung Jin;Kim, Sei Hwan;Jeung, In Seuck
    • 한국연소학회:학술대회논문집
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    • 2012.04a
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    • pp.247-248
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    • 2012
  • Unidentified self-ignitions were reported when the high-pressure hydrogen gas suddenly leaked out. This paper presents a flow visualization study to investigate the self-ignition mechanism in a test tube how the ignition process is initiated and the flame propagates with measurement of a number of pressure and light sensors installed in the tube supported the analysis of the self-ignition. The test result showed the location of the self-ignition taken place and critical static pressure at the boundary layer for self-ignition.

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A Study on the Residual stress of Diamond-like Carbon Films Deposited by RF PECVD (RF PECVD로 증착된 다이아몬드상 탄소막의 잔류응력에 관한 연구)

  • Choi, Woon;Nam, Seung-Eui;Kim, Hyoung-June
    • Korean Journal of Materials Research
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    • v.6 no.12
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    • pp.1162-1169
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    • 1996
  • rf 플라즈마 화학증착을 이용하여 증착된 hydrogenated DLC막의 잔류응력 거동에 대해 조사하였다. 합성된 DLC막의 압축 잔류응력은 이온 에너지뿐만 아니라 이온/원자 유입량 비에 의해 영향을 받는 것으로 조사되었다. 잔류응력의 최대치는 이온/원자 유입량비가 증가할수록 낮은 이온 에너지 구간에서 일어나며 그 값은 증가하였다. 이온 에너지에 따른 DLC막의 결합 구조의 변형을 Raman 스펙트럼을 이용하여 분석하였다. DLC막의 잔류응력은 sp3결합의 net working이 최대가 되는 점에서 최대치를 보이며, 이는 sp3 net working에 의한 부피팽창 요인에 기인하는 것으로 생각된다. DLC막 내의 유입되는 수소는 잔류응력의 직접적인 원인으로 작용하지 않는 것으로 분석되었다.

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An Experimental Study on the Variable Sonic Ejector System (가변형 음속 이젝터 시스템에 관한 실험적 연구)

  • Lee, Jun-Hee;Jung, Sung-Jae;Kim, Heuy-Dong;Koo, Byoung-Soo
    • Proceedings of the KSME Conference
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    • 2004.04a
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    • pp.2035-2040
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    • 2004
  • A cone cylinder is used to obtain variable operation conditions for the sonic ejector-diffuser system. The cone cylinder is designed to move upstream and downstream to change the ejector throat area ratio, thus obtaining variable mass flow rates. The present study investigates the effects of ejector throat area ratio and operating pressure ratio on the entrainment of secondary stream for the variable sonic ejector system. In experiment, the ejector throat area is varied in the range from ${\psi}=11.88$ to 66.69, and the operating pressure ratio from $p_{0p}/p_a=1.25$ to 9.0. The results show that the variable sonic ejector system is suitable for a required entrainment ratio of secondary stream by altering the ejector throat area ratio and operating pressure ratio.

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Effects of DME/Diesel as an ignition promoter on combustion of hydrogen homogeneous charge compression ignition (수소-예혼합 압축착화 엔진에서 착화제인 DME/diesel이 엔진 연소에 미치는 영향)

  • Jeon, Jeeyeon;Park, Hyeonwook;Bae, Choonsik
    • 한국연소학회:학술대회논문집
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    • 2013.06a
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    • pp.37-40
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    • 2013
  • Hydrogen-dimethy ether (DME) and hydrogen-diesel compression ignition engine combustion were investigated and compared each other in a single cylinder compression ignition engine. Hydrogen and DME were used as low carbon alternative fuels to reduce green house gases and pollutant. Hydrogen was injected at the intake manifold with an injection pressure of 0.5 MPa at fixed injection timing, $-210^{\circ}CA$ aTDC. DME and diesel were injected directly into the cylinder through the common-rail injection system at injection pressure of 30 MPa. DME and diesel inejction timing was varied to find the optimum CI combustion to reduce CO, HC and NOx emissions. When DME was injected early, CO and HC emissions were high while NOx emission was low. Fuel consumption, heat release rate, and exhaust emissions were measured to analyze each combustion characteristics of each ignition promoter. Fuel consumption was decreased when diesel was used as an ignition promoter. This is due to the lower volatility of diesel which created more stratified charge than DME.

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Improving Performance and Emissions in a Diesel Engine Dual Fueled with Compressed Natural Gas (CNG와 경유의 2원 연료 디젤기관의 성능 및 배출가스 개선을 위한 실험연구)

  • ;Masahiro Shioji
    • Transactions of the Korean Society of Automotive Engineers
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    • v.8 no.2
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    • pp.57-63
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    • 2000
  • This paper deals with a study on combustion and emission characteristics of a direct injection diesel engine dual fueled with natural gas. Dual fuelling systems tend to emit high unburned fuel especially at low load, resulting in a decreased thermal efficiency. This is because natural gas-air mixtures are too lean for flame to propagate under low load conditions. Suction air quantity and injection timing controls are very useful to improve emissions and thermal efficiency at low load.

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