• Applied Chemistry for Engineering
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• v.25 no.5
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• pp.520-525
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• 2014

In this paper, the effect of silane-treated silicas and epoxidized soybean oil (ESBO) addition on adhesion properties of silicas-filled epoxy adhesives was examined. The silicas were treated by ${\gamma}$-methacryloxy propyltrimethoxy silane (MPS), ${\gamma}$-glycidoxy propyl trimethoxy silane (GPS), and ${\gamma}$-mercapto propyl trimethoxy silane (MCPS). Surface and structural properties of the adhesives were determined by using scanning electron microscope (SEM) and Fourier transform infrared spectroscopy (FT-IR). The t-peel strength of the adhesives was estimated using the universal testing machine (UTM). And, the equilibrium spreading pressure, surface free energy, and specific surface area were investigated by BET methods with $N_2$/77 K adsorption. As a result, the peel strength of the adhesives was increased in the presence of silane-treated silicas in the adhesives compared to that of untreated silicas. This result indicated that the silane coupling agent played an important role in improving the dispersion of silicas in epoxy adhesives. And, the adhesives treated by MCPS were superior to the others in adhesion.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.28 no.4
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• pp.152-158
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• 2018

PVT (Physical Vapor Transport) method has advantages in producing high quality, large scale wafers where many researches are being carried out to commercialize nitride semiconductors. However, complex process variables cause various defects when it had non-equilibrium growth conditions. Annealing process after crystal growth has been widely used to enhance the crystallinity. It is important to set appropriate temperature, pressure, and annealing time to improve crystallinity effectively. In this study, the effect of the annealing conditions on the crystalline structure variation of the AlN single crystal grown by PVT method was investigated with synchrotron whitebeam X-ray topography, electron backscattered diffraction (EBSD), and Rietveld refinement. X-ray topography analysis showed secondary phases, sub-grains, impurities including carbon inclusion in the single crystal before annealing. EBSD analyses identified that sub-grains with slightly tilted basal plane appeared and the overall number of grains increased after the annealing process. Rietveld refinement showed that the stress caused by the temperature gradient during the annealing process between top and bottom in the hot zone not only causes distortion of grains but also changes the lattice constant.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2002.11a
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• pp.171-184
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• 2002

Approx. 200,000 bpd vacuum residue oil is produced from oil refineries in Korea. These are supplying to use asphalt, high sulfur fuel oil, and upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435-500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER(Korea Institute of Energy Research) are studing on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature : 1,100~1,25$0^{\circ}C$, reaction pressure : 1~6kg/$\textrm{cm}^2$G, oxygen/V.R ratio : 0.8~0.9 and steam/V.R ratio : 0.4-0.5. Experimental results show the syngas composition(CO+H$_2$) : 85~93%, syngas flow rate : 50~110Mm$^3$/hr, heating value : 2,300~3,000 ㎉/Nm$^3$, carbon conversion : 65~92, cold gas efficiency : 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• Economic and Environmental Geology
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• v.45 no.2
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• pp.137-144
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• 2012

Soil pan typically presents the problems in soil water movement or in aeration which is not appropriate for a plant root growth, In this study physico-chemical characteristics of soils and micromorphological characteristic of clay accumulated zone were investigated to identify redox characteristic and evolution of a fragipan of Gangreung series commonly developed in coastal terraces. Gangreung series is classified as Aquic Fragiudalfs according to the USDA soil taxonomy. It is known that sedimentary ocean floor results in soil pan having parallel liner soil structure due to landscape evolution around 200 to 250 million years ago. it is considered that illite, kaolinite, and vermiculite are major clay minerals contained in a fragipan of Gangreung series. Mixed gray and reddish brown colored band around soil pores was found and would be the redoxmorphic features of fragipan. It is possibly due to accumulated illuvial clay and ferriargillans in soil pores and aggregates in reducing conditions eluding ferrous material. Therefore, mixed colored band around pores in soils of Gangreung series would be developed from the eluted ferrous materials which were accumulated in fragipan during the emerged land formation.

