• Title/Summary/Keyword: 암석 참조물질

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Evaluation of LA-ICP-MS Whole Rock Trace Element Analysis Using Fused Glass Bead of Silicate Rocks (규산염 암석의 알칼리 용융 유리원판에 대한 LA-ICP-MS 전암 미량원소 분석법 평가)

  • Kim, Myong Jung;Kim, Taehoon;Park, Kye-Hun;Lee, Ye Ji;Yang, Yun Seok;Moon, Jeongjin
    • The Journal of the Petrological Society of Korea
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    • v.24 no.2
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    • pp.141-147
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    • 2015
  • Using laser-ablation inductively coupled plasma mass spectrometry (LA-ICP-MS), we evaluated the reliability of trace element abundance data measured from the silicate rock references of JR-3, JG-3, JGb-1 and JB-1b using glass discs made by alkali fusion. For 28 elements including rare earth elements, relative standard deviations (RSD) are better than 7% in case when the concentrations of the elements in the rock samples are greater than 10 ppm. However, RSD shows somewhat increased values for the concentrations less than 10 ppm, but never exceeds 25%. Compared with previously reported averages of the compiled abundance data, our data display satisfactory results for the most cases with differences less than 10%. We suggest that LA-ICP-MS analysis using fused glass beads is a reliable, precise and time-saving method of trace element analysis for the silicate rocks spanning from mafic to felsic compositions.

Neoproterozoic A-type Volcanic Activity within the Okcheon Metamorphic Belt (옥천변성대 충주지역의 신원생대 A-형 화산활동)

  • Koh Sang-Mo;Kim Jong-Hwan;Park Kye-Hun
    • The Journal of the Petrological Society of Korea
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    • v.14 no.3 s.41
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    • pp.157-168
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    • 2005
  • Trachytic rocks among the bimodal metavolcanic rocks of the Gyemyeongsan Formation and adjacent areas are investigated. Some rocks reveal very high content of iron and most rocks show very high abundances of rare earth elements and high field strength elements. Most rocks show significant Eu negative anomaly, which can be interpreted as the result of plagioclase fractionation. Lack of noticeable Nb negative anomaly indicates not-involvement of crustal material in their generation, which excludes the arc environment or remelting of continental crust from their genetic process. Metatrachytes of the Gymyeongsan Formation are plotted within the within-plate environment of the tectonic discrimination diagram utilizing immobile high field strength element Nb and Y. They also show typical characteristics of A-type magma, such as high Ga content. Considering their affinity to Al-type of Eby (1992) and their age of 750 Ma (Lee et al., 1998), they seem to have been produced by the differentiation of mantle-derived within-plate magmatism at the rift, related with the separation of Neoproterozoic supercontinent Rodinia. Possible connection of Gyemyeongsan and Munjuri Formations of the Okcheon metamorphic belt, at least part of them, to the Cathaysia block of South China during the Neoproterozoic is strongly suggested.

Design and Construction of Spectral Library for the Korean Peninsular (한반도 지역의 지표특성을 고려한 분광라이브러리의 설계 및 구축)

  • Shin, Jung-Il;Kim, Sun-Hwa;Lee, Kyu-Sung
    • Korean Journal of Remote Sensing
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    • v.26 no.5
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    • pp.465-475
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    • 2010
  • Spectral library is a database that archives spectral reflectance and related metadata of earth surface materials. Spectral library plays important role to assist analyzing several types of remote sensor data, to determine suitable wavelength band for detecting a certain material, and to classify hyperspectal image data. This paper describes the structure and content of a spectral library that is suitable for the environment of the Korea peninsula while existing spectral libraries have certain limitations to apply for surface materials covering the region. We designed a spectral library that includes vegetation and man-made materials indigenous to the region. The spectral library also includes spectra of mineral and rock, soil, liquid, and some man-made materials from existing spectral libraries. Newly augmented spectra of vegetation and man-made materials were obtained by spectral measurements in laboratory and field. The spectral library viewer was developed to increase efficiency of usage and searching.

Pb Isotopic Composition of Yeonhwa and Janggun Pb-Zn Ore Deposits and Origin of Pb: Role of Precambrian Crustal Basement and Mesozoic Igneous Rocks (연화 및 장군 연-아연 광상의 Pb 동위원소 조성 및 Pb의 근원: 선캠브리아 기저 지각 및 중생대 화성암의 역할)

  • Park Kye-Hun;Chang Ho Wan
    • The Journal of the Petrological Society of Korea
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    • v.14 no.3 s.41
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    • pp.141-148
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    • 2005
  • Lead isotopic compositions are analyzed from the sulfide minerals of the Yeonhwa, Janggun and Uljin deposits and from host limestone, intrusives, and basement rocks to reveal the source of Pb in these deposits. In the $^{206}Pb/^{204}Pb$ vs $^{207}Pb/^{204}Pb$ plot, Galenas from the Yeonhwa mine display relatively well defined positive linear array, similar to the Precambrian basement rocks of the Korean peninsula. A galena sample from the Uljin mine, Janggun limestone and the basement rocks also follow the variation of Yeonhwa mine. However, ore minerals from the Janggun mine, having relatively low $^{206}Pb/^{204}Pb$ values, reveal offset from such trend toward lower $^{207}Pb/^{204}Pb$ values. Considering the fact that Mesozoic igneous rocks and ores within the Gyeongsang basin display considerably lower $^{207}Pb/^{204}Pb$ values than basement rocks of the Korean peninsula, the deviation of Janggun ore minerals can be interpreted as to reflect mixing between leads from old continental crustal materials and from Mesozoic igneous rocks with more mantle signature. The lead of the Yeonhwa and Uljin mine, following trend of Precambrian basement rather well, seems to have been originated mostly from such basement. However, regarding that they occupy low $^{207}Pb/^{204}Pb$ side of the variation trend of the basement, the possibility of having some leads derived from the Mesozoic igneous rocks cannot be excluded.