• Journal of Energy Engineering
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• v.12 no.1
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• pp.49-57
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• 2003

Approx. 200.000 bpd vacuum residue oil is produced from oil refineries in Korea, and is supplied to use asphalt, high sulfur fuel oil and for upgrading at the residue hydro-desulfurization unit. Vacuum residue oil has high energy content, however its high sulfur content and high concentration of heavy metals represent improper low grade fuel. To meet growing demand for effective utilization of vacuum residue oil from refineries, recently some of the oil refinery industries in Korea, such as SK oil refinery and LG Caltex refinery, have already proceeded feasibility study to construct 435~500 MWe IGCC power plant and hydrogen production facilities. Recently, KIER (Korea Institute of Energy Research) are studying on the Vacuum Residue gasification process using an oxygen-blown entrained-flow gasifier. The experiment runs were evaluated under the reaction temperature: 1.100~l,25$0^{\circ}C$, reaction pressure: 1~6 kg/$\textrm{cm}^2$G, oxygen/V.R ratio: 0.8~0.9 and steam/V.R ratio: 0.4~0.5. Experimental results show the syngas composition (CO+H$_2$): 85~93%, syngas flow rate: 50~l10 Nm$^3$/hr, heating value: 2,300~3,000 k㎈/Nm$^3$, carbon conversion: 65~92, cold gas efficiency: 60~70%. Also equilibrium modeling was used to predict the vacuum residue gasification process and the predicted values were compared reasonably well with experimental data.

• 한국신재생에너지학회:학술대회논문집
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• 2005.11a
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• pp.689-692
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• 2005

2020년까지 전 세계 수송에너지의 수요가 현재의 2배까지 증가할 것으로 예상되면서 석유 자원의 안정적 공급이 어려워지기 이전에 이를 대체할 수 있는 에너지원 개발이 시급하다. 이러한 노력의 일환으로 최근 들어 대두되고 있는 가스화용융 기술은 석탄 폐기물 등으로부터 합성가스를 생산하는 고청정 고효율 기술이다. 여기에서 생산되는 합성가스는 천연가스를 대체하여 전기 및 화학원료를 생산하기 위한 원료로 이용 가능하다. 폐기물로부터 가스화용융기술을 통하여 생산되는 합성가스로부터 DME(dimethyl ether)를 생산할 수 있다. 가스화용융기술로부터 생산되는 합성가스는 자체의 일산화탄소와 수소의 조성비가 DME를 합성하는데 적당하다고 알려져 있다. DME는 에너지원의 다원화와 대기오염 물질의 저감, 지구온난화 대응 등과 아울러 제 4세대 수송 연료로 부각되고 있다. DME를 합성하는 방법은 합성가스로부터 메탄올의 합성 단계를 거친 후 DME를 합성하는 간접법과 단일단계의 반응에서 합성가스로부터 직접적으로 DME를 합성하는 직접법이 있다. 현재는 화학 평형적 측면 경제적 측면에서 이점을 가지고 있는 직접법에 관한 연구가 활발히 이루어지고 있다. DME 직접합성법에서는 메탄올 합성 촉매와 메탄올 탈수촉매의 물리적 혼합에 의한 혼성촉매가 주로 이용되고 있는 것으로 알려져 있다 본 연구에서는 일산화탄소와 수소로 이루어진 합성 가스로부터 직접 DME를 생산할 수 있는 직접 합성 공정에 적용 가능한 고효율 촉매 기술을 개발하기 위해 상용촉매의 스크린 테스트를 수행하였다. 상용촉매로는 sud-chemi사에서 메탄을 합성 촉매와 탈수촉매를 각각 구입하였으며, 이들 촉매를 원하는 조성비로 물리적으로 혼합한 다음 반응온도 ($250-290^{\circ}C$) 압력 (30-50 atm), $H_2$/CO 몰비 (0.5-2.0) 등의 다양한 반응조건 하에서 스크린 테스트를 수행하였다.대장조영영상을 얻을 수 있어 대장암의 위치에 관한 정보를 삼차원적으로 제공하므로 대장암의 성상을 정확히 알 수 있는데 도움을 주었다.요인은 없는 것으로 사료된다. 이 중 2예의 CT에서 선상 혹은망상형의 음영을 보였다. 결론: 유방암 환자의 방사선 치료 후 CT 소견은 방사선 치료의 방법에 따라 폐첨부 혹은 폐의전면 흉막하 부위에 선상 혹은 망상형의 음영으로서 방사선 폐렴 혹은 섬유화 소견이다. CT는 단순 흉부 촬영보다 이상 소견의 발견이 쉽다.이러한 소견은 후에 합병될 수 있는 다른 폐질환의 감별 진단에 도움이 될 것으로 보인다.moembolization via the radial artery approach were involved in this study. All underwent Allen’s test to check ulnar arterial patency. In all cases, we used the radial approach hepatic artery (RHA) catheter designed by ourselves, evaluating t\ulcorner selec\ulcorneron ability of the hepatic artery using an RHA cathter, the number of punctures, the procedure time, and compression time at the puncture site as well as complications occurring during and after the procedure. Results: Except for three in which puncture failure, brachial artery variation or hepatic artery variation occurred, all procedures were successful. The mean number of punctures was 3.5, and the

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.3
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• pp.724-731
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• 2016

This paper presents the interdisciplinary study of a combined mechanism on the interactions between ground and foot using bioengineering and geotechnical engineering. A new mechanism of advanced technology shoes, which can be made safe with a comfortable gait on both soft and hard ground, were developed combining the mechanism of conical top foundation. The experimental tests were carried out to verify the developed shoes. The prototype shoes and test grounds were designed and produced to perform the tests. The general existing shoes and advanced technology shoes were used to measure the pressures re-acting the sole during the tests by a special measurement system. The results clearly showed that the pressures acting on the sole of advanced technology shoes were distributed uniformly compared with that of the existing shoes, and were in good agreement with theoretical approach of the new mechanism. Therefore, the advanced technology shoes could allow a safe gait ergonomically by a new mechanism on any ground type. The load transfer could occur by the interaction between ground and shoes. In addition, these results are expected to be useful for the development of an interdisciplinary study of a new mechanism in the future.

• 한국방재학회:학술대회논문집
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• 2011.02a
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• pp.66-66
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• 2011

중위도 이북의 건물에서 고층건물의 혹한기 연돌효과는 건물의 여러 가지 기능에 큰 영향을 미치며, 승강기 승강로는 화재시 차압 때문에 연기의 주된 전파통로가 된다. 외피의 밀폐성능을 높여 건물 내부의 연도효과를 줄일 수 있으나, 외피의 밀폐기능은 비상시 피난을 위해 피난경로를 개방하는 순간 일시에 무력화된다. 또한 건물 외피의 밀폐성능이 우수할수록 연돌효과 그 자체로써 건물외피에 미치는 구조적 영향이 커진다. 고층부의 연돌효과는 외피를 밖으로 밀어내는 작용이므로 풍하측에서는 마이너스 풍압에 더하여 건물 외피에 부담을 증가시킨다. 그러므로 고층건물에 발생하는 혹한기 연돌효과의 영향을 정리하자면 다음과 같다. ${\bullet}$ 건물 외벽 및 창문에 미치는 구조적 영향 ${\bullet}$ 제연 시스템의 기능 저해 ${\bullet}$ 승강기 문 개폐 장애와 소음 등 설비 기능의 부정적 영향 ${\bullet}$ 공조기능 장애 ${\bullet}$ 화재시 승강기 승강로 등 수직 샤프트를 통한 연기 전파 혹한기 건물 안팎의 온도차가 40K일 때 높이 600m인 초고층 건물 최상층에 발생하는 연돌효과에 의한 차압은 풍속으로 환산할 때 32m/s에 달한다. 그러므로 초고층 건물 설계시에는 최상층의 풍하측에 설계상의 예상 최대풍속에다 이러한 환산풍속을 더한 고속 풍력이 창문을 밖으로 밀어내는 것으로 보아야 한다. 또한 공조 및 환기시스템에서는 이러한 차압을 고려하지 않으면 고층부에서 환기 성능이 무력화될 수 있다. 다음과 같은 방법들을 이용하여 고층건물의 연돌효과를 효과적으로 줄일 수 있다. 1) 계단실의 연돌효과 저감 방법 계단실에 발생하는 연돌효과에 의한 차압은 계단실에 상승기류를 발생시킨다. 이러한 차압과 상승기류는 계단실 상하부를 개방하면 자연적으로 평형을 이루게 되므로 별도의 제어가 필요 없게 된다. 또한 화재감지기와 연동하여 상하부 외벽의 개구부를 열어두게 되면 피난상황에 따라 문이 여닫힘으로써 발생하는 압력상태의 변화를 고려할 필요가 없게 된다. 2) 승강기 승강로의 연돌효과 승강로의 상하부에 대규모 개구를 두면 대규모의 외기가 도입되어 상승 유동 후 배출되므로 승강로 내부 온도 저하로 연돌효과가 저감되고, 승강로로 유입된 연기는 대규모의 외기에 희석되어 농도가 낮아지고 대부분 외부로 배출된다. 3) 샤프트 복합효과를 이용하는 방법 거실 평면적에 비해 승강기나 계단이 아주 많고 누설틈새 등 개구의 면적 합계가 크면 샤프트들이 서로 복합효과를 이루어 연돌효과에 의한 차압이 줄어든다. 연돌효과 제어용 샤프트를 하나 더 보조적으로 설치함으로써, 보조샤프트에 의해 발생하는 차압으로 거실을 가압 혹은 감압하여 문제가 되는 차압을 어느 정도 상쇄할 수 있다.

• Proceedings of the Korean Institute of Navigation and Port Research Conference
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• 2017.11a
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• pp.232-233
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• 2017

In this research, tunnel stern was applied on the asymmetric high-speed catamaran to evaluate vessel's hydrodynamic performance by numerical method, and the tunnel stern types are distinguished by angle of inclination of tunnel exit region into 3cases ($0^{\circ}$, $3^{\circ}$ and $6^{\circ}$). Consequently, it is confirmed that the total resistances of tunnel stern which have $0^{\circ}$ of inclination are lower about 4.8-17.9% than the bare hull in the wide speed range, but those of $3^{\circ}$ and $6^{\circ}$ of inclination tunnel stern are higher than bare hull about 5-14% and 5-29%, respectively. On the other hand, trim angles of $0^{\circ}$ of inclination tunnel stern show similar trend with those of bare hull in whole ranges of FnV but those of $3^{\circ}$ and $6^{\circ}$ of inclination tunnel stern are stabilized and declined respectively after FnV=1.54. These phenomena indicated that increasing angle of inclination of tunnel exit region had negative influence on resistance performance, however, it could make vessel's operation performance better than bare hull.

• The Korean Journal of Petroleum Geology
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• v.7 no.1_2 s.8
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• pp.1-6
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• 1999

Natural gas hydrate, a solid compound of natural gas (mainly methane) and water in the low temperature and high pressure, is widely distributed in permafrost region and deep sea sediments. Gas hydrate stability field (GHSF), which corresponds to the conditions of a stable existence of solid gas hydrate without dissociation, depends on temperature, pressure, and composition of gas and interstitial water. Gas hydrate-saturated sediment are easily recognized by the bottom simulating reflector (BSR), a strong-amplitude sea bottom-mimic reflector in seismic profiles. It is known that BSR is associated with the basal boundary of the GHSF, The purpose of this study is to define the GHSF and its occurrence in the southwestern part of Ulleung Basin, East Sea. The hydrothermal gradient is measured using the expandable bathythermograph (XBT) and the geothermal gradient data are utilized from previous drilling results for the adjacent area. By the laboratory work using methane and NaCl $3.0 wt{\%}$ solution, it is shown that the equilibrium pressures of the gas hydrate reach to 2,920.2 kPa at 274.15 K and to 18,090 kPa at 289.95 K for the study area. Consequently, it is interpreted that the lower boundary of the GHSF is about 210 m beneath 400-m-deep sea bottom and about 480 m beneath 1,100-m-deep sea bottom. The resultant boundary is well matched with the depth of the BSR obtained from the seismic data analysis for the study area.